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11. 发明授权

US08557939B2 Antifouling composition, method for its production and article treated therewith 有权
标题翻译：防污组合物，其生产方法和用其处理的制品
公开(公告)号：US08557939B2
公开(公告)日：2013-10-15
申请号：US12622949
申请日：2009-11-20
申请人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
发明人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
IPC分类号： C08F18/20
CPC分类号： D06M15/277 , C08F220/24 , C08F220/28 , D06M2200/11 , D06M2200/12
摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing. An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.
摘要翻译：提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

12. 发明申请

US20120259045A1 WATER/OIL REPELLENT COMPOSITION, METHOD FOR ITS PRODUCTION AND METHOD FOR TREATING ARTICLE 审中-公开
标题翻译：水/油组合物，其生产方法和处理方法
公开(公告)号：US20120259045A1
公开(公告)日：2012-10-11
申请号：US13530395
申请日：2012-06-22
申请人： Takao HIRONO , Yuuichi Oomori , Minako Shimada , Shuichiro Sugimoto
发明人： Takao HIRONO , Yuuichi Oomori , Minako Shimada , Shuichiro Sugimoto
IPC分类号： C08L33/10 , C08J3/205 , C08K13/02 , B82Y30/00
CPC分类号： D06M15/248 , D06M15/256 , D06M15/263 , D06M15/277 , D06M15/33 , D06M15/3335 , D06M15/353 , D06M2200/10 , D06M2200/11 , D06M2200/12 , D21H17/11 , D21H17/37 , D21H21/16 , D21H21/24
摘要： To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency to the surface of an article, has high stability of the particles of the copolymer, and presents a low environmental impact, a method for its production, and a method for treating an article. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a (meth)acrylate (b) having a C20-30 alkyl group and structural units based on a halogenated olefin (c), a surfactant (B), and a medium (C), wherein the medium (C) comprises water and a propylene glycol type solvent, and the amount of the propylene glycol type solvent is from 35 to 80 parts by mass per 100 parts by mass of the copolymer (A).
摘要翻译：为了提供能够赋予制品表面足够的动态拒水性的斥水斥油剂组合物，共聚物颗粒的稳定性高，环境影响小，其制造方法和方法用于处理物品。一种斥水斥油剂组合物，其含有具有基于具有C 1-6多氟烷基的单体（a）的结构单元的共聚物（A），基于具有C20-30烷基的（甲基）丙烯酸酯（b）的结构单元和基于卤代烯烃（c），表面活性剂（B）和介质（C）的结构单元，其中介质（C）包含水和丙二醇型溶剂，丙二醇型溶剂的量来自相对于共聚物（A）100质量份，为35〜80质量份。

13. 发明授权

US08193276B2 Fluorocopolymer and water and oil proofing composition, and processes for their production 有权
标题翻译：含氟聚合物和防水防油组合物及其生产方法
公开(公告)号：US08193276B2
公开(公告)日：2012-06-05
申请号：US12695246
申请日：2010-01-28
申请人： Shuichiro Sugimoto , Takao Hirono , Eiji Morimoto
发明人： Shuichiro Sugimoto , Takao Hirono , Eiji Morimoto
IPC分类号： C08L27/12
CPC分类号： C09D133/16 , C08F214/18 , C08F220/06 , C08F220/10 , C08F220/16 , C08F220/24 , C08F222/02 , C08J3/07 , C08J2333/16
摘要： A fluorocopolymer capable of exhibiting excellent water and oil resistance even with its perfluoroalkyl group being a short chain, and a water and oil proofing composition containing it, are provided.A water and oil proofing composition containing a fluorocopolymer (A) comprising from 40 to 98 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 1 to 50 mass % of polymerized units (b′) having an alkylene oxide and from 1 to 10 mass % of polymerized units (c′) based on a monomer represented by CH2═C(COOH)-Q-COOH (wherein Q is a C1-4 alkylene group, etc.).
摘要翻译：提供即使其全氟烷基为短链也能表现出优异的耐水和耐油性的含氟共聚物，以及含有它的防油防油组合物。一种含有含氟共聚物（A）的防油防油组合物，其含有40〜98质量％的具有C1-6全氟烷基的聚合单元（a'），1〜50质量％的具有亚烷基的聚合单元（b'）氧化物和1〜10质量％的基于由CH 2 = C（COOH）-Q-COOH（其中Q为C1-4亚烷基等）表示的单体的聚合单元（c'）。

14. 发明申请

US20100076168A1 ANTIFOULING COMPOSITION, METHOD FOR ITS PRODUCTION AND ARTICLE TREATED THEREWITH 有权
标题翻译：抗反射组合物及其生产方法及其处理方法
公开(公告)号：US20100076168A1
公开(公告)日：2010-03-25
申请号：US12626739
申请日：2009-11-27
申请人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
发明人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
IPC分类号： C08F220/22
CPC分类号： D06M15/263 , C09D5/1637 , C09D133/16 , C09K3/22 , D06M15/267 , D06M15/27 , D06M15/273 , D06M15/277 , D06M15/285 , D06M16/00 , D06M2200/11 , D06M2200/12
摘要： To provide an antifouling composition which is an fluorine-type antifouling composition using a short chain perfluoroalkyl group and which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has excellent soil release properties.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 70 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 20 to 69 mass % of polymerized units (b′) having an alkylene oxide chain and from 1 to 10 mass % of polymerized units (c′) having an amino group, and which has anionic groups at its main chain terminals.
摘要翻译：提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其可以基本上不含挥发性有机溶剂的水性分散体的形式制成，并且具有优异的防污性能。含有含氟共聚物的防污组合物，其含有30〜70质量％的具有C1-6全氟烷基的聚合单元（a'），20〜69质量％的具有环氧烷烃链的聚合单元（b'）和1 至10质量％的具有氨基的聚合单元（c'），并且在其主链末端具有阴离子基团。

15. 发明授权

US08609795B2 Water and oil repellent composition 有权
标题翻译：防水防油组成
公开(公告)号：US08609795B2
公开(公告)日：2013-12-17
申请号：US11940577
申请日：2007-11-15
申请人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
发明人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
IPC分类号： C08F118/00
CPC分类号： D06M15/256 , C08F218/08 , C08F220/18 , C08F220/22 , C08F220/24 , C08F220/34 , C08F220/36 , C08F230/08 , C09K3/18 , D06M15/263 , D06M2200/00 , D06M2200/11 , D06M2200/12 , D06M2200/50
摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.
摘要翻译：具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。作为必要成分的防水斥油剂组合物，其含有含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：含有Rf基的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自Rf基团的微晶，玻璃化转变点至少为20℃。单体（b）：不具有Rf基团的单体并具有可交联的官能团。

16. 发明申请

US20120309883A1 RELEASE AGENT COMPOSITION 有权
标题翻译：释放代理成分
公开(公告)号：US20120309883A1
公开(公告)日：2012-12-06
申请号：US13586064
申请日：2012-08-15
申请人： Hiroaki INOUE , Shuichiro Sugimoto
发明人： Hiroaki INOUE , Shuichiro Sugimoto
IPC分类号： C09D133/10 , C08K5/06
CPC分类号： C08F220/22 , C09D133/16 , C08F2220/1891 , C08F214/08 , C08F220/24 , C08F222/14 , C08F220/20 , C08F222/385
摘要： The present invention provides a release agent composition which can impart moderate adhesion and releasability to the surface of articles such as protective materials for adhesive face of repositional notes, pressure-sensitive adhesive sheets and tapes, release films and release paper, and which has a low environmental burden, and its production process.The release agent composition of the present invention is characterized by comprising a fluorocopolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group and structural units based on a (meth)acrylate (b) having a C18-30 alkyl group, and a medium.
摘要翻译：本发明提供一种剥离剂组合物，其能够对制品的表面赋予适度的粘合性和脱模性，例如用于复位粘合剂的表面的保护材料，压敏粘合片和带，脱模膜和剥离纸，并且具有低的环境负担及其生产过程。本发明的脱模剂组合物的特征在于含有具有基于具有C1-6多氟烷基的单体（a）的结构单元的含氟共聚物和基于具有C18-30烷基的（甲基）丙烯酸酯（b）的结构单元，组和媒介。

17. 发明申请

US20100069565A1 ANTIFOULING COMPOSITION, METHOD FOR ITS PRODUCTION AND ARTICLE TREATED THEREWITH 有权
标题翻译：抗反射组合物及其生产方法及其处理方法
公开(公告)号：US20100069565A1
公开(公告)日：2010-03-18
申请号：US12622949
申请日：2009-11-20
申请人： Hiroyuki HARA , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
发明人： Hiroyuki HARA , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
IPC分类号： C08L27/12 , C08F220/22
CPC分类号： D06M15/277 , C08F220/24 , C08F220/28 , D06M2200/11 , D06M2200/12
摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.
摘要翻译：提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

18. 发明授权

US08507580B2 Antifouling composition, process for its production and article treated therewith 有权
标题翻译：防污组合物，其生产方法和用其处理的物品
公开(公告)号：US08507580B2
公开(公告)日：2013-08-13
申请号：US12913900
申请日：2010-10-28
申请人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono
发明人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono
IPC分类号： C08L27/12 , C08K5/05
CPC分类号： D06M15/277 , C08F214/06 , C08F220/22 , C08F220/58 , C08F222/14 , C08F2220/1891
摘要： To provide a process for efficiently producing a fluorine type antifouling composition employing a short chain Rf group, which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has a good soil release property (SR property).A process for producing an antifouling composition, which comprises a step of subjecting monomer components (Z) comprising from 30 to 80 mass % of a monomer (a) having a polyfluoroalkyl group in which the number of carbon atoms to which fluorine atoms are bonded is from 4 to 6, and from 20 to 70 mass % of a monomer (b) having no polyfluoroalkyl group and having a hydrophilic group, to solution polymerization in a volatile organic solvent having a boiling point of at most 100° C. in the presence of a surfactant (c) comprising an ethylene oxide adduct of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to form a fluorocopolymer (A), and a step of volatilizing the volatile organic solvent after the solution polymerization and adding an aqueous medium to form an aqueous dispersion.
摘要翻译：为了提供一种能够有效地制造使用短链Rf基的氟型防污组合物的方法，其可以基本上不含挥发性有机溶剂的水性分散体的形式制备并且具有良好的去污性能（SR性能）。一种防污组合物的制造方法，其特征在于，包括含有30〜80质量％的具有与氟原子键合的碳原子数的多氟烷基的单体（a）的单体成分（Z）的工序是 4〜6质量％，20〜70质量％的不具有多氟烷基且具有亲水性基团的单体（b）在沸点为100℃以下的挥发性有机溶剂中进行溶液聚合，包含2,4,7,9-四甲基-5-癸炔-4,7-二醇的环氧乙烷加合物以形成含氟共聚物（A）的表面活性剂（c），以及在溶液之后使挥发性有机溶剂挥发的步骤聚合并加入水性介质以形成水分散体。

19. 发明申请

US20070015867A1 Water and oil producing composition 有权
标题翻译：防水防油组成
公开(公告)号：US20070015867A1
公开(公告)日：2007-01-18
申请号：US11524918
申请日：2006-09-22
申请人： Takashige Maekawa , Shuichiro Sugimoto , Minako Shimada , Kyouichi Kaneko , Harutaka Naruse , Yuuichi Nakajima
发明人： Takashige Maekawa , Shuichiro Sugimoto , Minako Shimada , Kyouichi Kaneko , Harutaka Naruse , Yuuichi Nakajima
IPC分类号： C08L27/12
CPC分类号： D06M15/263 , C08F214/18 , C08L27/00 , C08L35/00 , C09D133/00 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/333 , D06M15/3568 , D06M2200/11 , D06M2200/12 , D21H19/20 , D21H21/16 , C08L2666/06
摘要： The present invention provides a water and oil proofing composition which imparts excellent water and oil resistance. A composition which comprises a fluorocopolymer comprising polymerized units of (Z-Y)nX (wherein Z: a C1-6 perfluoroalkyl group or the like, Y: an alkylene group or the like, n: 1 or 2, X: a polymerizable unsaturated group), polymerized units of CH2═CR1-G-(R2O)q—R3 (wherein R1: a hydrogen atom or the like, R2: a C2-4 alkylene group or the like, q: an integer of from 1 to 50, G: —COO(CH2)r— (r: an integer of from 0 to 4), R3: a hydrogen atom or the like) and polymerized units of CH2═CR4-M-Q-NR5R6 (wherein R4: a hydrogen atom or the like, Q: a C2-4 alkylene group or the like, R5 and R6: C1-8 alkyl groups or the like) and an aqueous medium.
摘要翻译：本发明提供赋予耐油和耐油性优异的防油防油组合物。一种组合物，其包含含有（ZY）N X的聚合单元的含氟共聚物（其中Z：C 1-6烷基全氟烷基等，Y：亚烷基或类似物，n = 1或2，X为可聚合不饱和基团），CH 2 2 -CR 1 -G-（R 2）2的聚合单元，其中R 1是氢原子等，R 2，R 2，R 3，R 3，：C 2-4亚烷基等，q：1〜50的整数，G：-COO（CH 2）2，（R：0〜4的整数），R 3，氢原子等）和CH 2的基团的聚合单元 4其中R 4为氢原子等，Q为C 1 -C 6烷基，亚> 2-4个亚烷基等，R 5和R 6：C 1-8烷基或类似物）和水性介质。

20. 发明申请

US20050267241A1 Water and oil repellent composition 审中-公开
标题翻译：防水防油组成
公开(公告)号：US20050267241A1
公开(公告)日：2005-12-01
申请号：US11106641
申请日：2005-04-15
申请人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
发明人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
IPC分类号： C09K3/18 , C08F18/20
CPC分类号： D06M15/256 , C08F218/08 , C08F220/18 , C08F220/22 , C08F220/24 , C08F220/34 , C08F220/36 , C08F230/08 , C09K3/18 , D06M15/263 , D06M2200/00 , D06M2200/11 , D06M2200/12 , D06M2200/50
摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.
摘要翻译：具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

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