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11. 发明授权

US06218559B1 Hydrogenation catalyst, process for the preparation thereof and hydrogenation process 有权
标题翻译：氢化催化剂，其制备方法和氢化方法
公开(公告)号：US06218559B1
公开(公告)日：2001-04-17
申请号：US09267486
申请日：1999-03-11
申请人： Felix Spindler , Ulrich Pittelkow
发明人： Felix Spindler , Ulrich Pittelkow
IPC分类号： C07F726
CPC分类号： B01J31/1845 , B01J31/04 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2419 , B01J31/2452 , B01J31/26 , B01J31/30 , B01J2231/643 , B01J2531/0205 , B01J2531/0266 , B01J2531/827 , B01J2531/842 , C07C209/52 , C07F15/004 , C07F17/02
摘要： Reaction products of an iridium(III) salt or a hydrate thereof, a diphosphine having secondary phosphine groups and a metal or ammonium chloride, bromide or iodide are excellent hydrogenation catalysts for ketimine. Using chiral diphosphines and prochiral ketimines, diastereoisomeric secondary amines are obtained in high optical yields.
摘要翻译：铱（III）盐或其水合物，具有仲膦基的二膦和金属或氯化铵，溴化物或碘化物的反应产物是用于酮亚胺的优异的氢化催化剂。使用手性二膦和前手性酮亚胺，以高光学收率获得非对映异构仲胺。

12. 发明授权

US5583241A Fluoroalkyl-substituted ferrocenyl diphosphines as ligands for homogeneous catalysts 失效
标题翻译：氟烷基取代的二茂铁基二膦作为均相催化剂的配体
公开(公告)号：US5583241A
公开(公告)日：1996-12-10
申请号：US313485
申请日：1994-09-27
申请人： Felix Spindler
发明人： Felix Spindler
IPC分类号： B01J31/22 , B01J31/24 , C07C209/52 , C07C213/08 , C07F17/02
CPC分类号： B01J31/2291 , B01J31/1805 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J31/2409 , C07C209/52 , C07C213/08 , C07F17/02 , B01J2231/643 , B01J2231/645 , B01J2531/0216 , B01J2531/822 , B01J2531/827 , B01J2531/842 , B01J2540/12 , B01J2540/40 , Y10S526/943
摘要： Compounds of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.8 alkyl, phenyl or phenyl which is substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy groups; R.sub.2 is a radical of formula II ##STR2## wherein R.sub.12 is C.sub.1 -C.sub.5 alkyl which is partially or completely fluorinated;R.sub.13 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --SiR.sub.4 R.sub.5 R.sub.6, halogen, --SO.sub.3 M, CO.sub.2 M, --PO.sub.3 M, --NR.sub.7 R.sub.8 or --[.sup..sym. NR.sub.7 R.sub.8 R.sub.9 ]X.sup..crclbar. ;m is an integer from 1 to 3, n is 0 or an integer from 1 to 4, and the sum of m+n is 1 to 5;R.sub.3, R.sub.10, R.sub.11 have each independently of one another the same meaning as R.sub.2 or are each independently of one another C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl, C.sub.1 -C.sub.4 alkyl- or C.sub.1 -C.sub.4 alkoxy-substituted C.sub.5 -C.sub.12 cycloalkyl, or phenyl which is substituted by one to three identical or different members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --SiR.sub.4 R.sub.5 R.sub.6, halogen, --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 M, --NR.sub.7 R.sub.8 and --[.sup..sym. NR.sub.7 R.sub.8 R.sub.9 ]X.sup..crclbar. ;R.sub.4, R.sub.5 and R.sub.6 are each independently of one another C.sub.1 -C.sub.12 alkyl or phenyl;R.sub.7 and R.sub.8 are H, C.sub.1 -C.sub.12 alkyl or phenyl orR.sub.7 and R.sub.8, taken together, are tetramethylene, pentamethylene or 3-oxa-1,5-pentylene;R.sub.9 is H or C.sub.1 -C.sub.4 alkyl,M is H or an alkali metal, X.sup..crclbar. is the anion of a monobasic acid, and * is a stereogenic carbon atom, in the form of their racemates and diastereoisomers or mixtures of diastereoisomers. Rhodium and iridium complexes with these ligands are suitable for use as homogeneous enantioselective catalysts for the hydrogenation of prochiral compounds containing carbon double bonds or carbon/hetero atom double bonds.
摘要翻译：式I的化合物其中R 1是C 1 -C 8烷基，苯基或被1至3个C 1 -C 4烷基或C 1 -C 4烷氧基取代的苯基; R2是式II的基团（II）其中R12是部分或完全氟化的C 1 -C 5烷基; R13是C1-C4烷基，C1-C4烷氧基，-SiR4R5R6，卤素，-SO3M，CO2M，-PO3M，-NR7R8或 - [（+）NR7R8R9] X（ - ）; m为1〜3的整数，n为0或1〜4的整数，m + n的和为1〜5。 R 3，R 10，R 11各自独立地为与R 2相同的含义或彼此独立地彼此独立地为C 1 -C 12烷基，C 5 -C 12环烷基，苯基，C 1 -C 4烷基 - 或C 1 -C 4烷氧基取代的C 5 -C 12环烷基或被一至三个相同或不同的选自C1-C4烷基，C1-C4烷氧基，-SiR4R5R6，卤素，-SO3M，-CO2M，-PO3M，-NR7R8和 - [（+）NR7R8R9] X（ - ）; R4，R5和R6各自独立地为C1-C12烷基或苯基; R 7和R 8是H，C 1 -C 12烷基或苯基或R 7和R 8一起是四亚甲基，五亚甲基或3-氧杂-1,5-亚戊基; R9是H或C1-C4烷基，M是H或碱金属，X（ - ）是一元酸的阴离子，*是其外消旋体和非对映异构体或非对映异构体混合物形式的立体碳原子。与这些配体的铑和铱配合物适合用作含碳双键或碳/杂原子双键的前手性化合物氢化的均匀对映选择性催化剂。

13. 发明授权

US5198569A Process for the preparation of optically active aliphatic hydroxycarboxylic acids 失效
标题翻译：制备光学活性羟基羧酸的方法
公开(公告)号：US5198569A
公开(公告)日：1993-03-30
申请号：US758927
申请日：1991-09-11
申请人： Hans-Ulrich Blaser , Ulrich Pittelkow , Felix Spindler
发明人： Hans-Ulrich Blaser , Ulrich Pittelkow , Felix Spindler
IPC分类号： B01J31/24 , C07B53/00 , C07B61/00 , C07C67/30 , C07C67/31 , C07C69/66 , C07C69/67 , C07C69/73 , C07C69/74 , C07C69/76 , C07C227/16 , C07C229/22 , C07C239/22 , C07C255/20 , C07C323/52 , C07C323/53 , C07C323/55
CPC分类号： C07C67/31
摘要： The asymmetric hydrogenation of aliphatic .alpha.-keto esters in the presence of rhodium catalysts which contain as chiral ligand a diphosphine of formula IV(R.sub.3).sub.2 P--Q--P(R.sub.3)hd 2 (IV)wherein R.sub.3 is phenyl, C.sub.1 -C.sub.6 alkylphenyl or C.sub.1 -C.sub.6 alkoxyphenyl, and Q is [2,2,1]-bicyloheptan-1,2-ylene or [2,2,1]-bicyclohept-4,5-en-1,2-ylene, gives the corresponding (R)- or(S)-.alpha.-hydroxycarboxylic acid esters in high rates of chemical conversion and in high enantiomer excesses.
摘要翻译：在含有式IV（R3）2P-QP（R3）hd2（Ⅳ）的二膦的手性配体的铑催化剂存在下，脂族α-酮酯的不对称氢化，其中R3是苯基，C1-C6烷基苯基或C1- C6烷氧基苯基，Q是[2,2,1] - 双环庚烷-1,2-基或[2,2,1] - 双环庚基-4,5-烯-1,2-基，得到相应的（R） - 或（S）-α-羟基羧酸酯以高的化学转化率和高对映异构体过量。

14. 发明授权

US08314238B2 Process for the preparation of an enantiomeric trisubstituted 3,4-dihydro-isoquinoline derivative 有权
标题翻译：制备对映体三取代3,4-二氢异喹啉衍生物的方法
公开(公告)号：US08314238B2
公开(公告)日：2012-11-20
申请号：US12810176
申请日：2008-12-23
申请人： Erhard Bappert , Andreas Hendrikus Maria De Vries , Doris Domin , Matthias Helms , Christoph Imboden , Zarghun Nazir , Wolfgang Skranc , Felix Spindler , Michael Stanek , Wilhelm Tschebull , Gerardus Karel Maria Verzijl
发明人： Erhard Bappert , Andreas Hendrikus Maria De Vries , Doris Domin , Matthias Helms , Christoph Imboden , Zarghun Nazir , Wolfgang Skranc , Felix Spindler , Michael Stanek , Wilhelm Tschebull , Gerardus Karel Maria Verzijl
IPC分类号： C07D217/20 , A61K31/47
CPC分类号： C07D217/02
摘要： The present invention relates to a process for the preparation of the compound of formula (7) which process comprises the hydrogenation of the compound of formula (4) using bis[chloro-1,5-cyclooctadiene-iridium], (S)-i-dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]-ferrocene as a catalyst.
摘要翻译：本发明涉及制备式（7）化合物的方法，该方法包括使用双[氯-1,5-环辛二烯 - 铱]，（S）-i 二环己基膦基-2 - [（S）-α-（二甲基氨基）-2-（二环己基膦基）苄基] - 二茂铁作为催化剂。

15. 发明申请

US20090275761A1 Catalytic Preparation of Cyclic Carboxylic Esters 审中-公开
标题翻译：催化制备环状羧酸酯
公开(公告)号：US20090275761A1
公开(公告)日：2009-11-05
申请号：US11887447
申请日：2006-04-07
申请人： Felix Spindler
发明人： Felix Spindler
IPC分类号： C07D307/93
CPC分类号： C07D307/83 , C07D307/33 , C07D307/77 , C07D307/93 , C07D309/30
摘要： Preparation of cyclic esters by hydrogenation of a carbonyl group in at least one anhydride radical —C(O)—O—C(O)— of a cyclic dicarboxylic or polycarboxylic anhydride by means of hydrogen in the presence of a homogeneous noble metal catalyst, characterized in that the hydrogenation is carried out in a homogeneous reaction mixture using an iridium catalyst. The cyclic esters are obtained in good chemical and optical yields when prochiral anhydrides are used together with chiral iridium catalysts.
摘要翻译：通过在均相贵金属催化剂存在下，通过氢在环状二羧酸或多元羧酸酐的至少一个酸酐基-C（O）-OC（O））中氢化羰基来制备环状酯，其特征在于使用铱催化剂在均相反应混合物中进行氢化。当手性酸酐与手性铱催化剂一起使用时，环酯以良好的化学和光学收率获得。

16. 发明授权

US06008393A Iridium-diphospine complexes and process for the hydrogenation of imines 失效
标题翻译：铱二氢复合物和亚胺氢化方法
公开(公告)号：US06008393A
公开(公告)日：1999-12-28
申请号：US000071
申请日：1998-01-22
申请人： Rafael Sablong , John Anthony Osborn , Felix Spindler
发明人： Rafael Sablong , John Anthony Osborn , Felix Spindler
IPC分类号： C07D209/08 , B01J31/22 , B01J31/24 , C07B61/00 , C07C209/52 , C07C211/45 , C07C219/02 , C07F15/00 , C07F17/02 , C07F19/00
CPC分类号： B01J31/1845 , B01J31/1875 , B01J31/188 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2414 , B01J31/2433 , B01J31/2452 , B01J31/2457 , B01J31/2476 , B01J31/248 , B01J31/2495 , C07C209/52 , C07C219/02 , C07F15/004 , C07F17/02 , B01J2231/643 , B01J2531/02 , B01J2531/0266 , B01J2531/821 , B01J2531/827 , B01J2531/842 , B01J31/04 , B01J31/26
摘要： Compounds of formulae I: (DIP)IrX.sub.q Y.sub.r (Z), Ia: (DIP)IrX.sub.s Y.sub.t (Z).sub.2 and Ib: (DIP)Ir(Z).sub.3 or mixtures of at least two of those compounds, wherein DIP is a ditertiary diphosphine, the two phosphine groups of which are bonded to a C.sub.2 -, C.sub.3 - or C.sub.4 -carbon chain, with the result that the diphosphine forms a 5- to 7-membered ring together with the Ir atom, X is Cl, Br or I, Y is a hydrogen atom, q and r are 0, 1 or 2 and the sum of q+r is 2, s and t are 0 or 1 and the sum of s+t is 1, and Z is the anion of an organic oxy acid that contains a group C(.dbd.O), S(.dbd.O)O or P(.dbd.O)O in the anion. The compounds are excellent catalysts for the hydrogenation of imines, especially for the enantioselective hydrogenation of prochiral imines.
摘要翻译： PCT No.PCT / EP96 / 03146 Sec。 371日期：1998年1月22日 102（e）1998年1月22日PCT PCT 1996年7月17日PCT公布。公开号WO97 / 05150 日期：1997年2月13日化学式I：（DIP）IrXqYr（Z），Ia：（DIP）IrXsYt（Z）2和Ib：（DIP）Ir（Z）3的化合物或这些化合物中的至少两种的混合物，其中 DIP是二价二膦，其两个膦基与C2-，C3-或C4-碳键连接，结果是二膦与Ir原子一起形成5-至7-元环，X是 Cl，Br或I，Y是氢原子，q和r是0,1或2，q + r的和为2，s和t分别为0或1，s + t的和为1，Z 是在阴离子中含有基团C（= O），S（= O）O或P（= O）O）的有机氧酸的阴离子。该化合物是用于亚胺加氢的优异催化剂，特别是用于前手性亚胺的对映选择性氢化。

17. 发明授权

US5998636A Carbamate herbicides 失效
标题翻译：氨基甲酸酯除草剂
公开(公告)号：US5998636A
公开(公告)日：1999-12-07
申请号：US128651
申请日：1998-08-04
申请人： Hermann Rempfler , Fredrik Cederbaum , Felix Spindler , Willy Urs Lottenbach
发明人： Hermann Rempfler , Fredrik Cederbaum , Felix Spindler , Willy Urs Lottenbach
IPC分类号： A01N47/12 , C07C43/23 , C07C269/02 , C07C271/10 , C07C271/12 , C07C323/12 , C07D213/40 , C07D317/46 , C07D333/20 , C07D333/28 , C07D317/44 , C07C43/00
CPC分类号： C07D213/40 , A01N47/12 , C07C271/12 , C07C43/23 , C07D317/46 , C07D333/20 , C07D333/28 , C07B2200/07
摘要： Substituted N-phenyl- and N-heteroarylalkylcarbamates of the formula I ##STR1## in which Q is a group ##STR2## R is halogen, trifluoromethyl, cyano, nitro or C.sub.1 -C.sub.3 haloalkoxy;Z is hydrogen or halogen; orZ and R together in the 2- and 3-position of the phenyl ring form a group --OCF.sub.2 O--;R.sub.1 is C.sub.1 -C.sub.5 alkyl;R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, methyl or ethyl;X is oxygen, sulfur, --SO-- or --SO.sub.2 --;Y is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or cyano;n is 0, 1 or 2;n.sub.1 is 0 or 1; andm is 0 or 1,with the proviso that m is 1 if Q is group (1) or (2);and the diastereomers and enantiomers thereof,exhibit pre- and post-emergence herbicidal properties. The preparation of these compounds and their use as herbicidally active ingredients are described.
摘要翻译：其中Q为基团R的式I的取代的N-苯基 - 和N-杂芳基烷基氨基甲酸酯是卤素，三氟甲基，氰基，硝基或C 1 -C 3卤代烷氧基; Z是氢或卤素; 或Z和R在苯环的2-和3-位一起形成-OCF 2 O - 基团; R1是C1-C5烷基; R2，R3，R4和R5彼此独立地是氢，甲基或乙基; X是氧，硫，-SO-或-SO 2 - ; Y是氢，卤素，C 1 -C 3烷基，C 1 -C 3卤代烷基，C 1 -C 3烷氧基或氰基; n为0,1或2; n1为0或1; m为0或1，条件是如果Q为基团（1）或（2），则m为1; 及其非对映异构体和对映异构体，显示出芽前和芽后除草性质。描述了这些化合物的制备及其作为除草活性成分的用途。

18. 发明授权

US5912375A Hydrogenation catalyst, process for the preparation thereof and hydrogenation process 失效
标题翻译：氢化催化剂，其制备方法和氢化方法
公开(公告)号：US5912375A
公开(公告)日：1999-06-15
申请号：US871478
申请日：1997-06-09
申请人： Felix Spindler , Ulrich Pittelkow
发明人： Felix Spindler , Ulrich Pittelkow
IPC分类号： B01J31/22 , B01J31/24 , C07B61/00 , C07C209/52 , C07C211/07 , C07C211/08 , C07C211/17 , C07C211/35 , C07C211/45 , C07C211/54 , C07C211/57 , C07C211/60 , C07C213/02 , C07C215/08 , C07C215/42 , C07C215/50 , C07C217/08 , C07C217/52 , C07C217/58 , C07C227/06 , C07C229/12 , C07C229/38 , C07C229/46 , C07F15/00 , C07F17/02 , C07F7/24
CPC分类号： B01J31/1845 , B01J31/04 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2419 , B01J31/2452 , C07C209/52 , C07F15/004 , C07F17/02 , B01J2231/643 , B01J2531/0205 , B01J2531/0266 , B01J2531/827 , B01J2531/842 , B01J31/26 , B01J31/30
摘要： Reaction products of an iridium (III) salt or a hydrate thereof, a diphosphine having secondary phosphine groups and a metal or ammonium chloride, bromide or iodide are excellent hydrogenation catalysts for ketimine. Using chiral diphosphines and prochiral ketimines, diastereoisomeric secondary amines are obtained in high optical yields.
摘要翻译：铱（III）盐或其水合物，具有仲膦基的二膦和金属或氯化铵，溴化物或碘化物的反应产物是用于酮亚胺的优异的氢化催化剂。使用手性二膦和前手性酮亚胺，以高光学收率获得非对映异构仲胺。

19. 发明授权

US5382729A Diphosphines containing silane groups, immobilized diphosphins and the use thereof as hydrogenation catalysts 失效
标题翻译：含有硅烷基团的二膦，固定化的二磷杂菁及其作为氢化催化剂的用途
公开(公告)号：US5382729A
公开(公告)日：1995-01-17
申请号：US197095
申请日：1994-02-16
申请人： Benoit Pugin , Felix Spindler , Manfred Muller
发明人： Benoit Pugin , Felix Spindler , Manfred Muller
IPC分类号： B01J21/08 , B01J31/02 , B01J31/16 , B01J31/22 , B01J31/24 , B01J31/40 , C07B53/00 , C07B61/00 , C07C213/02 , C07C217/08 , C07F9/655 , C07F15/00 , C07C2/36 , C07C209/22
CPC分类号： C07F15/008 , B01J31/0274 , B01J31/1633 , B01J31/2291 , B01J31/2409 , B01J31/4023 , B01J31/4046 , B01J31/4053 , B01J31/4092 , C07F15/004 , C07F9/65515 , B01J21/08 , B01J2231/643 , B01J2231/645 , B01J2531/822 , B01J2531/827 , Y02P20/584 , Y02P20/588
摘要： Compounds of formula I ##STR1## wherein R.sub.1 denotes identical or different radicals and is linear or branched C.sub.1 -C.sub.12 alkyl, unsubstituted C.sub.5 -C.sub.6 cycloalkyl or C.sub.5 -C.sub.6 cycloalkyl which is substituted by C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, or is phenyl or benzyl, or both substituents R.sub.1 of a group (R.sub.1).sub.2 P are o,o-diphenylene, R.sub.2 is hydrogen, linear or branched C.sub.1 -C.sub.12 alkyl, phenyl or benzyl, R.sub.3 is C.sub.1 -C.sub.12 alkylene, R.sub.4 is C.sub.2 -C.sub.18 alkylene, phenylene or benzylene, and R.sub.5 is C.sub.1 -C.sub.6 alkyl or phenyl, can be applied to solid carriers, such as silica gel or aerosils, and complexed with rhodium or iridium compounds. These materials are heterogeneous and separable catalysts for the assymetrical hydrogenation of prochiral compounds containing carbon double bonds or carbon/hetero atom double bonds, for example ketones and imines.
摘要翻译：式I的化合物其中R 1表示相同或不同的基，并且是被C 1 -C 4烷基或C 1 -C 4烷氧基取代的直链或支链C 1 -C 12烷基，未取代的C 5 -C 6环烷基或C 5 -C 6环烷基，或者是苯基或苄基或基团（R 1）2 P的两个取代基R 1是邻，邻二亚苯基，R 2是氢，直链或支链C 1 -C 12烷基，苯基或苄基，R 3是C 1 -C 12亚烷基，R 4是C 2 -C 18亚烷基，亚苯基或亚苯基，R5为C1-C6烷基或苯基，可用于固体载体如硅胶或气溶胶，并与铑或铱化合物络合。这些材料是用于对含有碳双键或碳/杂原子双键的前手性化合物例如酮和亚胺进行非对称氢化的非均相和可分离的催化剂。

20. 发明授权

US4994615A Process for the preparation of optically active secondary arylamines 失效
标题翻译：光学活性仲芳基胺的制备方法
公开(公告)号：US4994615A
公开(公告)日：1991-02-19
申请号：US79054
申请日：1987-07-29
申请人： Felix Spindler , Benoit Pugin
发明人： Felix Spindler , Benoit Pugin
IPC分类号： C07B53/00 , B01J31/00 , B01J31/22 , B01J31/24 , C07B31/00 , C07B43/04 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/52 , C07C209/60 , C07C211/44 , C07C211/45 , C07C211/48 , C07C213/00 , C07C213/02 , C07C217/08 , C07C217/84 , C07C229/46 , C07C229/52 , C07C241/00 , C07C251/02 , C07C251/24 , C07C253/00 , C07C255/58 , C07C255/61 , C07C313/00 , C07C319/20 , C07C323/29 , C07C323/36 , C07D209/08 , C07D333/36
CPC分类号： C07C209/52
摘要： Asymmetric hydrogenation of prochiral N-arylketimines to give optically active secondary amines at a temperature of -20.degree. to 80.degree. C., a hydrogen pressure of 10.sup.5 to 6.10.sup.6 Pa with the addition of catalytic amounts of an iridium compound of the formula III or IIIa[XIrYZ] (III)or[XIrY.sup..sym. A.sup..crclbar. (IIIa)in which X is two olefin ligands or one diene ligand, Y is a chiral diphosphine, the secondary phosphine groups of which are linked by 2-4 C atoms and which, together with the Ir atom, forms a 5-, or 6- or 7-ring, or Y is a chiral diphosphinite, the phosphinite groups of which are linked via 2 C atoms and which together with the Ir atom forms a 7-ring, Z is Cl, Br or I and A.sup.63 is the anion of an oxygen acid or complex acid, and if appropriate with the addition of an ammonium or alkali metal chloride, bromide or iodide.
摘要翻译：在-20℃至80℃的温度下，前手性N-芳基酮亚胺的不对称氢化得到光学活性仲胺，氢气压力为105至6.106Pa，加入催化量的式III或IIIa的铱化合物其中X是两个烯属配体或一个二烯配体，Y是手性二膦，其次膦基基团连接在2-4个碳原子上的[XIrYZ]（III）或[XIrY（+）A（ - ）并且其与Ir原子一起形成5-或6-或7-环，或Y是手性二磷酸盐，其膦基基团通过2个C原子连接并且与Ir原子一起形成 7环，Z是Cl，Br或I，A63是氧酸或络合酸的阴离子，如果合适，加入铵或碱金属氯化物，溴化物或碘化物。

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