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    • 15. 发明申请
    • METHOD AND DESULFURIZING NITROGEN OXIDE STORAGE CATALYSTS IN THE EXHAUST GAS SYSTEM OF A LEAN MIX ENGINE
    • 炼油发动机排气系统中氮氧化物储存催化剂的方法与脱硫
    • US20100064665A1
    • 2010-03-18
    • US12520606
    • 2007-12-19
    • Stephan EckhoffSusanne PhilippWilfried MuellerThomas Kreuzer
    • Stephan EckhoffSusanne PhilippWilfried MuellerThomas Kreuzer
    • F01N9/00F01N3/00F01N3/10
    • F02D41/028F01N3/0814F01N3/0842F01N3/0885F01N3/101F01N3/106F01N3/2033F01N13/009F01N13/0093F01N13/04F01N13/107F01N2430/06F01N2430/08F01N2430/085F01N2560/025F01N2560/14F02D41/0082Y02T10/22Y02T10/26
    • Lean burn engines require an exhaust gas system comprising nitrogen oxide storage catalysts for removal of nitrogen oxides from their exhaust gases. When the lean burn engine is operated with a sulphur-containing exhaust gas, the storage catalysts have to be desulphurized from time to time. During the desulphurization, there is the risk of high pollutant emissions. These emissions can be reduced when the cylinders of the lean burn engine are combined in two groups which release their exhaust gas to two assigned exhaust legs, in each of which is arranged at least one nitrogen oxide storage catalyst. The two exhaust legs are combined beyond the storage catalysts to form a common exhaust leg which contains a catalyst which possesses a three-way function under stoichiometric conditions. The two nitrogen oxide storage catalysts are desulphurized offset in time with respect to one another. While rich exhaust gas at a high temperature flows through one storage catalyst for desulphurization, lean exhaust gas flows through the second storage catalyst, in such a way that the combined exhaust gas is of stoichiometric composition over the entire desulphurization period. Under the stoichiometric conditions, the catalyst with three-way function is capable of converting hydrocarbons, carbon monoxide and nitrogen oxides to harmless components.
    • 精益燃烧发动机需要包括用于从其废气中除去氮氧化物的氮氧化物储存催化剂的废气系统。 当贫燃机用含硫废气进行操作时,必须不时地将储存催化剂脱硫。 在脱硫过程中,存在污染物排放高的风险。 当贫燃发动机的气缸组合成两组时,可以减少这些排放物,这两组燃烧器将废气排放到两个分配的排气支路,每个排放管排列有至少一个氮氧化物储存催化剂。 两个排气支路结合在储存催化剂之外以形成一个共同的排气支管,它包含一个在化学计量条件下具有三通功能的催化剂。 两种氮氧化物储存催化剂相对于彼此在时间上被脱硫。 虽然高温下的废气通过一个用于脱硫的储存催化剂流过,贫废气以这样的方式流过第二储存催化剂,使得组合废气在整个脱硫周期内具有化学计量组成。 在化学计量条件下,具有三向功能的催化剂能够将碳氢化合物,一氧化碳和氮氧化物转化为无害成分。
    • 20. 发明申请
    • DUAL-STAGE METHOD FOR THE REACTIVATION OF THERMALLY AGED NITROGEN OXIDE STORAGE CATALYSTS
    • 热老化氧化物储存催化剂反应的双阶段方法
    • US20100300077A1
    • 2010-12-02
    • US12599411
    • 2008-04-16
    • Stephan Eckhoff
    • Stephan Eckhoff
    • F01N3/08B01J38/06B01J38/08B01J38/10
    • B01J35/002B01D53/9422B01D53/96B01D2255/2042B01D2255/2065B01J23/002B01J23/63B01J23/96B01J38/04B01J38/06B01J38/08B01J2523/00B01J2523/25B01J2523/3712B01J2523/828
    • Nitrogen oxide storage catalysts are used to remove the nitrogen oxides present in the lean exhaust gas of lean-burn engines. As a result of the stress due to high temperatures in vehicle operation, they are subject to thermal aging processes which affect both the nitrogen oxide storage components and the noble metals present as catalytically active components.The present invention provides a process with which the catalytic activity of a nitrogen oxide storage catalyst which comprises, in addition to platinum as a catalytically active component, basic compounds of strontium and/or barium on a support material comprising cerium oxide, said catalytic activity being lost owing to the thermal aging process, can be at least partly restored. The two-stage process is based on the fact that strontium and/or barium compounds formed during the thermal aging with the support material, which also comprise platinum, are recycled to the catalytically active forms by controlled treatment with specific gas mixtures.
    • 氮氧化物储存催化剂用于去除贫燃发动机的贫废气中存在的氮氧化物。 由于车辆操作中的高温引起的应力的结果,它们受到影响作为催化活性组分存在的氮氧化物存储组分和贵金属两者的热老化过程。 本发明提供了一种氮氧化物储存催化剂的催化活性的方法,除了铂作为催化活性组分之外,还包括锶和/或钡的碱性化合物在包含氧化铈的载体材料上,所述催化活性为 由于热老化过程而损失,可以至少部分恢复。 两阶段工艺是基于以下事实:在热老化期间形成的锶和/或钡化合物与支撑材料(其也包含铂)通过用特定气体混合物的控制处理再循环至催化活性形式。