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11. 发明申请

US20110052848A1 SALT RESISTANT POLYAMIDE COMPOSITIONS 审中-公开
标题翻译：耐盐聚酰胺组合物
公开(公告)号：US20110052848A1
公开(公告)日：2011-03-03
申请号：US12873826
申请日：2010-09-01
申请人： SHAILESH RATILAL DOSHI , MARVIN M. MARTENS , ANNAKUTTY MATHEW , STEVEN A. MESTEMACHER
发明人： SHAILESH RATILAL DOSHI , MARVIN M. MARTENS , ANNAKUTTY MATHEW , STEVEN A. MESTEMACHER
IPC分类号： C08L77/06 , C08G69/26 , B32B1/08
CPC分类号： C08G69/265 , C08L23/04 , C08L51/06 , C08L77/06 , F16L11/06 , Y10T428/139 , C08L2666/06 , C08L2666/24 , C08L2666/02
摘要： Polyamides made from 1,6-hexanediamine, and the dicarboxylic acids 1,10-decandioic acid, 1,12-dodecanedioic acid, or 1,14-tetradecanedioic acid and terephthalic acid in specified proportions are particularly resistant to salt stressed (induced) corrosion cracking. This makes them particularly useful as vehicular parts which may be exposed to salts. Particularly when these polyamides contain tougheners and/or plasticizers they are especially useful for hoses and tubes.
摘要翻译：由1,6-己二胺制成的聚酰胺和1,10-癸二酸，1,12-十二烷二酸或1,14-十四烷二酸和对苯二甲酸的二羧酸特定比例特别耐盐胁迫（诱导）腐蚀开裂这使得它们特别适用于可能暴露于盐的车辆部件。特别是当这些聚酰胺含有增韧剂和/或增塑剂时，它们特别适用于软管和软管。

12. 发明申请

US20110028621A1 HEAT AGING RESISTANT POLYAMIDE COMPOSITIONS INCLUDING POLYHYDROXY POLYMERS 审中-公开
标题翻译：耐高温聚酰胺组合物，包括聚羟基聚合物
公开(公告)号：US20110028621A1
公开(公告)日：2011-02-03
申请号：US12842115
申请日：2010-07-23
申请人： Marvin M. Martens , Toshikazu Kobayashi
发明人： Marvin M. Martens , Toshikazu Kobayashi
IPC分类号： C08K5/13 , C08K5/18
CPC分类号： C08L77/00 , C08K3/013 , C08K5/005 , C08L29/04 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2205/03 , C08L2666/04 , C08L2666/20 , C08L2666/02
摘要： Disclosed is a thermoplastic composition including A) a polyamide resin having a melting point and/or glass transition; B) 0.25 to 20 weight percent of at least one polyhydric polymer; C) 0 to 3 weight percent of one or more co-stabilizer(s); and, D) 0 to about 60 weight percent of one or more reinforcement agents, wherein said polyamide resin is selected from the group consisting of Group (III) Polyamides having said melting point of at least 210° C., and including about 20 to about 35 mole percent semiaromatic repeat units, Group (IV) Polyamides comprising about 50 to about 95 mole percent semiaromatic repeat units, Group (V) Polyamides having said melting point of at least 260° C., and including greater than 95 mole percent semiaromatic repeat units, and Group (VI) Polyamides having no melting point; with the proviso that when less than 10 weight percent said one or more reinforcement agent(s) is present, at least 0.1 weight % of said one or more co-stabilizer(s) also is present.
摘要翻译：公开了一种热塑性组合物，其包括A）具有熔点和/或玻璃化转变的聚酰胺树脂; B）0.25至20重量％的至少一种多羟基聚合物; C）0至3重量％的一种或多种共稳定剂; 和D）0至约60重量％的一种或多种增强剂，其中所述聚酰胺树脂选自具有所述熔点至少为210℃的组（III）聚酰胺，并且包括约20至约35摩尔％半芳族重复单元的组（IV）聚酰胺，其包含约50至约95摩尔％半芳族重复单元，（V）族聚酰胺，其熔点至少为260℃，并且包括大于95摩尔％的半芳族化合物重复单元和不具有熔点的第（VI）族聚酰胺; 条件是当存在少于10重量％的所述一种或多种增强剂时，还存在至少0.1重量％的所述一种或多种共稳定剂。

13. 发明授权

US07696301B2 Marine umbilical comprising hydrolysis resistant polyamides 有权
标题翻译：包含耐水解聚酰胺的海洋脐带
公开(公告)号：US07696301B2
公开(公告)日：2010-04-13
申请号：US11258285
申请日：2005-10-25
申请人： Robert B. Fish, Jr. , Marvin M. Martens , Steven A. Mestemacher , Rolando Umali Pagilagan
发明人： Robert B. Fish, Jr. , Marvin M. Martens , Steven A. Mestemacher , Rolando Umali Pagilagan
IPC分类号： C08G69/14
CPC分类号： C08G69/36 , C08G69/265 , C08L77/00 , C08L77/06 , C08L2205/02 , F16L9/19 , F16L11/22 , Y10T428/1393 , C08L2666/20
摘要： Marine umbilicals are provided comprising polyamide compositions having good hydrolysis resistance and that may optionally contain plasticizer.
摘要翻译：提供了包含具有良好耐水解性的聚酰胺组合物并且可任选地含有增塑剂的海洋脐带。

14. 发明授权

US5618865A Fire resistant resin compositions 失效
标题翻译：耐火树脂组合物
公开(公告)号：US5618865A
公开(公告)日：1997-04-08
申请号：US577357
申请日：1995-12-22
申请人： Marvin M. Martens , Robert V. Kasowski
发明人： Marvin M. Martens , Robert V. Kasowski
IPC分类号： C08K5/00 , C08K5/3492 , C08K5/34
CPC分类号： C08K5/34928 , C08K5/0066
摘要： This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 20 to about 30 weight percent of melamine phosphate and up to about 10 weight percent of a charring catalyst; (b) about 15 to about 30 weight percent of melamine phosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former; (c) about 25 to about 30 weight percent of melamine pyrophosphate; (d) about 15 to about 30 weight percent of melamine pyrophosphate and up to about 10 weight percent of a charring catalyst; or (e) about 15 to about 30 weight percent of melamine pyrophosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, wherein all percents by weight are based on the total weight of (1)+(2)+(3) only.
摘要翻译：本发明涉及用于聚酯和聚酰胺组合物的阻燃剂，具体涉及含有（1）约30至约70重量％的聚酯或合成的脂族聚酰胺的组合物; （2）约15至约40重量％的玻璃或矿物增强剂; 和（3）阻燃剂（a）约20至约30重量％的磷酸三聚氰胺和至多约10重量％的炭化催化剂; （b）约15至约30重量％的磷酸三聚氰胺，至多约10重量％的炭化催化剂和至多约10重量％的炭化剂; （c）约25至约30重量％的焦磷酸三聚氰胺; （d）约15至约30重量％的焦磷酸三聚氰胺和至多约10重量％的炭化催化剂; 或（e）约15至约30重量％的焦磷酸三聚氰胺，至多约10重量％的炭化催化剂和至多约10重量％的炭形成剂，其中所有百分比均为基于（ 1）+（2）+（3）。

15. 发明授权

US08530571B2 Polyamide compositions having high acid ends 有权
标题翻译：具有高酸性末端的聚酰胺组合物
公开(公告)号：US08530571B2
公开(公告)日：2013-09-10
申请号：US12965077
申请日：2010-12-10
申请人： Toshikazu Kobayashi , Marvin M. Martens , Shengmei Yuan
发明人： Toshikazu Kobayashi , Marvin M. Martens , Shengmei Yuan
IPC分类号： C08G69/26 , C08L77/06
CPC分类号： C08L77/06 , C08G69/265
摘要： Disclosed is a thermoplastic composition including (A) a polyamide resin independently selected from the group consisting of Group (I) Polyamides having a melting point of at least 260° C., and comprising (a) greater than 95 mole percent semiaromatic repeat units and (b) less than 5 mole percent aliphatic repeat units; (B) 0 to 60 weight percent of one or more reinforcement agents; and(C) 0 to 50 weight percent of one or more a polymeric tougheners; wherein the weight percentages are based on the total weight of said thermoplastic composition; and wherein said polyamide resin has at least 50 meq/Kg of acid ends.
摘要翻译：公开了一种热塑性组合物，其包含（A）聚酰胺树脂，其独立地选自组（I）熔点为至少260℃的聚酰胺，并且包含（a）大于95摩尔％的半芳族重复单元和（b）小于5摩尔％的脂肪族重复单元; （B）0〜60重量％的一种或多种增强剂; 和（C）0至50重量％的一种或多种聚合物增韧剂; 其中所述重量百分比基于所述热塑性组合物的总重量; 并且其中所述聚酰胺树脂具有至少50meq / Kg的酸末端。

16. 发明授权

US08211517B2 Multi-layered coextruded tube 有权
标题翻译：多层共挤出管
公开(公告)号：US08211517B2
公开(公告)日：2012-07-03
申请号：US12793157
申请日：2010-06-03
申请人： Marvin M. Martens , Annakutty Mathew , Georgios Topoulos
发明人： Marvin M. Martens , Annakutty Mathew , Georgios Topoulos
IPC分类号： B29D22/00
CPC分类号： B32B1/08 , B32B7/02 , B32B27/08 , B32B27/18 , B32B27/34 , B32B2250/24 , B32B2307/30 , B32B2307/306 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2597/00 , C08G69/265 , C08G69/36 , C08K3/16 , C08L23/0815 , C08L77/06 , F16L9/133 , Y10T428/1352 , Y10T428/1393 , C08L2666/06
摘要： Multi-layered co-extruded tubes are provided that include an outer layer including a first semiaromatic semicrystalline polyamide having a melt temperature of about 240° C. to 280° C., and a thermal stabilizer; and an inner layer including a second semiaromatic semicrystalline polyamide having a glass transition equal to or greater than 100° C.
摘要翻译：提供了多层共挤出管，其包括外层，其包括熔融温度为约240℃至280℃的第一半芳族半结晶聚酰胺和热稳定剂; 以及包含玻璃化转变等于或大于100℃的第二半芳族半结晶聚酰胺的内层。

17. 发明申请

US20100307626A1 MULTI-LAYERED COEXTRUDED TUBE 审中-公开
公开(公告)号：US20100307626A1
公开(公告)日：2010-12-09
申请号：US12793708
申请日：2010-06-04
申请人： Marvin M. Martens , Annakutty Mathew , Georgios Topoulos
发明人： Marvin M. Martens , Annakutty Mathew , Georgios Topoulos
IPC分类号： F16L9/14
CPC分类号： B32B1/08 , B32B7/02 , B32B27/08 , B32B27/18 , B32B27/34 , B32B2250/24 , B32B2307/30 , B32B2307/306 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2597/00 , C08G69/265 , C08G69/36 , C08K3/16 , C08L23/0815 , C08L77/06 , F16L9/133 , Y10T428/1352 , Y10T428/1393 , C08L2666/06
摘要： Multi-layered co-extruded tubes are provided that include an outer layer including a first semiaromatic semicrystalline polyamide having a melt temperature of about 240° C. to 280° C., and a thermal stabilizer; and an inner layer including a second semiaromatic semicrystalline polyamide having a glass transition equal to or greater than 100° C.

18. 发明申请

US20100307625A1 MULTI-LAYERED COEXTRUDED TUBE 有权
标题翻译：多层共挤管
公开(公告)号：US20100307625A1
公开(公告)日：2010-12-09
申请号：US12793157
申请日：2010-06-03
申请人： Marvin M. Martens , Annakutty Mathew , Georgios Topoulos
发明人： Marvin M. Martens , Annakutty Mathew , Georgios Topoulos
IPC分类号： F16L9/14
CPC分类号： B32B1/08 , B32B7/02 , B32B27/08 , B32B27/18 , B32B27/34 , B32B2250/24 , B32B2307/30 , B32B2307/306 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2597/00 , C08G69/265 , C08G69/36 , C08K3/16 , C08L23/0815 , C08L77/06 , F16L9/133 , Y10T428/1352 , Y10T428/1393 , C08L2666/06
摘要： Multi-layered co-extruded tubes are provided that include an outer layer including a first semiaromatic semicrystalline polyamide having a melt temperature of about 240° C. to 280° C., and a thermal stabilizer; and an inner layer including a second semiaromatic semicrystalline polyamide having a glass transition equal to or greater than 100° C.
摘要翻译：提供了多层共挤出管，其包括外层，其包括熔融温度为约240℃至280℃的第一半芳族半结晶聚酰胺和热稳定剂; 以及包含玻璃化转变等于或大于100℃的第二半芳族半结晶聚酰胺的内层。

19. 发明授权

US08349932B2 Polyamide compositions with improved salt resistance and heat stability 失效
标题翻译：具有改善的耐盐性和热稳定性的聚酰胺组合物
公开(公告)号：US08349932B2
公开(公告)日：2013-01-08
申请号：US13015616
申请日：2011-01-28
申请人： Shailesh Ratilal Doshi , Annakutty Mathew , Marvin M. Martens
发明人： Shailesh Ratilal Doshi , Annakutty Mathew , Marvin M. Martens
IPC分类号： C08K3/10 , C08K3/22
CPC分类号： C08G69/265 , C08K3/013 , C08L29/04 , C08L77/06 , C08L2666/04
摘要： Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH— (I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH— (II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and said polyamide has a melting point equal to or less than 225° C.; and 0.25 to 20 weight percent of one or more polyhydroxy polymer(s) having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene/vinyl alcohol copolymer and poly(vinyl alcohol). Also disclosed are molded or extruded articles including the polyamide composition.
摘要翻译：公开了包含至少一种半芳族共聚酰胺的聚酰胺组合物，所述半芳族共聚酰胺基本上由约25至约55摩尔％的式-C（O）（CH 2）m C（O）NHCH 2 ArCH 2 NH-（I ）和约45至约75摩尔％的式-C（O）（CH 2）m C（O）NH（CH 2）n NH-（II）的重复单元，其中m为8,10和/或12，n为6 ，10和/或12，Ar是间位取代的苯环; 并且所述聚酰胺具有等于或小于225℃的熔点; 和0.25至20重量％的数均分子量为至少2000的一种或多种多羟基聚合物，并且选自乙烯/乙烯醇共聚物和聚（乙烯醇）。还公开了包括聚酰胺组合物的模制或挤出制品。

20. 发明授权

US08232337B2 Polyamide compositions with improved salt resistance and heat stability 失效
标题翻译：具有改善的耐盐性和热稳定性的聚酰胺组合物
公开(公告)号：US08232337B2
公开(公告)日：2012-07-31
申请号：US13015613
申请日：2011-01-28
申请人： Shailesh Ratilal Doshi , Anna Kutty Mathew , Marvin M Martens
发明人： Shailesh Ratilal Doshi , Anna Kutty Mathew , Marvin M Martens
IPC分类号： C08K5/053
CPC分类号： C08G69/265 , C08K5/053 , C08K5/06 , C08L51/06 , C08L77/06
摘要： Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH— (I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH— (II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and said polyamide has a melting point equal to or less than 225° C.; and 0.1 to 15 weight percent of one or more polyhydric alcohols having more than two hydroxyl groups and having a number average molecular weight (Mn) of less than 2000. Also disclosed are molded or extruded articles including the polyamide composition.
摘要翻译：公开了包含至少一种半芳族共聚酰胺的聚酰胺组合物，所述半芳族共聚酰胺基本上由约25至约55摩尔％的式-C（O）（CH 2）m C（O）NHCH 2 ArCH 2 NH-（I ）和约45至约75摩尔％的式-C（O）（CH 2）m C（O）NH（CH 2）n NH - （II）的重复单元，其中m为8,10和/或12，n为6 ，10和/或12，Ar是间位取代的苯环; 并且所述聚酰胺具有等于或小于225℃的熔点; 和0.1至15重量％的一种或多种具有多于两个羟基并且数均分子量（Mn）小于2000的多元醇。还公开了包含聚酰胺组合物的模制或挤出制品。

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