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101. 发明授权

US07538240B2 Method for the hydrocyanation of butadiene 有权
标题翻译：丁二烯氢氰化方法
公开(公告)号：US07538240B2
公开(公告)日：2009-05-26
申请号：US10587026
申请日：2005-01-27
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
IPC分类号： C07C255/01
CPC分类号： C07C253/10 , C07C255/07
摘要： A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein the reaction is carried out in a loop reactor having external pumped circulation and jet nozzle for driving the internal circulation.
摘要翻译：描述了一种通过在至少一种催化剂存在下氢化1,3-丁二烯来制备3-戊烯腈的方法，其中反应在具有外部泵送循环的环流反应器和用于驱动内部循环的喷嘴中进行。

102. 发明申请

US20080227214A1 Method for the Hydrocyanation of 1,3-Butadiene 审中-公开
标题翻译： 1,3-丁二烯氢化方法
公开(公告)号：US20080227214A1
公开(公告)日：2008-09-18
申请号：US10586473
申请日：2005-01-26
申请人： Tim Jungkamp , Robert Baumann , Thorsten Schroder , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
发明人： Tim Jungkamp , Robert Baumann , Thorsten Schroder , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
IPC分类号： G01N31/16 , C07C253/10 , G01J5/02 , G01N9/00 , G01N30/02 , G01N25/18
CPC分类号： C07C253/10 , Y10T436/172307 , C07C255/07
摘要： A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein unhydrocyanated 1,3-butadiene is removed from the effluent of the hydrocyanation and recycled into the process, and the recycled 1,3-butadiene is monitored for the content of hydrogen cyanide.
摘要翻译：描述了一种通过在至少一种催化剂存在下氢化1,3-丁二烯制备3-戊烯腈的方法，其中将未氢化的1,3-丁二烯从氢化氰化物的流出物中除去并再循环至该方法中，监测氰化氢含量的3-丁二烯。

103. 发明申请

US20070287851A1 Isomerisation of Cis-2-Pentenenitrile to Form 3-Pentenenitrile in a Reactive Distillation 失效
标题翻译： Cis-2-戊烯腈在活性蒸馏中异构化形成3-戊烯腈
公开(公告)号：US20070287851A1
公开(公告)日：2007-12-13
申请号：US10585626
申请日：2005-01-27
申请人： Jens Scheidel , Tim Jungkamp , Michael Bartsch , Gerd Haderlein , Robert Baumann , Hermann Luyken
发明人： Jens Scheidel , Tim Jungkamp , Michael Bartsch , Gerd Haderlein , Robert Baumann , Hermann Luyken
IPC分类号： C07C291/00
CPC分类号： C07C253/30 , Y02P20/127 , C07C255/07
摘要： A process is described for isomerizing pentenenitrile in a reactant stream, wherein the isomerization is effected over a heterogeneous catalyst in a distillation column in such a way that, during the isomerization of the isomerization reactant, it is distillatively depleted in relation to the isomerization product in the reaction column of the distillation column.
摘要翻译：描述了在反应物流中异构化戊烯腈的方法，其中异构化在蒸馏塔中在非均相催化剂上进行，使得在异构化反应物的异构化期间，其相对于异构化产物馏出贫化蒸馏塔的反应塔。

104. 发明授权

US07147757B2 Method for separating an azepine derivative out of a mixture containing an amine an azepine derivative 有权
公开(公告)号：US07147757B2
公开(公告)日：2006-12-12
申请号：US10204966
申请日：2001-03-06
申请人： Hermann Luyken , Frank Ohlbach
发明人： Hermann Luyken , Frank Ohlbach
IPC分类号： B01D3/42 , C07C255/24 , C07C209/82 , C07D223/12
CPC分类号： C07C209/86 , C07C253/34 , C07D223/04 , C07D223/12 , Y10S203/90
摘要： The invention relates to a method for separating by distillation a portion or the entirety of an azeptine derivative (III), which is selected from the group consisting of aminohexylidene imine, tetrahydroazepine, hexylhexahydroazepine and of aminohexylhexahydroazepine, out of a mixture (II) containing an azepine derivative (III) and an amine (I). The inventive method is characterized in that the distillation is carried out with a maximum bottom temperature of 150° C.

105. 发明申请

US20050247624A1 Method for the recycling of a lewis acid 失效
标题翻译：路易斯酸回收方法
公开(公告)号：US20050247624A1
公开(公告)日：2005-11-10
申请号：US10520007
申请日：2003-07-04
申请人： Tim Jungkamp , Jens Scheidel , Hermann Luyken , Michael Bartsch , Robert Baumann , Gerd Haderlein
发明人： Tim Jungkamp , Jens Scheidel , Hermann Luyken , Michael Bartsch , Robert Baumann , Gerd Haderlein
IPC分类号： B01J31/18 , B01J27/32 , B01J31/40 , B01J38/00 , C07B61/00 , C07C253/10 , C07C255/04 , C07C255/07 , B01D11/00
CPC分类号： B01J31/24 , B01J27/32 , B01J31/1845 , B01J31/4015 , B01J31/403 , B01J2231/343 , C07C253/10 , Y02P20/584 , C07C255/07
摘要： A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions, to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile
摘要翻译：从在不饱和化合物的氢氰化中获得的反应混合物（I）中回收路易斯酸的方法，该反应混合物在一定压力和温度条件下，在与催化剂体系包含路易斯酸和络合物。该方法包括：a）从混合物（I）中除去配合物，得到混合物（II），b）在混合物（II）中加入水并将混合物（II）置于压力和温度条件下以提供相（III）和相（Ⅳ），c）加入一种不与水形成共沸物的液体稀释剂（Ⅴ），其某些压力条件下的沸点高于水，或c2）与水形成共沸混合物（III），d）在步骤c1）或c2）所述的压力条件下使相（III）和液体稀释剂（V）的混合物进行蒸馏，和e）使混合物（VII）对烯属不饱和化合物进行氢化，得到腈

106. 发明授权

US06169199A Method for separating 6-aminocaproic acid nitrile from mixtures containing 6-aminocaproic acid nitrile and an imine 失效
标题翻译：从含有6-氨基己酸腈和亚胺的混合物中分离6-氨基己酸腈的方法
公开(公告)号：US06169199A
公开(公告)日：2001-01-02
申请号：US09367068
申请日：1999-08-09
申请人： Alwin Rehfinger , Hermann Luyken
发明人： Alwin Rehfinger , Hermann Luyken
IPC分类号： C07C25500
CPC分类号： C07C253/34
摘要： A process for distillative removal of 6-aminocapronitrile from mixtures (I) comprising 6-aminocapronitrile and an imine (II) comprises performing the distillation in a distillation column using an average mean residence time for the distillation mixture of at least 5 minutes on at least one level of the distillation column.
摘要翻译：包含6-氨基己腈和亚胺（II）的混合物（I）从6-氨基己腈中蒸馏除去6-氨基己腈的方法包括使用至少5分钟至少5分钟的蒸馏混合物的平均停留时间在蒸馏塔中进行蒸馏一级蒸馏塔。

107. 发明授权

US6022999A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 有权
标题翻译：具有顺式/反式异构体比例为70:30以上的3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US6022999A
公开(公告)日：2000-02-08
申请号：US207623
申请日：1998-12-09
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
IPC分类号： C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36 , C07C209/22
CPC分类号： C07C209/26 , C07C209/48 , C07C209/52
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 bya) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degree. C. and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclo-hexanone imine followed byb) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree. C. and under a pressure of from 5 to 30 MPa,wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to give an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.
摘要翻译：一种制备顺式/反式异构体比例至少为70:30的3-氨基甲基-3,5,5-三甲基环己胺的制备方法，通过以下步骤：a）将3-氰基-3,5,5-三甲基环己酮与氨在在20至150℃的温度和1.5至30MPa的压力下存在仿制催化剂以形成3-氰基-3,5,5-三甲基环己酮亚胺，随后b）氢化3-氰基 -3,5,5-三甲基环己酮亚胺在含有铜和/或Ⅷ族金属的催化剂的存在下在80至160℃的温度和5至30MPa的压力下进行，其中 3-氰基-3,5,5-三甲基环己酮亚胺的催化氢化在酸的存在下进行，所用酸的用量使得酸值为0.1-2，基于3-氰基-3 ，使用5,5-三甲基环己酮。

108. 发明授权

US5496941A Process for continuous purification of crude caprolactam prepared from 6-aminocapronitrile 失效
标题翻译：从6-氨基己腈制备的己内酰胺的连续纯化方法
公开(公告)号：US5496941A
公开(公告)日：1996-03-05
申请号：US375410
申请日：1995-01-18
申请人： Josef Ritz , Rolf Fischer , Werner Schnurr , Gu/ nther Achhammer , Hermann Luyken , Eberhard Fuchs
发明人： Josef Ritz , Rolf Fischer , Werner Schnurr , Gu/ nther Achhammer , Hermann Luyken , Eberhard Fuchs
IPC分类号： C07D201/08 , C07D201/16
CPC分类号： C07D201/16 , Y02P20/52
摘要： Crude capronitrile is purified by hydrogenation, subsequent treatment in an acidic medium and subsequent distillation in an alkaline medium, by a process in which(a) 6-aminocapronitrile is converted into crude caprolactam by reaction with water,(b) high boilers and low boilers are separated off from the crude caprolactam from step (a),(c) the crude caprolactam from step (b) is treated with hydrogen at from 50.degree. to 150.degree. C. and from 1.5 to 250 bar in the presence of a hydrogenation catalyst and, if desired, of a solvent to give a mixture A,(d1) mixture A in a solvent is passed, at from 30.degree. to 80.degree. C. and from 1 to 5 bar, over an ion exchanger containing terminal acid groups to give a mixture B1, or(d2) mixture A is distilled in the presence of sulfuric acid, any solvent present being removed before the addition of the sulfuric acid, to give a mixture B2, and(e) mixture B1 or mixture B2 is distilled in the presence of a base to give pure caprolactam.
摘要翻译：通过氢化纯化粗碳腈，随后在酸性介质中处理，随后在碱性介质中进行蒸馏，其中（a）通过与水反应将（a）6-氨基己腈转化为粗己内酰胺，（b）高锅炉和低锅炉与步骤（a）中的粗己内酰胺分离，（c）步骤（b）中的粗己内酰胺在氢化催化剂存在下在50-150℃和1.5-250巴下用氢处理并且如果需要，得到溶剂以得到混合物A，（d1）溶剂中的混合物A在30℃至80℃和1至5巴条件下通过含有末端酸基团的离子交换剂得到混合物B1，或（d2）在硫酸存在下蒸馏混合物A，在加入硫酸之前，除去存在的任何溶剂，得到混合物B2，并且（e）蒸馏出混合物B1或混合物B2 在碱的存在下得到纯己内酰胺。

109. 发明授权

US4982018A Removal of cyclohexanol from aqueous solutions containing it and aromatic sulfonic acids 失效
标题翻译：从含有它的水溶液和芳族磺酸中除去环己醇
公开(公告)号：US4982018A
公开(公告)日：1991-01-01
申请号：US400530
申请日：1989-08-30
申请人： Hans-Juergen Gosch , Rolf Fischer , Hermann Luyken
发明人： Hans-Juergen Gosch , Rolf Fischer , Hermann Luyken
IPC分类号： B01J31/34 , C07B61/00 , C07C27/00 , C07C29/04 , C07C29/80 , C07C29/84 , C07C35/08 , C07C67/00
CPC分类号： C07C29/80 , C07C2101/14
摘要： Cyclohexanol is removed from aqueous solutions containing it and aromatic sulfonic acids, obtained by hydrating cyclohexene in aqueous solutions of aromatic sulfonic acids at elevated temperatures and subsequent removal of excess cyclohexene, by(a) feeding the aqueous solution which contains the cyclohexanol and the aromatic sulfonic acid into the upper third of a first column and from 1 to 50 parts by weight of steam per part by weight of cyclohexanol into the bottom third of the column, withdrawing at the top of the column a vapor which consists essentially of cyclohexanol, cyclohexene and water, and obtaining as a bottom product an aqueous solution of the aromatic sulfonic acid,(b) condensing the vapor which consists essentially of cyclohexanol, cyclohexene and water and(b1) obtaining a cyclohexanol-rich phase and(b2) an aqueous phase,(c) utilizing the aqueous phase (b2) for generating the steam required in stage (a) and any remainder for the hydration of cyclohexene, and(d) distilling off from the cyclohexanol-rich phase (b1) in a second column a mixture of cyclohexene and water with or without cyclohexanol as top product, leaving cyclohexanol as bottom product.
摘要翻译：通过（a）将含有环己醇和芳香族磺酸的水溶液进料，将环己醇从含有它的水溶液和芳族磺酸中除去，通过在高温下将环己烯在芳族磺酸的水溶液中水合并随后除去过量的环己烯而得到酸进入第一塔的上三分之一，并且每重量份1至50重量份的环己醇的环己醇至塔的底部三分之一，在塔的顶部抽出基本上由环己醇，环己烯和水，并且作为底部产物获得芳族磺酸的水溶液，（b）使基本上由环己醇，环己烯和水组成的蒸气冷凝，和（b1）获得富含环己醇的相和（b2）水相，（c）使用水相（b2）产生阶段（a）中所需的蒸汽和用于环己烯水合的任何剩余物，和（d）d 在第二列中从环己醇富含相（b1）中除去环己醇和水的混合物，其中有或没有环己醇作为顶部产物，留下环己醇作为底部产物。

110. 发明授权

US08278474B2 Method for the separation of pentenenitrile isomers 有权
标题翻译：戊烯腈异构体分离方法
公开(公告)号：US08278474B2
公开(公告)日：2012-10-02
申请号：US13047212
申请日：2011-03-14
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
IPC分类号： C07C253/34
CPC分类号： C07C253/34 , C07C255/07
摘要： A process is described for separating mixtures of isomeric pentenenitriles, in which at least one isomer is removed from the mixture, wherein the separation of the substance mixtures of isomeric pentenenitriles is effected distillatively under reduced pressure.
摘要翻译：描述了用于分离异构戊烯腈混合物的方法，其中从混合物中除去至少一种异构体，其中异构戊烯腈的物质混合物的分离在减压下进行蒸馏。

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