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    • 11. 发明授权
    • Process for producing electroactive inorganic organic hybrid materials
    • 电活性无机有机杂化材料的制备方法
    • US06277304B1
    • 2001-08-21
    • US09575438
    • 2000-05-22
    • Yen WeiJui-Ming YehWei WangGuang-Way Jang
    • Yen WeiJui-Ming YehWei WangGuang-Way Jang
    • H01B104
    • H01B1/127C08K9/08H01B1/122H01B1/128
    • Hybrid materials are formed having a homogeneous distribution of a conductive organic polymer or copolymer in an inorganic matrix. The conductive organic polymer may be electronically conductive, e.g., polyaniline, or may be ionically conductive, e.g., sulfonated polystyrene. The inorganic matrix is formed as a result of sol-gel chemistry, e.g., by the hydrolysis and condensation of tetraethyl orthosilicate and trialkoxysilyl groups in the organic polymers. A homogeneous distribution of organic polymer in the inorganic matrix is achieved by preparing separate solutions of organic polymer and sol-gel monomer, and then combining those solutions with a catalyst and stirring, to form a homogeneous clear solution. Upon evaporation of the solvent and other volatiles, a monolithic hybrid material may be formed. The combination of conductive organic polymer in an inorganic matrix provides desirable adhesion properties to an inorganic substrate while maintaining the conductivity of the organic polymer.
    • 在无机基质中形成具有均匀分布的导电有机聚合物或共聚物的杂化材料。 导电有机聚合物可以是电子导电的,例如聚苯胺,或者可以是离子导电的,例如磺化聚苯乙烯。 无机基质由溶胶 - 凝胶化学结果形成,例如通过在有机聚合物中水解和缩合原硅酸四乙酯和三烷氧基甲硅烷基。 有机聚合物在无机基质中的均匀分布通过制备有机聚合物和溶胶 - 凝胶单体的分离溶液,然后将这些溶液与催化剂混合并搅拌来形成均匀的澄清溶液来实现。 在蒸发溶剂和其它挥发物时,可以形成单体混合材料。 无机基质中的导电有机聚合物的组合在保持有机聚合物的导电性的同时提供了对无机基材的期望的粘附性质。
    • 12. 发明授权
    • Electroactive inorganic hybrid materials
    • 电动无机杂化材料
    • US6066269A
    • 2000-05-23
    • US173840
    • 1998-10-16
    • Yen WeiJui-Ming YehWei WangGuang-Way Jang
    • Yen WeiJui-Ming YehWei WangGuang-Way Jang
    • C08K9/08H01B1/12
    • H01B1/127C08K9/08H01B1/122H01B1/128
    • Hybrid materials are formed having a homogeneous distribution of a conductive organic polymer or copolymer in an inorganic matrix. The conductive organic polymer may be electronically conductive, e.g., polyaniline, or may be ionically conductive, e.g., sulfonated polystyrene. The inorganic matrix is formed as a result of sol-gel chemistry, e.g., by the hydrolysis and condensation of tetraethyl orthosilicate and trialkoxysilyl groups in the organic polymers. A homogeneous distribution of organic polymer in the inorganic matrix is achieved by preparing separate solutions of organic polymer and sol-gel monomer, and then combining those solutions with a catalyst and stirring, to form a homogeneous clear solution. Upon evaporation of the solvent and other volatiles, a monolithic hybrid material may be formed. The combination of conductive organic polymer in an inorganic matrix provides desirable adhesion properties to an inorganic substrate while maintaining the conductivity of the organic polymer.
    • 在无机基质中形成具有均匀分布的导电有机聚合物或共聚物的杂化材料。 导电有机聚合物可以是电子导电的,例如聚苯胺,或者可以是离子导电的,例如磺化聚苯乙烯。 无机基质由溶胶 - 凝胶化学结果形成,例如通过在有机聚合物中水解和缩合原硅酸四乙酯和三烷氧基甲硅烷基。 有机聚合物在无机基质中的均匀分布通过制备有机聚合物和溶胶 - 凝胶单体的分离溶液,然后将这些溶液与催化剂混合并搅拌来形成均匀的澄清溶液来实现。 在蒸发溶剂和其它挥发物时,可以形成单体混合材料。 无机基质中的导电有机聚合物的组合在保持有机聚合物的导电性的同时提供了对无机基材的期望的粘附性质。
    • 13. 发明授权
    • Electroactive inorganic organic hybrid materials
    • 电动无机有机杂化材料
    • US5868966A
    • 1999-02-09
    • US701570
    • 1996-08-22
    • Yen WeiJui-Ming YehWei WangGuang-Way Jang
    • Yen WeiJui-Ming YehWei WangGuang-Way Jang
    • C08K9/08H01B1/12H01B1/04C08K3/34H01B1/06
    • H01B1/127C08K9/08H01B1/122H01B1/128
    • Hybrid materials are formed having a homogeneous distribution of a conductive organic polymer or copolymer in an inorganic matrix. The conductive organic polymer may be electronically conductive, e.g., polyaniline, or may be ionically conductive, e.g., sulfonated polystyrene. The inorganic matrix is formed as a result of sol-gel chemistry, e.g., by the hydrolysis and condensation of tetraethyl orthosilicate and trialkoxysilyl groups in the organic polymers. A homogeneous distribution of organic polymer in the inorganic matrix is achieved by preparing separate solutions of organic polymer and sol-gel monomer, and then combining those solutions with a catalyst and stirring, to form a homogeneous clear solution. Upon evaporation of the solvent and other volatiles, a monolithic hybrid material may be formed. The combination of conductive organic polymer in an inorganic matrix provides desirable adhesion properties to an inorganic substrate while maintaining the conductivity of the organic polymer.
    • 在无机基质中形成具有均匀分布的导电有机聚合物或共聚物的杂化材料。 导电有机聚合物可以是电子导电的,例如聚苯胺,或可以是离子导电的,例如磺化聚苯乙烯。 无机基质由溶胶 - 凝胶化学结果形成,例如通过在有机聚合物中水解和缩合原硅酸四乙酯和三烷氧基甲硅烷基。 有机聚合物在无机基质中的均匀分布通过制备有机聚合物和溶胶 - 凝胶单体的分离溶液,然后将这些溶液与催化剂混合并搅拌来形成均匀的澄清溶液来实现。 在蒸发溶剂和其它挥发物时,可以形成单体混合材料。 无机基质中的导电有机聚合物的组合在保持有机聚合物的导电性的同时提供了对无机基材的期望的粘附性质。
    • 14. 发明授权
    • Compound and method for producing the same
    • 化合物及其制备方法
    • US08142857B2
    • 2012-03-27
    • US12330382
    • 2008-12-08
    • Chi-Fa HsiehJui-Ming YehTai-Kang Liu
    • Chi-Fa HsiehJui-Ming YehTai-Kang Liu
    • B05D1/34
    • C08G18/0823C08G18/3228C08G18/4277C08G18/6659C08G18/758C08K9/08C09D175/04
    • The invention provides a compound and method of producing the same. The method of the invention includes the following steps. First of all, Polycaprolactone (PCL), dimethylol propionic acid (DMPA), 4,4′-methylenebis (cyclohexyl isocyanate) (H12MDI), and dibutyltin dilaurate (DBT) are mixed in a solvent in the first place and a solution is formed. This solution is then mixed with triethylamine (TEA) and triethylene tetramine (TETA). After that, amino-terminated anionic waterborne polyurethane (WPU) is produced. A sol-gel process is proceeded with a mixture of amino-terminated anionic waterborne polyurethane, tetraethylorthosilicate (TEOS) without any extra catalyst, and a compound, waterborne polyurethane-silica nanocomposite materials, is eventually produced.
    • 本发明提供了一种化合物及其制备方法。 本发明的方法包括以下步骤。 首先将聚己内酯(PCL),二羟甲基丙酸(DMPA),4,4'-亚甲基双(环己基异氰酸酯)(H12MDI)和二月桂酸二丁基锡(DBT)首先在溶剂中混合,形成溶液 。 然后将该溶液与三乙胺(TEA)和三亚乙基四胺(TETA)混合。 之后,生成氨基封端的阴离子水性聚氨酯(WPU)。 溶胶 - 凝胶法用氨基封端的阴离子水性聚氨酯,原硅酸四乙酯(TEOS)与无任何额外催化剂的混合物进行,最终生产化合物水性聚氨酯 - 二氧化硅纳米复合材料。
    • 18. 发明申请
    • COMPOUND AND METHOD FOR PRODUCING THE SAME
    • 化合物及其制造方法
    • US20120101203A1
    • 2012-04-26
    • US13342034
    • 2012-01-01
    • Chi-Fa HsiehJui-Ming YehTai-Kang Liu
    • Chi-Fa HsiehJui-Ming YehTai-Kang Liu
    • C08K5/5415C08L75/04
    • C08G18/0823C08G18/3228C08G18/4277C08G18/6659C08G18/758C08K9/08C09D175/04
    • The invention provides a compound and method of producing the same. The method of the invention includes the following steps. First of all, Polycaprolactone (PCL), dimethylol propionic acid (DMPA), 4,4′-methylenebis (cyclohexyl isocyanate) (H12MDI), and dibutyltin dilaurate (DBT) are mixed in a solvent in the first place and a solution is formed. This solution is then mixed with triethylamine (TEA) and triethylene tetramine (TETA). After that, amino-terminated anionic waterborne polyurethane (WPU) is produced. A sol-gel process is proceeded with a mixture of amino-terminated anionic waterborne polyurethane, tetraethylorthosilicate (TEOS) without any extra catalyst, and a compound, waterborne polyurethane-silica nanocomposite materials, is eventually produced.
    • 本发明提供了一种化合物及其制备方法。 本发明的方法包括以下步骤。 首先将聚己内酯(PCL),二羟甲基丙酸(DMPA),4,4'-亚甲基双(环己基异氰酸酯)(H12MDI)和二月桂酸二丁基锡(DBT)首先在溶剂中混合,形成溶液 。 然后将该溶液与三乙胺(TEA)和三亚乙基四胺(TETA)混合。 之后,生成氨基封端的阴离子水性聚氨酯(WPU)。 溶胶 - 凝胶法用氨基封端的阴离子水性聚氨酯,原硅酸四乙酯(TEOS)与无任何额外催化剂的混合物进行,最终生产化合物水性聚氨酯 - 二氧化硅纳米复合材料。