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    • 17. 发明申请
    • PROCESS FOR TREATING A HYDROCARBON-CONTAINING FEED
    • 处理含油料饲料的方法
    • WO2011091201A2
    • 2011-07-28
    • PCT/US2011/021966
    • 2011-01-21
    • SHELL OIL COMPANYSHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.MILAM, Stanley NemecREYNOLDS, Michael AnthonyWELLINGTON, Scott Lee
    • MILAM, Stanley NemecREYNOLDS, Michael AnthonyWELLINGTON, Scott Lee
    • C10G47/06
    • C10G47/06B01J27/04B01J27/047B01J27/051B01J35/002B01J35/023B01J35/1014B01J35/1019B01J35/1038B01J35/1061B01J37/031B82Y30/00C01G39/006C01P2004/61C01P2004/62C01P2004/64C01P2006/12C01P2006/14C01P2006/16C10G47/26C10G2300/202C10G2300/206C10G2300/207C10G2300/301C10G2300/4006C10G2300/4012
    • A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt.% of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a catalyst to produce a hydrocarbon-containing product, where hydrogen sulfide is provided at a mole ratio relative to hydrogen of at least 0.5:9.5. The catalyst is comprised of a material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Ce, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb. The material of the catalyst may have a structure according to formula (I), formula (II), formula (III), or formula (IV): where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO 4 , PO 4 , oxalate (C 2 O 4 ), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO 4 , and NO3; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO 4 , PO 4 , oxalate (C2O 4 ), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO 3 ; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO 4 , PO 4 , oxalate (C2O 4 ), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO 4 , and NO 3 .
    • 提供了一种处理含烃进料的方法,其中将包含至少20重量%重烃的含烃进料与氢气,硫化氢和催化剂混合以产生含烃产物,其中硫化氢 以相对于氢的摩尔比提供至少0.5:9.5。 催化剂由包含第一金属和第二金属的材料组成,其中第一金属选自Cu,Fe,Ni,Co,Bi,Ag,Mn,Zn,Sn,Ru,La, Ce,Pr,Sm,Eu,Yb,Lu,Dy,Pb和Sb,第二金属是Mo,W,V,Sn和Sb。 催化剂的材料可以具有根据式(I),式(II),式(III)或式(IV)的结构:其中M是第一种金属或第二种金属,至少一种M是 第一金属和至少一个M是第二金属; 其中M是第一金属或第二金属,并且至少一个M是第一金属,并且至少一个M是第二金属,X选自SO 4,PO 4,草酸盐(C 2 O 4),乙酰丙酮化物 ,乙酸盐,柠檬酸盐,酒石酸盐,Cl,Br,I,ClO4和NO3; 其中M是第一金属或第二金属,并且至少一个M是第一金属,并且至少一个M是第二金属,X选自SO 4,PO 4,草酸盐(C 2 O 4),乙酰丙酮化物 ,乙酸盐,柠檬酸盐,酒石酸盐,Cl,Br,I,ClO4和NO3; 其中M是第一金属或第二金属,并且至少一个M是第一金属,并且至少一个M是第二金属,X选自SO 4,PO 4,草酸盐(C 2 O 4),乙酰丙酮化物 ,乙酸盐,柠檬酸盐,酒石酸盐,Cl,Br,I,ClO4和NO3。