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11. 发明授权

US4985403A Use of adamantane derivatives in augmenting or enhancing the aroma of consumable materials 失效
标题翻译：使用金刚烷衍生物增强或增强消耗材料的香气
公开(公告)号：US4985403A
公开(公告)日：1991-01-15
申请号：US545623
申请日：1990-06-29
申请人： Anubhav P. S. Narula , Charles E. J. Beck , Marie R. Hanna
发明人： Anubhav P. S. Narula , Charles E. J. Beck , Marie R. Hanna
IPC分类号： A24B15/34 , C07C35/37 , C07C43/18 , C07C43/188 , C07C43/196 , C07C45/49 , C07C45/50 , C07C45/75 , C07C47/267 , C07C49/453 , C07C49/653 , C07C69/00 , C07D311/00 , C11B9/00
CPC分类号： C07D311/00 , A24B15/345 , C07C35/37 , C07C43/18 , C07C43/188 , C07C43/196 , C07C45/49 , C07C45/50 , C07C45/75 , C07C47/267 , C07C49/453 , C07C49/653 , C07C67/08 , C07C69/00 , C07C69/07 , C11B9/0042 , C07C2103/00 , C07C2103/74
摘要： Described are adamantane derivatives defined according to the structure: ##STR1## wherein R.sub.1 is hydrogen or acetyl; R.sub.2 is hydrogen or methyl; and R.sub.3 is hydrogen or methylene (CH.sub.2) and wherein the dashed line represents a carbon-hydrogen single bond or a carbon-methylene double bond with the provisos that when R.sub.2 is methyl R.sub.1 and R.sub.3 are both hydrogen and when R.sub.2 is hydrogen, R.sub.3 is methylene and the dashed line is a carbon-methylene double bond and uses thereof in augmenting or enhancing the aroma of consumable materials selected from the group consisting of perfume compositions, colognes and perfumed articles.
摘要翻译：描述了根据以下结构定义的金刚烷衍生物：其中R 1是氢或乙酰基; R2是氢或甲基; 且R 3为氢或亚甲基（CH 2），并且其中虚线表示碳 - 氢单键或碳 - 亚甲基双键，条件是当R 2为甲基R 1且R 3均为氢时，并且当R 2为氢时，R 3为亚甲基，虚线是碳 - 亚甲基双键，并用于增强或增强选自香水组合物，古龙水和香料制品的消耗材料的香气。

12. 发明授权

US06906013B1 Cyclohexanbutanol derivative and fragrance use thereof 有权
标题翻译：环己烷丁醇衍生物及其香料用途
公开(公告)号：US06906013B1
公开(公告)日：2005-06-14
申请号：US10873566
申请日：2004-06-22
申请人： Anubhav P. S. Narula , Patrick M. Merritt , Richard Anthony Weiss , Charles E. J. Beck
发明人： Anubhav P. S. Narula , Patrick M. Merritt , Richard Anthony Weiss , Charles E. J. Beck
IPC分类号： C07C31/27 , C07C35/14 , C11B9/00 , C11D3/20 , C11D3/50 , A61K7/46
CPC分类号： C11B9/0034 , C07C31/276 , C07C2601/14 , C11D3/2051 , C11D3/50
摘要： The novel compound, cyclohexanbutanol, 4-(hydroxymethyl)-alpha, alpha-dimethyl- having the structure: and the use of the compound in creating fragrances, and scents in items such as perfumes, colognes and personal care products is disclosed.
摘要翻译：公开了具有以下结构的新型化合物环己烷丁醇4-（羟甲基）-α-二甲基 - 和该化合物在制备香料中的用途以及香料，古龙水和个人护理产品中的香料。

13. 发明授权

US07160852B2 Polyalklbicylic derivatives 有权
标题翻译：聚烷基胆碱衍生物
公开(公告)号：US07160852B2
公开(公告)日：2007-01-09
申请号：US10635954
申请日：2003-08-07
申请人： Anthony T. Levorse, Jr. , Anubhav P. S. Narula , Edward Mark Arruda , Charles E. J. Beck
发明人： Anthony T. Levorse, Jr. , Anubhav P. S. Narula , Edward Mark Arruda , Charles E. J. Beck
IPC分类号： A61Q13/00 , C11B9/00
CPC分类号： C07D307/92 , C07C45/68 , C07C45/71 , C07C49/477 , C07C49/653 , C07D307/93
摘要： The compound according to the formula set forth below and the use of the compound in creating fragrances, and scents in items such as perfumes, colognes and personal care products is disclosed.
摘要翻译：公开了根据以下公式所述的化合物以及该化合物在制备香料中的用途以及香料，古龙水和个人护理产品中的香料。

14. 发明授权

US06608010B2 Bicyclic lactones, perfumery uses thereof, processes for preparing same and intermediates therefor 有权
标题翻译：双环内酯，其香料用途，其制备方法及其中间体
公开(公告)号：US06608010B2
公开(公告)日：2003-08-19
申请号：US10210386
申请日：2002-08-01
申请人： Richard A. Weiss , Mark A. Sprecker , Marie R. Hanna , Charles E. J. Beck , Harold W. Jackson
发明人： Richard A. Weiss , Mark A. Sprecker , Marie R. Hanna , Charles E. J. Beck , Harold W. Jackson
IPC分类号： C11D350
CPC分类号： A61K8/498 , A61L9/01 , A61L9/012 , A61Q13/00 , C07D311/02 , C07D311/74 , C11B9/008 , C11D3/2096 , C11D3/50
摘要： Described are bicyclic lactones, both fused ring lactones defined according to the generic structure: and spiro lactones defined according to the generic structure: uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, perfumed articles, colognes and perfumed polymers; processes for preparing such bicyclic lactones and intermediates therefor. In the structure: Z is one of the moieties: one of R1 or R3 is methyl and the other is hydrogen; and R4, R5, R6, R7, R8 and R9 are hydrogen or nonadjacent C1-C3 alkyl. In the structure: Y represents C2-C12 substituted or unsubstituted alkylidenyl, alkenylidenyl or alkadienylidenyl having the structure: and completes a C5-C15 cycloalkyl, cycloalkadienyl or cycloalkenyl ring moiety; and wherein R12, R13, R14, R16, R17, R28, R29, R30 and R31 represent hydrogen or C1-C3 nonadjacent alkyl; wherein s is an integer of from 0 up to 10; t is an integer of from 0 up to 10; and v is an integer of 1 or 2; with the proviso that the sum of s and t is between 0 and 10 according to the inequalities: 0≦s+t≦10; 0≦s≦10; and 0≦t≦10.
摘要翻译：描述的是双环内酯，根据通用结构定义的稠环内酯和根据通用结构定义的螺内酯：用于增强，增强或赋予香料组合物，香料制品，古龙水和加香聚合物中的香气; 制备这种双环内酯的方法及其中间体。在结构中：Z是部分之一：R 1或R 3中的一个是甲基，另一个是氢; 且R 4，R 5，R 6，R 7，R 8和R 9为氢或不相邻的C 1 -C 3烷基。在结构中：Y表示具有以下结构的C 2 -C 12取代或未取代的亚烷基，亚烯基或链二烯基;并且完成C 5 -C 15环烷基，环链二烯基或环烯基环部分; 并且其中R12，R13，R14，R16，R17，R28，R29，R30和R31表示氢或C1-C3不相邻的烷基; 其中s为0至10的整数; t是0到10的整数; v为1或2的整数; 条件是根据不等式，s和t之和在0和10之间：0 <= s + t <= 10; 0 <= s <= 10; 0 <= t <= 10。

15. 发明授权

US4956481A Adamantane derivatives, compositions of matter containing same, processes for preparing said adamantane derivatives and said compositions, and organoleptic and deodorancy uses of said adamantane derivatives and said compositions 失效
标题翻译：金刚烷衍生物，含有其的物质组合物，制备所述金刚烷衍生物和所述组合物的方法，以及所述金刚烷衍生物和所述组合物的感官和除臭用途
公开(公告)号：US4956481A
公开(公告)日：1990-09-11
申请号：US261275
申请日：1988-10-21
申请人： William Gillaspey , Myrna L. Hagedorn , Marie R. Hanna , Kathleen E. Boardwick , Charles E. J. Beck , Futoshi Fujioka , Anthony G. Branco , Anubhav Narula , Richard M. Boden
发明人： William Gillaspey , Myrna L. Hagedorn , Marie R. Hanna , Kathleen E. Boardwick , Charles E. J. Beck , Futoshi Fujioka , Anthony G. Branco , Anubhav Narula , Richard M. Boden
IPC分类号： A24B15/34 , C07C35/37 , C07C43/18 , C07C43/188 , C07C43/196 , C07C45/49 , C07C45/50 , C07C45/75 , C07C47/267 , C07C49/453 , C07C49/653 , C07C69/00 , C07D311/00 , C11B9/00
CPC分类号： C07D311/00 , A24B15/345 , C07C35/37 , C07C43/18 , C07C43/188 , C07C43/196 , C07C45/49 , C07C45/50 , C07C45/75 , C07C47/267 , C07C49/453 , C07C49/653 , C07C67/08 , C07C69/00 , C07C69/07 , C11B9/0042 , C07C2103/00 , C07C2103/74
摘要： Described are hydroxy adamantane compounds and derivatives thereof and a process for preparing same.
摘要翻译：描述的是羟基金刚烷化合物及其衍生物及其制备方法。

16. 发明授权

US5097046A Process for preparing alkyl substituted tetra- or hexahydrobenzopyran derivatives 失效
标题翻译：制备烷基取代的四或六氢苯并吡喃衍生物的方法
公开(公告)号：US5097046A
公开(公告)日：1992-03-17
申请号：US642867
申请日：1991-01-18
申请人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna , Charles E. J. Beck , Salvatore M. Brucato
发明人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna , Charles E. J. Beck , Salvatore M. Brucato
IPC分类号： C07D311/74 , C07D311/94 , C11B9/00 , C11D3/50
CPC分类号： C07D311/74 , C07D311/94 , C11B9/008 , C11D3/50
摘要： Described are alkyl-substituted tetra- or hexahydrobenzopyran derivatives defined according to one of the generic structures: ##STR1## wherein Z is a moiety in the alternative either ##STR2## wherein in the moiety having the structure: ##STR3## R' is methyl or ethyl and in the moiety having the structure: ##STR4## one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines represent carbon-carbon single bonds; wherein R.sub.1 and R.sub.2 taken separately represent hydrogen or C.sub.1 -C.sub.3 lower alkyl (with the proviso that R.sub.1 and R.sub.2 are not both hydrogen) or R.sub.1 and R.sub.2 taken together complete a C.sub.5 or C.sub.6 cycloalkyl moiety; and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, cosmetic powders and perfumed polymers. Also described are synthesis processes for preparing such alkyl-substituted tetra- or hexahydrobenzopyran derivatives by means of reacting isopulegol or an isomer thereof with an acetal or ketal.
摘要翻译：描述了根据以下通用结构之一定义的烷基取代的四或六氢苯并吡喃衍生物：其中Z是可选择的部分或其中的“IMAGE”或“IMAGE”，其中在具有以下结构的部分中： R'是甲基或乙基，并且在具有以下结构的部分中：虚线之一是碳 - 碳双键，虚线中的每一个代表碳 - 碳单键; 其中R1和R2分别代表氢或C1-C3低级烷基（前提是R1和R2不同时为氢）或R1和R2一起形成C5或C6环烷基部分; 包括但不限于固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，毛发制品，化妆粉和加香聚合物的香料组合物，古龙水和香料制品的香气。。还描述了通过异丙醇或其异构体与缩醛或缩酮反应制备这种烷基取代的四或六氢苯并吡喃衍生物的合成方法。

17. 发明授权

US5030618A Alkyl-substituted tetra- or hexahydrobenzopyran derivatives, organoleptic uses thereof and process for preparing same 失效
标题翻译：烷基取代的四或六氢苯并吡喃衍生物，其感官用途及其制备方法
公开(公告)号：US5030618A
公开(公告)日：1991-07-09
申请号：US545625
申请日：1990-06-29
申请人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna , Charles E. J. Beck , Salvatore M. Brucato
发明人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna , Charles E. J. Beck , Salvatore M. Brucato
IPC分类号： C07D311/74 , C07D311/94 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07D311/74 , C07D311/94 , C11B9/008
摘要： Described are alkyl-substituted tetra- or hexahydrobenzopyran derivatives defined according to one of the generic structures: ##STR1## wherein Z is a moiety in the alternative either ##STR2## wherein in the moiety having the structure: ##STR3## R' is methyl or ethyl and in the moiety having the structure: ##STR4## one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines represent carbon-carbon single bonds; wherein R.sub.1 and R.sub.2 taken separately represent hydrogen or C.sub.1 -C.sub.3 lower alkyl (with the proviso that R.sub.1 and R.sub.2 are not both hydrogen) or R.sub.1 and R.sub.2 taken together complete a C.sub.5 or C.sub.6 cycloalkyl moiety; and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, cosmetic powders and perfumed polymers. Also described are synthesis processes for preparing such alkyl-substituted tetra- or hexahydrobenzopyran derivatives by means of reacting isopulegol or an isomer thereof with an acetal or ketal.
摘要翻译：描述了根据以下通用结构之一定义的烷基取代的四或六氢苯并吡喃衍生物：其中Z是可选择的部分或其中的“IMAGE”或“IMAGE”，其中在具有以下结构的部分中： R'是甲基或乙基，并且在具有以下结构的部分中：虚线之一是碳 - 碳双键，虚线中的每一个代表碳 - 碳单键; 其中R1和R2分别代表氢或C1-C3低级烷基（前提是R1和R2不同时为氢）或R1和R2一起形成C5或C6环烷基部分; 包括但不限于固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，毛发制品，化妆粉和加香聚合物的香料组合物，古龙水和香料制品的香气。。还描述了通过异丙醇或其异构体与缩醛或缩酮反应制备这种烷基取代的四或六氢苯并吡喃衍生物的合成方法。

18. 发明授权

US07169747B2 Bicyclic lactones, perfumery uses thereof, processes for preparing same and intermediates therefor 有权
标题翻译：双环内酯，其香料用途，其制备方法及其中间体
公开(公告)号：US07169747B2
公开(公告)日：2007-01-30
申请号：US10705786
申请日：2003-11-10
申请人： Richard A. Weiss , Mark A. Sprecker , Marie R. Hanna , Charles E. J. Beck , Harold W. Jackson
发明人： Richard A. Weiss , Mark A. Sprecker , Marie R. Hanna , Charles E. J. Beck , Harold W. Jackson
IPC分类号： A61K7/46
CPC分类号： A61K8/498 , A61L9/01 , A61L9/012 , A61Q13/00 , C07D311/02 , C07D311/74 , C11B9/008 , C11D3/2096 , C11D3/50
摘要： Described are bicyclic lactones, both fused ring lactones defined according to the generic structure: and spiro lactones defined according to the generic structure: uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, perfumed articles, colognes and perfumed polymers; processes for preparing such bicyclic lactones and intermediates therefor. In the structure: Z is one of the moieties: one of R1 or R3 is methyl and the other is hydrogen; and R4, R5, R6, R7, R8 and R9 hydrogen or nonadjacent C1–C3 alkyl. In the structure: Y represents C2–C12 substituted or unsubstituted alkylidenyl, alkenylidenyl or alkadienylidenyl having the structure: and completes a C5–C15 cycloalkyl, cycloalkadienyl or cycloalkenyl ring moiety; and wherein R12, R13, R14, R16, R17, R28, R29, R30 and R31 represent hydrogen or C1–C3 nonadjacent alkyl; wherein s is an integer of from 0 up to 10; t is an integer of from 0 up to 10; and v is an integer of 1 or 2; with the proviso that the sum of s and t is between 0 and 10 according to the inequalities: 0≦s+t≦10; 0≦S≦10; and 0≦t≦10.
摘要翻译：描述的是双环内酯，根据通用结构定义的稠环内酯和根据通用结构定义的螺内酯：用于增强，增强或赋予香料组合物，香料制品，古龙水和加香聚合物中的香气; 制备此类双环内酯的方法及其中间体。在结构中：Z是部分之一：R 1或R 3中的一个是甲基，另一个是氢; 和R 4，R 5，R 6，R 7，R 8，和R 9的氢或不相邻的C 1 -C 3烷基。在结构中：Y表示具有以下结构的取代或未取代的亚烷基，亚烯基或链二烯基的取代或未取代的C 1 -C 12 - C 15环烷基，环链二烯基或环烯基环部分; 并且其中R 12，R 13，R 14，R 16，R 17， >，R 28，R 29，R 30和R 31表示氢或C 1〜 N 3 -C 3不相邻的烷基; 其中s为0至10的整数; t是0到10的整数; v为1或2的整数; 条件是根据不等式，s和t之和在0和10之间：0 <= s + t <= 10; 0 <= S <= 10; 0 <= t <= 10。

19. 发明授权

US06310032B1 &agr;-Oxygen-substituted cyclohexane propionitriles, perfumery uses thereof and processes for preparing same 有权
标题翻译： α-氧代取代的环己烷丙腈，其香料用途及其制备方法
公开(公告)号：US06310032B1
公开(公告)日：2001-10-30
申请号：US09517603
申请日：2000-03-02
申请人： Mark A. Sprecker , Richard A. Weiss , Marie R. Hanna , Charles E. J. Beck
发明人： Mark A. Sprecker , Richard A. Weiss , Marie R. Hanna , Charles E. J. Beck
IPC分类号： A61K746
CPC分类号： C11B9/0061 , C11B9/0034
摘要： Described are &agr;-oxygen-substituted cyclohexane propionitriles having the structure: wherein R20 and R21 are the same or different C1-C3 lower alkoxy; or wherein R20 is hydrogen and R21 is hydroxy, C1-C3 lower alkoxy or C1-C3 lower acyloxy; and wherein R1, R2, R3, R4, R5, R6 and R7 are the same or different hydrogen or C1-C4 lower alkyl, and uses thereof for their organoleptic properties in augmenting or enhancing or imparting aromas in or to perfume compositions, colognes, microporous polymers or perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair care compositions and the like.
摘要翻译：描述的是具有以下结构的α-氧取代的环己烷丙腈：其中R20和R21是相同或不同的C1-C3低级烷氧基; 或其中R 20是氢，R 21是羟基，C 1 -C 3低级烷氧基或C 1 -C 3低级酰氧基; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7是相同或不同的氢或C 1 -C 4低级烷基，以及其用于增强或增强或赋予香料组合物或香水组合物中的香气的感官特性，包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂的微孔聚合物或加香制品，织物柔软剂组合物，织物柔软剂制品，护发组合物等。

20. 发明授权

US5389608A 1-phenyl-1-cyano-C.sub.5 -C.sub.7 alkanes, organoleptic uses thereof and process for preparing same 失效
标题翻译： 1-苯基-1-氰基-C 5 -C 7烷烃，其感官用途及其制备方法
公开(公告)号：US5389608A
公开(公告)日：1995-02-14
申请号：US241725
申请日：1994-05-12
申请人： Anthony T. Levorse , Marie R. Hanna , Charles E. J. Beck , Kathleen E. Boardwick
发明人： Anthony T. Levorse , Marie R. Hanna , Charles E. J. Beck , Kathleen E. Boardwick
IPC分类号： C07C255/33 , C07C255/34 , C07C255/37 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0065 , C07C255/33 , C07C255/34 , C07C255/37
摘要： Described are 1-phenyl-1-cyano-C.sub.5 -C.sub.7 alkanes defined according to the structure: ##STR1## wherein R.sub.1 and R.sub.2 each represents hydrogen or methoxy with the proviso that when R.sub.1 is methoxy, R.sub.2 is hydrogen and when R.sub.2 is methoxy, R.sub.1 is hydrogen; and wherein X is C.sub.3 -C.sub.5 straight chain or branched chain alkylene and uses thereof in augmenting, enhancing or modifying perfume compositions, perfumed articles and colognes. Also described is a process for preparing such 1-phenyl-1-cyano-C.sub.5 -C.sub.7 alkanes by means of reacting benzyl cyanide with an aldehyde or ketone and then hydrogenating the resulting product using a supported palladium catalyst.
摘要翻译：描述根据以下结构定义的1-苯基-1-氰基-C 5 -C 7烷烃：其中R 1和R 2各自表示氢或甲氧基，条件是当R 1是甲氧基时，R 2是氢，当R 2是甲氧基时， R1是氢; 并且其中X是C 3 -C 5直链或支链亚烷基及其用于增强，增强或改性香料组合物，香料制品和古龙水的用途。还描述了通过使苄基氰与醛或酮反应制备这种1-苯基-1-氰基-C 5 -C 7烷烃，然后使用负载的钯催化剂氢化所得产物的方法。

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