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    • 15. 发明授权
    • Methods for preparing a semiconductor assembly
    • 半导体组件的制备方法
    • US07256101B2
    • 2007-08-14
    • US10893596
    • 2004-07-15
    • Fabrice LetertreBruno GhyselenOlivier Rayssac
    • Fabrice LetertreBruno GhyselenOlivier Rayssac
    • H01L21/30H01L21/46
    • H01L21/76254H01L21/0445H01L21/187H01L21/7602H01L33/0012H01L33/0029
    • Methods for preparing a semiconductor assembly are disclosed. In an implementation, the technique includes providing a support substrate and a bonding surface thereon, providing a donor substrate having a weakened zone that defines a useful layer and a bonding surface on the useful layer, and providing an interface layer of a predetermined material on the bonding surface of either the support substrate or the useful layer to provide a bonding surface thereon. The method also includes molecularly bonding the bonding surface of the interface layer to the bonding surface of the other of the support substrate or the useful layer to form a separable bonding interface therebetween, and to thus form the semiconductor assembly, and heat treating the semiconductor assembly to a temperature of at least 1000 to 1100° C. without substantially increasing molecular bonding between the bonding surface of the interface layer and the bonding surface of the other of the support substrate or the useful layer, so that the separable bonding interface maintains a sufficiently weak bond that can later be overcome by applying stresses to detach the useful layer from the donor substrate.
    • 公开了制备半导体组件的方法。 在一个实施方案中,该技术包括在其上提供支撑衬底和结合表面,提供施主衬底,其具有限定可用层的弱化区和在有用层上的结合表面,以及在有用层上提供预定材料的界面层 粘合表面,以在其上提供粘合表面。 该方法还包括将界面层的结合表面分别结合到支撑衬底或有用层中的另一个的接合表面,以在其之间形成可分离的接合界面,从而形成半导体组件,并对半导体组件进行热处理 达到至少1000〜1100℃的温度,而不会在界面层的接合面与支撑基板或有用层的另一方的接合面之间基本上增加分子接合,使得可分离的接合界面保持足够的 弱键可以随后通过施加应力来克服有用层与施主衬底的分离。
    • 17. 发明申请
    • Semiconductor substrates having useful and transfer layers
    • 具有有用和转移层的半导体衬底
    • US20060189095A1
    • 2006-08-24
    • US11402052
    • 2006-04-12
    • Bruno GhyselenFabrice Letertre
    • Bruno GhyselenFabrice Letertre
    • H01L21/30H01L21/425
    • H01L21/3148H01L21/318H01L21/76254H01L29/1608H01L29/165H01L29/2003H01L29/267Y10T428/24479
    • Methods for fabricating final substrates for use in optics, electronics, or optoelectronics are described. The method includes forming a zone of weakness beneath a surface of a source substrate to define a transfer layer; detaching the transfer layer from the source substrate along the zone of weakness; depositing a useful layer upon the transfer layer; and depositing a support material on the useful layer to form the final substrate. The useful layer may be deposited on the transfer layer before or after detaching the transfer layer from the source substrate. The useful layer is typically made of a material having a large band gap, and comprises at least one of gallium nitride, or aluminum nitride, or of compounds of at least two elements including at least one element of aluminum, indium, and gallium. The zone of weakness may advantageously be formed by implanting atomic species into the source substrate.
    • 描述了用于制造用于光学,电子学或光电子学的最终衬底的方法。 该方法包括在源极衬底的表面下方形成弱化区以限定转移层; 沿着弱化区域将转移层从源底物分离; 在转移层上沉积有用的层; 以及在有用层上沉积支撑材料以形成最终的基底。 在从源极衬底分离转移层之前或之后,有用层可以沉积在转移层上。 有用层通常由具有大带隙的材料制成,并且包括氮化镓或氮化铝中的至少一种,或包括至少两种元素的化合物,包括至少一种铝,铟和镓元素。 可以通过将原子物质注入到源底物中来有利地形成弱点区域。
    • 18. 发明授权
    • Method of manufacturing a free-standing substrate made of monocrystalline semi-conductor material
    • 制造由单晶半导体材料制成的独立基板的方法
    • US06964914B2
    • 2005-11-15
    • US10349295
    • 2003-01-22
    • Bruno GhyselenFabrice LetertreCarlos Mazure
    • Bruno GhyselenFabrice LetertreCarlos Mazure
    • C30B29/38C23C16/01C23C16/34C30B25/02C30B29/04H01L21/20H01L21/762H01L21/30H01L21/46H01L21/76
    • H01L21/76254Y10S438/977
    • A method for manufacturing a free-standing substrate made of a semiconductor material. A first assembly is provided and it includes a relatively thinner nucleation layer of a first material, a support of a second material, and a removable bonding interface defined between facing surfaces of the nucleation layer and support. A substrate of a relatively thicker layer of a third material is grown, by epitaxy on the nucleation layer, to form a second assembly with the substrate attaining a sufficient thickness to be free-standing. The third material is preferably a monocrystalline material. Also, the removable character of the bonding interface is preserved with at least the substrate being heated to an epitaxial growth temperature. The coefficients of thermal expansion of the second and third materials are selected to be different from each other by a thermal expansion differential, determined as a function of the epitaxial growth temperature or subsequent application of external mechanical stresses, such that, as the second assembly cools from the epitaxial growth temperature, stresses are induced in the removable bonding interface to facilitate detachment of the nucleation layer from the substrate.
    • 一种制造由半导体材料制成的自立式基板的方法。 提供了第一组件,并且其包括第一材料的相对更薄的成核层,第二材料的支撑体和限定在成核层和支撑体的相对表面之间的可去除的结合界面。 通过在成核层上外延生长相对较厚的第三材料层的衬底,以形成第二组件,其中衬底获得足够的厚度以使其独立。 第三种材料优选是单晶材料。 而且,至少将衬底加热到​​外延生长温度来保存接合界面的可去除特性。 第二和第三材料的热膨胀系数被选择为相互不同的热膨胀差异,其被确定为外延生长温度的函数或随后的外部机械应力的应用,使得当第二组件冷却时 从外延生长温度,在可除去的结合界面中诱发应力以促进成核层与基底的分离。
    • 19. 发明授权
    • Methods for fabricating final substrates
    • 制造最终基板的方法
    • US06867067B2
    • 2005-03-15
    • US10446604
    • 2003-05-27
    • Bruno GhyselenFabrice Letertre
    • Bruno GhyselenFabrice Letertre
    • H01L27/12H01L21/02H01L21/762H01L29/165H01L29/20H01L29/24H01L29/267H01L21/44H01L21/30
    • H01L21/3148H01L21/318H01L21/76254H01L29/1608H01L29/165H01L29/2003H01L29/267Y10T428/24479
    • Methods for fabricating final substrates for use in optics, electronics, or optoelectronics are described. In an embodiment, the method includes forming a zone of weakness beneath a surface of a source substrate to define a transfer layer, and forming a first bonding layer on the source substrate surface. A second bonding layer may be formed on a surface of an intermediate support, and the exposed surfaces of the first and second bonding layers joined to form a composite substrate. Next, the source substrate is detached from the composite substrate along the zone of weakness to expose a surface of the transfer layer, and a support material is deposited onto the exposed surface of the transfer layer. The transfer layer and support material are then separated from the composite substrate by elimination of at least the first bonding layer to form the final substrate. The zone of weakness may advantageously be formed by implanting atomic species into the source substrate.
    • 描述了用于制造用于光学,电子学或光电子学的最终衬底的方法。 在一个实施例中,该方法包括在源极衬底的表面下方形成弱化区以限定转移层,以及在源极衬底表面上形成第一结合层。 第二接合层可以形成在中间支撑体的表面上,并且第一和第二接合层的暴露表面接合以形成复合衬底。 接下来,源极衬底沿着弱化区从复合衬底分离以暴露转移层的表面,并且将载体材料沉积到转印层的暴露表面上。 然后通过消除至少第一结合层以形成最终的基底,将转移层和载体材料与复合基材分离。 可以通过将原子物质注入到源底物中来有利地形成弱点区域。