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    • 13. 发明申请
    • USE OF POLYMER POWDER CONTAINING UV ABSORBER FOR THE STABILISATION OF POLYMERS AGAINST THE EFFECTS OF UV RADIATION
    • 包含紫外线吸收剂的聚合物粉末对紫外线辐射效应的聚合物稳定化的应用
    • US20100190929A1
    • 2010-07-29
    • US12756061
    • 2010-04-07
    • Rainer Dyllick-BrenzingerOliver KochDirk WulffAlban Glaser
    • Rainer Dyllick-BrenzingerOliver KochDirk WulffAlban Glaser
    • C08L23/00
    • C08K5/005
    • The present invention relates to the use, for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, of fine-particle polymer powders comprising at least one UV absorber. The present invention further relates to stabilizer mixtures for stabilizing polymers with respect to exposure to UV radiation, oxygen and heat, which, inter alia, comprise these polymer powders, and to a process for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, oxygen and heat, which comprises adding, to the polymers, in particular to the polyolefins, an effective amount of these stabilizers. The present invention further relates to polymers, in particular polyolefins, which have been stabilized with respect to exposure to UV radiation or with respect to exposure to UV radiation, oxygen and heat, which comprise an effective amount of these polymer powders or, respectively, stabilizer mixtures, and to articles produced from these stabilized polymers, in particular polyolefins.
    • 本发明涉及用于稳定聚合物,特别是关于暴露于UV辐射的聚烯烃,包含至少一种UV吸收剂的细颗粒聚合物粉末的用途。 本发明还涉及用于稳定聚合物相对于暴露于UV辐射,氧和热的稳定剂混合物,其特别包括这些聚合物粉末,以及用于稳定聚合物,特别是聚烯烃的方法,涉及暴露于 UV辐射,氧气和热量,其包括向聚合物,特别是聚烯烃中加入有效量的这些稳定剂。 本发明还涉及聚合物,特别是聚烯烃,其已经相对于暴露于UV辐射或相对于暴露于UV辐射,氧和热而被稳定,其包含有效量的这些聚合物粉末或分别为稳定剂 混合物,以及由这些稳定的聚合物,特别是聚烯烃生产的制品。
    • 14. 发明申请
    • STABILIZER MIXTURE
    • 稳定剂混合物
    • US20100160502A1
    • 2010-06-24
    • US12160724
    • 2007-01-12
    • Simon SchambonyAlban GlaserHubert TrauthManfred AppelSylke Haremza
    • Simon SchambonyAlban GlaserHubert TrauthManfred AppelSylke Haremza
    • C08K5/3435
    • C08K5/3435C07B63/04C07D211/58C08K5/34C08K2201/014C08L23/12C08L2201/08C09D7/48C09K15/20C09K15/30
    • Suitable stabilizers for organic material are a mixture comprising A. at least one oligomeric compound, comprising repeat units of the formula (I), in which the meanings of the symbols are as follows: R1 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5-C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula —CR′═CH—CO—OR″, where R′ is hydrogen, C1-C6-alkyl or a radical of the formula —CO—OR″, and R″ is C1-C18-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl, or tolyl; R2 is a mixture composed of C14-C28-alkyl groups, where two of these alkyl groups whose number of carbon atoms is not permitted to differ by more than two respectively make up at least 30% of this mixture; R3 and R4, independently of one another, are C1-C6-alkyl; and B. at least one compound of the formula (II) or (III) where the meanings of the symbols and indices are as follows: n and m, independently of one another, are a natural number from 2 to 22, and R1, R3 and R4, independently of one another, have the meanings given in formula (I).
    • 用于有机材料的合适的稳定剂是包含A.至少一种低聚化合物的混合物,其包含式(I)的重复单元,其中符号的含义如下:R 1是氢,C 1 -C 6 - 烷基,甲酰基, C 2 -C 6 - 烷酰基,C 1 -C 12 - 烷氧基,C 5 -C 6 - 环烷氧基,氰基甲基,2-羟基乙基,苄基或式-CR'≡CH-CO-OR的基团,其中R'是氢,C1- C6烷基或式-CO-OR基团,R“为C1-C18-烷基,C5-C8-环烷基,C7-C18-芳烷基,苯基或甲苯基; R2是由C14-C28-烷基组成的混合物,其中不允许两个以上碳原子数不同的这些烷基中的两个分别构成该混合物的至少30% R 3和R 4彼此独立地为C 1 -C 6 - 烷基; 和B.至少一种式(II)或(III)的化合物,其中符号和指数的含义如下:n和m彼此独立地是2至22的自然数,并且R 1, R 3和R 4彼此独立地具有式(I)中给出的含义。
    • 18. 发明申请
    • Use of polymer powder containing uv absorber for the stabilisation of polymers against the effects of uv radiation
    • 使用含有紫外吸收剂的聚合物粉末来稳定聚合物以抵抗紫外辐射的影响
    • US20060058430A1
    • 2006-03-16
    • US10535860
    • 2003-11-11
    • Rainer Dyllick-BrenzingerOliver KochDirk WulffAlban Glaser
    • Rainer Dyllick-BrenzingerOliver KochDirk WulffAlban Glaser
    • C08K5/49
    • C08K5/005
    • The present invention relates to the use, for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, of fine-particle polymer powders comprising at least one UV absorber. The present invention further relates to stabilizer mixtures for stabilizing polymers with respect to exposure to UV radiation, oxygen and heat, which, inter alia, comprise these polymer powders, and to a process for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, oxygen and heat, which comprises adding, to the polymers, in particular to the polyolefins, an effective amount of these stabilizers. The present invention further relates to polymers, in particular polyolefins, which have been stabilized with respect to exposure to UV radiation or with respect to exposure to UV radiation, oxygen and heat, which comprise an effective amount of these polymer powders or, respectively, stabilizer mixtures, and to articles produced from these stabilized polymers, in particular polyolefins.
    • 本发明涉及用于稳定聚合物,特别是关于暴露于UV辐射的聚烯烃,包含至少一种UV吸收剂的细颗粒聚合物粉末的用途。 本发明还涉及用于稳定聚合物相对于暴露于UV辐射,氧和热的稳定剂混合物,其特别包括这些聚合物粉末,以及用于稳定聚合物,特别是聚烯烃的方法,涉及暴露于 UV辐射,氧气和热量,其包括向聚合物,特别是聚烯烃中加入有效量的这些稳定剂。 本发明还涉及聚合物,特别是聚烯烃,其已经相对于暴露于UV辐射或相对于暴露于UV辐射,氧和热而被稳定,其包含有效量的这些聚合物粉末或分别为稳定剂 混合物,以及由这些稳定的聚合物,特别是聚烯烃生产的制品。
    • 20. 发明申请
    • STABILISERS FOR INANIMATE ORGANIC MATERIALS
    • 用于有机材料的稳定剂
    • US20110214590A1
    • 2011-09-08
    • US13060705
    • 2009-08-14
    • Alban GlaserSylke HaremzaSimon Schambony
    • Alban GlaserSylke HaremzaSimon Schambony
    • C09D7/12C08K5/3435C07D401/12C07D401/04C07D211/56
    • C07D211/94
    • The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
    • 本发明涉及包含一个或多个通式(I)的基团的空间位阻胺的用途,用于稳定无生命的有机材料,更特别的是塑料或涂料,其中R 1和R 2各自独立地或不同地是H, C 1 -C 20烷基,C 3 -C 15环烷基,芳基,杂芳基或杂环,R 4,R 5,R 6和R 7各自独立地为不同或不同的是C 1 -C 20烷基,或R 4和R 6或R 5和R 7一起是四亚甲基 或五亚甲基,R 3为芳基或杂芳基。 本发明还涉及稳定无生命的有机材料,特别是塑料或涂料的方法。 本发明另外提供的是包含一个或多个通式(I)的基团的空间位阻胺。 本发明另外提供的是包含选定的空间位阻胺的材料。