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131. 发明授权

US06486357B2 Catalytic oxidation of alcohols using manganese oxides 失效
标题翻译：使用氧化锰催化氧化醇
公开(公告)号：US06486357B2
公开(公告)日：2002-11-26
申请号：US09929302
申请日：2001-08-14
申请人： Steven L. Suib , Young Chan Son , Amy R. Howell
发明人： Steven L. Suib , Young Chan Son , Amy R. Howell
IPC分类号： C07C4529
CPC分类号： C07D333/22 , C07C45/38 , C07C45/39 , C07D213/50 , C07D307/46 , C07D307/83 , C07C49/403
摘要： A method of oxidizing an organic alcohol, wherein the organic alcohol is contacted with a stoichiometric excess of oxygen in the presence of an effective catalytic amount of a maganese-containing octahedral molecular sieve or octahedral layer. Primary alcohols are selectively oxidized to aldehydes, and secondary alcohols are selectively oxidized to ketones.
摘要翻译：一种氧化有机醇的方法，其中有机醇在有效催化量的含有锰的八面体分子筛或八面体层的存在下与化学计量过量的氧接触。伯醇被选择性氧化成醛，仲醇被选择性地氧化成酮。

132. 发明授权

US5750768A Method of manufacturing .alpha.-oxocarboxylate and catalyst adopted in the method 失效
标题翻译：方法中采用α-氧代羧酸酯和催化剂的制备方法
公开(公告)号：US5750768A
公开(公告)日：1998-05-12
申请号：US689274
申请日：1996-08-06
申请人： Yoshitaka Arita , Akihiko Ohta , Ren Hasebe , Noboru Saito
发明人： Yoshitaka Arita , Akihiko Ohta , Ren Hasebe , Noboru Saito
IPC分类号： B01J23/50 , B01J27/16 , B01J27/18 , B01J27/185 , B01J27/188 , B01J27/198 , B01J31/18 , C07B61/00 , C07C45/38 , C07C45/39 , C07C67/39 , C07C67/40 , C07C69/67 , C07C69/716 , C07C69/66
CPC分类号： C07C45/39 , B01J27/16 , C07C45/38 , C07C67/39
摘要： A method of manufacturing .alpha.-oxocarboxylate includes the steps of: (i) carrying out a vapor phase oxidation of 1,2-diol of formula (1) in a primary reaction vessel, (ii) introducing a resulting gaseous .alpha.-oxoaldehyde and/or .alpha.-hydroxyaldehyde in a secondary reaction vessel together with alcohol or olefin which is converted into a gas form in a vaporizing chamber, and (iii) carrying out an oxidative esterification of the gaseous .alpha.-oxoaldehyde and/or .alpha.-hydroxyaldehyde molecular oxygen in a presence of inorganic oxide containing phosphorus as a catalyst in the secondary reaction vessel, ##STR1## (R is a hydrogen atom or an organic residue). The described method permits .alpha.-oxocarboxylate to be manufactured economically and effectively in practically one step using inexpensive 1,2-diol such as ethylene glycol or propylene glycol.
摘要翻译：制备α-氧代羧酸酯的方法包括以下步骤：（i）在初级反应容器中进行式（1）的1,2-二醇的气相氧化，（ii）将所得的气态α-氧代醛和/ 或α-羟基醛在二次反应容器中与醇或烯烃一起在汽化室中转化成气体形式，和（iii）进行气态α-氧代醛和/或α-羟基甲醛分子氧的氧化酯化反应在二次反应容器中存在含磷作为催化剂的无机氧化物，（1）（R是氢原子或有机残基）。所描述的方法允许α-氧代羧酸酯在几乎一步中经济地和有效地制备，使用廉价的1,2-二醇如乙二醇或丙二醇。

133. 发明授权

US5689011A Process for the production of glyoxals and catalysts therefor 失效
标题翻译：用于生产乙二醛和其催化剂的方法
公开(公告)号：US5689011A
公开(公告)日：1997-11-18
申请号：US443665
申请日：1995-05-18
申请人： Kazuo Wakimura , Kazuhuyu Sudoh , Masao Tanaka , Hatuo Inoue , Nobuhisa Iwane
发明人： Kazuo Wakimura , Kazuhuyu Sudoh , Masao Tanaka , Hatuo Inoue , Nobuhisa Iwane
IPC分类号： B01J23/50 , C07C45/38 , C07C45/39 , C07C45/00
CPC分类号： C07C45/39 , B01J23/50 , C07C45/38
摘要： The present invention provides a process for the production of glyoxals which comprises effecting the oxidative dehydrogenation of a glycol at a temperature of 400.degree. to 700.degree. C. in the presence of a silver-based catalyst composed of silver and at least one element selected from the group consisting of gold, platinum, rhodium and palladium, and phosphorus or a phosphorus compound, as well as such catalysts. These process and catalysts make it possible to produce high-quality glyoxals in high yield and with industrial advantages while minimizing the contents of unreacted raw material and reaction intermediates such as glycolaldehyde and acetol.
摘要翻译：本发明提供一种生产乙二醛的方法，该方法包括在由银组成的银基催化剂和至少一种选自以下的元素的银基催化剂存在下，在400-700℃的温度下进行二醇的氧化脱氢反应由金，铂，铑和钯组成的组，以及磷或磷化合物，以及这些催化剂。这些方法和催化剂使得可以以高产率和具有工业优势生产高质量乙二醛，同时最小化未反应的原料和反应中间体如乙二醇和丙酮醇的含量。

134. 发明授权

US5430181A Process for improving a controlled oxidation reaction 失效
标题翻译：改善受控氧化反应的方法
公开(公告)号：US5430181A
公开(公告)日：1995-07-04
申请号：US19878
申请日：1993-02-19
申请人： Philippe Arpentinier , Jacques Koenig , Yves Torre
发明人： Philippe Arpentinier , Jacques Koenig , Yves Torre
IPC分类号： B01J27/122 , C07B33/00 , C07B41/00 , C07B61/00 , C07C17/156 , C07C19/045 , C07C29/03 , C07C31/12 , C07C37/58 , C07C37/60 , C07C39/04 , C07C45/34 , C07C45/38 , C07C45/39 , C07C51/215 , C07C51/23 , C07C51/235 , C07C51/25 , C07C51/265 , C07C51/31 , C07C53/08 , C07C55/14 , C07C57/05 , C07C67/05 , C07C67/39 , C07D301/19 , C07D307/36 , C07C51/10 , C07C17/42 , C07C37/00 , C07C51/255
CPC分类号： C07D301/19 , C07B33/00 , C07B41/00 , C07C17/156 , C07C37/50 , C07C37/58 , C07C45/34 , C07C45/38 , C07C45/39 , C07C51/215 , C07C51/23 , C07C51/235 , C07C51/252 , C07C51/265 , C07C51/313 , C07C67/05 , C07C67/39 , Y02P20/52
摘要： Process for improving a controlled oxidation reaction between at least one reactant and oxygen, in which at least one reactant is reacted with oxygen or an oxygen containing gas, constituting a reaction mixture, in the presence of at least one additional gas which is introduced into said reaction mixture and is selected from methane, ethane and helium, and the resulting reaction product from the oxidation reaction is possibly treated so as to give a final product.
摘要翻译：用于改善至少一种反应物和氧之间的受控氧化反应的方法，其中至少一种反应物与构成反应混合物的氧气或含氧气体在至少一种另外的气体的存在下反应，该气体被引入所述反应混合物，并且选自甲烷，乙烷和氦气，并且可以处理所得到的来自氧化反应的反应产物以得到最终产物。

135. 发明授权

US5015778A Catalytic method to produce hydroxy substituted arylophenones 失效
标题翻译：催化方法生产羟基取代的芳香酮
公开(公告)号：US5015778A
公开(公告)日：1991-05-14
申请号：US452452
申请日：1989-12-18
申请人： Anthony P. Haag , E. W. Otterbacher
发明人： Anthony P. Haag , E. W. Otterbacher
IPC分类号： B01J27/10 , B01J27/122 , B01J27/128 , B01J27/132 , C07B61/00 , C07C39/15 , C07C45/36 , C07C45/39 , C07C49/83
CPC分类号： C07C45/36 , C07C39/15 , C07C45/39
摘要： Hydroxy substituted arylophenones in general, and 4,4'-dihydroxybenzophenones in particular, are produced by catalytic oxidation of diaryl compounds containing hydroxy substituted diaryl moieties in a liquid medium. Oxidation occurs by contact of the diaryl compounds with an oxygen-containing gas in the presence of a solvent, base, a metal atom catalyst, and optionally, activated carbon. The arylophenones produced are useful as monomers in the production of epoxy and polycarbonate resins.
摘要翻译：一般来说，羟基取代的芳香族酮，特别是4,4'-二羟基二苯甲酮，是通过在液体介质中催化氧化含有羟基取代的二芳基部分的二芳基化合物来制备的。在溶剂，碱，金属原子催化剂和任选的活性炭存在下，二芳基化合物与含氧气体的接触发生氧化。所生产的芳香酮可用作生产环氧树脂和聚碳酸酯树脂的单体。

136. 发明授权

US4975266A Production of hydrogen peroxide 失效
标题翻译：生产过氧化氢
公开(公告)号：US4975266A
公开(公告)日：1990-12-04
申请号：US457662
申请日：1989-12-27
申请人： Rajendra S. Albal , Robert N. Cochran , Lawrence M. Candela
发明人： Rajendra S. Albal , Robert N. Cochran , Lawrence M. Candela
IPC分类号： C01B15/013 , C01B15/026 , C07C45/39
CPC分类号： C01B15/026 , C01B15/013 , C07C45/39
摘要： Hydrogen peroxide is produced by liquid phase molecular oxygen oxidation of methyl benzyl alcohol. Inhibiting impurities are removed prior to oxidation.
摘要翻译：过氧化氢通过甲基苄醇的液相分子氧氧化产生。在氧化之前除去杂质。

137. 发明授权

US4918239A Method of producing cyclohexanone from cyclohexanol through oxidative dehydrogenation 失效
标题翻译：通过氧化脱氢从环己醇生产环己酮的方法
公开(公告)号：US4918239A
公开(公告)日：1990-04-17
申请号：US289680
申请日：1988-12-27
申请人： Ikai Wang , Yu-Ming Lin
发明人： Ikai Wang , Yu-Ming Lin
IPC分类号： B01J23/80 , B01J23/89 , C07C45/39
CPC分类号： B01J23/8953 , B01J23/80 , B01J23/8926 , C07C45/39
摘要： This invention provides a method for producing cyclohexanone from cyclohexanol using oxidative dehydrogenation. More particularly, this invention comprises adding a certain amount of a gaseous oxidant to the cyclohexanol feed stream; and, converting the cyclohexanol to cyclohexanone over a CuO-ZnO catalyst.
摘要翻译：本发明提供了使用氧化脱氢从环己醇制备环己酮的方法。更具体地说，本发明包括向环己醇进料流中加入一定量的气态氧化剂; 并通过CuO-ZnO催化剂将环己醇转化成环己酮。

138. 发明授权

US4897252A Production of hydrogen peroxide 失效
标题翻译：生产过氧化氢
公开(公告)号：US4897252A
公开(公告)日：1990-01-30
申请号：US295409
申请日：1989-01-10
申请人： Robert N. Cochran , Lawrence M. Candela
发明人： Robert N. Cochran , Lawrence M. Candela
IPC分类号： A61K8/00 , A61K8/65 , A61K8/66 , A61K8/98 , A61K35/14 , A61K38/22 , A61Q5/00 , C01B15/013 , C01B15/026 , C07C45/39
CPC分类号： C01B15/026 , C01B15/013 , C07C45/39
摘要： Hydrogen peroxide is produced by liquid phase molecular oxygen oxidation of methyl benzyl alcohol, water concentration in the reaction mixture being maintained below 4% by weight, more preferably below 2% by weight, and most preferably below 1% by weight.

139. 发明授权

US4346238A Process for the preparation of crystalline sodium paraformylphenolate 失效
标题翻译：制备结晶多聚甲酚钠的方法
公开(公告)号：US4346238A
公开(公告)日：1982-08-24
申请号：US147678
申请日：1980-05-07
申请人： Alain Schouteeten , Yani Christidis
发明人： Alain Schouteeten , Yani Christidis
IPC分类号： C07C45/00 , C07C45/39 , C07C47/565 , C07C47/575 , C07C67/00 , C07C45/54
CPC分类号： C07C47/565 , C07C45/39
摘要： Sodium paraformylphenolate crystallized with two molecules of water is manufactured by:(a) condensing glyoxylic acid with an excess of phenol in water in the presence of sodium hydroxide at a temperature comprised between 30.degree. C. and 100.degree. C.;(b) neutralizing the solution thus obtained and then freeing it from the unconverted phenol by steam distillation or extraction with a water-immiscible organic solvent and then subjecting it hot under a pressure of oxygen, to a catalytic decarboxylating oxidizing degradation in the presence of sodium hydroxide;(c) allowing the aqueous solution so-obtained, after removal of the catalyst by filtration, and then concentration hot under vacuum to 60% plus or minus 10% of its initial volume, to crystallize; and(d) draining the precipitated crystals, washing them and then drying them to constant weight under vacuum of 1 mm of mercury at 20.degree. C., to obtain sodium paraformylphenolate crystallized with 2 molecules of water or dried to constant weight under a vacuum of 1 mm of mercury at 100.degree. C. to obtain it in anhydrous form. The product is useful for preparing parahydroxy benzaldehyde quantitatively and without other purification reactions.
摘要翻译：用两分子水结晶的多聚甲硫醇钠是通过以下方法制造的：（a）在氢氧化钠存在下，在30℃至100℃的温度下，使乙醛酸与过量的苯酚在水中冷凝; （b）中和所得溶液，然后通过水蒸气蒸馏或与水不混溶的有机溶剂萃取，然后将其从未转化的苯酚中释出，然后在氧气压力下热处理，在钠存在下进行催化脱羧氧化降解氢氧化物; （c）通过过滤除去催化剂后，使真空度为60％±10％，使其结晶，得到如此得到的水溶液。和（d）排出沉淀的晶体，洗涤，然后在20℃下在1mm汞柱的真空下将其干燥至恒重，得到用2分子水结晶的多聚甲酰基苯酚钠，或在真空下干燥至恒重在100℃下加入1毫米汞柱，以无水形式得到。该产品可用于定量和无其他纯化反应制备对羟基苯甲醛。

140. 发明授权

US4250121A Catalytic oxidation of alcohols with molecular oxygen to form carbonyl compounds 失效
标题翻译：用分子氧催化氧化醇形成羰基化合物
公开(公告)号：US4250121A
公开(公告)日：1981-02-10
申请号：US41855
申请日：1979-05-24
申请人： Hubert Mimoun
发明人： Hubert Mimoun
IPC分类号： C07C45/38 , C07C45/39
CPC分类号： C07C45/39 , C07C45/38
摘要： Carbonyl compounds are manufactured by oxidizing alcohols or polyalcohols with molecular oxygen in the presence of a catalyst which comprises ruthenium salts or complexes associated with copper or iron salts or complexes.
摘要翻译：羰基化合物通过在包含与铜或铁盐或络合物相关的钌盐或络合物的催化剂存在下用分子氧氧化醇或多元醇来制备。

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