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    • 94. 发明授权
    • Novel nonlinear optical materials and processes employing diacetylenes
    • 新型非线性光学材料和采用二乙炔的方法
    • US4431263A
    • 1984-02-14
    • US129560
    • 1980-03-12
    • Anthony F. Garito
    • Anthony F. Garito
    • B05D1/20C07C57/18C07C57/52C07C205/37C08F138/00G02B6/138G02F1/00G02F1/35G02F1/361G02F1/377G02F3/00G03F7/025G02B5/172
    • B82Y20/00B05D1/202B82Y30/00B82Y40/00C07C205/37C07C57/18C07C57/52C08F138/00G02B6/138G02F1/0018G02F1/3615G02F1/3618G03F7/025G02F1/3515G02F1/377G02F3/00
    • Novel nonlinear optical, piezoelectric, pyroelectric, waveguide, and other materials are presented together with processes for their employment and articles formed thereby. Such materials, processes and articles comprise diacetylenes and polymers formed from diacetylenic species, which polymers are amenable to close geometric, steric, structural, and electronic control. Accordingly, it is now possible to design, formulate and employ new diacetylenic species and polymers formed therefrom to provide nonlinear optic, waveguide, piezoelectric, and pyroelectric materials and devices having surprising efficiencies and degrees of effect. According to a preferred embodiment of the invention, diacetylenes which are crystallizable into crystals having a noncentrosymmetric unit cell may form single crystals or may be elaborated into a thin film upon a substrate by the Langmuir-Blodgett technique. Such films may, optionally, be polymerized either thermally or by irradiation for use in nonlinear optical and other systems. According to other preferred embodiments, diacetylenes are covalently bonded to substrates through the employment of silane species and subsequently polymerized to yield nonlinear optic and other devices having high structural integrity in addition to high efficiencies and effects.
    • 新型非线性光学,压电,热电,波导和其他材料与其使用的工艺和由此形成的制品一起呈现。 这些材料,方法和制品包括二乙炔和由二炔类物质形成的聚合物,该聚合物适于闭合几何,立体,结构和电子控制。 因此,现在可以设计,配制和使用由其形成的新的二炔类物质和聚合物,以提供令人惊奇的效率和效果的非线性光学,波导,压电和热电材料和装置。 根据本发明的优选实施方案,可结晶成具有非中心对称单元电池的晶体的二乙炔可以形成单晶,或者可以通过Langmuir-Blodgett技术在基底上被精制成薄膜。 任选地,这样的膜可以热或通过照射聚合用于非线性光学和其它系统中。 根据其它优选的实施方案,二乙炔通过使用硅烷物质共价键合到基底上,随后聚合以产生除了高效率和效果之外具有高结构完整性的非线性光学元件和其它器件。
    • 100. 发明申请
    • Method for forming nanoparticle films and applications thereof
    • 形成纳米颗粒膜的方法及其应用
    • US20050255236A1
    • 2005-11-17
    • US10843832
    • 2004-05-12
    • Tao DengAmy Smentkowski
    • Tao DengAmy Smentkowski
    • B05D1/00B05D1/12B05D1/20B05D7/22B32B5/16C03C17/00C03C17/10C23C2/04C23C26/00G01N21/65
    • C03C17/006B05D1/00B05D1/20B05D1/202B05D7/222B82Y30/00C03C17/10C03C2217/255C03C2217/42C03C2218/111C23C2/04C23C26/00G01N21/658Y10S977/84Y10T428/25
    • Disclosed herein is a method for making a nanoparticle film comprising dispersing nanoparticles in a first liquid; adding a second liquid to the first liquid to form a nanoparticle film on top of a solution comprising the first liquid, the second liquid and the nanoparticles, wherein the second liquid has a dielectric constant that is different from a dielectric constant of the first liquid; and contacting a substrate with the solution to deposit the nanoparticle film onto the contacted portion of the substrate. Disclosed herein too is a method for detecting an analyte comprising dispersing nanoparticles in a first liquid; adding a second liquid to the first liquid to form a nanoparticle film on top of a solution comprising the first liquid, the second liquid and the nanoparticles, wherein the second liquid has a dielectric constant that is different from a dielectric constant of the first liquid; contacting a substrate with the solution to deposit the nanoparticle film onto the substrate; disposing upon the nanoparticle film an analyte; and performing surface enhanced Raman spectroscopy to determine the identity of the analyte.
    • 本文公开了一种制备纳米颗粒膜的方法,包括将纳米颗粒分散在第一液体中; 向第一液体添加第二液体以在包含第一液体,第二液体和纳米颗粒的溶液的顶部上形成纳米颗粒膜,其中第二液体具有不同于第一液体的介电常数的介电常数; 以及使基底与溶液接触以将纳米颗粒膜沉积在基底的接触部分上。 本文还公开了一种用于检测分析物的方法,包括将纳米颗粒分散在第一液体中; 向第一液体添加第二液体以在包含第一液体,第二液体和纳米颗粒的溶液的顶部上形成纳米颗粒膜,其中第二液体具有不同于第一液体的介电常数的介电常数; 使基底与溶液接触以将纳米颗粒膜沉积到基底上; 在纳米颗粒膜上放置分析物; 并进行表面增强拉曼光谱以确定分析物的身份。