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11. 发明授权

US5714560A Water-soluble or water-dispersible graft polymers of proteins as leather tanning agents 失效
标题翻译：作为皮革鞣剂的蛋白质的水溶性或水分散性接枝聚合物
公开(公告)号：US5714560A
公开(公告)日：1998-02-03
申请号：US737329
申请日：1996-11-13
申请人： Walter Denzinger , Axel Kistenmacher , Heinrich Hartmann , Gunter Bernhardt , Gerhard Wolf
发明人： Walter Denzinger , Axel Kistenmacher , Heinrich Hartmann , Gunter Bernhardt , Gerhard Wolf
IPC分类号： C08F289/00 , C14C3/22
CPC分类号： C08F289/00 , C14C3/22
摘要： Water-soluble or water-dispersible graft polymers which are obtainable by free-radical-initiated polymerization of (A) a monomer or monomer mixture comprising (a) from 20 to 100% by weight of acrylic acid or methacrylic acid or a mixture thereof or alkali metal, alkaline earth metal or ammonium salts thereof, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which can be copolymerized with the monomers (a), and (c) from 0 to 5% by weight of monomers containing at least 2 ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of proteins (B) in an A:B weight ratio of from (95 to 10):(5 to 90), are used as tanning agents for self-tanning, pretanning and assist tanning of pelts and skin pelts and for the retanning of leather and skin.
摘要翻译： PCT No.PCT / EP95 / 01720 Sec。 371日期：1996年11月13日 102（e）日期1996年11月13日PCT提交1995年5月6日PCT公布。公开号WO95 / 31576 日期1995年11月23日可通过（A）单体或单体混合物的自由基引发聚合获得的水溶性或水分散性接枝聚合物，其包含（a）20至100重量％的丙烯酸或甲基丙烯酸或其混合物或其碱金属，碱土金属或铵盐，（b）0至80重量％的其它单烯属不饱和单体，其可与单体（a）和（c）共聚0至5 （B）重量比为（95〜10）：（5〜90）的蛋白质（B）存在下，分子中含有至少2个烯属不饱和的非共轭双键的单体重量％用作鞣制剂，用于自动鞣制，预处理和辅助皮肤和皮肤鞣制以及皮革和皮肤的复鞣。

12. 发明授权

US6033442A Use of aqueous solutions or dispersions of copolymers of carboxyl-group-containing monomers, ethylenically unsaturated acetals, ketals or orthocarboxylic acid esters and optionally other copolymerizable monomers as leather tanning agents 失效
标题翻译：使用含羧基单体，烯属不饱和缩醛，缩酮或原羧酸酯和任选的其它可共聚单体的共聚物的水溶液或分散体作为皮革鞣剂
公开(公告)号：US6033442A
公开(公告)日：2000-03-07
申请号：US77881
申请日：1998-06-10
申请人： Walter Denzinger , Axel Kistenmacher , Gerhard Wolf , Michael Kneip , Norbert Greif , Knut Oppenlander
发明人： Walter Denzinger , Axel Kistenmacher , Gerhard Wolf , Michael Kneip , Norbert Greif , Knut Oppenlander
IPC分类号： C08F216/38 , C08F222/00 , C14C3/22 , C14C3/28
CPC分类号： C08F216/38 , C08F222/00 , C14C3/22 , C14C3/28
摘要： The use of aqueous solutions or dispersions of copolymers composed ofA) from 5 to 95 mol % of ethylenically unsaturated mono- or dicarboxylic acids having 3 to 10 carbons, their anhydrides, their alkali metal, alkaline earth metal or ammonium salts, or mixtures thereof,B) from 5 to 95 mol % of ethylenically unsaturated acetals, ketals or orthocarboxylic esters of the formula I ##STR1## where R.sup.1 to R.sup.12 independently are hydrogen or an organic radical anda to d independently are 0 or 1, andC) from 0 to 70 mol % of other copolymerizable monomersor their hydrolysis products or polymer-analogous reaction products, as tanning agents for the self-tanning, pretanning or assist tanning of leather pelts and skin pelts or for the retanning of leather and skins.
摘要翻译： PCT No.PCT / EP96 / 05318 Sec。 371日期：1998年6月10日 102（e）1998年6月10日PCT 1996年12月2日PCT PCT。公开号WO97 / 21839 日期：1997年6月19日使用由A）5〜95摩尔％的碳原子数为3〜10的烯属不饱和单羧酸或二羧酸，其酸酐，其碱金属，碱土金属或铵组成的共聚物的水溶液或分散体盐或其混合物，B）5至95摩尔％的式I的烯键式不饱和缩醛，缩酮或邻羧基酯，其中R 1至R 12独立地为氢或有机基团，且d独立地为0或1，C ）0至70摩尔％的其它可共聚单体或其水解产物或聚合物 - 类似反应产物，作为用于皮革毛皮和皮肤皮肤的自晒黑，预处理或辅助鞣制或用于皮革和皮肤的复鞣的鞣剂。

13. 发明授权

US5914442A Aqueous solutions or dispersions of copolymers 失效
标题翻译：共聚物的水溶液或分散体
公开(公告)号：US5914442A
公开(公告)日：1999-06-22
申请号：US676233
申请日：1996-07-25
申请人： Hermann Birkhofer , Michael Kneip , Peter Danisch , Walter Denzinger , Axel Kistenmacher , Heinrich Hartmann
发明人： Hermann Birkhofer , Michael Kneip , Peter Danisch , Walter Denzinger , Axel Kistenmacher , Heinrich Hartmann
IPC分类号： C14C9/00 , B01F17/22 , B01F17/42 , C08F220/18 , C08F222/06 , C08J3/03 , C14C9/02 , C14C11/00
CPC分类号： C08J3/03 , C08F220/18 , C08F222/06 , C14C9/02
摘要： Aqueous solution or aqueous dispersion of copolymers suitable for the fatliquoring and filling of leather and fur skins are obtained by free-radical copolymerization ofA.sup.1) C.sub.6 -C.sub.40 -monoolefins or C.sub.6 -C.sub.40 -alkyl vinyl ethers or mixtures thereof withB.sup.1) monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides or by free-radical copolymerization ofA.sup.2) C.sub.6 -C.sub.40 -alkyl acrylates or methacrylates or vinyl esters of C.sub.6 -C.sub.40 -carboxylic acids or mixtures thereof withB.sup.2) monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids, monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids, amides of monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids or mixtures thereofto give copolymers with molecular weights of 500 to 30,000, where the carboxyl groups which are present in aqueous medium are at least partially neutralized, and some of the carboxylic groups can be in amidated form,containing 0.5-40% by weight, based on the amount of copolymer, of defined emulsifiers.
摘要翻译： PCT No.PCT / EP95 / 00144 Sec。 371日期：1996年7月25日 102（e）日期1996年7月25日PCT提交1995年1月16日PCT公布。 WO95 / 20056 PCT公开号日期1995年7月27日适用于加脂和填充皮革和毛皮的共聚物的水溶液或水分散体通过A1）C6-C40-单烯烃或C6-C40-烷基乙烯基醚或其混合物与 B1）单烯键式不饱和C 4 -C 8二羧酸酐或通过A2）C6-C40烷基丙烯酸酯或甲基丙烯酸酯或C6-C40-羧酸的乙烯酯或其混合物与B2）单烯属不饱和C 3 -C 12羧酸的自由基共聚合酸，单烯属不饱和C 4 -C 12二羧酸酐，单烯属不饱和C 4 -C 12二羧酸的单酯或单酰胺，单烯属不饱和C 3 -C 12羧酸的酰胺或其混合物，得到分子量为500至30,000的共聚物，其中存在于水性介质中的羧基至少部分中和，并且一些羧基可以是酰胺化形式，其含有0.5 -40重量％，基于共聚物的量，定义的乳化剂。

14. 发明授权

US4956421A Preparation of oxyalkylated, carboxyl-containing polymers 失效
标题翻译：烷氧基化的含羧基聚合物的制备
公开(公告)号：US4956421A
公开(公告)日：1990-09-11
申请号：US367680
申请日：1989-06-19
申请人： Walter Denzinger , Heinrich Hartmann , Richard Baur , Johannes Perner , Wolfgang Trieselt , Horst Trapp , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Richard Baur , Johannes Perner , Wolfgang Trieselt , Horst Trapp , Hans-Juergen Raubenheimer
IPC分类号： C08F8/14 , C08F20/00 , C08F20/04 , C08F22/00 , C08F22/02
CPC分类号： C08F8/14
摘要： Oxyalkylated, carboxyl-containing polymers are prepared by reacting(A) a polymer which contains one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units with(B) an alkylene oxidein an aqueous medium at not more than 120.degree. C. by a process in which the reaction is started at a pH of from 5.0 to 5.9 and is ended after a pH of from 5.5 to 8.5 has been reached. As a result of monitoring of the pH, the selectivity of the addition reaction of alkylene oxides with the polymers (A) is substantially improved compared with known processes.
摘要翻译：通过使（A）含有一种或多种单烯键式不饱和C 3 -C 6 - 羧酸作为共聚单元的聚合物与水性介质中的（B）环氧烷烃在不大于120℃下反应来制备烷氧基化的含羧基聚合物。通过反应开始于5.0至5.9的pH并在达到5.5至8.5的pH后结束的方法。作为监测pH的结果，与已知方法相比，烯化氧与聚合物（A）的加成反应的选择性显着提高。

15. 发明授权

US4814102A Detergents containing oxyalkylated, carboxyl-containing polymers 失效
标题翻译：含有烷氧基化的含羧基聚合物的洗涤剂
公开(公告)号：US4814102A
公开(公告)日：1989-03-21
申请号：US175176
申请日：1988-03-31
申请人： Richard Baur , Walter Denzinger , Albrecht Eckell , Heinrich Hartmann , Josef Mueller , Hans-Juergen Raubenheimer , Wolfgang Trieselt
发明人： Richard Baur , Walter Denzinger , Albrecht Eckell , Heinrich Hartmann , Josef Mueller , Hans-Juergen Raubenheimer , Wolfgang Trieselt
IPC分类号： C08F8/14 , C08G65/26 , C11D3/37 , D06L1/12 , C11D17/00
CPC分类号： C11D3/378 , C08F8/14 , C11D3/3757 , C11D3/3773 , C11D3/3784
摘要： Detergents which contain from 0.01 to 20% by weight of oxyalkylated, carbonyl-containing polymers can be prepared by reacting.(A) a polymer which contains, as copolymerized units, one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids with(B) ethylene oxide, propylene oxide, n-butylene oxide, isobutylene oxide or a mixture of these, in an aqueous medium at up to 150.degree. C.
摘要翻译：含有0.01至20重量％的烷氧基化的含羰基的聚合物的洗涤剂可通过使其反应来制备。（A）一种聚合物，其在水性介质中含有一种或多种单烯属不饱和C3-C6-羧酸与（B）环氧乙烷，环氧丙烷，正丁烯氧化物，异丁烯氧化物或它们的混合物作为共聚单元在150℃

16. 发明授权

US06171583B2 Powdery iodine complexes 失效
标题翻译：粉状碘络合物
公开(公告)号：US06171583B2
公开(公告)日：2001-01-09
申请号：US09068305
申请日：1998-05-07
申请人： Jörg Breitenbach , Axel Sanner , Walter Denzinger , Siegfried Lang
发明人： Jörg Breitenbach , Axel Sanner , Walter Denzinger , Siegfried Lang
IPC分类号： A61K3318
CPC分类号： C08F226/06 , C08F8/22 , C08F26/06
摘要： Complexes in powder form of iodine and a crosslinked polymer based on N-vinyl compounds are obtainable by dry heating of iodine and a polymer which is obtained by polymerization of monovinyl compounds (monomers A) whose vinyl group is bonded to a nitrogen atom of a nitrogen-containing heterocycle, in the presence of from 0.5 to 10% by weight, based on the monomers (A), of a compound (B) of the formula I; where A is —CH— or a nitrogen atom, and n is 2 or 3. The complexes are suitable for producing antidiarrheals.
摘要翻译：可以通过干燥加热碘和聚合物获得碘粉末形式和基于N-乙烯基化合物的交联聚合物的复合物，该聚合物是通过乙烯基结合在氮的氮原子上的单乙烯基化合物（单体A）基于单体（A），在式I化合物（B）为0.5〜10重量％的存在下，其中A为-CH-或氮原子，n为2 或3.该配合物适于产生止泻药。

17. 发明授权

US5753759A Graft polymers containing N-vinyl units, their preparation and their use 失效
标题翻译：含有N-乙烯基单元的接枝聚合物，其制备及其用途
公开(公告)号：US5753759A
公开(公告)日：1998-05-19
申请号：US704772
申请日：1996-10-24
申请人： Heinrich Hartmann , Walter Denzinger , Claudia Nilz
发明人： Heinrich Hartmann , Walter Denzinger , Claudia Nilz
IPC分类号： B01F17/00 , B01F17/52 , C05G3/00 , C08F263/00 , C08F265/00 , C08F271/00 , C09B67/46 , C09D17/00 , C09K17/20 , C11D3/37 , D21H17/34
CPC分类号： C09D17/00 , B01F17/005 , C05G3/0029 , C08F271/00 , C09B67/0085 , C09K17/20 , C11D3/3788 , D21H17/34
摘要： Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25.degree. C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.
摘要翻译： PCT No.PCT / EP95 / 00912 Sec。 371日期1996年10月24日第 102（e）日期1996年10月24日PCT 1995年3月3日PCT PCT。公开号WO95 / 25759 日期1995年9月28日含有N-乙烯基单元的接枝聚合物，其中接枝碱是一种聚合物，其在每种情况下含有至少5重量％的式（I）的单元（I）其中R 1和R 2各自为H或C 1 -C 6烷基，单烯属不饱和单体以100:1至1:100的重量比接枝到接枝基上，并且其K值至少为7（根据 H. Fikentscher在25℃和pH7的5重量％水溶液中）通过在聚合物存在下聚合单烯属不饱和单体来制备，每种情况下聚合物含有至少5重量％的式 I和/或II作为接枝基质，重量比为100：1至1：100，并用作颜料分散剂，作为洗涤剂和清洁剂的添加剂，以及用于纸张和土壤稳定剂的强度剂，肥料压实。

18. 发明授权

US5710228A Maleimide/.alpha.-olefin copolymers and their use as light stabilizers and stabilizers for organic material 失效
标题翻译：马来酰亚胺/α-烯烃共聚物及其用作有机材料的光稳定剂和稳定剂
公开(公告)号：US5710228A
公开(公告)日：1998-01-20
申请号：US644123
申请日：1996-05-10
申请人： Alfred Krause , Walter Denzinger , Albert Hettche , Alexander Aumueller , Hubert Trauth
发明人： Alfred Krause , Walter Denzinger , Albert Hettche , Alexander Aumueller , Hubert Trauth
IPC分类号： C08F2/06 , C08F8/32 , C08F210/14 , C08F222/40 , C08F210/00
CPC分类号： C08F8/32 , C08F210/14
摘要： Maleimide/.alpha.-olefin copolymers are composed of structural units I ##STR1## where R.sup.1 is a tetramethylpiperidinyl radical of the formula II ##STR2## R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, formyl, C.sub.2 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.5 - or C.sub.6 -cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula --CR.sup.4 =CH--CO--OR.sup.5, R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.5, and R.sup.5 is C.sub.5 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.18 -aralkyl, phenyl or tolyl, and up to 8 mol %, based on II, of R.sup.1 may furthermore be hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and R.sup.2 is a mixture of C.sub.14 -C.sub.28 -alkyl groups, where two of these alkyl groups, which may differ by no more than two carbon atoms, each account for at least 30% of this mixture, having an average molecular weight of from 1,000 to 50,000. The copolymers described are suitable as light stabilizers and stabilizers for organic material, in particular plastics and coatings.
摘要翻译：马来酰亚胺/α-烯烃共聚物由结构单元Ⅰ（II）组成，其中R 1是式II的四甲基哌啶基，其中R 3是氢，C 1 -C 6烷基，甲酰基，C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 - 或C 6 - 环烷氧基，氰基甲基，2-羟乙基，苄基或式-CR 4 = CH-CO-OR 5基团，R 4是氢，C 1 -C 6烷基或式-CO-OR5和R5是C5-C18-烷基，C5-C8-环烷基，C7-C18-芳烷基，苯基或甲苯基，并且基于II的至多8摩尔％的R 1还可以是氢， C 1 -C 22 - 烷基或C 5 -C 8 - 环烷基，并且R 2是C 14 -C 28 - 烷基的混合物，其中两个可以不超过两个碳原子的烷基各自占据至少30％的该混合物，其平均分子量为1,000至50,000。所述的共聚物适合用作有机材料的光稳定剂和稳定剂，特别是塑料和涂料。

19. 发明授权

US5662781A Elimination of nitrile impurities from polymers 失效
标题翻译：从聚合物中消除腈杂质
公开(公告)号：US5662781A
公开(公告)日：1997-09-02
申请号：US569137
申请日：1996-01-11
申请人： Walter Denzinger , Heinrich Hartmann , Michael Kroener , Claudia Nilz
发明人： Walter Denzinger , Heinrich Hartmann , Michael Kroener , Claudia Nilz
IPC分类号： C08F6/10 , C08F6/00 , C08F6/16 , C08F8/06 , C08F8/12 , C08F26/02 , D21H21/10 , C07B63/00 , C08J3/28
CPC分类号： D21H21/10 , C08F6/006 , C08F8/06 , Y02W10/37
摘要： Nitrile impurities are eliminated from polymers which contain acyclic N-vinyl-carboxamide and/or vinylamine units by treating the polymers with at least one oxidizing agent a) with exposure to light and/or b) in the presence of heavy metal ions.
摘要翻译： PCT No.PCT / EP94 / 02082 Sec。 371日期1996年1月11日 102（e）日期1996年1月11日PCT Filed 1994年6月27日PCT Pub。出版物WO95 / 02615 日期1995年1月26日通过用暴露于光和/或b）在沉重的存在下用至少一种氧化剂a）处理聚合物，从含有非环状N-乙烯基 - 甲酰胺和/或乙烯胺单元的聚合物中除去腈杂质金属离子。

20. 发明授权

US5334287A Graft polymers of natural substances containing saccharide structures or derivatives thereof and ethylenically unsaturated compounds and their use 失效
标题翻译：含有糖结构或其衍生物和烯属不饱和化合物的天然物质的接枝聚合物及其用途
公开(公告)号：US5334287A
公开(公告)日：1994-08-02
申请号：US914926
申请日：1992-07-17
申请人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
发明人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
IPC分类号： C08F251/02 , C08F251/00 , D21H17/34 , D21H17/35 , D21H17/37 , D21H21/18 , D21H21/06 , D21H21/10
CPC分类号： C08F251/00 , D21H17/35 , D21H17/375 , D21H21/18
摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
摘要翻译：接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的单烯属不饱和单体0-5重量％的分子中含有两个或更多个烯属不饱和的非共轭双键的单体含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

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