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91. 发明授权

US06191181B1 Urethane acrylates and their use in coating compositions 有权
标题翻译：聚氨酯丙烯酸酯及其在涂料组合物中的用途
公开(公告)号：US06191181B1
公开(公告)日：2001-02-20
申请号：US09433854
申请日：1999-11-04
申请人： Jan Weikard , Wolfgang Fischer , Frank Richter , Christian Zwiener
发明人： Jan Weikard , Wolfgang Fischer , Frank Richter , Christian Zwiener
IPC分类号： C08F246
CPC分类号： C08G18/792 , C08G18/672 , C09D175/16
摘要： The present invention relates to urethane acrylates, which may be cured with high-energy radiation, in which the urethane acrylates are the reaction product of a) a polyisocyanate component containing 20 to 100 mole %, based on the moles of the polyisocyanate component a), of iminooxadiazine dione group-containing polyisocyanate trimers corresponding to formula A wherein R1, R2and R3 are the same or different and represent linear or branched, C4-C20 (cyclo)alkyl groups and X is the same or different and represents isocyanate groups or isocyanate group-containing radicals that also contain iminooxadiazine dione, isocyanurate, uretdione, urethane, allophanate, biuret or oxadiazine trione groups, wherein R1, R2 and R3 are attached to a nitrogen atom, with b) an alcohol component containing at least one monobasic, hydroxy-functional, linear or branched C1-C12 alkyl ester of (meth)acrylic acid. The present invention further relates to the use of the urethane acrylates as binder components for coating compositions that are curable with high-energy radiation.
摘要翻译：本发明涉及聚氨酯丙烯酸酯，其可以用高能量辐射固化，其中聚氨酯丙烯酸酯是基于多异氰酸酯组分a）的摩尔数为20-100摩尔％的多异氰酸酯组分的反应产物，对应于式A的亚氨基恶二嗪二酮基多异氰酸酯三聚体，其中R 1，R 2和R 3相同或不同，表示直链或支链的C 4 -C 20（环）烷基，X相同或不同，表示异氰酸酯基或异氰酸酯基还含有亚氨基恶二酮二酮，异氰脲酸酯，脲二酮，氨基甲酸酯，脲基甲酸酯，缩二脲或恶二嗪三酮基团的基团，其中R1，R2和R3连接到氮原子上，b）含有至少一个一元羟基官能或（甲基）丙烯酸的支链C1-C12烷基酯。本发明还涉及聚氨酯丙烯酸酯作为共聚物的粘合剂成分的用途可以用高能量辐射固化的组合物。

92. 发明授权

US6022915A Thermoplastic molding compounds and a method of reducing the formation of residual monomers in these molding compounds 失效
标题翻译：热塑性成型化合物和减少这些模塑料中残留单体形成的方法
公开(公告)号：US6022915A
公开(公告)日：2000-02-08
申请号：US981688
申请日：1998-05-12
申请人： Anton Ticktin , Graham Edmund Mc Kee , Wolfgang Fischer , Binnur Gunesin , Norbert Guntherberg
发明人： Anton Ticktin , Graham Edmund Mc Kee , Wolfgang Fischer , Binnur Gunesin , Norbert Guntherberg
IPC分类号： C08J3/20 , C08F2/44 , C08F6/00 , C08K5/1545 , C08L25/16 , C08L33/12 , C08L33/20 , C08L55/02 , C08K5/15
CPC分类号： C08K5/1545
摘要： The invention relates to thermoplastic molding compositions consisting ofA) 98-99.995% by weight, based on A+B, of at least one acrylonitrile-containing polymer, andB) 0.005-2% by weight, based on A+B, of .alpha.-tocopherol.The invention also relates to a method for reducing the formation of residual monomers on thermal stress and shearing of the thermoplastic molding compositions by adding .alpha.-tocopherol.
摘要翻译： PCT No.PCT / EP96 / 02896 Sec。 371日期：1998年5月12日 102（e）日期1998年5月12日PCT 1996年7月2日PCT公布。出版物WO97 / 02314 日本1997年1月23日本发明涉及由A）98-99.995重量％（基于A + B）至少一种含丙烯腈的聚合物组成的热塑性模塑组合物，以及B）0.005-2重量％ A + B，α-生育酚。本发明还涉及通过加入α-生育酚来减少残余单体在热应力上的形成和热塑性模塑组合物的剪切的方法。

93. 发明授权

US5795938A Preparation of toughened polystyrene molding materials 失效
标题翻译：增韧聚苯乙烯成型材料的制备
公开(公告)号：US5795938A
公开(公告)日：1998-08-18
申请号：US849894
申请日：1997-06-16
申请人： Konrad Knoll , Wolfgang Loth , Wolfgang Fischer , Hermann Gausepohl
发明人： Konrad Knoll , Wolfgang Loth , Wolfgang Fischer , Hermann Gausepohl
IPC分类号： C08F2/42 , C08F6/00 , C08F297/04 , C08J3/00 , C08L25/06 , C08L53/02
CPC分类号： C08J3/005 , C08F297/04 , C08F6/003 , C08L25/06 , C08L53/02
摘要： Toughened vinyl aromatic compounds, in particular high impact polystyrene, are prepared by a continuous process in which the vinyl aromatic compound and the impact modifier, an elastomeric block copolymer, are each prepared separately in a reaction zone by anionic polymerization, with or without heat exchange with the environment and, if required, with the addition of a solvent, and are polymerized until complete conversion is achieved, and the living chain ends are terminated in a manner known per se, and a thermoplastic, toughened molding material is based on a vinyl aromatic compound having a residual content of less than 50 ppm of monomers and less than 100 ppm of oligomers.
摘要翻译： PCT No.PCT / EP95 / 04809 Sec。 371日期：1997年6月16日 102（e）日期1997年6月16日PCT提交1995年12月7日PCT公布。 WO96 / 18682 PCT出版物日期1996年6月20日通过连续方法制备乙烯基芳族化合物，特别是高抗冲聚苯乙烯，其中乙烯基芳族化合物和抗冲改性剂弹性体嵌段共聚物各自通过阴离子聚合在反应区中分别制备，与环境进行或不进行热交换，并且如果需要，通过加入溶剂，并且聚合直至完全转化，并且活性链末端以本身已知的方式终止，并且将热塑性增韧的模塑材料基于剩余含量小于50ppm的单体和小于100ppm的低聚物的乙烯基芳族化合物。

94. 发明授权

US5749601A Belt force limiter for a vehicle seat belt 失效
标题翻译：用于车辆安全带的皮带力限制器
公开(公告)号：US5749601A
公开(公告)日：1998-05-12
申请号：US825157
申请日：1997-03-26
申请人： Heinz Knoll , Wolfgang Fischer
发明人： Heinz Knoll , Wolfgang Fischer
IPC分类号： B60R22/28
CPC分类号： B60R22/28
摘要： A belt force limiter for a vehicle seat belt is mounted fixed to the vehicle by one end and, at its opposite free end, secures the shoulder strap approximately at shoulder level. The shoulder strap is displaced forward in relation to the vehicle seat with a limited amount of travel by the belt force limiter when tensile loading occurs due to a crash, tensile energy being absorbed in the belt force limiter. The belt force limiter has a pivot lever which is linked to an energy-absorbing component and in the position of rest is aligned approximately vertically and whose free end can be pivoted forward by the tension on the shoulder strap in the event of a crash, as a result of which the energy-absorbing component is deformed in an energy-absorbing manner.
摘要翻译：用于车辆安全带的皮带束限制器通过一端固定到车辆，并且在其相对的自由端将肩带固定在肩部水平。当由于碰撞引起拉伸载荷时，肩带相对于车辆座位向前移动，带张力限制器的有限行程由拉力能量吸收在带力限制器中。带力限制器具有枢转杆，其连接到能量吸收部件，并且在休止的位置大致垂直地对齐并且在碰撞的情况下，其自由端可以通过肩带上的张力向前枢转，如其结果是能量吸收部件以能量吸收的方式变形。

95. 发明授权

US5747656A Indicators for determining the proton concentration of strongly alkaline aqueous solutions 失效
标题翻译：确定强碱性水溶液质子浓度的指标
公开(公告)号：US5747656A
公开(公告)日：1998-05-05
申请号：US448413
申请日：1995-06-01
申请人： Wolfgang Fischer , Sylvia Baum , Thorsten Hartig , Michael Schleehahn
发明人： Wolfgang Fischer , Sylvia Baum , Thorsten Hartig , Michael Schleehahn
IPC分类号： C07D277/66 , G01N31/22 , C09B29/12 , C09B29/00 , C09B29/36 , C09B67/42
CPC分类号： C07D277/66 , G01N31/221
摘要： The invention relates to indicators for determine the proton concentration of strongly alkaline aqueous solutions which contain compounds of the formula (I) ##STR1## in which ##STR2##
摘要翻译： PCT No.PCT / EP94 / 03156 Sec。 371日期：1995年6月1日 102（e）1995年6月1日PCT PCT 1994年9月21日PCT公布。公开号WO95 / 09894 日期1995年04月13日本发明涉及用于确定含有式（I）化合物的强碱性水溶液的质子浓度的指标，其中

96. 发明授权

US5747568A Thermoplastic molding material 失效
标题翻译：热塑性成型材料
公开(公告)号：US5747568A
公开(公告)日：1998-05-05
申请号：US638593
申请日：1996-04-29
申请人： Wolfgang Fischer , Norbert Guntherberg
发明人： Wolfgang Fischer , Norbert Guntherberg
IPC分类号： C08K5/36 , C08K5/1545 , C08K5/372 , C08L25/12 , C08L51/00 , C08L51/04 , C08L51/06 , C08K5/15
CPC分类号： C08K5/1545 , C08K5/372 , C08L51/04
摘要： A thermoplastic molding material consists of A) 30-80% by weight, based on A+B, of an elastomeric grafting base A defined in more detail and B) 20-70% by weight, based on A+B, of a shell grafted onto the grafting base A and defined in more detail and C) 0.001-1 part by weight, based on 100 parts by weight of A+B, of .alpha.-tocopherol and D) from a half to ten times the amount, based on C, of a thiodipropionic ester selected from dilauryl and distearyl thiodipropionate.
摘要翻译：热塑性成型材料由A）30-80％（重量），基于A + B，更详细地定义的弹性体接枝基体A和B）基于A + B的20-70％重量的壳接枝到接枝基材A上并且更详细地定义为C）0.001-1重量份，基于100重量份的A + B，α-生育酚和D），其量为该组合物的一半至十倍，基于 C，选自二月桂基和硫代二丙酸二硬脂酯的硫代二丙酸酯。

97. 发明授权

US5726258A Continuous preparation of polymers 失效
标题翻译：连续制备聚合物
公开(公告)号：US5726258A
公开(公告)日：1998-03-10
申请号：US671308
申请日：1996-07-01
申请人： Wolfgang Fischer , Michael Baumgartel
发明人： Wolfgang Fischer , Michael Baumgartel
IPC分类号： C08F2/00 , B01J19/24 , C08F2/02 , C08F2/04
CPC分类号： B01J19/242 , B01J19/245 , B01J2219/00085 , B01J2219/00103 , B01J2219/00162 , B01J2219/00164 , B01J2219/00168
摘要： A process for the continuous preparation of polymers from reaction components, in particular of copolymers of styrene and acrylonitrile, by bulk or solution polymerization, where the reaction components are passed through the tubes of a recycle reactor, the recycle reactor has at least one tube bundle reactor with straight tubes around which a liquid heat-transfer medium flows, and each tube bundle reactor consists of at least two shell and tube heat exchangers which are connected together by at least one intermediate mixing section. Moreover the volume of the shell and tube heat exchangers is at least 50% of the total volume of the arrangement. The intermediate mixing sections consist of tubes with static mixing elements, around which tubes a heat-transfer medium flows.
摘要翻译：从反应组分，特别是苯乙烯和丙烯腈的共聚物中通过本体或溶液聚合连续制备聚合物的方法，其中反应组分通过循环反应器的管，该再循环反应器具有至少一个管束具有液体传热介质流动的直管的反应器，并且每个管束反应器由至少两个壳管式热交换器组成，其通过至少一个中间混合段连接在一起。此外，壳管式热交换器的体积至少为总体积的50％。中间混合部分由具有静态混合元件的管组成，传热介质管在该管周围。

98. 发明授权

US5710197A Crosslinked polymer particles containing a fluorescent dye 失效
标题翻译：含有荧光染料的交联聚合物颗粒
公开(公告)号：US5710197A
公开(公告)日：1998-01-20
申请号：US501927
申请日：1995-07-13
申请人： Wolfgang Fischer , Andreas Deckers , Norbert Guntherberg , Ekkehard Jahns , Sylke Haremza , Werner Ostertag , Helmut Schmidt
发明人： Wolfgang Fischer , Andreas Deckers , Norbert Guntherberg , Ekkehard Jahns , Sylke Haremza , Werner Ostertag , Helmut Schmidt
IPC分类号： C09K11/06 , C08K5/00 , C09B3/14 , C09B57/02 , C09B67/20 , C09D11/50 , C09K11/02 , C08K5/45
CPC分类号： C09K11/02 , C08K5/0041 , C09B67/0061 , C09D11/50
摘要： Fluorescent pigments contain essentially a polymer matrix based on polymethyl methacrylate and a nonpolar fluorescent dye from the coumarin or perylene series, the polymer matrix being a crosslinked polymethacrylate or polyacrylate prepared by suspension polymerization.
摘要翻译：荧光颜料基本上包含基于聚甲基丙烯酸甲酯和来自香豆素或苝系列的非极性荧光染料的聚合物基质，聚合物基质是通过悬浮聚合制备的交联的聚甲基丙烯酸酯或聚丙烯酸酯。

99. 发明授权

US5631323A Composition of styrene-acrylonitrile copolymer matrix with particles of graft copolymer and crosslinked copolymer 失效
标题翻译：苯乙烯 - 丙烯腈共聚物基体与接枝共聚物和交联共聚物颗粒的组成
公开(公告)号：US5631323A
公开(公告)日：1997-05-20
申请号：US567056
申请日：1995-12-04
申请人： Norbert Guntherberg , Ekkehard Jahns , Wolfgang Fischer , Graham E. McKee , Bernhard Rosenau
发明人： Norbert Guntherberg , Ekkehard Jahns , Wolfgang Fischer , Graham E. McKee , Bernhard Rosenau
IPC分类号： C08F2/18 , C08F2/20 , C08F212/06 , C08F212/10 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L35/04
CPC分类号： C08L25/12 , C08F212/10 , C08L55/02 , C08L51/04
摘要： Thermoplastic molding materials preparedA) from 35 to 99.5% by weight of a matrix copolymer (A) ofa.sub.1) from 50 to 95% by weight of styrene and/or .alpha.-methylstyrene,a.sub.2) from 5 to 50% by weight of acrylonitrile anda.sub.3) from 0 to 20% by weight of further comonomersB) from 0 to 50% by weight of a particulate graft copolymer (B) which is insoluble in (A), has a median particle diameter of from 0.03 to 1 .mu.m and preparedb.sub.1) from 30 to 80% by weight of a core comprising an elastomeric polymer having a glass transition temperature of less than -10.degree. C. andb.sub.2) from 20 to 70% by weight of a graft shell comprising a polymer which is compatible or partly compatible with (A)andC) from 0.5 to 30% by weight of a particulate crosslinked copolymer (C) which is insoluble in (A), has a median particle diameter of from 0.5 to 50 .mu.m and comprisesc.sub.1) from 50 to 89.95% by weight of styrene and/or .alpha.-methylstyrene,c.sub.2) from 10 to 50% by weight of acrylonitrile,c.sub.3) from 0.05 to 5% by weight of a polyfunctional, crosslinking monomer,c.sub.4) from 0 to 10% by weight of a monomer which contains acidic or basic groups andc.sub.5) from 0 to 20% by weight of further comonomers.
摘要翻译：制备的热塑性成型材料A）35至99.5重量％的a1）的基质共聚物（A），50-95重量％的苯乙烯和/或α-甲基苯乙烯，a2）5-50重量％的丙烯腈和a3）0至20重量％的另外的共聚单体B）0至50重量％的不溶于（A）的颗粒接枝共聚物（B），其中值粒径为0.03至1μm 并且制备b1）30至80重量％的芯，其包含玻璃化转变温度低于-10℃的弹性体聚合物，和b2）20至70重量％的包含聚合物的接枝壳，所述聚合物是与（A）和C）相容或部分相容的0.5至30重量％的不溶于（A）的颗粒状交联共聚物（C），其中值粒径为0.5至50μm，并包含c1）苯乙烯和/或α-甲基苯乙烯的50至89.95重量％，c2）10至50重量％的丙烯腈，c 3）0.05至5重量％ t的多官能交联单体，c4）0至10重量％的含酸性或碱性基团的单体，和c 5）0至20重量％的其它共聚单体。

100. 发明授权

US5561661A Method for synchronizing redundantly transmitted message cell streams 失效
标题翻译：用于同步冗余传输的消息单元流的方法
公开(公告)号：US5561661A
公开(公告)日：1996-10-01
申请号：US438788
申请日：1995-05-11
申请人： Bernhard Edmaier , Wolfgang Fischer
发明人： Bernhard Edmaier , Wolfgang Fischer
IPC分类号： H04L7/00 , H04J3/06 , H04L1/22 , H04L12/70 , H04Q3/00 , H04Q11/04 , H04L12/56
CPC分类号： H04Q11/0478 , H04J3/0629 , H04L1/22 , H04L2012/5627 , H04L2012/5674
摘要： In a cell-oriented communication network (ATMN), respective control cells are inserted at predetermined time intervals into two message cell streams redundantly transmitted via a path pair (EP,AP). The control cells respectively contain a sequence number that varies continuously from control cell to control cell. The appearance of control cells is separately monitored for the two message cell streams at the end of the path pair. Which of the two message cell streams is the leading message cell stream is thereby first determined on the basis of the sequence numbers appearing in the message cell streams. The leading message cell stream is then delayed until the appearance of identical sequence numbers in the message cell streams.
摘要翻译：在面向小区的通信网络（ATMN）中，各个控制小区以预定的时间间隔插入经由路径对（EP，AP）冗余传输的两个消息小区流中。控制细胞分别含有从对照细胞到对照细胞连续变化的序列号。在路径对的末尾分别监视两个消息单元流的控制单元的外观。因此，首先基于消息单元流中出现的序列号来确定两个消息单元流中的哪一个是前导消息单元流。领先的消息单元流然后被延迟，直到在消息单元流中出现相同的序列号。

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