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    • 14. 发明授权
    • Tin-zinc alloy electroplating bath and method for electroplating using
the same
    • 锡锌合金电镀浴及其电镀方法
    • US5618402A
    • 1997-04-08
    • US180345
    • 1994-01-12
    • Hitoshi SakuraiTadahiro Ohnuma
    • Hitoshi SakuraiTadahiro Ohnuma
    • C25D3/56C25D3/60
    • C25D3/60
    • A tin-zinc alloy electroplating bath comprises an amphoteric surfactant, a water-soluble stannous salt, a water-soluble zinc salt and a balance of water. When the tin-zinc alloy plating bath of the present invention is used, the formed coating film comprises a uniform alloy composition even in case where the current density varies over a wide range. Therefore, the coating film having the uniform alloy composition can be formed even on the substance having a complicated shape and the chromate treatment becomes satisfactory. As a result, the effect of the coating is improved, the resultant product is stable and the productivity is improved. Thus the tin-zinc alloy coating film having a high quality can be provided.
    • 锡 - 锌合金电镀浴包括两性表面活性剂,水溶性亚锡盐,水溶性锌盐和余量的水。 当使用本发明的锡 - 锌合金电镀液时,即使在电流密度在宽范围内变化的情况下,形成的涂膜也具有均匀的合金组成。 因此,即使是具有复杂形状的物质,也可以形成具有均匀合金组成的涂膜,并且铬酸盐处理变得令人满意。 结果,改善了涂层的效果,所得产品是稳定的并且提高了生产率。 因此,可以提供具有高质量的锡 - 锌合金涂膜。
    • 16. 发明申请
    • Surface-Treating Aqueous Solution and Treatment Methods for Forming Corrosion-Resistant Coating Film Over Zinc or Zinc Alloy Deposit
    • 表面处理水溶液和锌或锌合金沉积物上形成耐腐蚀涂膜的处理方法
    • US20100297454A1
    • 2010-11-25
    • US12746549
    • 2008-12-08
    • Hitoshi SakuraiSatoshi YuasaKeisuke Nonomura
    • Hitoshi SakuraiSatoshi YuasaKeisuke Nonomura
    • C09D5/08C23F11/00B32B15/04
    • C23C22/05C04B28/26C04B2103/0046C04B2111/00525C08G2150/90C09D1/04C09D5/084C09D163/00C23C22/60C23C22/68C23C2222/20Y10T428/31663C04B24/023C04B24/281C04B24/2641C04B24/282
    • A chromium-free treating liquid and treatment methods which are for imparting to a zinc or zinc alloy deposit a coating film which is highly corrosion-resistant, has a uniform appearance free from sag stains/puddle stains, has no failure concerning thickness unevenness, and has satisfactory adhesion. The surface-treating aqueous solution, which is for forming a corrosion-resistant coating film over a zinc or zinc alloy deposit, is characterized by comprising (a) an alkali metal silicate (M2O.nSiO2 (wherein M represents an alkali metal and n indicates SiO2/M2O molar ratio)), (b) a water-soluble or water-dispersible silane coupling agent, and (c) a water-soluble or water-dispersible glycidyl ether compound. One of the surface treatment methods for forming a highly corrosion-resistant coating film over a zinc or zinc alloy deposit includes bringing the surface of the zinc or zinc alloy deposit into contact with the surface-treating aqueous solution. The surface-treating aqueous solution is applicable also to the surface of a chemical conversion coating film formed on a zinc or zinc alloy deposit and free from hexavalent chromium or from chromium in any form. Namely, another surface treatment method for forming a highly corrosion-resistant coating film over a zinc or zinc alloy deposit comprises bringing the surface of a chemical conversion coating film formed on a zinc or zinc alloy deposit into contact with the surface-treating aqueous solution. Furthermore provided is a highly corrosion-resistant coating film formed by bringing the solution into contact with the surface of a zinc or zinc alloy deposit or with the surface of a chemical conversion coating film formed on a zinc or zinc alloy deposit.
    • 无铬处理液和用于赋予锌或锌合金的处理方法沉积具有高耐腐蚀性的涂膜,具有没有凹陷污渍/水泥污渍的均匀外观,对于厚度不均匀性没有失败,并且 具有令人满意的粘合力。 用于在锌或锌合金沉积物上形成耐腐蚀涂膜的表面处理水溶液的特征在于包含(a)碱金属硅酸盐(M 2 O·nSiO 2(其中M表示碱金属,n表示 SiO 2 / M 2 O摩尔比)),(b)水溶性或水分散性硅烷偶联剂,和(c)水溶性或水分散性缩水甘油醚化合物。 在锌或锌合金沉积物上形成高耐腐蚀涂膜的表面处理方法之一包括使锌或锌合金沉积物的表面与表面处理水溶液接触。 表面处理水溶液也可用于形成于锌或锌合金沉积物上且不含六价铬或以任何形式的铬形成的化学转化膜的表面。 也就是说,用于在锌或锌合金沉积物上形成高耐腐蚀涂膜的另一种表面处理方法包括使形成在锌或锌合金沉积物上的化学转化膜的表面与表面处理水溶液接触。 此外,还提供了通过使溶液与锌或锌合金沉积物的表面或与锌或锌合金沉积物上形成的化学转化膜的表面接触而形成的高度耐腐蚀的涂膜。
    • 20. 发明申请
    • SURFACE-TREATING AQUEOUS SOLUTION AND TREATMENT METHODS FOR FORMING CORROSION-RESISTANT COATING FILM OVER ZINC OR ZINC ALLOY DEPOSIT
    • 表面处理水溶液和处理方法,用于在锌或锌合金沉积物上形成耐腐蚀涂层膜
    • US20150125708A1
    • 2015-05-07
    • US14591049
    • 2015-01-07
    • Hitoshi SakuraiSatoshi YuasaKeisuke Nonomura
    • Hitoshi SakuraiSatoshi YuasaKeisuke Nonomura
    • C23C22/05
    • A chromium-free treating liquid and treatment methods which are for imparting to a zinc or zinc alloy deposit a coating film which is highly corrosion-resistant, has a uniform appearance free from sag stains/puddle stains, has no failure concerning thickness unevenness, and has satisfactory adhesion. The surface-treating aqueous solution, which is for forming a corrosion-resistant coating film over a zinc or zinc alloy deposit, is characterized by comprising (a) an alkali metal silicate (M2O.nSiO2 (wherein M represents an alkali metal and n indicates SiO2/M2O molar ratio)), (b) a water-soluble or water-dispersible silane coupling agent, and (c) a water-soluble or water-dispersible glycidyl ether compound. One of the surface treatment methods for forming a highly corrosion-resistant coating film over a zinc or zinc alloy deposit includes bringing the surface of the zinc or zinc alloy deposit into contact with the surface-treating aqueous solution. The surface-treating aqueous solution is applicable also to the surface of a chemical conversion coating film formed on a zinc or zinc alloy deposit and free from hexavalent chromium or from chromium in any form. Namely, another surface treatment method for forming a highly corrosion-resistant coating film over a zinc or zinc alloy deposit comprises bringing the surface of a chemical conversion coating film formed on a zinc or zinc alloy deposit into contact with the surface-treating aqueous solution. Furthermore provided is a highly corrosion-resistant coating film formed by bringing the solution into contact with the surface of a zinc or zinc alloy deposit or with the surface of a chemical conversion coating film formed on a zinc or zinc alloy deposit.
    • 无铬处理液和用于赋予锌或锌合金的处理方法沉积具有高耐腐蚀性的涂膜,具有没有凹陷污渍/水泥污渍的均匀外观,对于厚度不均匀性没有失败,并且 具有令人满意的粘合力。 用于在锌或锌合金沉积物上形成耐腐蚀涂膜的表面处理水溶液的特征在于包含(a)碱金属硅酸盐(M 2 O·nSiO 2(其中M表示碱金属,n表示 SiO 2 / M 2 O摩尔比)),(b)水溶性或水分散性硅烷偶联剂,和(c)水溶性或水分散性缩水甘油醚化合物。 在锌或锌合金沉积物上形成高耐腐蚀涂膜的表面处理方法之一包括使锌或锌合金沉积物的表面与表面处理水溶液接触。 表面处理水溶液也可用于形成于锌或锌合金沉积物上且不含六价铬或以任何形式的铬形成的化学转化膜的表面。 也就是说,用于在锌或锌合金沉积物上形成高耐腐蚀涂膜的另一种表面处理方法包括使形成在锌或锌合金沉积物上的化学转化膜的表面与表面处理水溶液接触。 此外,还提供了通过使溶液与锌或锌合金沉积物的表面或与锌或锌合金沉积物上形成的化学转化膜的表面接触而形成的高度耐腐蚀的涂膜。