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11. 发明授权

US06486365B1 Production and purification of phenol: hydroxyacetone removal by hydrotalcite 有权
标题翻译：苯酚的生产和纯化：通过水滑石除去羟基丙酮
公开(公告)号：US06486365B1
公开(公告)日：2002-11-26
申请号：US10063258
申请日：2002-04-04
申请人： John W. Fulmer , Bharat Singh , Pramod Kumbhar , Prashant Anil Tatake , Umesh Hasyagar
发明人： John W. Fulmer , Bharat Singh , Pramod Kumbhar , Prashant Anil Tatake , Umesh Hasyagar
IPC分类号： C07C3708
CPC分类号： C07C37/86 , C07C2521/10 , C07C39/04
摘要： A process for converting carbonyl-type impurities contained in a phenolic solvent to high-boiling derivatives is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The phenol can be separated from the high-boiling derivatives using conventional separation techniques, such as distillation, so the invention also provides a process for separating carbonyl-type impurities, such as hydroxyacetone (HA), from a phenolic solvent. The process can be applied in the conventional industrial process for converting cumene to phenol to remove carbonyl-type impurities from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of an HTM to produce phenol and high-boiling derivatives. The phenol may be further purified using conventional separation techniques, such as distillation, to remove the high-boiling derivatives.
摘要翻译：通过使酚类溶剂与水滑石类材料（HTM）接触来提供将酚类溶剂中所含的羰基型杂质转化成高沸点衍生物的方法。苯酚可以使用常规的分离技术如蒸馏从高沸点衍生物中分离，因此本发明还提供了从酚类溶剂中分离羰基型杂质如羟基丙酮（HA）的方法。该方法可用于将异丙基苯转化为苯酚以从苯酚产物中除去羰基型杂质的常规工业方法。提供了通过将异丙基苯转化成苯酚来生产纯化苯酚的方法和设备。在异丙苯转化为苯酚时，苯酚常含有羰基型杂质。苯酚和羰基型杂质在HTM存在下反应生成苯酚和高沸点衍生物。可以使用常规分离技术如蒸馏进一步纯化苯酚，以除去高沸点衍生物。

12. 发明授权

US6025530A Phenol tar cracking process 失效
标题翻译：苯酚焦油开裂过程
公开(公告)号：US6025530A
公开(公告)日：2000-02-15
申请号：US18662
申请日：1998-02-04
申请人： Arkady Samuilovich Dyckman , Andrey Zinenkov , Boris Issakovich Gorovits , John W. Fulmer
发明人： Arkady Samuilovich Dyckman , Andrey Zinenkov , Boris Issakovich Gorovits , John W. Fulmer
IPC分类号： C07C37/52 , C07C37/72 , C07C37/86 , C07C39/06 , C10C1/19 , C07C37/68 , C07C45/00
CPC分类号： C07C37/86 , C07C37/72 , C10C1/19
摘要： The present invention relates generally to a method for treating phenol tar, and, more particularly to a method for separating valuable products from phenol tar by treating the tar with steam.
摘要翻译：本发明一般涉及一种处理苯酚焦油的方法，更具体地说，涉及通过用蒸汽处理焦油来分离有价值的产物与苯酚焦油的方法。

13. 发明授权

US07491855B2 Integrated process for the production of bisphenol A from cumene hydroperoxide 有权
标题翻译：由氢过氧化枯烯生产双酚A的综合工艺
公开(公告)号：US07491855B2
公开(公告)日：2009-02-17
申请号：US10250114
申请日：2003-06-04
申请人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
发明人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
IPC分类号： C07C39/16
CPC分类号： C07C37/20 , C07C37/08 , Y02P20/125 , Y02P20/52 , C07C39/04 , C07C39/16
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of an acid treated clay such as acid treated Montmorillonite clay to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译：用于将CHP转化为BPA的方法的第一和第二步骤的特定的催化剂组合的使用提供了高产率的BPA和低杂质产率，而不需要中间纯化步骤。在第一步中，CHP在酸处理的粘土如酸处理的蒙脱石粘土存在下裂解，以产生苯酚和丙酮。在第二步中，所生产的苯酚和丙酮优选不经中间纯化，在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂以产生BPA的阳离子交换树脂催化剂的存在下反应。

14. 发明授权

US5908962A Cumene oxidation process 失效
标题翻译：枯烯氧化过程
公开(公告)号：US5908962A
公开(公告)日：1999-06-01
申请号：US20395
申请日：1998-02-09
申请人： Vladimir Mikhailovich Zakoshansky , Andrei Konstantinovich Griaznov , Irina I. Vasilieva , John W. Fulmer , William D. Kight
发明人： Vladimir Mikhailovich Zakoshansky , Andrei Konstantinovich Griaznov , Irina I. Vasilieva , John W. Fulmer , William D. Kight
IPC分类号： C07C407/00 , C07C409/10
CPC分类号： C07C409/10 , C07C407/00
摘要： Greater efficiency in a water-alkaline emulsion cumene oxidation process using a cascade of reactors is obtained by splitting the reactor cascade into 2 stages with the first stage utilizing NH.sub.4 NaCO.sub.3 as the active carbonate in the stage containing less than 18% by weight cumene hydroperoxide and using Na.sub.2 CO.sub.3 as the active carbonate in the stage containing more than 18% by weight cumene hydroperoxide. By directly injecting ammonia into a recycle stream organic acids are efficiently neutralized. A counter current water wash of the second stage also increases process efficiency by scrubbing out unwanted impurities. Control of pH in the process improves efficiency and reduces impurity levels.
摘要翻译：在使用级联反应器的水 - 碱性乳液异丙苯氧化过程中，通过将反应器级联分为两个阶段获得更高的效率，其中第一阶段利用NH 4 NaCO 3作为活性碳酸酯在含有少于18重量％氢过氧化枯烯的阶段中使用在含有超过18重量％氢过氧化枯烯的阶段中，作为活性碳酸钠的Na 2 CO 3。通过将氨直接注入循环流中，有机酸被有效地中和。第二阶段的逆流水洗还通过洗去不需要的杂质来提高工艺效率。该过程中pH值的控制可提高效率并降低杂质浓度。

15. 发明授权

US5767322A Cumene oxidation process 失效
公开(公告)号：US5767322A
公开(公告)日：1998-06-16
申请号：US670304
申请日：1996-06-27
申请人： Vladimir Mikhailovich Zakoshansky , Andrei Konstantinovich Griaznov , Irina I. Vasilieva , John W. Fulmer , William D. Kight
发明人： Vladimir Mikhailovich Zakoshansky , Andrei Konstantinovich Griaznov , Irina I. Vasilieva , John W. Fulmer , William D. Kight
IPC分类号： C07C407/00 , C07C409/10
CPC分类号： C07C409/10 , C07C407/00
摘要： Greater efficiency in a water-alkaline emulsion cumene oxidation process using a cascade of reactors is obtained by splitting the reactor cascade into 2 stages with the first stage utilizing NH.sub.4 NaCO.sub.3 as the active carbonate in the stage containing less than 18% by weight cumene hydroperoxide and using Na.sub.2 CO.sub.3 as the active carbonate in the stage containing more than 18% by weight cumene hydroperoxide. By directly injecting ammonia into a recycle stream organic acids are efficiently neutralized. A counter current water wash of the second stage also increases process efficiency by scrubbing out unwanted impurities. Control of pH in the process improves efficiency and reduces impurity levels.

16. 发明授权

US5672774A Phenol tar processing method 失效
标题翻译：酚焦油加工方法
公开(公告)号：US5672774A
公开(公告)日：1997-09-30
申请号：US547252
申请日：1995-10-24
申请人： Arkady S. Dyckman , Vadim P. Boyarsky , Alexander S. Malinovskii , Yurii I. Petrov , Leontii M. Krasnov , Andrey V. Zinenkov , Boris I. Gorovits , Sergey N. Chernukhim , Anatoly D. Sorokin , John W. Fulmer
发明人： Arkady S. Dyckman , Vadim P. Boyarsky , Alexander S. Malinovskii , Yurii I. Petrov , Leontii M. Krasnov , Andrey V. Zinenkov , Boris I. Gorovits , Sergey N. Chernukhim , Anatoly D. Sorokin , John W. Fulmer
IPC分类号： C07C37/08 , C07C39/04 , C10C1/19 , C07C37/68
CPC分类号： C07C37/52
摘要： Valuable products are recovered from phenol tar by thermocracking under controlled conditions in the presence of polyphosphoric acid. Bisphenol A tars can be optionally cracked under these conditions mixed with the phenol tar and enhanced yields obtained.
摘要翻译：有价值的产品通过在多磷酸的存在下在受控条件下热分解从苯酚焦油中回收。双酚A焦油可以在与酚焦油混合的这些条件下任选地裂解并获得所获得的产率。

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