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    • 11. 发明公开
    • PHOTO-LATENT TITANIUM-OXO-CHELATE CATALYSTS
    • PHOTOLATENTE TITAN-OXO-CHELAT-KATALYSATOREN
    • EP2694211A1
    • 2014-02-12
    • EP12713685.1
    • 2012-04-02
    • BASF SE
    • HINTERMANN, TobiasCARROY, AntoineLORDELOT, CarolineBAUER, DidierKOHLI STECK, RachelFALLER, Marc
    • B01J31/02B01J31/22C08G18/22
    • C09D175/16B01J31/0208B01J31/2234B01J2231/14B01J2231/48B01J2531/46C08G18/222C08G18/6229C08G18/68C08G18/792C09J175/04Y02P20/52
    • A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.
    • 一种钛 - 氧代 - 螯合催化剂制剂,其包含:(i)至少一种式(I)化合物,其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10,R 11和R 12独立地 彼此是例如氢,卤素,未取代或取代的C 1 -C 20烷基,C 6 -C 14芳基; 或R 1,R 2和R 3和/或R 4,R 5和R 6和/或R 7,R 8和R 9和/或R 10,R 11和R 12与它们所连接的C原子一起形成C 6 -C 14芳基, 未取代或取代的; 或R 1和R 2和/或R 4和R 5和/或R 7和R 8和/或R 10和R 11与它们所连接的C原子一起形成5-至7-元碳环; 至少一种式(IIa),(IIb)或(IIc)的螯合配体化合物,其中R 1,R 2,R 3,R 4,R 5和R 6如上文对式(I)所定义,适合作为用于 能够在路易斯酸存在下交联的聚合化合物。