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    • 94. 发明申请
    • DYE LOADED ZEOLITE MATERIAL
    • DYE加载沸石材料
    • WO02036490A1
    • 2002-05-10
    • PCT/CH2001/000647
    • 2001-11-05
    • B01J39/14C09K11/06G01Q30/20H01L51/30C01B39/42B01J29/04C01B39/00C01B39/32
    • C09K11/06B01J20/3204B01J39/14B82Y15/00H01L51/005H01L51/0064H01L51/0069H01L51/0071H01L51/008H01L51/447Y02E10/549
    • The present invention provides a dye loaded zeolite material comprising: a) at least one zeolite crystal having straight through uniform channels each having a channel axis parallel to, and a channel width transverse to, a c-axis of crystal unit cells; b) closure molecules having an elongated shape and consisting of a head moiety and a tail moiety, the tail moiety having a longitudinal extension of more than a dimension of the crystal unit cells along the c-axis and the head moiety having a lateral extension that is larger than said channel width and will prevent said head moiety from penetrating into a channel; c) a channel being terminated, in generally plug-like manner, at least at one end thereof located at a surface of the zeolite crystal by a closure molecule hose tail moiety penetrates into said chanel and whose head moiety substantially occludes said channel end while projecting over said surface; and d) an essentially linear arrangement of luminescent dye molecules enclosed within a terminated channel adjacent to at least one closure molecule and exhibiting properties related to supramolecular organization.
    • 本发明提供一种负载染料的沸石材料,包括:a)至少一种具有直通均匀通道的沸石晶体,每个通道均具有平行于晶体单元晶胞的c轴的沟道轴线和沟道宽度; b)具有细长形状并由头部部分和尾部部分组成的封闭分子,所述尾部部分具有比c轴更多的晶体单位细胞尺寸的纵向延伸,并且头部部分具有侧向延伸, 大于所述通道宽度,并且将防止所述头部部分穿透通道; c)通常通过塞子状方式终止位于沸石晶体的表面的通道,封闭分子软管尾部穿透到所述香烟中,并且其头部基本上封闭所述通道端,同时突出 在所述表面上; 以及d)包封在与至少一个封闭分子相邻的封端通道中并且显示与超分子组织相关的性质的发光染料分子的基本线性排列。
    • 95. 发明申请
    • SMALL DIAMETER WATER STABLE ZEOLITE COMPOSITE USEFUL AS AN ION EXCHANGE MATERIAL
    • 小直径水稳定沸石复合材料作为离子交换材料有用
    • WO00001459A1
    • 2000-01-13
    • PCT/US1999/015022
    • 1999-07-02
    • B01D15/04B01J29/06B01J39/14B01J47/00C02F1/28C02F1/42B01J29/00
    • B01J29/06B01J39/14B01J47/018C02F1/281C02F1/42
    • The present invention relates to the production of zeolite particle composites that have average diameters in the range of about 10 mu m to about 180 mu m. These diameter sizes are especially suitable to be used in conjunction with carbon block filters in household potable water applications. The composite particles are produced by mixing 4 to 5 ANGSTROM commercial zeolite with water and organic or inorganic binders. The particles are then calcined at high temperatures to remove water and organic binders, which results in a water-stable structure. The particles are then ground in a low-shear grinder under extremely precise control to produce high yield of particles with particle sizes that are suitable for use with carbon block purifiers and other composite filter elements.
    • 本发明涉及平均直径在约10μm至约180μm范围内的沸石颗粒复合材料的生产。 这些直径尺寸特别适合与家用饮用水应用中的碳阻挡过滤器一起使用。 通过将4至5个ANGSTROM商业沸石与水和有机或无机粘合剂混合来制备复合颗粒。 然后将颗粒在高温下煅烧以除去水和有机粘合剂,这导致水稳定的结构。 然后将颗粒在非常精确的控制下在低剪切研磨机中研磨以产生高产率的颗粒,其颗粒尺寸适合用于碳块式净化器和其它复合过滤元件。
    • 96. 发明申请
    • ANTIMONY SILICATE SORBENT FOR REMOVAL OF METAL IONS
    • 用于去除金属离子的抗微生物硅酸盐溶液
    • WO99059161A1
    • 1999-11-18
    • PCT/GB1999/001305
    • 1999-05-13
    • B01D15/00B01J20/10B01J20/30B01J39/14C02F1/28G21F9/12
    • G21F9/12B01J39/14
    • The invention provides a use of a material comprising antimony silicate as a sorbent in the removal of metal ions, e.g. radioactive metal ions, from an acidic liquid medium. The metal ions may be selectively removed from amongst other ions such as Na, K, Mg, and Ca ions. Strontium is particularly effectively removable in this way. There is also provided a method of preparing an antimony silicate material for use in removing metal ions. The invention further provides a material comprising antimony silicate doped with one or more elements selected from the group consisting of tungsten, niobium and tantalum. The doped material has been found to be particularly effective as a sorbent in the removal of metal ions from a liquid medium.
    • 本发明提供了包含锑硅酸盐作为吸附剂的材料在去除金属离子中的用途,例如, 放射性金属离子,来自酸性液体介质。 可以从诸如Na,K,Mg和Ca离子的其它离子中选择性地除去金属离子。 锶以这种方式特别有效地拆除。 还提供了一种制备用于除去金属离子的硅酸锑材料的方法。 本发明还提供一种包含掺杂有选自钨,铌和钽的一种或多种元素的锑硅酸盐的材料。 已经发现掺杂材料作为吸附剂在从液体介质中除去金属离子时是特别有效的。
    • 98. 发明申请
    • PROCESS FOR THE OXIDATIVE REGENERATION OF A DEACTIVATED CATALYST AND AN APPARATUS THEREFOR
    • 灭活催化剂氧化还原过程及其装置
    • WO2013079500A1
    • 2013-06-06
    • PCT/EP2012/073781
    • 2012-11-28
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.SHELL OIL COMPANY
    • SADASIVAN VIJAYAKUMARI, SivakumarCHEWTER, Leslie, AndrewVAN WESTRENEN, Jeroen
    • B01J39/02B01D53/26B01D53/28B01J29/90B01J38/12B01J20/18B01J39/14C07C1/20C07C11/02C07C11/04C07C11/06B01J29/85B01J29/40
    • B01J29/90B01J20/18B01J20/3408B01J20/3458B01J29/40B01J29/85B01J38/12C07C1/20C07C4/06C07C2529/00Y02P20/584Y02P30/42C07C11/02
    • The present invention relates to a process for the oxidative regeneration of a deactivated catalyst, an apparatus therefore and a process for the preparation of an olefinic product incorporating such a regeneration process, said oxidative regeneration process comprising at least the steps of: - providing a catalyst comprising molecular sieve in hydrogen form to a guard zone (200); - passing a regeneration gas stream (185, 185a) comprising oxidant through the guard zone (200) to remove at least a part of one or both of any alkali metal ion and any alkaline earth metal ion from the regeneration gas stream (185, 185a) by ion exchange with the catalyst, to provide a treated regeneration gas stream comprising oxidant (205); - providing deactivated catalyst comprising molecular sieve in a regeneration zone (100), said deactivated catalyst from one or both of an oxygenate to olefin process and an olefin cracking process, wherein said regeneration zone (100) is separated from said guard zone (200) such that there is no transfer of catalyst from the guard zone (200) to the regeneration zone (100); - regenerating the deactivated catalyst in the regeneration zone (100) with the treated regeneration gas stream (205) to provide regenerated catalyst comprising regenerated molecular sieve; wherein said catalyst comprising molecular sieve in hydrogen form in said guard zone (200) is one or both of deactivated catalyst comprising molecular sieve in hydrogen form and regenerated catalyst comprising regenerated molecular sieve in hydrogen form.
    • 本发明涉及一种失活催化剂的氧化再生方法,一种装置及其制备包含这种再生方法的烯烃产物的方法,所述氧化再生方法至少包括以下步骤: - 提供催化剂 包括氢形式的分子筛到保护区(200); - 通过所述保护区(200)使包含氧化剂的再生气流(185,185a)通过所述再生气流(185,185a)去除至少一部分任何碱金属离子和任何碱土金属离子中的一种或两种 ),以提供包含氧化剂(205)的经处理的再生气流; - 在再生区(100)中提供包含分子筛的失活催化剂,所述失活催化剂从含氧化合物至烯烃方法中的一种或两种和烯烃裂解方法,其中所述再生区(100)与所述保护区(200)分离, 使得催化剂不从保护区(200)转移到再生区(100); - 用经处理的再生气流(205)再生再生区(100)中的失活的催化剂,以提供包含再生分子筛的再生催化剂; 其中在所述保护区(200)中包含氢形式的分子筛的所述催化剂是包含氢形式的分子筛的失活催化剂之一或两者以及包含氢形式的再生分子筛的再生催化剂。