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11. 发明申请

US20070131362A1 Process for producing a fibrous product 审中-公开
标题翻译：纤维制品的制造方法
公开(公告)号：US20070131362A1
公开(公告)日：2007-06-14
申请号：US10583712
申请日：2004-12-23
申请人： Johanna Buchert , Hannu Mikkonen , Soili Peltonen , Liisa Viikari , Stina Gronqvist , Tarja Oksanen , Anna Suurnakki
发明人： Johanna Buchert , Hannu Mikkonen , Soili Peltonen , Liisa Viikari , Stina Gronqvist , Tarja Oksanen , Anna Suurnakki
IPC分类号： D21H11/20 , D21H21/14 , C08F251/02
CPC分类号： D21C9/002 , C08F251/02 , C08L51/02 , D21H11/20 , D21H21/40 , C08L2666/02
摘要： The present invention concerns a process for modifying a lignocellulosic fibre material. In particular, the present invention gives new properties to the fibrous matrix of the material. This is achieved by producing fibrous products with modified properties by activating the fibres of the matrix with an oxidizing agent and attaching compounds to the activated fibre in order to incorporate desired, pre-selected properties in to the fibre matrix. The invention makes possible to produce novel kinds of fibrous materials having practically a large variety of properties. Examples of such properties include hydrophobic hydrophilic character.
摘要翻译：本发明涉及一种改性木质纤维素纤维材料的方法。特别地，本发明给出材料的纤维基质的新特性。这通过用氧化剂活化基质的纤维并将化合物连接到活化的纤维上以产生纤维基质中所需的预先选择的性质来制备具有改性特性的纤维制品来实现。本发明使得可以生产具有实际上具有多种性质的新型纤维材料。这些性质的实例包括疏水亲水性。

12. 发明申请

US20050107603A1 Novel starch derivatives and a method for their preparation 失效
标题翻译：新型淀粉衍生物及其制备方法
公开(公告)号：US20050107603A1
公开(公告)日：2005-05-19
申请号：US10504296
申请日：2003-02-17
申请人： Soili Peltonen , Hannu Mikkonen , Thomas Gadda
发明人： Soili Peltonen , Hannu Mikkonen , Thomas Gadda
IPC分类号： C08B31/00 , C08B31/16 , C09J103/04 , C08B33/02
CPC分类号： C09J103/04 , C08B31/006 , C08B31/16
摘要： The invention relates to novel transglycosylation products and their preparation. The transglycosylation products according to the invention are prepared from starch derivatives, such as esters or ethers of starch. The products are obtained by reacting a starch derivative with an alcohol in the presence of an acid catalyst. The forming product is separated by precipitation or by removing any unreacted alcohol by evaporation. In the products according to the invention the good properties of starch derivatives, such as the excellent water resistance of esters, are combined with the versatility of transglycoside products. The products can be used as adhesives, in which case they are formulated, for example as hot-melt adhesives, and as comonomers, prepolymers or macroinitiators in the preparation of polymers.
摘要翻译：本发明涉及新型转糖基化产物及其制备方法。根据本发明的转糖基化产物由淀粉衍生物如淀粉的酯或醚制备。产物通过在酸催化剂存在下使淀粉衍生物与醇反应获得。通过沉淀或通过蒸发除去任何未反应的醇来分离成型产物。在根据本发明的产品中，淀粉衍生物的良好性能，例如酯的优异耐水性与转糖苷产物的通用性相结合。这些产品可以用作粘合剂，在这种情况下，它们被配制成例如热熔粘合剂，以及作为聚合物制备中的共聚单体，预聚物或大分子引发剂。

13. 发明申请

US20070164468A1 Process for producing fibre compositions 审中-公开
标题翻译：生产纤维组合物的方法
公开(公告)号：US20070164468A1
公开(公告)日：2007-07-19
申请号：US10583339
申请日：2004-12-23
申请人： Johanna Buchert , Stina Gronqvist , Hannu Mikkonen , Tarja Oksanen , Soili Peltonen , Anna Suurnakki , Liisa Viikari
发明人： Johanna Buchert , Stina Gronqvist , Hannu Mikkonen , Tarja Oksanen , Soili Peltonen , Anna Suurnakki , Liisa Viikari
IPC分类号： B32B37/00
CPC分类号： D21H11/20 , C08F251/02 , C08L51/02 , D21H15/10 , C08L2666/02
摘要： The present invention concerns a process for producing fibre composites. In particular, the invention provides a novel way of producing biodegradable composites comprising a hydrophobic polymer material and a reinforcing component of fibres derived from plant materials. Composite material produced by means of the present invention has improved strength properties and enhanced adhesion between the bifunctional fibre and the natural or synthetic polymer.
摘要翻译：本发明涉及一种生产纤维复合材料的方法。特别地，本发明提供了生产可生物降解复合材料的新方法，其包括疏水性聚合物材料和源自植物材料的纤维的增强组分。通过本发明生产的复合材料具有改善的强度性能和双官能纤维与天然或合成聚合物之间增强的粘附性。

14. 发明申请

US20070163737A1 Porous filler or coating pigment of paper and cardboard and a method of manufacturing it 审中-公开
标题翻译：纸和纸板的多孔填料或涂料颜料及其制造方法
公开(公告)号：US20070163737A1
公开(公告)日：2007-07-19
申请号：US10573028
申请日：2004-10-01
申请人： Allan Johansson , Pia Qvintus-Leino , Petri Varjos , Soili Peltonen , Hannu Mikkonen , Mauno Miettinen , Saija Luukkanen
发明人： Allan Johansson , Pia Qvintus-Leino , Petri Varjos , Soili Peltonen , Hannu Mikkonen , Mauno Miettinen , Saija Luukkanen
IPC分类号： D21F1/66
CPC分类号： C08J9/30 , C08J2201/032 , C08J2303/00 , D21H17/28 , D21H19/42 , D21H21/56
摘要： A porous, starch-based pigment and filler product, which comprises a foam, which contains foam bubbles, the average size of which is less than approximately 10 micrometres, and a method of manufacturing it. From the starch, microporous foam can be prepared, which can be stabilized to microcapsules. By means of a suitable choice of the inner diameter and the wall thickness of these capsules the light scattering ability of the material is maximized, which means that the structure has good opacity properties. Good strength properties in relation to the capsule mass is also characteristic of the micro capsule structure.
摘要翻译：一种多孔淀粉基颜料和填料产品，其包含泡沫，其泡沫气泡的平均尺寸小于约10微米，以及其制造方法。从淀粉中可以制备微孔泡沫，其可以稳定化成微胶囊。通过适当选择这些胶囊的内径和壁厚，材料的光散射能力最大化，这意味着该结构具有良好的不透明性。与胶囊质量相关的良好的强度性质也是微胶囊结构的特征。

15. 发明申请

US20060128889A1 New starch-based composition and process for the production thereof 失效
标题翻译：新型淀粉基组合物及其制备方法
公开(公告)号：US20060128889A1
公开(公告)日：2006-06-15
申请号：US10532398
申请日：2003-10-24
申请人： Hannu Mikkonen , Kyosti Valta , Eino Sivonen , Soili Peltonen
发明人： Hannu Mikkonen , Kyosti Valta , Eino Sivonen , Soili Peltonen
IPC分类号： C08B31/00
CPC分类号： C08B31/16 , C08B31/00 , C08B31/02 , C08B31/08 , C09J103/04
摘要： A process for manufacturing transglycosylation products. According to the process, a starch derivative is reacted at acidic conditions with an alkanol containing 1-6 hydroxyl groups and the reaction product is recovered as such or it is subjected to further processing. According to the method, the transglycosylation reaction between the starch derivatives and the alkanol is carried out in a reactive extrusion process, whereby the reaction can essentially be performed in the absence of liquid media at high yield. The invention also relates to new transglycosylation products of starch derivative, containing anions derived from a phosphorus-containing acid, which are chemically bonded to the product.
摘要翻译：制造转糖基化产物的方法。根据该方法，淀粉衍生物在酸性条件下与含有1-6个羟基的链烷醇反应，反应产物原样回收或进行进一步处理。根据该方法，淀粉衍生物和链烷醇之间的转糖基化反应是在反应性挤出方法中进行的，其中反应基本上可以在没有液体介质的情况下以高收率进行。本发明还涉及淀粉衍生物的新的转糖基化产物，其含有衍生自含磷酸的阴离子，其与产物化学键合。

16. 发明授权

US08623504B2 Polysaccharide-based pigments and fillers 失效
标题翻译：多糖类颜料和填料
公开(公告)号：US08623504B2
公开(公告)日：2014-01-07
申请号：US13142875
申请日：2009-12-30
申请人： Hannu Mikkonen , Kaisa Putkisto , Soili Peltonen , Sari Hyvärinen , Kimmo Koivunen
发明人： Hannu Mikkonen , Kaisa Putkisto , Soili Peltonen , Sari Hyvärinen , Kimmo Koivunen
IPC分类号： B32B5/16
CPC分类号： D21H17/27 , C08B31/04 , C08L3/06 , D21H17/26 , D21H17/28 , D21H19/42 , D21H19/54
摘要： Particles of a polysaccharide derivative, having at least one substituent with conjugated unsaturated bonds and exhibiting an index of refraction in excess of 1.50 and a method for the production thereof. In the method, the raw-material is suspended in an organic solvent to form a suspension, which is contacted with an organic reactant comprising a residue with conjugated unsaturated bonds; the raw-material and the organic reactant are reacted to form a derivative exhibiting ester or ether bond between the raw-material and the residue with conjugated unsaturated bonds; the polysaccharide derivative is dissolved in a solvent to form a solution; and the solution is contacted with a non-solvent to precipitate particles of the polysaccharide derivative. The invention provides lightweight, optically improved organic pigments and fillers based on renewable resources and which are recyclable by combustion or composting.
摘要翻译：具有至少一个具有共轭不饱和键的取代基并且具有超过1.50的折射率的多糖衍生物的颗粒及其制备方法。在该方法中，将原料悬浮在有机溶剂中以形成悬浮液，其与包含具有共轭不饱和键的残基的有机反应物接触; 使原料和有机反应物反应形成在原料与残留物之间呈现共轭不饱和键的酯或醚键的衍生物; 将多糖衍生物溶解在溶剂中以形成溶液; 并使溶液与非溶剂接触以沉淀多糖衍生物的颗粒。本发明提供了基于可再生资源的轻质，光学改进的有机颜料和填料，其可通过燃烧或堆肥回收。

17. 发明授权

US08597432B2 Starch-based filler and coating pigment composition for fibre webs and method for the manufacture thereof 失效
标题翻译：用于纤维网的淀粉基填料和涂料颜料组合物及其制备方法
公开(公告)号：US08597432B2
公开(公告)日：2013-12-03
申请号：US11990444
申请日：2006-08-17
申请人： Hannu Mikkonen , Mauno Miettinen , Kirsi Kataja , Saija Luukkanen , Soili Peltonen , Pia Qvintus-Leino
发明人： Hannu Mikkonen , Mauno Miettinen , Kirsi Kataja , Saija Luukkanen , Soili Peltonen , Pia Qvintus-Leino
IPC分类号： C08B30/00
CPC分类号： B41M5/5236 , C08J3/12 , C08J2303/06 , C08L3/06 , C09D7/41 , D21H17/28 , D21H19/42
摘要： A material which is suitable as filler or coating pigment for a fibrous web and a method for manufacturing thereof. According to the method, a feed comprising organic polymer material is cooled to at least approximately −50° C., after which it is refined in a jet refiner to a desired particle size. The present invention generates uniform pigment particles which comprise, for instance, starch esters, and which particles have a porous surface structure, in which case they are suitable for instance as coating pigments and fillers for offset and ink-jet papers.
摘要翻译：适合用作纤维网的填料或涂料颜料的材料及其制造方法。根据该方法，将包含有机聚合物材料的进料冷却至至少约-50℃，然后将其在喷射精炼机中精制至所需的粒度。本发明产生均匀的颜料颗粒，其包括例如淀粉酯，并且哪些颗粒具有多孔表面结构，在这种情况下，它们适合用作胶印和喷墨纸的涂料颜料和填料。

18. 发明授权

US08119792B2 Starch derivatives and a method for their preparation 失效
标题翻译：淀粉衍生物及其制备方法
公开(公告)号：US08119792B2
公开(公告)日：2012-02-21
申请号：US10504296
申请日：2003-02-17
申请人： Soili Peltonen , Hannu Mikkonen , Thomas Gädda
发明人： Soili Peltonen , Hannu Mikkonen , Thomas Gädda
IPC分类号： C08B31/02 , C08B31/08
CPC分类号： C09J103/04 , C08B31/006 , C08B31/16
摘要： The invention relates to novel transglycosylation products and their preparation. The transglycosylation products according to the invention are prepared from starch derivatives, such as esters or ethers of starch. The products are obtained by reacting a starch derivative with an alcohol in the presence of an acid catalyst. The forming product is separated by precipitation or by removing any unreacted alcohol by evaporation. In the products according to the invention the good properties of starch derivatives, such as the excellent water resistance of esters, are combined with the versatility of transglycoside products. The products can be used as adhesives, in which case they are formulated, for example as hot-melt adhesives, and as comonomers, prepolymers or macroinitiators in the preparation of polymers.
摘要翻译：本发明涉及新型转糖基化产物及其制备方法。根据本发明的转糖基化产物由淀粉衍生物如淀粉的酯或醚制备。产物通过在酸催化剂存在下使淀粉衍生物与醇反应获得。通过沉淀或通过蒸发除去任何未反应的醇来分离成型产物。在根据本发明的产品中，淀粉衍生物的良好性能，例如酯的优异耐水性与转糖苷产物的通用性相结合。这些产品可以用作粘合剂，在这种情况下，它们被配制成例如热熔粘合剂，以及作为聚合物制备中的共聚单体，预聚物或大分子引发剂。

19. 发明申请

US20110046365A1 CELLULOSE DERIVATIVES, METHOD OF PRODUCING THE SAME AND USE THEREOF 审中-公开
标题翻译：纤维素衍生物，其生产方法及其用途
公开(公告)号：US20110046365A1
公开(公告)日：2011-02-24
申请号：US12919172
申请日：2009-02-25
申请人： Hannu Mikkonen , Soili Peltonen , Aki Laine , Kyösti Valta , Eino Sivonen , Tero Malm , Juha Sarlin
发明人： Hannu Mikkonen , Soili Peltonen , Aki Laine , Kyösti Valta , Eino Sivonen , Tero Malm , Juha Sarlin
IPC分类号： C08B3/08 , C08B3/00 , C08B11/02 , C08B11/08
CPC分类号： C09J101/08 , C08B3/22 , C08B11/20 , C08B15/00
摘要： A transglycosylation product, a method of producing the same and use of the product. The transglycosylation product comprises an alkyl or hydroxyalkyl glycoside of a cellulose ester or ether, wherein the alkyl or hydroxyalkyl groups of the glycoside residue comprise a carbon chain having 1 to 4 carbon atoms, and having 0 to 2 free hydroxyl groups and being attached to the 1-carbon of the anhydroglucose unit via an oxy group. The product can be produced by mixing the cellulose derivative with mono-, di- or triol to form a reaction mixture, after which the reaction mixture is heated and the reaction is continued until a clear mixture is obtained. After cooling the recoverable product is suitable for use for example as an adhesive or as a hydrophobic coating.
摘要翻译：转糖基化产物，其生产方法和产品的用途。转糖基化产物包含纤维素酯或醚的烷基或羟基烷基糖苷，其中糖苷残基的烷基或羟烷基包含具有1至4个碳原子的碳链，并且具有0至2个游离羟基并且连接到脱水葡萄糖单元的1-碳通过氧基。该产物可以通过将纤维素衍生物与一，二或三醇混合以形成反应混合物来制备，之后将反应混合物加热并继续反应直到获得澄清的混合物。冷却后，可回收的产品适用于例如粘合剂或疏水涂层。

20. 发明申请

US20090255441A1 Starch-Based Filler and Coating Pigment Composition for Fibre Webs and Method for the Manufacture Thereof 失效
标题翻译：纤维网的淀粉基填料和涂料颜料组合物及其制造方法
公开(公告)号：US20090255441A1
公开(公告)日：2009-10-15
申请号：US11990444
申请日：2006-08-17
申请人： Hannu Mikkonen , Mauno Miettinen , Kirsi Kataja , Saija Luukkanen , Soili Peltonen , Pia Qvintus-Leino
发明人： Hannu Mikkonen , Mauno Miettinen , Kirsi Kataja , Saija Luukkanen , Soili Peltonen , Pia Qvintus-Leino
IPC分类号： C04B16/08 , C08B31/04
CPC分类号： B41M5/5236 , C08J3/12 , C08J2303/06 , C08L3/06 , C09D7/41 , D21H17/28 , D21H19/42
摘要： A material which is suitable as filler or coating pigment for a fibrous web and a method for manufacturing thereof. According to the method, a feed comprising organic polymer material is cooled to at least approximately −50° C., after which it is refined in a jet refiner to a desired particle size. The present invention generates uniform pigment particles which comprise, for instance, starch esters, and which particles have a porous surface structure, in which case they are suitable for instance as coating pigments and fillers for offset and ink-jet papers.
摘要翻译：适合用作纤维网的填料或涂料颜料的材料及其制造方法。根据该方法，将包含有机聚合物材料的进料冷却至至少约-50℃，然后将其在喷射精炼机中精制至所需的粒度。本发明产生均匀的颜料颗粒，其包括例如淀粉酯，并且哪些颗粒具有多孔表面结构，在这种情况下，它们适合用作胶印和喷墨纸的涂料颜料和填料。

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