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11. 发明授权

US5268499A Preparation of mixtures of 3-aminopropionitrile and ethylene cyanohydrin 失效
标题翻译：制备3-氨基丙腈和乙烯氰醇的混合物
公开(公告)号：US5268499A
公开(公告)日：1993-12-07
申请号：US47303
申请日：1993-04-19
申请人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
发明人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
IPC分类号： C07C253/30
CPC分类号： C07C253/30
摘要： A process for preparing mixtures of 3-aminopropionitrile of the formula IH.sub.2 N--CH.sub.2 --CH.sub.2 --CN (I)and ethylene cyanohydrin of the formula IIHO--CH.sub.2 --CH.sub.2 --CN (II)comprises reacting bis(2-cyanoethyl) ether of the formula IIINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN (III)with ammonia at from 50 to 170.degree. C. and under from 1 to 500 bar thermally or in the presence of a heterogeneous catalyst.
摘要翻译：制备式I H 2 N-CH 2 -CH 2 -N（I）的3-氨基丙腈和式II HO-CH2-CH2-CN（Ⅱ）的乙烯氰醇的混合物的方法包括使双（2-氰乙基）醚式III NC-CH2-CH2-O-CH2-CH2-CN（III）与氨在50至170℃下和在1至500巴下加热或在多相催化剂存在下反应。

12. 发明授权

US5166447A Preparation of cyclopentanones 失效
标题翻译：环戊酮的制备
公开(公告)号：US5166447A
公开(公告)日：1992-11-24
申请号：US776688
申请日：1991-10-15
申请人： Franz Merger , Tom Witzel
发明人： Franz Merger , Tom Witzel
IPC分类号： C07C45/60 , C07C49/395 , C07C49/523
CPC分类号： C07C49/395 , C07C45/60 , C07C49/523 , Y02P20/582
摘要： Cyclopentanones of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each an organic radical or R.sup.1 or R.sup.2 may be hydrogen and R.sup.3 is hydrogen or formyl, are prepared by a process in which a 2-formyl-3,4-dihydropyran of the general formula II ##STR2## where R.sup.1 and R.sup.2 have the abovementioned meanings, a) where R.sup.3 is formyl, is converted in the presence of an acidic heterogeneous catalyst at from 50.degree. to 500.degree. C., andb) where R.sup.3 is hydrogen,b.sub.1) is reacted with water or an alcohol in the presence of an acidic heterogeneous catalyst at from 100.degree. to 500.degree. C. in the gas phase orb.sub.2) a compound II or an acrolein of the general formula III ##STR3## is reacted with water or with water in the presence of an acid or with an alcohol in the presence of an acid at from 150.degree. to 400.degree. C. in the liquid phase. Novel 2-formylcyclopentanones are obtained.
摘要翻译：其中R 1和R 2各自为有机基团或R 1或R 2可以是氢并且R 3为氢或甲酰基的通式I（I）的环戊烷酮通过其中2-甲酰基-3,4 - 二氢吡喃，其中R 1和R 2具有上述含义，a）其中R 3是甲酰基，在酸性多相催化剂存在下在50-500℃下转化，和 b）其中R3是氢，b1）在酸性非均相催化剂存在下，在气相中在100-500℃下与水或醇反应，或b2）化合物II或通式为的丙烯醛在酸的存在下，在酸的存在下，在液相中，在150℃至400℃的条件下，将III（III）化合物与水或水在酸或醇的存在下反应。得到新的2-甲酰基环戊烷酮。

13. 发明授权

US5087744A Preparation of methacrylic acid 失效
标题翻译：甲基丙烯酸的制备
公开(公告)号：US5087744A
公开(公告)日：1992-02-11
申请号：US213837
申请日：1988-06-30
申请人： Richard Krabetz , Gerd Duembgen , Franz Merger , Michael Jaeger , Fritz Thiessen , Herbert Vogal
发明人： Richard Krabetz , Gerd Duembgen , Franz Merger , Michael Jaeger , Fritz Thiessen , Herbert Vogal
IPC分类号： B01J27/19 , C07B63/04 , C07C51/00 , C07C51/235 , C07C51/25 , C07C57/055 , C07C57/07 , C07C67/00
CPC分类号： C07C51/252
摘要： Methacrylic acid can be prepared with advantage by gas phase oxidation of methacrolein or isobutyraldehyde over Mo- and P-containing catalysts at from 250.degree. to 400.degree. C. with cooling of the hot reaction gas to below 100.degree. C., absorption of the methacrylic acid in a water-operated absorption column, at below 100.degree. C. and partial recycling into the oxidation reactor after admixture of methacrolein or isobutyraldehyde and oxygen by feeding a quantity of methacrolein or isobutyraldehyde equal to the quantity of methacrolein or isobutyraldehyde consumed in the reaction in liquid form together with a polymerization inhibitor into the reactor gas in the lower two-thirds of the absorber column and upstream of the feed point for the fresh methacrolein or isobutyraldehyde or down-stream of the absorption column splitting off the reactor off-gas a side stream which is washed in a wash column operated with water at
摘要翻译：甲基丙烯酸可以通过在250℃至400℃的含Mo和P的催化剂上甲基丙烯醛或异丁醛的气相氧化来制备，同时将热反应气体冷却至低于100℃，吸收甲基丙烯酸酸在水性吸收塔中，低于100℃，并通过加入与反应中消耗的甲基丙烯醛或异丁醛的量相等的量的异丁烯醛或异丁醛，将甲基丙烯醛或异丁醛和氧气混合后，部分再循环进入氧化反应器液体形式与聚合抑制剂一起在吸收塔的下三分之二的反应器气体中，在新鲜的甲基丙烯醛或异丁醛的进料点的上游或吸收塔的下游分离反应器废气a 侧流在洗涤塔中用水在<10℃下洗涤以除去未转化的异丁烯醛或异丁醛，其为f 作为吸收塔顶部的水溶液。

14. 发明授权

US4981913A Bridged, water-soluble copolymers, their preparation and their use 失效
标题翻译：桥接，水溶性共聚物，其制备及其用途
公开(公告)号：US4981913A
公开(公告)日：1991-01-01
申请号：US409747
申请日：1989-09-20
申请人： Dietmar Moench , Andreas Stange , Joerg Liebe , Heinrich Hartman , Franz Merger , Manfred Schwartz
发明人： Dietmar Moench , Andreas Stange , Joerg Liebe , Heinrich Hartman , Franz Merger , Manfred Schwartz
IPC分类号： C08C19/00 , C08F8/12 , C08F8/28 , D21H17/37
CPC分类号： C08F8/12 , C08F2800/10 , C08F2810/50
摘要： Bridged, water-soluble copolymers are obtainable by(A) copolymerization of a monomer mixture of(a) from 50 to 99 mol % of acrylamide and/or methacrylamide,(b) from 50 to 1 mol % of a monoethylenically unsaturated monomer containing actual groups and(c) from 0 to 20 mol % of monomers which differ from (a) and (b), in the presence of a polymerization initiator under conditions such that the acetal groups of the monomers (b) undergo virtually no hydrolysis,(B) hydrolysis of the acetal groups of the monomers (b), present as copolymerized units in the copolymers (A),(C) condensation of the copolymers (B) containing aldehyde groups at a pH above 5, at most to a degree such that the resulting condensates are still water-soluble and(D) stopping of the condensation reaction by adding acid until the pH reaches 3 or less,and are used as paper stock additives in papermaking for increasing the wet strength of paper.
摘要翻译：桥接的水溶性共聚物可通过（A）（a）50至99mol％的丙烯酰胺和/或甲基丙烯酰胺的单体混合物共聚获得，（b）50至1mol％的单烯属不饱和单体含有实际基团和（c）0〜20摩尔％的不同于（a）和（b）的单体，在聚合引发剂存在下，使单体（b）的缩醛基基本上不经水解的条件下， B）在共聚物（A），（C）中作为共聚单元存在的单体（b）的缩醛基团的水解在pH5以上含有醛基的共聚物（B）的缩合最多至一定程度所得缩合物仍然是水溶性的，（D）通过加入酸直到pH达到3以下停止缩合反应，并且在造纸中用作增加纸的湿强度的纸浆添加剂。

15. 发明授权

US4874889A Isomerization of 2-pentenoates to 3-pentenoates 失效
标题翻译： 2-戊烯酸酯异构化为3-戊烯酸酯
公开(公告)号：US4874889A
公开(公告)日：1989-10-17
申请号：US122941
申请日：1987-11-18
申请人： Rolf Fischer , Franz Merger , Hans-Juergen Gosch
发明人： Rolf Fischer , Franz Merger , Hans-Juergen Gosch
IPC分类号： B01J31/02 , B01J31/00 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533 , C07C69/593
CPC分类号： C07C69/52
摘要： 3-Pentenoates are prepared by isomerization of 2-pentenoates to 3-pentenoates by a process in which the 2-pentenoate is treaated with from 0.01 to 0.5 mole of cyclic tertiary amine having a pK.sub.a of >6 per mole of 2-pentenoate at from 50.degree. to 250.degree. C. and the 3-pentenoate is distilled off continuously.
摘要翻译： 3-戊烯酸酯通过2-戊烯酸酯异构化制备成3-戊烯酸酯，其中2-戊烯酸酯与0.01至0.5摩尔每摩尔2-戊烯酸酯具有pKa> 6的环状叔胺， 50℃至250℃，并连续蒸馏除去3-戊烯酸甲酯。

16. 发明授权

US4766237A Preparation of 6-aminocaproates 失效
标题翻译： 6-氨基己酸酯的制备
公开(公告)号：US4766237A
公开(公告)日：1988-08-23
申请号：US7578
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： C07B61/00 , B01J21/16 , B01J23/00 , B01J23/74 , B01J23/755 , B01J25/02 , C07C67/00 , C07C227/00 , C07C227/04 , C07C227/08 , C07C229/08 , C07C67/30
CPC分类号： C07C227/08
摘要： In an improved process for the preparation of 6-aminocaproates by reacting a 5-formylvalerate with ammonia and hydrogen using an alkanol as a solvent in the presence of a hydrogenation catalyst at elevated temperatures and under superatmospheric pressure, the improvement comprises carrying out the reaction at from 40.degree. to 95.degree. C.
摘要翻译：在氢化催化剂存在下，在升高的温度和超大气压下，通过使用烷醇作为溶剂使5-甲酰基戊酸与氨和氢反应制备6-氨基己酸酯的改进方法，其改进包括在从40℃到95℃

17. 发明授权

US4713476A Process for the preparation of aliphatic di- and polyurethanes 失效
标题翻译：制备脂肪族二 - 和聚氨酯的方法
公开(公告)号：US4713476A
公开(公告)日：1987-12-15
申请号：US879025
申请日：1986-06-26
申请人： Franz Merger , Friedrich Towae
发明人： Franz Merger , Friedrich Towae
IPC分类号： C07C269/00 , C07B61/00 , C07C67/00 , C07C239/00 , C07C269/04 , C07C271/06 , C07C271/20 , C07D239/10 , C07D295/12 , C07D295/13 , C08G18/70 , C07C125/073
CPC分类号： C07D239/10 , C07D295/13 , C08G18/701
摘要： A process for the preparation of aliphatic, cycloaliphatic, arylaliphatic and aliphatic-cycloaliphatic di- and polyurethanes wherein primary aliphatic, cycloaliphatic, arylaliphatic or aliphatic-cycloaliphatic di- or polyamines are reacted with urea and a primary or secondary aliphatic alcohol at temperatures of above 190.degree. C. to 300.degree. C., following which ammonia and other by-products are separated from the aliphatic, cycloaliphatic, arylaliphatic or aliphatic-cycloaliphatic di- or polyurethane product.
摘要翻译：脂族，脂环族，芳基脂肪族和脂族 - 脂环族二 - 和聚氨酯的制备方法，其中将伯脂肪，脂环族，芳基脂肪族或脂肪族 - 脂环族二胺或多胺与尿素和伯或仲脂族醇在190以上的温度下反应 ℃至300℃，随后将氨和其它副产物与脂族，脂环族，芳基脂族或脂族 - 脂环族二 - 或聚氨酯产物分离。

18. 发明授权

US4694107A Preparation of ketones by isomerization of aldehydes 失效
标题翻译：通过醛的异构化制备酮
公开(公告)号：US4694107A
公开(公告)日：1987-09-15
申请号：US865007
申请日：1986-07-02
申请人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Rolf Fischer
发明人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Rolf Fischer
IPC分类号： C07C45/67 , B01J29/00 , B01J29/06 , B01J29/86 , B01J29/88 , C07B31/00 , C07B41/06 , C07B61/00 , C07C45/00 , C07C45/54 , C07C49/04 , C07C49/105 , C07C67/00
CPC分类号： C07C45/54 , B01J29/86 , B01J29/88
摘要： Ketones are prepared by isomerization of aldehydes at elevated temperatures over zeolites.
摘要翻译：酮通过在升高的温度下通过沸石异构化醛来制备。

19. 发明授权

US4599458A Preparation of 2-methylalk-2-enals 失效
标题翻译： 2-甲基-2-烯的制备
公开(公告)号：US4599458A
公开(公告)日：1986-07-08
申请号：US742200
申请日：1985-06-07
申请人： Rolf Fischer , Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Hans-Martin Weitz
发明人： Rolf Fischer , Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Hans-Martin Weitz
IPC分类号： C07C45/67 , C07C47/21 , C07C47/22 , C07C47/232 , C07C45/61
CPC分类号： C07C45/67 , C07C47/21 , C07C47/22 , C07C47/232
摘要： 2-Methylalk-2-enals of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, alkyl or an aromatic radical, are prepared by isomerization of an acrolein derivative of the formula ##STR2## with a zeolite catalyst, an aluminum silicate and/or an aluminum phosphate.
摘要翻译：其中R 1和R 2各自为氢，烷基或芳族基团的通式为其的化合物的2-甲基-2-烯酮-2-烯是通过使用沸石催化剂，铝的方法异构化式II的丙烯醛衍生物来制备的硅酸盐和/或磷酸铝。

20. 发明授权

US4497963A Process for the preparation of an aliphatic, cycloaliphatic, and/or aliphatic-cycloaliphatic di- and/or polyurethane 失效
标题翻译：用于制备脂族，脂环族和/或脂族 - 脂环族二 - 和/或聚氨酯的方法
公开(公告)号：US4497963A
公开(公告)日：1985-02-05
申请号：US135259
申请日：1980-03-31
申请人： Franz Merger , Friedrich Towae
发明人： Franz Merger , Friedrich Towae
IPC分类号： C07C269/04 , C07B61/00 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/08 , C07C271/34 , C07D239/04 , C07D239/10 , C07D295/12 , C07D295/13 , C08G18/70 , C07C125/073
CPC分类号： C07D239/10 , C07D295/13 , C08G18/701
摘要： A process for the preparation of an aliphatic, cyclo-aliphatic, and/or aliphatic-cycloaliphatic di- and/or polyurethane comprising the steps ofA. reacting a primary aliphatic, cycloaliphatic, and/or aliphatic-cycloaliphatic di- and/or polyamine with a carbamate in the presence of alcohol at temperatures of 160.degree. C. to 300.degree. C., andB. separating the ammonia and other by-products from the aliphatic, cycloaliphatic, and/or aliphatic-cycloaliphatic di- and/or polyurethane.One or more catalysts may be added to the reactants to increase the reaction rate. The aliphatic, cycloaliphatic, and/or aliphatic-cycloaliphatic di- and/or polyurethanes produced are valuable end and intermediate products. They can be transferred into the corresponding isocyanates which can then be used for the preparation of polyurethanes.
摘要翻译：一种制备脂族，环脂族和/或脂族 - 脂环族二 - 和/或聚氨酯的方法，包括以下步骤：A.使脂族，脂环族和/或脂族 - 脂环族二 - 和/或多胺在160℃至300℃的温度下在醇存在下与氨基甲酸酯反应，并将氨和其它副产物与脂族，脂环族和/或脂族 - 脂环族二 - 和/或聚氨酯。可以向反应物中加入一种或多种催化剂以提高反应速率。生产的脂族，脂环族和/或脂族 - 脂环族二 - 和/或聚氨酯是有价值的终端和中间产品。它们可以转移到相应的异氰酸酯中，然后可以将其用于制备聚氨酯。

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