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131. 发明申请

US20070077452A1 Organic light emitting devices having latent activated layers and methods of fabricating the same 审中-公开
标题翻译：具有潜活化层的有机发光器件及其制造方法
公开(公告)号：US20070077452A1
公开(公告)日：2007-04-05
申请号：US11243194
申请日：2005-10-04
申请人： Jie Liu , Larry Lewis , Anil Duggal , Rubinsztajn Slawomir
发明人： Jie Liu , Larry Lewis , Anil Duggal , Rubinsztajn Slawomir
IPC分类号： B32B19/00
CPC分类号： H01L51/0021 , C23C18/08 , C23C18/14 , H01L51/5052 , H01L51/5221
摘要： An organic light emitting device with a latent activator material is presented. An organic light emitting device including activation products of a latent activator material is also presented. Embodiments of patterned organic light emitting devices are also contemplated wherein patterning can occur prior or post fabrication of the devices. A method of fabricating an organic light emitting device with a latent activator material or with activation products of an activator material is also provided.
摘要翻译：提出了具有潜在活化剂材料的有机发光器件。还提供了包括潜活化剂材料的活化产物的有机发光器件。还构想了图案化有机发光器件的实施例，其中图案化可以在器件制造之前或之后发生。还提供了制造具有潜活化剂材料或活化剂材料的活化产物的有机发光器件的方法。

132. 发明申请

US20060131566A1 Organic electronic devices having two dimensional series interconnections 有权
标题翻译：具有二维串联互连的有机电子器件
公开(公告)号：US20060131566A1
公开(公告)日：2006-06-22
申请号：US11021265
申请日：2004-12-22
申请人： Jie Liu , Anil Duggal
发明人： Jie Liu , Anil Duggal
IPC分类号： H01L35/24
CPC分类号： H01L27/3204 , H01L27/283 , H01L51/0021 , H01L51/0545 , H01L51/5203 , H01L51/56 , Y02E10/549
摘要： A device includes a plurality of organic electronic devices disposed on a substrate, wherein each of the plurality of organic electronic devices comprises a first electrode and a second electrode, and wherein each of the plurality of organic electronic devices is electrically coupled in series. Further, the device includes an electro-active material disposed between the first and second electrodes of each of the plurality of organic electronic devices. In addition, the device includes an interconnect layer disposed on the substrate, wherein the interconnect layer is configured to electrically couple each of the plurality of organic electronic devices in series via coupling the respective first and second electrodes of each of the plurality of organic electronic devices.
摘要翻译：一种器件包括设置在衬底上的多个有机电子器件，其中所述多个有机电子器件中的每一个包括第一电极和第二电极，并且其中所述多个有机电子器件中的每一个均串联电耦合。此外，该器件包括设置在多个有机电子器件中的每一个的第一和第二电极之间的电活性材料。另外，该器件包括布置在衬底上的互连层，其中互连层被配置为通过将多个有机电子器件中的每一个的相应的第一和第二电极耦合而串联耦合多个有机电子器件中的每一个。

133. 发明授权

US07048999B2 Method for producing self-assembled objects comprising single-wall carbon nanotubes and compositions thereof 有权
公开(公告)号：US07048999B2
公开(公告)日：2006-05-23
申请号：US10033228
申请日：2001-12-28
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： D01F9/12
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to a method for producing self-assembled objects comprising single-wall carbon nanotubes (SWNTs) and compositions thereof. In one embodiment, the present invention involves a three-dimensional structure of derivatized single-wall nanotube molecules that spontaneously form. It includes several component molecule having multiple derivatives brought together to assemble into the three-dimensional structure. In another embodiment, objects may be obtained by bonding functionally-specific agents (FSAs) groups of nanotubes into geometric structures. The bond selectivity of FSAs allow selected nanotubes of a particular size or kind to assemble together and inhibit the assembling of unselected nanotubes that may also be present.

134. 发明申请

US20050260120A1 Method for forming an array of single-wall carbon nanotubes in an electric field and compositions thereof 有权
标题翻译：在电场中形成单壁碳纳米管阵列的方法及其组合物
公开(公告)号：US20050260120A1
公开(公告)日：2005-11-24
申请号：US10635976
申请日：2003-08-07
申请人： Richard Smalley , Daniel Colbert , Hongjie Dai , Jie Liu , Andrew Rinzler , Jason Hafner , Kenneth Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard Smalley , Daniel Colbert , Hongjie Dai , Jie Liu , Andrew Rinzler , Jason Hafner , Kenneth Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B01J8/06 , B01J19/08 , B01J19/10 , B01J19/12 , B01L7/00 , B82B3/00 , C01B31/02 , D01F9/12 , D01F9/127 , G01Q70/06 , G01Q70/12 , G11B9/00 , G11C13/02 , H01G9/20 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/583 , H01M4/587 , H01M4/62 , H01M10/0525 , H01M10/36
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to a forming an array of single-wall carbon nanotubes (SWNT) in an electric field and compositions thereof. In one embodiment, a purified bucky paper of single-wall carbon nanotubes is used as the starting material. Upon oxidative treatment of the bucky paper surface, many tube and/or rope ends protrude up from the surface of the paper. Disposing the resulting bucky paper in an electric field results in the protruding tubes and or ropes of single-wall carbon nanotubes aligning in a direction substantially perpendicular to the paper surface. These tubes tend to coalesce to form a molecular array. In another embodiment, a molecular array of SWNTs can be made by “combing” the purified bucky paper starting material with a sharp microscopic tip to align the nanotubes.
摘要翻译：本发明一般涉及在电场中形成单壁碳纳米管阵列（SWNT）及其组成。在一个实施方案中，使用单壁碳纳米管的纯化的巴氏纸作为原料。在对纸张表面进行氧化处理时，许多管和/或绳索端部从纸表面向上突出。将所得到的负压纸放置在电场中导致单壁碳纳米管的突出管和/或绳索在基本上垂直于纸表面的方向上对齐。这些管倾向于聚结形成分子阵列。在另一个实施方案中，SWNT的分子阵列可以通过用精细的微观尖端“精梳”纯化的巴基纸原料来制备纳米管。

135. 发明申请

US20050249656A1 METHOD FOR FORMING A PATTERNED ARRAY OF SINGLE-WALL CARBON NANOTUBES 有权
标题翻译：形成单壁碳纳米管阵列的方法
公开(公告)号：US20050249656A1
公开(公告)日：2005-11-10
申请号：US10033092
申请日：2001-12-28
申请人： Richard Smalley , Daniel Colbert , Hongjie Dai , Jie Liu , Andrew Rinzler , Jason Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard Smalley , Daniel Colbert , Hongjie Dai , Jie Liu , Andrew Rinzler , Jason Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B01J8/06 , B01J19/08 , B01J19/10 , B01J19/12 , B01L7/00 , B82B3/00 , C01B31/02 , D01F9/12 , D01F9/127 , G01Q70/06 , G01Q70/12 , G11B9/00 , G11C13/02 , H01G9/20 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/583 , H01M4/587 , H01M4/62 , H01M10/0525 , H01M10/36
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to forming a patterned array of single-wall carbon nanotubes (SWNT). In one embodiment, a nanoscale array of microwells is provided on a substrate; a metal catalyst is deposited in each microwells; and a stream of hydrocarbon or CO feedstock gas is directed at the substrate under conditions that effect growth of single-wall carbon nanotubes from each microwell.
摘要翻译：本发明一般涉及形成单壁碳纳米管（SWNT）的图案化阵列。在一个实施例中，在衬底上提供纳米尺寸的微孔阵列; 在每个微孔中沉积金属催化剂; 并且在从每个微孔产生单壁碳纳米管的生长的条件下，烃或CO原料气流被引导到基底。

136. 发明授权

US06936233B2 Method for purification of as-produced single-wall carbon nanotubes 失效
标题翻译：纯化生产的单壁碳纳米管的方法
公开(公告)号：US06936233B2
公开(公告)日：2005-08-30
申请号：US10032933
申请日：2001-12-28
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B01J8/06 , B01J19/08 , B01J19/10 , B01J19/12 , B01L7/00 , B82B3/00 , C01B31/02 , D01F9/12 , D01F9/127 , G01Q70/06 , G01Q70/12 , G11B9/00 , G11C13/02 , H01G9/20 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/583 , H01M4/587 , H01M4/62 , H01M10/0525 , H01M10/36
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to a single-wall carbon nanotube (SWNT) purification process and more particularly to a purification process that comprises heating the SWNT-containing felt under oxidizing conditions to remove the amorphous carbon deposits and other contaminating materials. In a preferred mode of this purification procedure, the felt is heated in an aqueous solution of an inorganic oxidant, such as nitric acid, a mixture of hydrogen peroxide and sulfuric acid, or a potassium permanganate. Preferably, SWNT-containing felts are refluxed in an aqueous solution of an oxidizing acid at a concentration high enough to etch away amorphous carbon deposits within a practical time frame, but not so high that the single-wall carbon nanotube material will be etched to a significant degree. When material having a high proportion of SWNT is purified, the preparation produced will be enriched in single-wall nanotubes, so that the SWNT are substantially free of other material.
摘要翻译：本发明一般涉及单壁碳纳米管（SWNT）纯化方法，更具体地涉及一种净化方法，其包括在氧化条件下加热含SWNT的毡以除去无定形碳沉积物和其它污染物质。在该纯化方法的优选方式中，将毡在无机氧化剂如硝酸，过氧化氢和硫酸的混合物或高锰酸钾的水溶液中加热。优选地，含SWNT的毡在氧化酸的水溶液中以足够高的浓度回流，以在实用的时间框架内去除非晶碳沉积物，但不要太高，使得单壁碳纳米管材料将被蚀刻到重要程度当具有高比例的SWNT的材料被纯化时，所制备的制剂将富集在单壁纳米管中，使得SWNT基本上不含其它材料。

137. 发明授权

US06875412B2 Chemically modifying single wall carbon nanotubes to facilitate dispersal in solvents 有权
标题翻译：化学修饰单壁碳纳米管以便于在溶剂中分散
公开(公告)号：US06875412B2
公开(公告)日：2005-04-05
申请号：US09810150
申请日：2001-03-16
申请人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
发明人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
IPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/06 , C01B31/00 , C01B31/02 , C07C1/32 , C07C13/64 , C07C17/007 , C07C23/46 , D01F11/12 , D01F9/12
CPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/06 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/08 , D01F11/121 , Y10S977/745 , Y10S977/75 , Y10S977/835 , Y10S977/843 , Y10S977/848 , Y10T428/139 , Y10T428/2918
摘要： This invention is directed to making chemical derivatives of carbon nanotubes and to uses for the derivatized nanotubes, including making arrays as a basis for synthesis of carbon fibers. In one embodiment, this invention also provides a method for preparing single wall carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce single wall carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents will, of course, be dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium. Alternatively, fluorine may be fully or partially removed from fluorine derivatized carbon nanotubes by reacting the fluorine derivatized carbon nanotubes with various amounts of hydrazine, substituted hydrazine or alkyl amine. The present invention also provides seed materials for growth of single wall carbon nanotubes comprising a plurality of single wall carbon nanotubes or short tubular molecules having a catalyst precursor moiety covalently bound or physisorbed on the outer surface of the sidewall to provide the optimum metal cluster size under conditions that result in migration of the metal moiety to the tube end.
摘要翻译：本发明涉及制备碳纳米管的化学衍生物和衍生纳米管的用途，包括制备阵列作为碳纤维合成的基础。在一个实施方案中，本发明还提供了通过使单壁碳纳米管与氟气反应并回收氟衍生的碳纳米管，制备具有连接到纳米管侧壁上的取代基的单壁碳纳米管的方法，然后使氟衍生的碳纳米管与亲核试剂一些氟取代基被亲核取代取代。如果需要，可以完全或部分地除去剩余的氟以产生具有连接到纳米管的侧壁上的取代基的单壁碳纳米管。取代基当然取决于亲核试剂，优选的亲核试剂包括烷基锂物质如甲基锂。或者，可以通过使氟衍生的碳纳米管与各种量的肼，取代的肼或烷基胺反应，从氟衍生的碳纳米管中完全或部分地除去氟。本发明还提供用于生长单壁碳纳米管的种子材料，其包含多个单壁碳纳米管或具有在侧壁的外表面上共价结合或物理吸附的催化剂前体部分的短管状分子，以提供最佳金属簇尺寸导致金属部分迁移到管端的条件。

138. 发明授权

US06871183B2 System and method of preparing and processing data for trade promotion 有权
标题翻译：制定和处理促进贸易数据的制度和方法
公开(公告)号：US06871183B2
公开(公告)日：2005-03-22
申请号：US09768144
申请日：2001-01-24
申请人： Scott R. Gilday , Vic Orler , Alex Zaks , Jie Liu , Gary E. Singer
发明人： Scott R. Gilday , Vic Orler , Alex Zaks , Jie Liu , Gary E. Singer
IPC分类号： G06Q10/08 , G06Q30/02 , G06F17/60
CPC分类号： G06Q30/02 , G06Q10/087 , G06Q30/0201 , G06Q30/0242 , G06Q30/0243
摘要： A system and method for the preparation of data into an organized and effective methodology provides users with a data modeling tool. Data is confirmed and baseline calculations, event extraction, key performance indicator calculations and the production of event outputs are performed. Analytical tools can then be used to visualize patterns, trends and relationships in the data.
摘要翻译：将数据准备为有组织且有效的方法的系统和方法为用户提供了数据建模工具。确认数据，并执行基线计算，事件提取，关键绩效指标计算和事件输出的生成。然后可以使用分析工具来可视化数据中的模式，趋势和关系。

139. 发明授权

US06841139B2 Methods of chemically derivatizing single-wall carbon nanotubes 有权
标题翻译：化学衍生单壁碳纳米管的方法
公开(公告)号：US06841139B2
公开(公告)日：2005-01-11
申请号：US09810390
申请日：2001-03-16
申请人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
发明人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
IPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/06 , C01B31/00 , C01B31/02 , C07C1/32 , C07C13/64 , C07C17/007 , C07C23/46 , D01F11/12 , D01F9/12
CPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/06 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/08 , D01F11/121 , Y10S977/745 , Y10S977/75 , Y10S977/835 , Y10S977/843 , Y10S977/848 , Y10T428/139 , Y10T428/2918
摘要： This invention is directed to making chemical derivatives of carbon nanotubes and to uses for the derivatized nanotubes, including making arrays as a basis for synthesis of carbon fibers. In one embodiment, this invention also provides a method for preparing single wall carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce single wall carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents will, of course, be dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium. Alternatively, fluorine may be fully or partially removed from fluorine derivatized carbon nanotubes by reacting the fluorine derivatized carbon nanotubes with various amounts of hydrazine, substituted hydrazine or alkyl amine. The present invention also provides seed materials for growth of single wall carbon nanotubes comprising a plurality of single wall carbon nanotubes or short tubular molecules having a catalyst precursor moiety covalently bound or physisorbed on the outer surface of the sidewall to provide the optimum metal cluster size under conditions that result in migration of the metal moiety to the tube end.
摘要翻译：本发明涉及制备碳纳米管的化学衍生物和衍生纳米管的用途，包括制备阵列作为碳纤维合成的基础。在一个实施方案中，本发明还提供了通过使单壁碳纳米管与氟气反应并回收氟衍生的碳纳米管，制备具有连接到纳米管侧壁上的取代基的单壁碳纳米管的方法，然后使氟衍生的碳纳米管与亲核试剂一些氟取代基被亲核取代取代。如果需要，可以完全或部分地除去剩余的氟以产生具有连接到纳米管的侧壁上的取代基的单壁碳纳米管。取代基当然取决于亲核试剂，优选的亲核试剂包括烷基锂物质如甲基锂。或者，可以通过使氟衍生的碳纳米管与各种量的肼，取代的肼或烷基胺反应，从氟衍生的碳纳米管中完全或部分地除去氟。本发明还提供用于生长单壁碳纳米管的种子材料，其包含多个单壁碳纳米管或具有在侧壁的外表面上共价结合或物理吸附的催化剂前体部分的短管状分子，以提供最佳金属簇尺寸导致金属部分迁移到管端的条件。

140. 发明授权

US06827918B2 Dispersions and solutions of fluorinated single-wall carbon nanotubes 有权
标题翻译：氟化单壁碳纳米管的分散体和溶液
公开(公告)号：US06827918B2
公开(公告)日：2004-12-07
申请号：US09809865
申请日：2001-03-16
申请人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
发明人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
IPC分类号： D01F912
CPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/06 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/08 , D01F11/121 , Y10S977/745 , Y10S977/75 , Y10S977/835 , Y10S977/843 , Y10S977/848 , Y10T428/139 , Y10T428/2918
摘要： This invention is directed to making chemical derivatives of carbon nanotubes and to uses for the derivatized nanotubes, including making arrays as a basis for synthesis of carbon fibers. In one embodiment, this invention also provides a method for preparing single wall carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce single wall carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents will, of course, be dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium. Alternatively, fluorine may be fully or partially removed from fluorine derivatized carbon nanotubes by reacting the fluorine derivatized carbon nanotubes with various amounts of hydrazine, substituted hydrazine or alkyl amine. The present invention also provides seed materials for growth of single wall carbon nanotubes comprising a plurality of single wall carbon nanotubes or short tubular molecules having a catalyst precursor moiety covalently bound or physisorbed on the outer surface of the sidewall to provide the optimum metal cluster size under conditions that result in migration of the metal moiety to the tube end.
摘要翻译：本发明涉及制备碳纳米管的化学衍生物和衍生纳米管的用途，包括制备阵列作为碳纤维合成的基础。在一个实施方案中，本发明还提供了通过使单壁碳纳米管与氟气反应并回收氟衍生的碳纳米管，制备具有连接到纳米管侧壁上的取代基的单壁碳纳米管的方法，然后使氟衍生的碳纳米管与亲核试剂一些氟取代基被亲核取代取代。如果需要，可以完全或部分地除去剩余的氟以产生具有连接到纳米管的侧壁上的取代基的单壁碳纳米管。取代基当然取决于亲核试剂，优选的亲核试剂包括烷基锂物质如甲基锂。或者，可以通过使氟衍生的碳纳米管与各种量的肼，取代的肼或烷基胺反应，从氟衍生的碳纳米管中完全或部分地除去氟。本发明还提供用于生长单壁碳纳米管的种子材料，其包含多个单壁碳纳米管或具有在侧壁的外表面上共价结合或物理吸附的催化剂前体部分的短管状分子，以提供最佳金属簇尺寸导致金属部分迁移到管端的条件。

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