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11. 发明授权

US06316640B1 Preparation of tetrahydrofuran 有权
标题翻译：四氢呋喃的制备
公开(公告)号：US06316640B1
公开(公告)日：2001-11-13
申请号：US09396356
申请日：1999-09-15
申请人： Rolf Fischer , Shelue Liang , Rolf Pinkos
发明人： Rolf Fischer , Shelue Liang , Rolf Pinkos
IPC分类号： C07D30708
CPC分类号： C07D307/08 , Y02P20/582
摘要： In a process for preparing THF (tetrahydrofuran) by reaction of a 1,4-butanediol-containing reaction mixture over an acid catalyst, the reaction mixture comprises further alcohols different from 1,4-butanediol and is essentially free of water.
摘要翻译：在通过在酸催化剂上通过含1,4-丁二醇的反应混合物反应制备THF（四氢呋喃）的方法中，反应混合物包含与1,4-丁二醇不同的基本上不含水的其它醇。

12. 发明授权

US06689914B2 Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US06689914B2
公开(公告)日：2004-02-10
申请号：US10234170
申请日：2002-09-05
申请人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Shelue Liang , Frank Funke
发明人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Shelue Liang , Frank Funke
IPC分类号： C07C2926
CPC分类号： C07C209/26
摘要： The preparation of amines of the formula (I): R1R2CH—N R3R4 (I) in which R1, R2, R3 and R4, independently of one another, are hydrogen, straight-chain or branched C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, takes place by catalytic, reductive amination of mixtures comprising carbonyl compounds of the formula (II) and/or alcohols of the formula (III) R1—C(═O)—R2 (II) R1—CH(OH)—R2 (III) which also comprise at least 50 ppm, based on the mixtures, of halogen, with nitrogen compounds of the formula (IV): H N R3 R4 (IV) with the abovementioned meanings for R1 to R4, in the presence of Co- and/or Ni-containing catalysts, which comprises carrying out the reductive amination additionally in the presence of solid acidic cocatalysts.
摘要翻译：式（I）的胺的制备：其中R 1，R 2，R 3和R 4彼此独立地是氢，直链或支链的C 1 -C 12 - 烷基，C 3 -C 12 - 环烷基，C 6 -C 10 - 芳基或C 7 -C 11 - 芳烷基，其通过催化还原胺化包括式（II）的羰基化合物和/或式（III）的醇，包含基于混合物的卤素至少50ppm与式（IV）的氮化合物：在上述对R 1至R 4的含义中，在Co-和/或Ni- 其包括另外在固体酸性助催化剂存在下进行还原胺化。

13. 发明授权

US06462236B2 Preparation of amines 有权
标题翻译：胺的制备
公开(公告)号：US06462236B2
公开(公告)日：2002-10-08
申请号：US09983307
申请日：2001-10-24
申请人： Shelue Liang , Frank Funke , Arthur Höhn
发明人： Shelue Liang , Frank Funke , Arthur Höhn
IPC分类号： C07C20926
CPC分类号： C07C209/26 , C07C211/29
摘要： Amines of the formula (I) R1R2CH—NR3R4 (I) where R1, R2, R3 and R4 are each, independently of one another, hydrogen, straight-chain or branched C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, where at least one of the radicals R1 and R2 is aryl or aralkyl whose aromatic unit is substituted by at least one halogen, are prepared by catalytic, hydrogenative amination of carbonyl compounds of the formula (II) or alcohols of the formula (III) R1—C(═O)—R2 (II) R1—CH(OH)—R2 (III) by means of nitrogen compounds of the formula (IV) HNR3R4 (IV) where R1 to R4 are as defined above, in the presence of Co- and/or Ni-containing catalysts, in the additional presence of solid acid cocatalysts and in the absence of organic sulfur compounds.
摘要翻译：式（I）的胺其中R 1，R 2，R 3和R 4各自独立地为氢，直链或支链C 1 -C 12 - 烷基，C 3 -C 12 - 环烷基，C 6 -C 10 - 芳基或C 7 -C 12 - C 11 - 芳烷基，其中基团R 1和R 2中的至少一个是其芳族单元被至少一个卤素取代的芳基或芳烷基，其通过式（II）的羰基化合物的催化，氢化胺化或式（III）通过其中R 1至R 4如上所定义的式（Ⅳ）的氮化合物在存在Co和/或Ni的催化剂的情况下，在固体酸助催化剂的另外存在下，在不存在有机硫化合物。

14. 发明授权

US06429339B1 Method for producing cyclopentanone 失效
标题翻译：环戊酮生产方法
公开(公告)号：US06429339B1
公开(公告)日：2002-08-06
申请号：US09700365
申请日：2000-11-15
申请人： Shelue Liang , Rolf Fischer , Frank Stein , Joachim Wulff-Döring
发明人： Shelue Liang , Rolf Fischer , Frank Stein , Joachim Wulff-Döring
IPC分类号： C07C4500
CPC分类号： B01J23/10 , C07C45/48 , C07C49/395
摘要： A process for preparing cyclopentanone by reacting adipic esters of the formula R1OOC—(CH2)4—COOR2 I where R1 and R2 are each alkyl having from 1 to 12 carbon atoms, cycloalkyl having 5 or 6 carbon atoms, aralkyl or aryl and R2 may additionally be hydrogen, in the presence of oxidic catalysts comprises reacting adipic esters of the formula I having less than 5% by weight of by-products other than adipic esters in the gas phase in the presence of water, a carrier gas and a) from 0.01 to 10% by weight of at least one metal oxide selected from the first or second main group of the periodic table or from the group of the rare earth metals on titanium dioxide or zirconium dioxide as catalyst support, or b) from 0.01 to 50% by weight of at least one metal oxide selected from the second main group of the periodic table on zink oxide as catalyst support.
摘要翻译：通过使式R 1和R 2的己二酸酯反应制备环戊酮的方法各自是在氧化催化剂存在的情况下，可以另外为氢，其中R 1和R 2各自为具有1至12个碳原子的烷基，具有5或6个碳原子的环烷基或芳基，包括使式I的己二酸酯在水，载气的存在下，在气相中具有小于5重量％的除己二酸酯之外的副产物，和（ii）0.01至10重量％的至少一种金属氧化物，其选自周期表的第一或第二主族，或者来自稀土金属的二氧化钛或二氧化锆的组，作为催化剂载体，orb）为0.01至50重量％的至少一种选自氧化锌作为催化剂载体的周期表第二主要组。

15. 发明授权

US06407294B1 Method for producing 1,6-hexanediol 有权
标题翻译： 1,6-己二醇的制备方法
公开(公告)号：US06407294B1
公开(公告)日：2002-06-18
申请号：US09529789
申请日：2000-04-20
申请人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
发明人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C2601/08 , C07C35/06 , C07C31/135 , C07C31/20
摘要： A process for producing 1,6-hexanediol by hydrogenation of adipic esters and/or 6-hydroxycaproic esters in the gas phase at elevated temperature and elevated pressure in the presence of chromium-free catalysts comprises hydrogenating a) over a catalyst comprising copper, manganese and aluminum as essential constituents or over Raney copper, b) at a temperature of from 150 to 230° C. and a pressure of from 10 to 70 bar, c) at a molar ratio of hydrogen to ester to be hydrogenated within the range from 150:1 to 300:1, and d) at a catalyst space velocity of from 0.01 to 0.3 kg of C6 ester per liter of catalyst per hour.
摘要翻译：在无铬催化剂存在下，在升高的温度和升高的压力下，气相中己二酸酯和/或6-羟基己酸酯的氢化制备1,6-己二醇的方法包括在包含铜，锰和铝作为必需组分或在阮内铜上，b）在150-230℃的温度和10至70巴的压力下，c）以氢化至酯的摩尔比在150℃的范围内：1至300:1，和d），催化剂空速为每升催化剂每小时0.01至0.3kg的C6酯。

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