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11. 发明申请

US20050131254A1 Multitube reactor, vapor phase catalytic oxidation method using the multitube reactor, and start up method applied to the multitube reactor 有权
标题翻译：多管反应器，使用多管反应器的气相催化氧化法，以及应用于多管反应器的启动方法
公开(公告)号：US20050131254A1
公开(公告)日：2005-06-16
申请号：US11049106
申请日：2005-02-03
申请人： Shuhei Yada , Hirochika Hosaka , Masayasu Goriki , Kimikatsu Jinno , Yasushi Ogawa , Yoshiro Suzuki
发明人： Shuhei Yada , Hirochika Hosaka , Masayasu Goriki , Kimikatsu Jinno , Yasushi Ogawa , Yoshiro Suzuki
IPC分类号： B01J8/06 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/25 , C07C51/16 , B01J8/04
CPC分类号： B01J35/026 , B01J8/06 , B01J8/067 , B01J23/002 , B01J23/8876 , B01J2208/00221 , B01J2208/0053 , B01J2208/00716 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/252 , F28D7/1607 , F28D2021/0022 , F28F9/026 , F28F9/028 , F28F9/22 , F28F2265/10 , C07C47/22 , C07C57/04 , B01J2523/12 , B01J2523/13 , B01J2523/22 , B01J2523/305 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： A multitube reactor, wherein tubes having smaller tolerance between a nominal size and actual sizes are used as reaction tubes to stably perform a high yield reaction for a long period, a catalyst is filled into the reaction tubes so that the catalyst layer peak temperature portions of the reaction tubes are not overlapped with the connection sites thereof with baffles to effectively prevent hot spots from occurring and stably perform a reaction for a long period without the clogging of the reaction tubes, a heat medium and raw material gas are allowed to flow in the direction of a countercurrent and a specified type of catalyst is filled into the reaction tubes so that activity is increased from the inlet of the raw material gas to the outlet thereof to prevent the autooxidation of products so as to prevent equipment from being damaged due to the reaction, and, at the time of starting, gas with a temperature of 100 to 400° C. is led to the outside of the reaction tubes to increase the temperature of the reaction tubes and, a heat medium, which is solid at the room temperature, is heated to circulate to the outside of the reaction tubes to efficiently start up the reactor without affecting the activity of the catalyst.
摘要翻译：使用多管反应器，其中具有公称尺寸和实际尺寸之间的较小公差的管用作反应管以长期稳定地进行高产率反应，将催化剂填充到反应管中，使得催化剂层峰值温度部分反应管不与其连接位置与挡板重叠，以有效地防止热点发生并且长时间稳定地进行反应而不会使反应管堵塞，允许热介质和原料气体流入将反向的方向和特定类型的催化剂填充到反应管中，使得活性从原料气体的入口到其出口增加，以防止产品的自氧化，从而防止设备因为反应，并且在起始时，将温度为100〜400℃的气体导入反应管的外部以增加反应管的温度和在室温下为固体的热介质被加热以循环到反应管的外部，以有效启动反应器而不影响催化剂的活性。

12. 发明授权

US5910607A Process for producing acrylic acid 失效
标题翻译：丙烯酸生产工艺
公开(公告)号：US5910607A
公开(公告)日：1999-06-08
申请号：US508697
申请日：1995-07-28
申请人： Yasuyuki Sakakura , Masahiko Yamagishi , Hirochika Hosaka
发明人： Yasuyuki Sakakura , Masahiko Yamagishi , Hirochika Hosaka
IPC分类号： C07C51/46 , C07C57/07 , C07C51/21 , C07C51/235
CPC分类号： C07C51/46
摘要： In a process for producing acrylic acid, wherein propylene and/or acrolein is catalytically oxidized with molecular oxygen in a vapor phase and the gas resulting from the oxidation is cooled and/or absorbed in water to form a crude aqueous acrylic acid, followed by azeotropic distillation to remove the water with an entrainer of a boiling point of no higher than 130.degree. C. on the crude aqueous acrylic acid which may have, upon necessity, undergone removal of aldehydes contained therein to produce acrylic acid purified in that the crude aqueous acrylic acid is substantially dehydrated, the improvement which comprises conducting the azeotropic distillation under such conditions that concentrations of the entrainer and water in the bottom product of the azeotropic distillation are from 5% to 30% by weight and no higher than 0.5% by weight, respectively, where the theoretical number of plates in the azeotropic distillation column for dehydration used and that in the distillation column for separating acetic acid used are preferably from 5 to 20. Highly-purified acrylic acid can thus be obtained from the crude aqueous acrylic acid without causing unfavorable polymerization of acrylic acid.
摘要翻译：在制备丙烯酸的方法中，其中丙烯和/或丙烯醛在气相中用分子氧催化氧化，并且由氧化产生的气体在水中冷却和/或吸收以形成粗水性丙烯酸，然后共沸蒸馏以除去水，其中沸点不高于130℃的夹带剂在粗水性丙烯酸上，根据需要，可以将其除去其中所含的醛以产生纯化的丙烯酸，因为粗水性丙烯酸酸基本脱水，其改进包括在共沸蒸馏的底部产物中的夹带剂和水的浓度分别为5重量％至30重量％且不高于0.5重量％的条件下进行共沸蒸馏，其中用于脱水的共沸蒸馏塔中的理论塔板数和蒸馏塔中的板的理论数量所使用的分离乙酸优选为5〜20。因此，可以从粗水性丙烯酸获得高度纯化的丙烯酸，而不会引起丙烯酸的不利聚合。

13. 发明申请

US20080253943A1 Method for vapor phase catalytic oxidation 审中-公开
标题翻译：汽相催化氧化法
公开(公告)号：US20080253943A1
公开(公告)日：2008-10-16
申请号：US12081918
申请日：2008-04-23
申请人： Shuhei Yoda , Masayasu Goriki , Hirochika Hosaka , Kimikatsu Jinno , Teruo Saito , Yoshiro Suzuki
发明人： Shuhei Yoda , Masayasu Goriki , Hirochika Hosaka , Kimikatsu Jinno , Teruo Saito , Yoshiro Suzuki
IPC分类号： B01J4/00 , B01J8/00 , B65G69/04
CPC分类号： B01J8/003 , B01J8/0085 , B01J8/067 , B01J23/002 , B01J23/28 , B01J23/31 , B01J23/8876 , B01J35/026 , B01J2208/00212 , B01J2208/00221 , B01J2208/00513 , B01J2208/00539 , B01J2208/00663 , B01J2208/00752 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/12 , B01J2523/13 , B01J2523/305 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： An object of the present invention is to provide a method for vapor phase catalytic oxidation which is almost free of variations in reaction states in respective reaction tubes of the fixed bed multi-tube heat-exchanger type reactor.Provided is a method for vapor phase catalytic oxidation for obtaining a reaction product gas by using a fixed bed multi-tube heat-exchanger type reactor provided with a plurality of reaction tubes and by feeding a raw material gas inside the reaction tubes packed with a catalyst, wherein the method comprises: adjusting pressure losses of the respective reaction tubes so that the pressure losses of the respective reaction tubes after catalyst packing is within ±20% of an average pressure loss of the reaction tubes by: packing an inert substance at a raw material gas inlet portion of the reaction tubes or removing and re-packing the catalyst packed, for a reaction tube having a pressure loss lower than the average pressure loss of the reaction tubes; and removing and re-packing the catalyst packed, for a reaction tube having a pressure loss higher than the average pressure loss of the reaction tubes.
摘要翻译：本发明的目的是提供一种气相催化氧化方法，其几乎不含固定床多管式热交换器型反应器各反应管中的反应状态的变化。本发明提供一种气相催化氧化法，其特征在于，使用具有多个反应管的固定床多管式热交换型反应器，在反应管内填充有催化剂的原料气体其中所述方法包括：调节各反应管的压力损失，使得在催化剂填充之后各反应管的压力损失在反应管的平均压力损失的±20％内，通过以下方式包装惰性物质：反应管的原料气体入口部分或者拆卸并重新填充催化剂，对于压力损失低于反应管的平均压力损失的反应管; 并且对于具有高于反应管的平均压力损失的压力损失的反应管，除去并重新填充催化剂。

14. 发明授权

US07388108B2 Oxidation reactor, process for producing (meth)acrylic acids, and method for analyzing easily-polymerizable compounds 有权
公开(公告)号：US07388108B2
公开(公告)日：2008-06-17
申请号：US11586691
申请日：2006-10-26
申请人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Hirochika Hosaka , Yasuhiko Samura
发明人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Hirochika Hosaka , Yasuhiko Samura
IPC分类号： C07C51/16 , G01N35/08
CPC分类号： B01J8/008 , B01J4/002 , B01J8/02 , B01J19/26 , B01J2208/00973 , B01J2208/025 , B01J2219/00006 , B01J2219/00119 , B01J2219/00247 , B01J2219/00252 , C07C45/35 , C07C51/215 , C07C51/252 , G01N1/2035 , G01N1/2247 , G01N31/005 , G01N33/44 , G01N2001/1062 , G01N2001/2057 , G01N2001/2285 , Y10T436/117497 , C07C47/22 , C07C57/04
摘要： An oxidation reactor includes a reactor body, a manhole nozzle projecting from the reactor body, and a partition plate separating an inside of the manhole nozzle and an inside of the reactor body from each other. In an oxidation reactor including the reactor body and a nozzle projecting from the reactor body, there is provided a means for feeding an inert gas into the nozzle. In a process for producing (meth)acrylic acids by subjecting propane, propylene or isobutylene to catalytic gas-phase oxidation reaction in an oxidation reactor for producing (meth)acrolein or (meth)acrylic acid, the above oxidation reactor is used as the oxidation reactor. In a method for analyzing an easily-polymerizable compound by introducing a gas containing the easily-polymerizable compound into an analyzing apparatus through a sampling tube, a double tube is used as the sampling tube, and a heating medium is fed into an outer tube of the double tube. According to these methods, the oxidation reaction can be stably conducted, and the reaction product gas can be prevented from being condensed and polymerized in the sampling tube, so that an on-line analysis can be performed at a high accuracy for a long period of time.

15. 发明申请

US20070256921A1 Process for producing (meth) acrylic acids and process for distilling the same 审中-公开
标题翻译：（甲基）丙烯酸的制造方法及蒸馏法
公开(公告)号：US20070256921A1
公开(公告)日：2007-11-08
申请号：US11812716
申请日：2007-06-21
申请人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Kimikatsu Jinno , Hirochika Hosaka , Kenji Takasaki , Masayasu Goriki
发明人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Kimikatsu Jinno , Hirochika Hosaka , Kenji Takasaki , Masayasu Goriki
IPC分类号： B01D3/00
CPC分类号： C07C51/44 , B01D3/14 , B01D3/146 , B01D3/42 , B01D3/4211 , C07C67/54 , C07C57/04 , C07C69/54
摘要： In the stopping and starting operations of a distillation column used for producing (meth)acrylic acids according to the present invention, upon stopping the operation of the distillation column, the heating of a reboiler attached thereto is interrupted and then the reboiler is rapidly cooled; and/or upon starting the operation of the distillation column for production of the (meth)acrylic acids, an inner wall surface of the distillation column is heated to a temperature higher than a condensation temperature of the (meth)acrylic acids and the operation of the distillation column is started under the heated condition. According to the present invention, it is possible to early and safely stop the operation of the distillation column while preventing the occurrence of polymerization within the distillation column, and stably perform an operation for distillation of acrylic monomers for a long period of time.
摘要翻译：在根据本发明的用于生产（甲基）丙烯酸的蒸馏塔的停止和开始操作中，停止蒸馏塔的操作后，连接的再沸器的加热被中断，然后再沸器被快速冷却; 和/或在开始用于生产（甲基）丙烯酸的蒸馏塔的操作时，将蒸馏塔的内壁表面加热到高于（甲基）丙烯酸的冷凝温度的温度和蒸馏塔在加热条件下启动。根据本发明，能够在避免蒸馏塔内发生聚合的同时，早日安全地停止蒸馏塔的运转，并且能够长时间稳定地进行丙烯酸类单体的蒸馏操作。

16. 发明申请

US20070021633A1 Process for producing (meth)acrylic acids and process for distilling the same 有权
标题翻译：（甲基）丙烯酸的制造方法及蒸馏法
公开(公告)号：US20070021633A1
公开(公告)日：2007-01-25
申请号：US11526730
申请日：2006-09-26
申请人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Kimikatsu Jinno , Hirochika Hosaka , Kenji Takasaki , Masayasu Goriki
发明人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Kimikatsu Jinno , Hirochika Hosaka , Kenji Takasaki , Masayasu Goriki
IPC分类号： C07C51/42
CPC分类号： C07C51/44 , B01D3/14 , B01D3/146 , B01D3/42 , B01D3/4211 , C07C67/54 , C07C57/04 , C07C69/54
摘要： In the stopping and starting operations of a distillation column used for producing (meth)acrylic acids according to the present invention, upon stopping the operation of the distillation column, the heating of a reboiler attached thereto is interrupted and then the reboiler is rapidly cooled; and/or upon starting the operation of the distillation column for production of the (meth)acrylic acids, an inner wall surface of the distillation column is heated to a temperature higher than a condensation temperature of the (meth)acrylic acids and the operation of the distillation column is started under the heated condition. According to the present invention, it is possible to early and safely stop the operation of the distillation column while preventing the occurrence of polymerization within the distillation column, and stably perform an operation for distillation of acrylic monomers for a long period of time.
摘要翻译：在根据本发明的用于生产（甲基）丙烯酸的蒸馏塔的停止和开始操作中，停止蒸馏塔的操作后，连接的再沸器的加热被中断，然后再沸器被快速冷却; 和/或在开始用于生产（甲基）丙烯酸的蒸馏塔的操作时，将蒸馏塔的内壁表面加热到高于（甲基）丙烯酸的冷凝温度的温度和蒸馏塔在加热条件下启动。根据本发明，能够在避免蒸馏塔内发生聚合的同时，早日安全地停止蒸馏塔的运转，并且能够长时间稳定地进行丙烯酸类单体的蒸馏操作。

17. 发明授权

US07119227B2 Process for catalytic vapor phase oxidation 有权
标题翻译：催化气相氧化工艺
公开(公告)号：US07119227B2
公开(公告)日：2006-10-10
申请号：US10937657
申请日：2004-09-10
申请人： Yasuyuki Sakakura , Shuhei Yada , Kimikatsu Jinno , Hirochika Hosaka , Yoshiro Suzuki
发明人： Yasuyuki Sakakura , Shuhei Yada , Kimikatsu Jinno , Hirochika Hosaka , Yoshiro Suzuki
IPC分类号： C07C51/16
CPC分类号： C07C45/35 , B01J8/067 , B01J2208/00053 , B01J2208/00061 , B01J2208/00088 , B01J2208/00221 , B01J2208/00256 , B01J2208/0053 , B01J2208/025 , B01J2219/0002 , B01J2219/00259 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The present invention provides a process for catalytic vapor phase oxidation which prevents runaway reaction or early deterioration of a catalyst, in the production of (meth)acrylic acid or the like from propylene or isobutylene by the catalytic vapor phase oxidation process using a multi-tubular reactor, which can lead to the production thereof constantly in high yield for a long period of time. Further, the present invention provides a process for catalytic vapor phase oxidation wherein raw material gas is introduced for oxidation into reaction tubes of a multi-tubular reactor which is equipped with, as arranged within the shell of the reactor, a plurality of reaction tubes having a catalyst packed therein and a plurality of baffle plates for changing the direction of the flow of a heating medium introduced into the shell, characterized in that the temperature of the catalyst packed in a reaction tube which is not connected with at least one baffle plate is measured at plural points in the direction of an axis of the reaction tube.
摘要翻译：本发明提供催化气相氧化方法，其通过使用多管状催化气相氧化法从丙烯或异丁烯生产（甲基）丙烯酸等，防止催化剂失控反应或早期劣化反应器，其可以长时间以高产率持续地生产。此外，本发明提供了一种催化气相氧化方法，其中将原料气体引入氧化成多管式反应器的反应管中，该多管式反应器配备有布置在反应器壳体内的多个反应管，其具有填充在其中的催化剂和用于改变引入壳体的加热介质的流动方向的多个挡板，其特征在于，填充在与至少一个挡板相连的反应管中的催化剂的温度为在反应管的轴线方向的多个点处测量。

18. 发明授权

US07080654B2 Method for transporting easily polymerizable liquid by pipeline 有权
标题翻译：通过管道输送容易聚合的液体的方法
公开(公告)号：US07080654B2
公开(公告)日：2006-07-25
申请号：US10856804
申请日：2004-06-01
申请人： Shuhei Yada , Kenji Takasaki , Yasushi Ogawa , Yoshiro Suzuki , Hirochika Hosaka
发明人： Shuhei Yada , Kenji Takasaki , Yasushi Ogawa , Yoshiro Suzuki , Hirochika Hosaka
IPC分类号： F17D1/08
CPC分类号： F17D1/08 , Y10T137/0318 , Y10T137/87265 , Y10T137/87354 , Y10T137/87394
摘要： A method for transporting an easily polymerizable liquid by a pipeline having branches, wherein among pipelines branched at a branch point, one pipeline which may not be used over a long period of time, is provided with a valve to close the pipeline, within 500 mm from the branch point.
摘要翻译：通过具有分支的管道输送容易聚合的液体的方法，其中在分支点分支的管道中，一个长时间不使用的管道设置有阀，以在500mm内关闭管道从分支点。

19. 发明申请

US20050209482A1 Storage tank for easily polymerizable compound and method of storage 有权
标题翻译：容易聚合的化合物储存罐和储存方法
公开(公告)号：US20050209482A1
公开(公告)日：2005-09-22
申请号：US11133184
申请日：2005-05-20
申请人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Kimikatsu Jinno , Hirochika Hosaka , Masayasu Goriki
发明人： Shuhei Yada , Yasushi Ogawa , Yoshiro Suzuki , Kimikatsu Jinno , Hirochika Hosaka , Masayasu Goriki
IPC分类号： B01J4/00 , B01J19/00 , B65D90/00 , C07C51/42 , C07C51/50 , C07C57/04 , C07C67/48 , F16L23/00 , F17D1/08 , G05D7/00
CPC分类号： B01J19/00 , B01J2219/00006 , B01J2219/00083 , B01J2219/00247 , B01J2219/00252 , B01J2219/00254 , Y10T137/0391 , Y10T137/6416 , Y10T137/6579 , Y10T137/85978
摘要： The storage tank of the invention for an easily polymerizable compound is a storage tank having an acceptance piping and a delivery piping and is characterized by having a circulation line which directly connects the acceptance piping to the delivery piping or having circulation lines which respectively connect the acceptance piping to the storage tank and the storage tank to the delivery piping; the method of storing of the invention is characterized by storing an easily polymerizable compound in the storage tank while circulating the compound in the storage tank through the circulation line(s); the method of pipe jointing and apparatus therefor of the invention are a method of jointing pipes fitted to a handling apparatus in a production apparatus, storage apparatus, or the like for the purpose of transporting a corrosive liquid, the method being characterized in that the pipes are jointed with flanges, bolts, and nuts made of a material having resistance to corrosion by the corrosive liquid; the process for (meth)acrylic acid compound production of the invention is a process for producing and/or purifying a (meth)acrylic acid compound, and is characterized in that the temperature of a purified (meth)acrylic acid compound obtained which is being supplied to a storage tank is regulated so as to be not higher than the temperature of the purified (meth)acrylic acid compound residing in the storage tank; and the process of the invention for producing an easily polymerizable compound which is a (meth)acrylic acid compound is characterized in that the temperature of a (meth)acrylic acid compound-containing liquid which has been discharged as an off-specification product and is being supplied to a storage tank is regulated so as to be not higher than the temperature of the off-specification liquid stored in the storage tank.
摘要翻译：用于易聚合化合物的本发明的储罐是具有接受管道和输送管道的储罐，其特征在于，具有将接收管道直接连接到输送管道的循环管线或具有分别连接接收的循环管线管道到储罐和储罐到输送管道; 本发明的储存方法的特征在于，通过在循环管道中使化合物在储罐中循环而将容易聚合的化合物储存在储罐中; 本发明的管接头方法及其设备是在制造装置，储存装置等中装配于处理装置的管道的输送腐蚀性液体的方法，其特征在于，管道与由腐蚀性液体具有腐蚀性的材料制成的法兰，螺栓和螺母接合; 本发明的（甲基）丙烯酸化合物的制造方法是（甲基）丙烯酸化合物的制造和/或纯化方法，其特征在于，得到的纯化的（甲基）丙烯酸化合物的温度为调节供给到储罐的温度不高于存储在储罐中的纯化的（甲基）丙烯酸化合物的温度; 本发明的制备作为（甲基）丙烯酸化合物的易聚合性化合物的方法的特征在于，作为脱离规格的产品排出的（甲基）丙烯酸化合物的液体的温度为被调节为不高于储存在储罐中的不合格液体的温度。

20. 发明申请

US20050107483A1 Process for catalytic vapor phase oxidation 有权
标题翻译：催化气相氧化工艺
公开(公告)号：US20050107483A1
公开(公告)日：2005-05-19
申请号：US10937657
申请日：2004-09-10
申请人： Yasuyuki Sakakura , Shuhei Yada , Kimikatsu Jinno , Hirochika Hosaka , Yoshiro Suzuki
发明人： Yasuyuki Sakakura , Shuhei Yada , Kimikatsu Jinno , Hirochika Hosaka , Yoshiro Suzuki
IPC分类号： C07C27/04 , B01J8/06 , C07C45/35 , C07C51/25 , C07C27/26
CPC分类号： C07C45/35 , B01J8/067 , B01J2208/00053 , B01J2208/00061 , B01J2208/00088 , B01J2208/00221 , B01J2208/00256 , B01J2208/0053 , B01J2208/025 , B01J2219/0002 , B01J2219/00259 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The present invention provides a process for catalytic vapor phase oxidation which prevents runaway reaction or early deterioration of a catalyst, in the production of (meth)acrylic acid or the like from propylene or isobutylene by the catalytic vapor phase oxidation process using a multi-tubular reactor, which can lead to the production thereof constantly in high yield for a long period of time. Further, the present invention provides a process for catalytic vapor phase oxidation wherein raw material gas is introduced for oxidation into reaction tubes of a multi-tubular reactor which is equipped with, as arranged within the shell of the reactor, a plurality of reaction tubes having a catalyst packed therein and a plurality of baffle plates for changing the direction of the flow of a heating medium introduced into the shell, characterized in that the temperature of the catalyst packed in a reaction tube which is not connected with at least one baffle plate is measured at plural points in the direction of an axis of the reaction tube.
摘要翻译：本发明提供催化气相氧化方法，其通过使用多管状催化气相氧化法从丙烯或异丁烯生产（甲基）丙烯酸等，防止催化剂失控反应或早期劣化反应器，其可以长时间以高产率持续地生产。此外，本发明提供了一种催化气相氧化方法，其中将原料气体引入氧化成多管式反应器的反应管中，该多管式反应器配备有布置在反应器壳体内的多个反应管，其具有填充在其中的催化剂和用于改变引入壳体的加热介质的流动方向的多个挡板，其特征在于，填充在与至少一个挡板相连的反应管中的催化剂的温度为在反应管的轴线方向的多个点处测量。

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