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11. 发明授权

US07560056B2 Photochromic contact lenses and methods of manufacturing 有权
标题翻译：光致变色隐形眼镜及制造方法
公开(公告)号：US07560056B2
公开(公告)日：2009-07-14
申请号：US12027522
申请日：2008-02-07
申请人： Barry Van Gemert , Anil Kumar , Frank P. Mallak , Robert W. Walters
发明人： Barry Van Gemert , Anil Kumar , Frank P. Mallak , Robert W. Walters
IPC分类号： G02C7/10 , B29D11/00
CPC分类号： B29D11/00048 , B29D11/00317 , B29D11/00653
摘要： Described are contact lenses having photochromic materials within the central or pupillary area of the lens and methods for manufacturing such lenses. In one method, a photochromic amount of at least one photochromic material is added to the pupillary region of a casting mold containing a polymerizable monomer that can be at least partially cured before and/or after the addition. Another method involves providing an amount of polymerizable photochromic monomer for the pupillary region and an amount of polymerizable non-photochromic monomer for the remainder of the contact lens in a casting mold. The photochromic and non-photochromic monomers can differ by their degree of polymerization, viscosity and/or density.
摘要翻译：描述了在透镜的中心或瞳孔区域内具有光致变色材料的隐形眼镜及其制造方法。在一种方法中，将光致变色量的至少一种光致变色材料添加到含有可聚合单体的铸模的瞳孔区域中，该可聚合单体可以在添加之前和/或之后至少部分固化。另一种方法包括提供一定量的用于瞳孔区域的可聚合光致变色单体和一定量的用于在模具中的隐形眼镜的其余部分的可聚合的非光致变色单体。光致变色和非光致变色单体可以通过其聚合度，粘度和/或密度而不同。

12. 发明申请

US20080125512A1 PHOTOCHROMIC CONTACT LENSES AND METHODS OF MANUFACTURING 有权
标题翻译：光敏接触镜片及其制造方法
公开(公告)号：US20080125512A1
公开(公告)日：2008-05-29
申请号：US12027522
申请日：2008-02-07
申请人： Barry Van Gemert , Anil Kumar , Frank P. Mallak , Robert W. Walters
发明人： Barry Van Gemert , Anil Kumar , Frank P. Mallak , Robert W. Walters
IPC分类号： G02C7/04 , B29D11/02
CPC分类号： B29D11/00048 , B29D11/00317 , B29D11/00653
摘要： Described are contact lenses having photochromic materials within the central or pupillary area of the lens and methods for manufacturing such lenses. In one method, a photochromic amount of at least one photochromic material is added to the pupillary region of a casting mold containing a polymerizable monomer that can be at least partially cured before and/or after the addition. Another method involves providing an amount of polymerizable photochromic monomer for the pupillary region and an amount of polymerizable non-photochromic monomer for the remainder of the contact lens in a casting mold. The photochromic and non-photochromic monomers can differ by their degree of polymerization, viscosity and/or density.
摘要翻译：描述了在透镜的中心或瞳孔区域内具有光致变色材料的隐形眼镜及其制造方法。在一种方法中，将光致变色量的至少一种光致变色材料添加到含有可聚合单体的铸模的瞳孔区域中，该可聚合单体可以在添加之前和/或之后至少部分固化。另一种方法包括提供一定量的用于瞳孔区域的可聚合光致变色单体和一定量的用于在模具中的隐形眼镜的其余部分的可聚合的非光致变色单体。光致变色和非光致变色单体可以通过其聚合度，粘度和/或密度而不同。

13. 发明授权

US07094368B2 Pyrano-quinolines, pyrano-quinolinones, combinations thereof, photochromic compositions and articles 失效
标题翻译：吡喹啉，吡喃 - 喹啉酮，其组合，光致变色组合物和制品
公开(公告)号：US07094368B2
公开(公告)日：2006-08-22
申请号：US10732008
申请日：2003-12-10
申请人： Beon-Kyu Kim , Anil Kumar , Barry Van Gemert
发明人： Beon-Kyu Kim , Anil Kumar , Barry Van Gemert
IPC分类号： G02B5/23 , C08K5/1545 , G02C7/10
CPC分类号： C07D491/04
摘要： Described are compositions of at least one material represented by a pyrano[3,2-c]quinoline structure, a pyrano[3,2-c]quinolinone structure or mixtures thereof. The pyrano[3,2-c]quinoline structure is characterized by having a nitrogen atom at the 6-position ring atom and an oxy-substituent at the 5-position ring atom. The pyrano[3,2-c]quinolinone structure is characterized by having a substituted nitrogen atom at the 6-position ring atom and an oxo-substituent at the 5-position ring atom, the nitrogen atom substituents being hydrogen, aliphatic substituents, cycloaliphatic substituents, aromatic substituents, heteroaromatic substituents or a combination thereof. Both of the pyrano[3,2-c]quinoline and pyrano[3,2-c]quinolinone structures are characterized by having two substituents at the 2-position ring atom. Also described are photochromic articles that contain or that have coatings or films containing at least one of the novel compositions or combinations thereof with other photochromic materials.
摘要翻译：描述了由吡喃并[3,2-c]喹啉结构，吡喃并[3,2-c]喹啉酮结构或其混合物表示的至少一种材料的组合物。吡喃并[3,2-c]喹啉结构的特征在于在6-位环原子上具有氮原子和在5位环原子上具有氧取代基。吡喃并[3,2-c]喹啉酮结构的特征在于在6位环原子上具有取代的氮原子，在5位环原子上具有氧代取代基，氮原子取代基为氢，脂族取代基，脂环族取代基，芳族取代基，杂芳族取代基或其组合。吡喃并[3,2-c]喹啉和吡喃并[3,2-c]喹啉酮结构的特征在于在2-位环原子上具有两个取代基。还描述了含有或具有包含至少一种新组合物或其组合与其它光致变色材料的涂层或膜的光致变色制品。

14. 发明授权

US5658500A Substituted naphthopyrans 失效
标题翻译：取代萘并吡喃
公开(公告)号：US5658500A
公开(公告)日：1997-08-19
申请号：US490188
申请日：1995-06-14
申请人： Anil Kumar , David B. Knowles , Barry Van Gemert
发明人： Anil Kumar , David B. Knowles , Barry Van Gemert
IPC分类号： C07D311/94 , C07D405/04 , G02B5/23 , C08K5/15 , C07D311/78 , C07D405/02
CPC分类号： C07D405/04 , C07D311/94 , G02B5/23
摘要： Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho-portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
摘要翻译：描述了新的可逆光致变色的2H-萘并[1,2-b]吡喃化合物，其实例是在萘并吡喃的萘酚部分的5个碳原子上具有某些取代基的化合物和在吡喃环的2位上。某些取代基也可以存在于萘并吡喃的萘酚部分的6,7,8,9或10个碳原子上。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（二氢吲哚）型化合物的引入新的萘并吡喃化合物或其组合与互补的光致变色化合物的眼用透镜或其它塑料透明胶片制成的物品。

15. 发明授权

US5466398A Photochromic substituted naphthopyran compounds 失效
标题翻译：光致变色取代萘并吡喃化合物
公开(公告)号：US5466398A
公开(公告)日：1995-11-14
申请号：US80246
申请日：1993-06-21
申请人： Barry Van Gemert , Anil Kumar
发明人： Barry Van Gemert , Anil Kumar
IPC分类号： G02C7/10 , C07D311/92 , C07D311/96 , C07D405/04 , C07D407/04 , C07D409/04 , C08K5/10 , C08K5/1545 , C08L25/00 , C08L33/04 , C08L67/00 , C08L67/02 , C08L75/00 , C08L75/04 , C08L101/00 , C09K9/02 , C09K11/06 , G02B1/04 , G02B5/23 , G02B27/00
CPC分类号： G02B5/23 , C07D311/92
摘要： Described are novel reversible photochromic 3H-naphtho[2,1-b]pyran compounds, of the following graphic formula: ##STR1## wherein R.sub.1 is hydrogen or alkyl, R.sub.2 is hydrogen or preferably a carboalkoxy group and R.sub.3 is hydrogen or preferably an alkyl group, provided that either R.sub.1 or R.sub.2 is hydrogen, and B and B' are the aryl groups phenyl or naphthyl, a heterocyclic aromatic group or together form a spiro adamantylene group. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(oxazine) type compounds, are also described.
摘要翻译：描述了新颖的可逆光致变色的3H-萘并[2,1-b]吡喃化合物，其具有下列结构式：其中R 1是氢或烷基，R 2是氢或优选烷氧基，R 3是氢或优选烷基基团，其中R 1或R 2为氢，B和B'为芳基苯基或萘基，杂环芳基或一起形成螺金刚烷基。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（恶嗪）型化合物引入新颖的萘并吡喃化合物或其组合与互补的光致变色化合物，例如螺（恶嗪）类化合物的眼用透镜或其它塑料透明胶片的物品。

16. 发明授权

US5651923A Substituted naphthopyrans 失效
标题翻译：取代萘并吡喃
公开(公告)号：US5651923A
公开(公告)日：1997-07-29
申请号：US571000
申请日：1995-12-12
申请人： Anil Kumar , David B. Knowles , Barry Van Gemert
发明人： Anil Kumar , David B. Knowles , Barry Van Gemert
IPC分类号： G02C7/10 , C07D307/77 , C07D311/78 , C07D311/92 , C07D311/94 , C07D311/96 , C07D405/04 , C07D407/04 , C07D413/04 , C07D491/052 , C07D493/04 , C07D493/10 , C07D495/04 , C08K5/00 , C08K5/15 , C08K5/1545 , C08L101/00 , C09K9/02 , G02B5/23 , G02F1/17 , G03C1/73 , C07D405/02
CPC分类号： C08K5/15 , C07D307/77 , C07D311/92 , C07D311/94 , C07D493/04 , C08K5/1545
摘要： Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds fused on the naphtho-portion of the naphthopyran ring with an indeno group or certain heterocyclic substituents. Certain substituents are also present at the 2 and 5 positions and sometimes at the 6 position of the naphthopyran ring. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
摘要翻译：描述了新颖的可逆光致变色的2H-萘并[1,2-b]吡喃化合物，其实例是在萘并吡喃环的萘基上稠合的茚基或某些杂环取代基。某些取代基也存在于萘并吡喃环的2位和5位，有时位于6位。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（二氢吲哚）型化合物的引入新的萘并吡喃化合物或其组合与互补的光致变色化合物的眼用透镜或其它塑料透明胶片制成的物品。

17. 发明授权

US5637262A Photochromic substituted naphthopyran compounds 失效
标题翻译：光致变色取代萘并吡喃化合物
公开(公告)号：US5637262A
公开(公告)日：1997-06-10
申请号：US454784
申请日：1995-05-31
申请人： Barry Van Gemert , Anil Kumar
发明人： Barry Van Gemert , Anil Kumar
IPC分类号： G02C7/10 , C07D311/92 , C07D311/96 , C07D405/04 , C07D407/04 , C07D409/04 , C08K5/10 , C08K5/1545 , C08L25/00 , C08L33/04 , C08L67/00 , C08L67/02 , C08L75/00 , C08L75/04 , C08L101/00 , C09K9/02 , C09K11/06 , G02B1/04 , G02B5/23 , G02B27/00
CPC分类号： G02B5/23 , C07D311/92
摘要： Described are novel reversible photochromic 3H-naphtho[2,1-b]pyran compounds, of the following graphic formula: ##STR1## wherein R.sub.1 is hydrogen or alkyl, R.sub.2 is hydrogen or preferably a carboalkoxy group and R.sub.3 is hydrogen or preferably an alkyl group, provided that either R.sub.1 or R.sub.2 is hydrogen, and B and B' are the aryl groups phenyl or naphthyl, a heterocyclic aromatic group or together form a spiro adamantylene group. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(oxazine) type compounds, are also described.
摘要翻译：描述了新颖的可逆光致变色的3H-萘并[2,1-b]吡喃化合物，其具有下列结构式：其中R 1是氢或烷基，R 2是氢或优选烷氧基，R 3是氢或优选烷基基团，其中R 1或R 2为氢，B和B'为芳基苯基或萘基，杂环芳基或一起形成螺金刚烷基。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（恶嗪）型化合物引入新颖的萘并吡喃化合物或其组合与互补的光致变色化合物，例如螺（恶嗪）类化合物的眼用透镜或其它塑料透明胶片的物品。

18. 发明授权

US5650098A Substituted naphthopyrans 失效
标题翻译：取代萘并吡喃
公开(公告)号：US5650098A
公开(公告)日：1997-07-22
申请号：US542999
申请日：1995-10-13
申请人： Anil Kumar , David B. Knowles , Barry Van Gemert
发明人： Anil Kumar , David B. Knowles , Barry Van Gemert
IPC分类号： C07D311/92 , C07D311/96 , C07D407/04 , C09K9/02 , G02B5/23 , C08K5/15
CPC分类号： C07D311/92 , C07D311/96 , C07D407/04 , C09K9/02 , G02B5/23
摘要： Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds having certain substituents at the 5 and 6-positions of the naphtho portion of the naphthopyran and at the 2-position of the pyran ring, e.g., 2,2-bis(4-methoxy phenyl)-5-methoxycarbonyl-6-morpholino-2H-naphtho[1,2-b]pyran. Certain substituents may also be present at the number 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
摘要翻译：描述了新颖的可逆光致变色的2H-萘并[1,2-b]吡喃化合物，其实例是在萘并吡喃的萘酚部分的5位和6位具有某些取代基的化合物和吡喃环的2位，例如2,2-双（4-甲氧基苯基）-5-甲氧基羰基-6-吗啉代-2H-萘并[1,2-b]吡喃。某些取代基也可以存在于萘并吡喃的萘酚部分的数目7,8,9或10个碳原子上。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（二氢吲哚）型化合物的引入新的萘并吡喃化合物或其组合与互补的光致变色化合物的眼用透镜或其它塑料透明胶片制成的物品。

19. 发明授权

US5658501A Substituted naphthopyrans 失效
标题翻译：取代萘并吡喃
公开(公告)号：US5658501A
公开(公告)日：1997-08-19
申请号：US490258
申请日：1995-06-14
申请人： Anil Kumar , David B. Knowles , Barry Van Gemert
发明人： Anil Kumar , David B. Knowles , Barry Van Gemert
IPC分类号： C07D311/12 , C07D311/92 , C08K5/1545 , C09K9/02 , G02B5/23 , C08K5/15 , C07D311/78 , C07D405/02
CPC分类号： C07D311/12 , C07D311/92 , C08K5/1545 , C09K9/02 , G02B5/23
摘要： Described are novel reversible photochromic 2H-naphtho[1,2-b] pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho-portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
摘要翻译：描述了新的可逆光致变色的2H-萘并[1,2-b]吡喃化合物，其实例是在萘并吡喃的萘酚部分的5个碳原子上具有某些取代基的化合物和在吡喃环的2位上。某些取代基也可以存在于萘并吡喃的萘酚部分的6,7,8,9或10个碳原子上。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（二氢吲哚）型化合物的引入新的萘并吡喃化合物或其组合与互补的光致变色化合物的眼用透镜或其它塑料透明胶片制成的物品。

20. 发明授权

US5656206A Substituted naphthopyrans 失效
标题翻译：取代萘并吡喃
公开(公告)号：US5656206A
公开(公告)日：1997-08-12
申请号：US490190
申请日：1995-06-14
申请人： David B. Knowles , Barry Van Gemert , Anil Kumar
发明人： David B. Knowles , Barry Van Gemert , Anil Kumar
IPC分类号： G02C7/10 , C07D311/78 , C07D311/92 , C07D311/96 , C07D407/10 , C08K5/15 , C08K5/1545 , G02B5/23 , G02B27/00 , C07D405/02 , C02B1/04 , C02B5/23
CPC分类号： G02B5/23 , C07D311/92 , C08K5/1545
摘要： Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
摘要翻译：描述了新颖的可逆光致变色的2H-萘并[1,2-b]吡喃化合物，其实例是在萘并吡喃的萘酚部分的5个碳原子上和在吡喃环的2位上具有某些取代基的化合物。某些取代基也可以存在于萘并吡喃的萘酚部分的6,7,8,9或10个碳原子上。还描述了含有或涂覆有这些化合物的有机主体材料。还描述了将诸如螺旋（二氢吲哚）型化合物的引入新的萘并吡喃化合物或其组合与互补的光致变色化合物的眼用透镜或其它塑料透明胶片制成的物品。

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