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    • 13. 发明公开
    • X-ray fluorescence analysis
    • X射线荧光分析
    • EP0816834A3
    • 1998-07-29
    • EP97304505.7
    • 1997-06-25
    • OXFORD ANALYTICAL INSTRUMENTS LIMITED
    • Finney, Mark Simon
    • G01N23/223
    • G01N23/223G01N2223/076
    • A method of obtaining information concerning the content of an experimental sample. The method comprises:
      (i) irradiating a standard sample with X-rays and monitoring fluorescent X-rays emitted by the standard sample to obtain a correction coefficient I SID related to the intensity of the monitored X-rays. (ii) Irradiating the experimental sample under substantially the same experimental conditions as in step (i) with X-rays and monitoring fluorescent X-rays emitted by the experimental sample to obtain one or more experimental values I X , each experimental value being related to the intensity of the monitored X-rays corresponding to a particular analyte. (iii) Obtaining the information concerning the content of the experimental sample in accordance with an algorithm incorporating the experimental value I X , a calibration curve for the or each analyte and the correction coefficient I STD . The correction coefficient I STD is used to correct for any difference between the experimental conditions prevailing in steps (i) and (ii) and the calibration experimental conditions associated with the calibration curve.
    • 14. 发明公开
    • X-ray fluorescence analysis
    • X射线荧光分析
    • EP0816834A2
    • 1998-01-07
    • EP97304505.7
    • 1997-06-25
    • OXFORD ANALYTICAL INSTRUMENTS LIMITED
    • Finney, Mark Simon
    • G01N23/223
    • G01N23/223G01N2223/076
    • A method of obtaining information concerning the content of an experimental sample. The method comprises:

      (i) irradiating a standard sample with X-rays and monitoring fluorescent X-rays emitted by the standard sample to obtain a correction coefficient I SID related to the intensity of the monitored X-rays.
      (ii) Irradiating the experimental sample under substantially the same experimental conditions as in step (i) with X-rays and monitoring fluorescent X-rays emitted by the experimental sample to obtain one or more experimental values I X , each experimental value being related to the intensity of the monitored X-rays corresponding to a particular analyte.
      (iii) Obtaining the information concerning the content of the experimental sample in accordance with an algorithm incorporating the experimental value I X , a calibration curve for the or each analyte and the correction coefficient I STD .

      The correction coefficient I STD is used to correct for any difference between the experimental conditions prevailing in steps (i) and (ii) and the calibration experimental conditions associated with the calibration curve.
    • 一种获取有关实验样本内容的信息的方法。 该方法包括:(i)用X射线照射标准样品并监测由标准样品发射的荧光X射线,以获得与监测的X射线的强度相关的校正系数ISID。 (ii)在与步骤(i)基本上相同的实验条件下用X射线照射实验样品并监测由实验样品发射的荧光X射线以获得一个或多个实验值IX,每个实验值与 被监测的X射线对应于特定分析物的强度。 (iii)根据包含实验值IX,该分析物或每个分析物的校准曲线和校正系数ISTD的算法获得关于实验样品的内容的信息。 校正系数ISTD用于校正步骤(i)和(ii)中的实验条件与校准曲线相关的校准实验条件之间的任何差异。
    • 15. 发明公开
    • Improvements relating to sample monitoring
    • Verbesserungen一个Proben-Überwachung。
    • EP0605948A1
    • 1994-07-13
    • EP93309088.8
    • 1993-11-12
    • OXFORD ANALYTICAL INSTRUMENTS LIMITED
    • Crookell, AndrewVan Wyk, Claudius Baldwin
    • G01R33/44
    • G01R33/44
    • Apparatus for monitoring a sample having 'solid' and 'liquid' content as hereinbefore defined, the apparatus comprising a magnetic field generator (3) for subjecting the sample to a static magnetic field in the first direction to cause the magnetic vectors of nuclei to precess about the first direction; means (2) for reorienting the bulk magnetic vector of the sample so as to gain a component in a plane orthogonal to the first direction and for monitoring the resultant FID; and a controller (8) for causing the apparatus to carry out the following steps.

      i) Causing the bulk magnetic vector to gain a component in a second direction orthogonal to the first direction;
      ii) after a first relaxation period less than the time for the 'solid' component of the resulting FID to decay to zero, causing the spins of the nuclei to rephase in such a way as to give an echo from which the 'solid' component in the sample can be determined;
      iii) after a second relaxation period, following step (ii), and during which the part of the FID due to the 'solid' content of the sample decays to zero, causing the spins of the nuclei to rephase giving an echo arising from the 'liquid' component of the sample; and
      iv) monitoring the resultant FID signal after step (ii) and after step (iii) to obtain a measure of the 'solid' and 'liquid' content of the sample.
    • 用于监测如上文所定义的具有“固体”和“液体”含量的样品的装置,该装置包括用于使样品在第一方向上受到静磁场的磁场发生器(3),以使核的磁矢量发生 关于第一个方向; 用于重新定向样品的体磁矢量的装置(2),以便获得与第一方向正交的平面中的分量并监测所得的FID; 以及用于使装置执行以下步骤的控制器(8)。 i)使体磁矢量在与第一方向正交的第二方向上获得分量; ii)在小于所得FID的“固体”组分的时间的第一弛豫时间衰减到零之后,导致细胞核的自旋重新形成,从而产生“固体”成分的回波 在样品中可以确定; iii)在第二个松弛期之后,在步骤(ii)之后,并且由于样品的“固体”含量而导致FID的部分衰减为零,导致细胞核的自旋再次产生由 样品的“液体”成分; 和iv)在步骤(ii)之后和步骤(iii)之后监测所得FID信号,以获得样品的“固体”和“液体”含量的量度。