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    • 11. 发明授权
    • Mixtures comprising tetrakis(pyrrolidino/piperdino)phosphonium salts
    • 包含四(吡咯烷子基/哌啶子)鏻盐的混合物
    • US06407029B1
    • 2002-06-18
    • US09617470
    • 2000-07-17
    • Berthold SchiemenzThomas WesselRalf PfirmannAndreas BeckWalter Hahn
    • Berthold SchiemenzThomas WesselRalf PfirmannAndreas BeckWalter Hahn
    • B01J2714
    • C07C45/63C07B39/00C07F9/572C07F9/59C07C47/55
    • The present invention relates to mixtures comprising from 70 to 99.5% by weight of a compound of the formula (R)4P+X− (1) and from 30 to 0.5% by weight of a compound of the formula (R)3P═O (2), where R is in each case a radical and X− is an inorganic or organic anion or the equivalent of a multiply charged inorganic or organic anion, also to a process for preparing the mixtures by reacting a phosphorus pentahalide with pyrrolidine or piperidine in the molar ratio 1:6 to 1:50 in the presence of an inert solvent initially at −20 to 80° C., subsequently continuing the reaction at 90 to 180° C., treating the resulting reaction product at 0 to 80° C. with aqueous alkali at a pH of 7 to 15, and separating aqueous and organic phase from one another, and to the use of the mixtures as catalyst and cocatalyst for phase-transfer reactions, nucleophilic substitution reactions or halogen-fluorine exchange reactions.
    • 本发明涉及包含70-99.5重量%的式(R)4P + X-(1)的化合物和30至0.5重量%的式(R)化合物3P = O的混合物 (2),其中R在每种情况下是基团,X是无机或有机阴离子或相当于多电荷无机或有机阴离子,也是通过使五卤化磷与吡咯烷或哌啶反应制备混合物的方法 摩尔比1:6至1:50,最初在-20至80℃的惰性溶剂存在下,随后在90至180℃下继续反应,在0至80℃下处理所得反应产物 与碱水溶液在pH为7至15,并分离水相和有机相,并将混合物用作催化剂和助催化剂用于相转移反应,亲核取代反应或卤素 - 氟交换反应。
    • 14. 发明授权
    • Novel fluorinated resorcinol ethers
    • 新型氟化间苯二酚醚
    • US4670604A
    • 1987-06-02
    • US801012
    • 1985-11-22
    • Andreas BeckAlfred SallmannRobert W. LangPaul Wenk
    • Andreas BeckAlfred SallmannRobert W. LangPaul Wenk
    • C07C39/24C07C43/225C07C43/23C07C45/46C07C45/71C07C49/825C07C49/84C07C205/37C07D257/04
    • C07D257/04C07C205/37C07C39/24C07C39/245C07C43/225C07C43/23C07C45/46C07C45/71C07C49/825C07C49/84
    • 4-Acylresorcinol ethers of the formula ##STR1## in which R.sub.1 is lower alkyl, R.sub.2 is fluorinated lower alkyl, R.sub.3 is hydrogen, lower alkoxy, trifluoromethyl or halogen, alk is an alkylene or hydroxyalkylene radical which is uninterrupted or interrupted by oxygen, one of the radicals R.sub.4, R.sub.5 and R.sub.7 is a group of the formula --NH--C(.dbd.O)--R.sub.8, a radical R.sub.4 or R.sub.5 which differs from this is a radical R.sub.9 and a radical R.sub.7 which differs from this is a radical R.sub.10, R.sub.6 is hydrogen, lower alkyl, trifluoromethyl, halogen, carboxyl which is free, esterified or amidated, cyano or lower alkanoyl, R.sub.8 is carboxyl which is free, esterified or amidated or 5-tetrazolyl, R.sub.9 is hydrogen, lower alkyl, lower alkoxy, halogen or trifluoromethyl and R.sub.10 is hydrogen, lower alkyl, lower alkoxy, halogen, trifluoromethyl, cyano or carboxyl which is free, esterified or amidated, and their salts have antiallergic and antiinflammatory properties. They are prepared, for example, by reacting compounds of the formulae ##STR2## in which one of the radicals X.sub.5 and X.sub.6 is hydroxyl which is free or in salt form and the other is an alkoxy radical substituted by reactive esterified hydroxyl or epoxy. The invention also relates to intermediates of the formula ##STR3## in which R.sub.2 is fluorinated lower alkyl, R.sub.3 is hydrogen, lower alkoxy, trifluoromethyl or halogen and R.sub.11 is hydrogen or a group of the formula R.sub.1 --O(.dbd.O)--, in which R.sub.1 is lower alkyl, and their salts.
    • 其中R 1是低级烷基,R 2是氟化的低级烷基,R 3是氢,低级烷氧基,三氟甲基或卤素的式(I)的4-间酰基间苯二酚醚,alk是不间断或中断的亚烷基或羟基亚烷基 氧,基团R4,R5和R7之一是式-NH-C(= O)-R8的基团,与此不同的基团R 4或R 5是基团R 9和与此不同的基团R 7, 基团R 10,R 6为氢,低级烷基,三氟甲基,卤素,羧基,其游离,酯化或酰胺化,氰基或低级烷酰基,R8为羧基,其为游离的,酯化的或酰胺化的或5-四唑基,R 9为氢,低级烷基 ,低级烷氧基,卤素或三氟甲基,R 10是氢,低级烷基,低级烷氧基,卤素,三氟甲基,氰基或羧基,它们是游离的,酯化的或酰胺化的,并且它们的盐具有抗过敏和抗炎性质。 它们例如通过使式(IMAGE)的化合物与基团X5和X6中的一个是游离的或盐形式的羟基反应而制备,另一种是被反应性酯化的羟基或环氧基取代的烷氧基。 本发明还涉及其中R 2是氟化的低级烷基,R 3是氢,低级烷氧基,三氟甲基或卤素,R 11是氢或式R 1 -O(= O)的基团的式(ⅩⅩⅢ)中间体, - ,其中R1是低级烷基,及其盐。
    • 17. 发明申请
    • DOOR HANDLE ASSEMBLY FOR A MOTOR VEHICLE
    • 车门组件用于电动车
    • US20170044802A1
    • 2017-02-16
    • US15336280
    • 2016-10-27
    • Andreas BeckRalf LennhoffMario Christensen
    • Andreas BeckRalf LennhoffMario Christensen
    • E05B77/06E05B85/10
    • E05B77/06E05B77/02E05B85/10Y10S292/22Y10T292/57
    • A door handle assembly for a motor vehicle includes an operating handle moveably supported on a handle mounting, a mechanical coupling device and a locking device. An acceleration force can move the locking device from a normal operating position, in which an actuation of the operating handle is possible, in a first blocking direction, in which an actuation of the closing assembly via the operating handle and/or the coupling device, is blocked. The locking device also blocks the door handle assembly when long lasting or strongly pronounced oscillations occur as a result of a crash. In that event, the locking device can move from the normal operating position in a second blocking direction, in which an actuation of the closing assembly via the operating handle and/or the coupling device is blocked, wherein the second blocking direction is oriented opposite the first blocking direction.
    • 用于机动车辆的门把手组件包括可移动地支撑在手柄安装件上的操作手柄,机械联接装置和锁定装置。 加速力可以将锁定装置从第一阻挡方向的操作手柄的致动操作的正常操作位置移动,其中通过操作手柄和/或联接装置致动闭合组件, 被封锁。 当由于碰撞而发生长时间或强烈显着的振荡时,锁定装置还阻挡门把手组件。 在这种情况下,锁定装置可以在第二阻挡方向上从正常操作位置移动,其中经由操作手柄和/或联接装置的关闭组件的致动被阻挡,其中第二阻挡方向与 第一阻挡方向。
    • 18. 发明授权
    • Secure door handle unit
    • 安全门把手单元
    • US09151090B2
    • 2015-10-06
    • US13541145
    • 2012-07-03
    • Andreas Beck
    • Andreas Beck
    • E05B3/00E05B85/14E05B77/02E05B77/04E05B77/06E05B65/10
    • E05B85/14E05B77/02E05B77/04E05B77/06Y10S292/22Y10T292/57
    • The invention relates to a door handle unit for a lock in a vehicle with a door handle to open a door by a user, an operating unit showing at least the door handle, a coupling unit, or a combination of the door handle and the coupling unit, where by the mechanical coupling unit a motion of the door handle from a resting position into a operating position can be transferred to the lock, a crash block with a normal position, allowing a motion of the operating unit to operate the lock, and with a blocking position, which results during or after the impact of a force of acceleration, blocking any motion of the operating unit such that any operation of the lock is prevented, characterized in that the crash block in its blocking position can be transferred by a motion of the operating unit into the normal position.
    • 本发明涉及一种用于车辆锁定的门把手单元,其具有用于使用者打开门的门把手,至少示出门把手的操作单元,联接单元或门把手和联接器的组合 其中,通过机械联接单元,门把手从静止位置进入操作位置的运动可以传递到锁,具有正常位置的碰撞块,允许操作单元运动以操作锁,以及 具有在加速力的冲击期间或之后产生的阻塞位置,阻止操作单元的任何运动,使得防止锁的任何操作,其特征在于,其阻挡位置中的碰撞块可以通过 操作单元的运动进入正常位置。