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11. 发明专利

CA2606063A1 A HYDROCRACKING CATALYST, ITS PREPARATION AND USE 未知
公开(公告)号：CA2606063A1
公开(公告)日：2006-11-09
申请号：CA2606063
申请日：2006-04-26
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING
发明人： XIONG ZHENLIN , HU ZHIHAI , DONG JIANWEI , NIE HONG , MAO YICHAO , LI DADONG , SHI YAHUA
IPC分类号： B01J31/18 , B01J29/00 , B01J31/04 , C10G45/50
摘要： The present invention provides a kind of hydrocracking catalyst, the catalys t includes a compound support consisting of zeolite molecular sieve and alumin a, at least a metal component of VIII group, at least a metal component of VIB group, and an organic additive. The said organic compound is selected from t he group of oxygen containing or nitrogen containing organic additive. Based on the weight of the catalyst, the content of the zeolite molecular sieve is 3- 60 w%, the content of the alumina is 10-80 w%, the content of the organic additive is 0.1-40 w%. Calculated as the oxide and based on the weight of th e catalyst, the content of the metal component of VIII group is 1-15 w%, the content of the metal component of VIB group is 5-40 w%. The present inventio n also relates to the preparation method of the said catalyst and its use in hydrocracking method of the hydrocarbon oil. Compared with the catalyst provided by the kown technology, the aromatics hydroconverting activity of t he catalyst provided by the present invention has been improved notably.

12. 发明专利

CA2605505C A HYDROGENATION CATALYST AND USE THEREOF 未知
公开(公告)号：CA2605505C
公开(公告)日：2015-06-16
申请号：CA2605505
申请日：2006-04-20
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING
发明人： LONG XIANGYUN , LIU XUEFEN , NIE HONG , WANG KUI , XIN JING , LIU QINGHE , GAO XIAODONG , HU ZHIHAI , SHI YAHUA , LI DADONG
IPC分类号： B01J23/883 , B01J23/888 , B01J27/128 , B01J27/132 , B01J27/185 , B01J27/19 , B01J29/00 , C10G47/04 , C10G47/10
摘要： The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. In another embodiment, the preset invention provides a hydrogenation catalyst, containing a carrier and metal components of nickel, molybdenum and tungsten supported thereon, wherein said carrier contains a molecular sieve. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.

13. 发明专利

FR2864102B1 CATALYSEUR D'HYDROGENATION SELECTIVE D'OLEFINES ET SA PREPARATION AINSI QUE SON UTILISATION 未知
公开(公告)号：FR2864102B1
公开(公告)日：2011-03-04
申请号：FR0413779
申请日：2004-12-22
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING
发明人： LI MINGFENG , CHU YANG , FU YUNJIAN , XIA GUOFU , NIE HONG , SHI YAHUA , LI DADONG
IPC分类号： B01J21/04 , B01J23/04 , B01J23/28 , B01J23/30 , B01J23/85 , B01J23/883 , B01J23/887 , B01J23/888 , B01J37/02 , C07C7/163 , C10G45/38

14. 发明专利

CA2605505A1 A HYDROGENATION CATALYST AND ITS APPLICATION 未知
公开(公告)号：CA2605505A1
公开(公告)日：2006-10-26
申请号：CA2605505
申请日：2006-04-20
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING
发明人： HU ZHIHAI , GAO XIAODONG , LONG XIANGYUN , LIU XUEFEN , NIE HONG , SHI YAHUA , WANG KUI , LI DADONG , LIU QINGHE , XIN JING
IPC分类号： B01J23/883 , B01J23/888 , B01J27/128 , B01J27/132 , B01J27/185 , B01J27/19 , B01J29/00 , C10G47/04 , C10G47/10
摘要： The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.

15. 发明专利

AU2003289799A1 A process for reducing sulfur and olefin contents in gasoline 未知
公开(公告)号：AU2003289799A1
公开(公告)日：2005-07-14
申请号：AU2003289799
申请日：2003-12-23
申请人： RES INST PETROLEUM PROCESSING , CHINA PETROLEUM & CHEMICAL
发明人： LI DADONG , SHI YULIN , HU YUNJIAN , XI YUANBING , LI MINGFENG , SHI YAHUA
IPC分类号： C10G45/02

16. 发明专利

FR2864102A1 Catalyst for selective hydrogenation of olefins, especially dienes, comprises cobalt and/or nickel, molybdenum and/or tungsten and alkali metal on an alumina support 未知
公开(公告)号：FR2864102A1
公开(公告)日：2005-06-24
申请号：FR0413779
申请日：2004-12-22
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING
发明人： LI MINGFENG , CHU YANG , FU YUNJIAN , XIA GUOFU , NIE HONG , SHI YAHUA , LI DADONG
IPC分类号： B01J21/04 , B01J23/04 , B01J23/28 , B01J23/30 , B01J23/85 , B01J23/883 , B01J23/887 , B01J23/888 , B01J37/02 , C07C7/163 , C10G45/38
摘要： Catalyst for selective hydrogenation of olefins comprises 0.5-8 wt.% cobalt and/or nickel, 2-15 wt.% molybdenum and/or tungsten and 2-8 wt.% alkali metal on an alumina support. Independent claims are also included for: (1) selective hydrogenation of a distillate oil to remove olefins by contacting the oil with a catalyst as above under hydrorefining conditions; (2) producing a catalyst as above by contacting the alumina support with a solution containing cobalt and/or nickel, a solution containing molybdenum and/or tungsten and a solution containing alkali metal compounds and drying and calcining the product.

17. 发明公开

EP1142637A4 CATALYST FOR HYDROREFINING DISTILLATE OIL, ITS CARRIER AND PREPARATION THEREOF 有权
标题翻译：催化剂的馏出物的HYDRO改进他的用于生产支持和过程
公开(公告)号：EP1142637A4
公开(公告)日：2004-09-15
申请号：EP00969164
申请日：2000-10-13
申请人： CHINA PETROCHEMICAL CORP , RES INST PETROLEUM PROCESSING
发明人： YANG QINGHE , LIU BIN , NIE HONG , LIU XUEFEN , LI DADONG , SHI YAHUA , ZHUANG FUCHENG
IPC分类号： B01J21/04 , B01J23/85 , B01J27/132 , B01J35/10 , B01J37/02 , B01J37/03 , C10G45/08 , C10G45/04
CPC分类号： B01J23/85 , B01J21/04 , B01J35/0026 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/033 , C10G45/08
摘要： A catalyst for hydrofining fraction oils, comprises an alumina carrier and at least one metal and/or thereof oxide of Group VIB and at least one metal and/or thereof oxide of Group VIII supported on said alumina carrier. The pore volume of said alumina carrier is not less than 0.35 ml/g, in which the pore volume of the pores having a diameter of 40-100 angstrom accounts for more than 80% of the total pore volume, the alumina carrier is prepared by a special process. The catalyst possesses relatively high hydrogenation activity.
摘要翻译：一种用于加氢精制馏分油，氧化铝载体包括与至少一种金属和/或氧化物的第VIB族，以及至少一种金属和/或氧化物催化剂及其VIII族的支撑在所述氧化铝载体上。所述氧化铝载体的孔体积不小于0.35毫升/克，其中具有直径为40-100埃占总孔体积的80％以上的孔的孔体积，所述氧化铝载体通过以下步骤制备以下特殊的工艺。该催化剂具有相对较高的加氢活性。

18. 发明公开

EP0916404A4 A HYDROFINING CATALYST OF A DISTILLATE OIL AND PRODUCTION METHOD 失效
标题翻译： HYDRORAFFINIERKATALYSATOR VON EINEMDISTILLATÖLUND VERFAHREN ZUR HERSTELLUNG
公开(公告)号：EP0916404A4
公开(公告)日：2000-03-22
申请号：EP97928102
申请日：1997-06-27
申请人： CHINA PETROCHEMICAL CORP , RES INST PETROLEUM PROCESSING
发明人： SHI YAHUA , LI DADONG , LIU XUEFEN , NIE HONG , GAO XIAODONG , YING YIBING
IPC分类号： B01J23/888 , B01J27/132 , C10G45/08 , B01J23/755 , B01J21/04
CPC分类号： C10G45/08 , B01J23/888 , B01J27/132
摘要： The present invention discloses a hydrofining catalyst. The catalyst has the following composition based on the total weight of the entire catalyst composition: 1-5 % (wt.) nickel oxide, 12-35 % (wt.) tungsten oxide, 1-9 % (wt.) fluorine, and the balancing amount of composite alumina. Said composite alumina is composed of one or several kinds of micropore alumina and one or several kinds of macropore alumina, wherein the weight ratio of micropore alumina to macropore alumina is 75:25 to 50:50. The term "micropore alumina" in the context means the alumina in which the volume of the pore of diameter less than 80 angstrom occupies more than 95 % of its total pore volume, while the term "macropore alumina" in the context means the alumina in which the volume of the pore of diameter 60-600 angstrom occupies more that 70 % of its total pore volume. The pore distribution mentioned above is determined by BET method of nitrogen adsorption at low temperature. This catalyst is especially suitable for the hydrofining of inferior distillates with high sulfure content and boiling range of 80-550 DEG C.
摘要翻译：本发明公开了一种加氢精制催化剂。基于整个催化剂组合物的总重量，催化剂具有以下组成：1-5％（重量）的氧化镍，12-35％（重量）的氧化钨，1-9％（重量）的氟和复合氧化铝的平衡量。所述复合氧化铝由一种或几种微孔氧化铝和一种或几种大孔氧化铝组成，其中微孔氧化铝与大孔氧化铝的重量比为75:25至50:50。在本文中术语“微孔氧化铝”是指其中直径小于80埃的孔的体积占其总孔体积的95％以上的氧化铝，而术语“大孔氧化铝”在本文中是指氧化铝其中直径60-600埃的孔隙的体积占其总孔隙体积的70％以上。上述孔分布是通过低温下氮吸附的BET法测定的。该催化剂特别适用于加氢精制硫含量高，沸程80-550℃的劣质馏分油

19. 发明公开

EP0913195A4 A HYDROCRACKING CATALYST OF A DISTILLATE OIL AND PRODUCTION METHOD THEREOF 失效
标题翻译：馏分油及其制造方法的加氢裂化及其催化剂
公开(公告)号：EP0913195A4
公开(公告)日：2000-03-22
申请号：EP97928100
申请日：1997-06-27
申请人： CHINA PETROCHEMICAL CORP , RES INST PETROLEUM PROCESSING
发明人： SHI JIANWEN , NIE HONG , SHI YAHUA , SHI YULIN , ZHANG YANPING , LI DADONG
IPC分类号： B01J29/076 , B01J23/888 , B01J27/132 , B01J29/16 , B01J29/26 , B01J29/48 , B01J29/78 , C10G45/12 , C10G47/18 , B01J29/08 , B01J29/06 , C10G45/08 , C10G47/20
CPC分类号： C10G47/18 , B01J23/888 , B01J27/132
摘要： The present invention relates to a hydrocracking catalyst containing nickel, tungsten, fluorine, zeolite as well as alumina. Said catalyst is composed of, based on the total weight of the catalyst, 0.5-5.0 wt.% fluorine, 2.5-6.0 wt.% nickel oxide, 10-38 wt.% tungsten oxide, and a catalyst carrier. Said carrier is composed of 20-90 wt.% alumina and 10-80 wt.% zeolite wherein the zeolite is mesopore or macropore zeolite of an acidity strength value 1.0-2.0 mmol/g determined by NH3-TPD, the alumina is the alumina of an acidity strength value 0.5-0.8 mmol/g determined by NH3-TPD. Said catalyst possesses good desulfurization activity, denitrogenation activity, and higher selectivity with respect to middle distillates than that of the prior art.

20. 发明专利

HRP970355B1 A HYDROCRACKING CATALYST OF A DISTILLATE OIL AND PRODUCTION METHOD THEREOF 未知
公开(公告)号：HRP970355B1
公开(公告)日：2004-12-31
申请号：HRP970355
申请日：1997-06-27
申请人： CHINA PETROCHEMICAL CORP , RES INST PETROLEUM PROCESSING
发明人： SHI JIANWEN , NIE HONG , SHI YAHUA , SHI YULIN , ZHANG YANPING , LI DADONG
IPC分类号： B01J29/076 , B01J23/888 , B01J27/132 , B01J29/16 , B01J29/26 , B01J29/48 , B01J29/78 , C10G45/12 , C10G47/18 , B01J29/08 , C10G45/08 , B01J29/06 , C10G47/20
摘要： The present invention relates to a hydrocracking catalyst containing nickel, tungsten, fluorine, zeolite as well as alumina, said catalyst is composed of, based on the total weight of the catalyst, 0.5-5.0wt% fluorine, 2.5-6.0wt% nickel oxide, 10-38wt% tungsten oxide, and a catalyst carrier. Said carrier is composed of 20-90wt% alumina and 10-80wt% zeolite wherein the zeolite is mesopore or macropore zeolite of an acidity strength value 1.0-2.0mmol/g determined by NH3-TPD, the alumina is the alumina of an acidity strength value 0.5-0.8mmol/g determined by NH3-TPD. Said catalyst possesses good desulfurization activity, denitrogenation activity, and higher selectivity with respect to middle distillates than that of the prior art.

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