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11. 发明授权

US5474811A Composite color-plus-clear coating utilizing carbamate-functional polymer composition in the clearcoat 失效
标题翻译：在透明涂层中使用氨基甲酸酯官能聚合物组合物的复合颜色加透明涂层
公开(公告)号：US5474811A
公开(公告)日：1995-12-12
申请号：US241925
申请日：1994-05-11
申请人： John W. Rehfuss , Donald L. St. Aubin
发明人： John W. Rehfuss , Donald L. St. Aubin
IPC分类号： B05D1/36 , B05D7/24 , C08G18/38 , C08G18/72 , C08L61/20 , C08L73/00 , C08L73/02 , C09D133/06 , C09D157/12 , C09D161/20 , C09D161/28 , C09D183/04 , C09D201/00 , C09D201/02
CPC分类号： C09D201/025 , C08G18/3831 , C08G18/728 , C09D133/062 , C08L61/20 , Y10T428/31855
摘要： A method of producing an article with a color-plus-clear composite coating is described. The method comprises the steps of applying a colored coating composition to a substrate, and applying a clear coating composition over the colored coating composition, wherein the clear coating composition is a curable coating composition comprising:(a) a first component comprising a polymer backbone having appended thereto at least one carbamate functional group, and(b) a second component comprising a compound having a plurality of functional groups that are reactive with said carbamate group.
摘要翻译：描述了制造具有彩色 - 透明复合涂层的制品的方法。该方法包括以下步骤：将着色涂料组合物施用到基材上，以及在着色涂料组合物上施用透明涂料组合物，其中透明涂料组合物是可固化涂料组合物，其包含：（a）第一组分，其包含聚合物主链，附加至少一个氨基甲酸酯官能团，和（b）第二组分，其包含具有多个与所述氨基甲酸酯基团反应的官能团的化合物。

12. 发明授权

US5021470A Flexible aryl alkyl epoxy resins, their amine resin derivatives and their use in electrodeposition coatings 失效
标题翻译：柔性芳基烷基环氧树脂，它们的胺树脂衍生物及其在电沉积涂料中的应用
公开(公告)号：US5021470A
公开(公告)日：1991-06-04
申请号：US327751
申请日：1989-03-23
申请人： James A. Laugal , Glenn E. Martin , Donald L. St. Aubin , Gerald G. Wold
发明人： James A. Laugal , Glenn E. Martin , Donald L. St. Aubin , Gerald G. Wold
IPC分类号： C08G59/06 , C08G59/22 , C08G59/50 , C09D5/44 , C09D163/00
CPC分类号： C09D5/4434 , C08G59/066 , C08G59/226 , C08G59/50 , C09D163/00
摘要： A series of oligomeric adducts of diols and diepoxides are disclosed which are precursors of amine resins for use in electrodeposition coatings. The adducts are epoxide-alcohol addition products of a polyaromatic and/or a mono-aromatic diol and a polyaromatic bis-glycidyl ether, and/or a monoaromatic bis-glycidyl ether and/or an alkoxy arylene bis-glycidyl ether, thioether or amine. The coatings which include amine resin, cross linking agent, grind resin and pigment exhibit excellent corrosion resistance.
摘要翻译：公开了一系列二醇和二环氧化物的低聚加合物，其是用于电沉积涂料的胺树脂的前体。加合物是多芳族和/或单芳族二醇和多芳族双缩水甘油醚和/或单芳族双缩水甘油醚和/或烷氧基亚芳基双缩水甘油醚，硫醚或胺的环氧化物 - 醇加成产物。包括胺树脂，交联剂，研磨树脂和颜料的涂层表现出优异的耐腐蚀性。

13. 发明授权

US4857567A Flexible aryl alkyl epoxy resins, their amine resin derivatives and their use in electrodeposition coatings 失效
标题翻译：柔性芳基烷基环氧树脂，它们的胺树脂衍生物及其在电沉积涂料中的应用
公开(公告)号：US4857567A
公开(公告)日：1989-08-15
申请号：US77492
申请日：1987-07-24
申请人： James A. Laugal , Glenn E. Martin , Donald L. St. Aubin , Gerald G. Wold
发明人： James A. Laugal , Glenn E. Martin , Donald L. St. Aubin , Gerald G. Wold
IPC分类号： C08G59/62 , C08G59/06 , C08G59/14 , C08G59/20 , C08G59/22 , C08G59/40 , C08G59/50 , C09D5/44 , C09D163/00
CPC分类号： C08G59/226 , C08G59/066 , C08G59/50 , C09D163/00 , C09D5/4434
摘要： A series of oligomeric adducts of diols and diepoxides are disclosed which are precursors of amine resins for use in electrodeposition coatings. The adducts are epoxide-alcohol addition products of a polyaromatic and/or a mono-aromatic diol and a polyaromatic bis-glycidyl ether, and/or a monoaromatic bis-glycidyl ether and/or an alkoxy arylene bis-glycidyl ether, thioether or amine. The coatings which include amine resin, cross linking agent, grind resin and pigment exhibit excellent corrosion resistance.

14. 发明授权

US07179861B2 Carbamate functional addition polymers and a method for their preparation 失效
标题翻译：氨基甲酸酯官能加成聚合物及其制备方法
公开(公告)号：US07179861B2
公开(公告)日：2007-02-20
申请号：US10815327
申请日：2004-04-01
申请人： Donald H. Campbell , Donald L. St. Aubin , Walter H. Ohrbom
发明人： Donald H. Campbell , Donald L. St. Aubin , Walter H. Ohrbom
IPC分类号： C08F8/30
CPC分类号： C09D201/025 , C08F222/20 , C08F222/22
摘要： A carbamate or terminal urea functional vinyl polymer is prepared by reacting a compound having an hydroxyl group and a carbamate group, terminal urea group, or a group that can be converted to a carbamate or terminal urea group, with a cyclic carboxylic acid anhydride group to form an ester bond and a free acid group from the anhydride; and reacting the free acid group with a compound having an epoxide group. The cyclic carboxylic acid anhydride group may be pendant to a vinyl polymer, or one of the compound having an hydroxyl group, a compound having the cyclic carboxylic acid anhydride group, and the compound having an epoxide group may have polymerizable ethylenic unsaturation that is polymerized, optionally with one or more copolymerizable monomers to form a vinyl polymer. When the compound having an hydroxyl group has a group that can be converted to a carbamate or terminal urea group, the group is converted to the carbamate or terminal urea group after step (a). The carbamate or terminal urea functional vinyl polymer may be included in a coating composition. The coating composition may be applied to a substrate and cured to form a cured coating on the substrate.
摘要翻译：通过将具有羟基和氨基甲酸酯基的化合物，末端脲基团或可转化为氨基甲酸酯或末端脲基团的化合物与环状羧酸酐基团反应制备氨基甲酸酯或末端脲官能乙烯基聚合物，从酸酐形成酯键和游离酸基团; 并使游离酸基与具有环氧基的化合物反应。环状羧酸酐基可以侧链至乙烯基聚合物，或具有羟基的化合物，具有环状羧酸酐基的化合物和具有环氧基的化合物之间可具有可聚合的烯属不饱和基团，任选地与一种或多种可共聚单体形成乙烯基聚合物。当具有羟基的化合物具有可以转化为氨基甲酸酯或末端脲基团的基团时，在步骤（a）之后将该基团转化为氨基甲酸酯或末端脲基团。氨基甲酸酯或末端脲官能的乙烯基聚合物可以包括在涂料组合物中。涂料组合物可以施加到基底上并固化以在基底上形成固化的涂层。

15. 发明授权

US06890994B2 Curable coating compositions with carbamate-containing acrylic polymers 失效
标题翻译：含氨基甲酸酯的丙烯酸聚合物的可固化涂料组合物
公开(公告)号：US06890994B2
公开(公告)日：2005-05-10
申请号：US10305284
申请日：2002-11-26
申请人： Walter H. Ohrbom , Craig S. Schang , Donald Campbell , Donald L. St. Aubin
发明人： Walter H. Ohrbom , Craig S. Schang , Donald Campbell , Donald L. St. Aubin
IPC分类号： C07C217/12 , C07C271/16 , C08F20/36 , C08G18/28 , C08G18/38 , C08G71/04 , C09D175/04 , C09D201/02 , C08F2/00
CPC分类号： C07C217/12 , C07C271/16 , C08F20/36 , C08G18/285 , C08G18/3831 , C08G71/04 , C09D175/04 , C09D201/025 , Y10T428/31529 , Y10T428/31663 , C08L2666/16 , C08L2666/02 , C08L2666/28
摘要： The invention provides an acrylic polymer or oligomer comprising random repeating units of the formula: a method of making said polymers and curable coating compositions comprising the same.
摘要翻译：本发明提供了包含下式的无规重复单元的丙烯酸聚合物或低聚物：制备所述聚合物的方法和包含该聚合物的可固化涂料组合物。

16. 发明授权

US06858693B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
标题翻译：具有改进粘合性的氨基甲酸酯官能树脂，其制备方法以及改进层间粘附性的方法
公开(公告)号：US06858693B2
公开(公告)日：2005-02-22
申请号：US10602852
申请日：2003-06-24
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C09D5/00 , C08F8/00 , C08F8/30 , C08F220/00 , C08G18/38 , C08G18/81 , C09D133/00 , C09D157/06 , C09D183/04 , C09D201/02 , C09J5/00 , C08F126/02
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
摘要翻译：本发明提供氨基甲酸酯官能树脂和包含所述树脂的涂料组合物，其相对于随后施加的膜或涂层具有改善的粘合性。更具体地说，本发明涉及具有每个氨基甲酸酯基团至少250克聚合物的氨基甲酸酯官能加成聚合物，它们以小于35重量％的非官能单体，优选小于20重量％，最优选0至小于10重量％，基于聚合物的总重量。本发明还提供一种制备通过所要求保护的方法制备的氨基甲酸酯官能聚合物和氨基甲酸酯官能聚合物的方法。最后，本发明提供了一种用于改善第一涂料组合物与随后施加的材料的粘附性的方法，以及制备包含涂覆的基材，粘合剂组合物和具有至少一个表面的玻璃的复合材料的方法。

17. 发明授权

US06855789B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06855789B2
公开(公告)日：2005-02-15
申请号：US10348484
申请日：2003-03-25
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C09D5/00 , C08F8/00 , C08F8/30 , C08F220/00 , C08G18/38 , C08G18/81 , C09D133/00 , C09D157/06 , C09D183/04 , C09D201/02 , C09J5/00 , C08F126/02
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

18. 发明授权

US06696159B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06696159B2
公开(公告)日：2004-02-24
申请号：US10348491
申请日：2003-01-21
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce Oermann
IPC分类号： B32B2700
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

19. 发明授权

US6106951A Curable coating compositions containing carmamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的可固化涂料组合物
公开(公告)号：US6106951A
公开(公告)日：2000-08-22
申请号：US198472
申请日：1998-11-24
申请人： Walter H Ohrbom , Donald L. St. Aubin , John W. Rehfuss
发明人： Walter H Ohrbom , Donald L. St. Aubin , John W. Rehfuss
IPC分类号： B05D7/24 , C08F8/30 , C08L61/20 , C09D133/00 , C09D133/06 , C09D161/20 , C09D161/28 , B32B27/30 , B32B27/42 , C09D133/04
CPC分类号： C08F8/30 , C09D133/062 , C08L61/20 , Y10T428/31551 , Y10T428/31605 , Y10T428/31688 , Y10T428/31699 , Y10T428/31935 , Y10T428/31942
摘要： The invention provides a process that includes a first step of reacting the hydroxyl groups of a acrylic resin having hydroxyl groups and carbamate groups with a compound that converts the hydroxyl groups to new groups unreactive with an aminoplast crosslinker; a second step of combining the acrylic resin reaction product with at least an aminoplast crosslinker to form a coating composition; and a third step of applying the coating composition to a substrate and curing the applied coating layer, in which substantially no ether linkages are formed. Aminoplast crosslinkers are desirable for other reasons such as providing high solids coatings having excellent appearance that cure under moderate conditions. Avoiding the ether linkages that could be formed by reaction of aminoplast crosslinkers with hydroxyl groups improves the resistance of the cured coating to environmental etch.
摘要翻译：本发明提供了一种方法，其包括使具有羟基的丙烯酸树脂和氨基甲酸酯基团的羟基与将羟基转化为不与氨基塑料交联剂反应的新基团的化合物的第一步骤; 将丙烯酸树脂反应产物与至少一种氨基塑料交联剂组合以形成涂料组合物的第二步骤; 以及第三步骤，将涂料组合物施加到基材上并固化涂覆的涂层，其中基本上不形成醚键。氨基塑料交联剂由于其它原因是理想的，例如提供在中等条件下固化的具有优异外观的高固含量涂层。避免通过氨基塑料交联剂与羟基反应形成的醚键可以改善固化涂层对环境蚀刻的阻力。

20. 发明授权

US5719237A Coating composition utilizing non-polymeric carbamate-functional compound 失效
标题翻译：使用非聚合氨基甲酸酯官能化合物的涂料组合物
公开(公告)号：US5719237A
公开(公告)日：1998-02-17
申请号：US333915
申请日：1994-11-03
申请人： John W. Rehfuss , Walter H. Ohrbom , Donald L. St. Aubin , Robert J. Taylor
发明人： John W. Rehfuss , Walter H. Ohrbom , Donald L. St. Aubin , Robert J. Taylor
IPC分类号： C08G18/80 , C08G18/28 , C08G18/83 , C09D161/20 , C09D175/00 , C09D175/04 , C08F283/00
CPC分类号： C08G18/83 , C08G18/285 , C09D175/04
摘要： Coatings are described derived from a curable coating composition comprising: (a) a non-polymeric organic compound having a molecular weight of from 75 to 2000 comprising a plurality of carbamate active hydrogens, and (b) a second component comprising a compound having a plurality of functional groups that are reactive with said carbamate active hydrogens.
摘要翻译：来自可固化涂料组合物的涂料的描述包括：（a）分子量为75至2000的包含多个氨基甲酸酯活性氢的非聚合有机化合物，和（b）包含具有多个氨基甲酸酯化合物的化合物的第二组分与所述氨基甲酸酯活性氢反应的官能团。

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