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    • 14. 发明授权
    • Manufacture of shear-resistant aqueous copolymer emulsions
    • 抗剪水性共聚物乳液的制造
    • US4051093A
    • 1977-09-27
    • US626749
    • 1975-10-29
    • Kurt WendelFritz ReichelChristof Taubitz
    • Kurt WendelFritz ReichelChristof Taubitz
    • C08F212/08C08F220/12C08F220/44D21H17/42D21H17/43D21H17/45C08L25/04C08L33/02
    • D21H17/43C08F212/08C08F220/12C08F220/44D21H17/42D21H17/45D21H17/455
    • Shear-resistant aqueous copolymer emulsions which can be used for sizing paper are manufactured by first copolymerizing, in the aqueous phase of an aqueous emulsion, using conventional polymerization initiators which form free radicals, (A) from 0.5 to 15 per cent by weight of monomers containing a polymerizable C.dbd.C bond and at least one carboxyl and/or sulfonic acid or phosphate or phosphite group with (B) from 5 to 30 per cent by weight of monomers containing a C.dbd.C bond and a tertiary or quaternary amino group, or a nitrogen-containing heterocyclic group, and then adding, while continuing the copolymerization, (C) from 0 to 94.5 per cent by weight of styrene and/or acrylonitrile and (D) from 0 to 94.5 per cent by weight of acrylic or methacrylic acid esters of alkanols of 1 to 8 carbon atoms as well as (E) from 0 to 30 per cent by weight of further olefinically unsaturated monomers, and completing the polymerization, the pH during the polymerization being less than 7 and the amount of monomers (C) and (D) together being at least 25 per cent by weight.
    • 可以用于上浆纸的抗剪切水性共聚物乳液通过首先在水性乳液的水相中使用常规的形成自由基的聚合引发剂共聚制备(A)0.5至15重量%的单体 含有可聚合的C = C键和至少一个羧酸和/或磺酸或磷酸酯或亚磷酸酯基团与(B)5-30重量%的含有C = C键和叔或季氨基的单体, 或含氮杂环基,然后在继续共聚的同时加入(C)0至94.5重量%的苯乙烯和/或丙烯腈,和(D)0至94.5重量%的丙烯酸或甲基丙烯酸 1至8个碳原子的链烷醇的酸酯以及(E)0-30重量%的其它烯属不饱和单体,并且完成聚合,聚合期间的pH小于7, f单体(C)和(D)一起为至少25重量%。