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91. 发明授权

US07060357B2 Powder coatings containing symmetrical additives 失效
标题翻译：包含对称添加剂的粉末涂料
公开(公告)号：US07060357B2
公开(公告)日：2006-06-13
申请号：US10265036
申请日：2002-10-04
申请人： Walter H. Ohrbom , David J. Law , Robert D. Weise , James A. Laugal
发明人： Walter H. Ohrbom , David J. Law , Robert D. Weise , James A. Laugal
IPC分类号： B32B27/40 , B32B27/42 , C08L75/04
CPC分类号： C09D5/037 , C08G2150/20 , C09D161/20 , Y10S525/934 , Y10T428/31551 , C08L2666/02
摘要： A coating composition contains solid particulates of a mixture of an aminoplast crosslinking agent, a solid polymer having functionality reactive with the aminoplast crosslinking agent, and a crystalline, carbamate-functional additive. The crystalline, carbamate-functional additive has a melting point of at least about 30° C. and is up to about 15% by weight of the powder coating composition.
摘要翻译：涂料组合物含有氨基塑料交联剂，具有与氨基塑料交联剂反应的官能团的固体聚合物和结晶的氨基甲酸酯官能添加剂的混合物的固体颗粒。结晶的氨基甲酸酯官能添加剂具有至少约30℃的熔点并且高达粉末涂料组合物的约15重量％。

92. 发明授权

US07034080B1 Pigment dispersant, method of making coating compositions, and coating compositions 有权
标题翻译：颜料分散剂，制备涂料组合物的方法和涂料组合物
公开(公告)号：US07034080B1
公开(公告)日：2006-04-25
申请号：US11087958
申请日：2005-03-23
申请人： Walter H. Ohrbom , Nicholas Caiozzo , Sergio Balatan , Zenon Paul Czornij , Clair J. Certo , Janice E. Echols
发明人： Walter H. Ohrbom , Nicholas Caiozzo , Sergio Balatan , Zenon Paul Czornij , Clair J. Certo , Janice E. Echols
IPC分类号： C08F263/00
CPC分类号： C08G18/0823 , C08G18/348 , C08G18/3829 , C08G18/728 , C08L75/04 , C09D5/027 , C08L2666/20
摘要： A coating composition comprises at least one pigment dispersed in an acrylic polymer, wherein the acrylic polymer is prepared by first polymerizing a mixture of ethylenically unsaturated monomers comprising: (a) at least about 15% by weight unsaturated meta-isopropenyl-α,α-dimethylbenzyl isocyanate; (b) at least one further aromatic polymerizable monomer, in an amount so that monomers (a) and (b) combined are at least about 50 percent by weight of the mixture of ethylenically unsaturated monomers; and (c) at least one alkyl (meth)acrylate to form a polymer, and secondly, reacting the isocyanate groups of the polymer with a (d) a hydroxyalkyl acid in which the hydroxy and acid groups are separated by at least four atoms or with a diol having both a primary hydroxyl group and a secondary hydroxyl group and then with a cyclic anhydride and, optionally, with one or more members selected from the group consisting of (e) hydroxyethylene ethyl urea, (f) methoxypolyethylene glycols, and (g) other, different materials having a functional group reactive with isocyanate.
摘要翻译：涂料组合物包含分散在丙烯酸聚合物中的至少一种颜料，其中丙烯酸类聚合物通过首先聚合烯键式不饱和单体的混合物来制备，所述混合物包含：（a）至少约15重量％的不饱和间 - 异丙烯基-α，异氰酸二甲基苄酯; （b）至少一种其它芳族可聚合单体，其量使得单体（a）和（b）的组合为烯属不饱和单体混合物的至少约50重量％; 和（c）至少一种（甲基）丙烯酸烷基酯以形成聚合物，其次，使聚合物的异氰酸酯基与（d）羟烷基酸反应，其中羟基和酸基被至少四个原子分开，或与二醇具有伯羟基和仲羟基，然后与环状酸酐和任选地与一种或多种选自（e）羟乙烯乙基脲，（f）甲氧基聚乙二醇和（ g）具有与异氰酸酯反应的官能团的其它不同材料。

93. 发明授权

US06977309B2 Compounds having a secondary or tertiary hydroxy of halide group separated from a primary carbamate group by three or more carbon atoms and a method of making the same 失效
标题翻译：具有通过三个或更多个碳原子与伯氨基甲酸酯基分离的卤化物的仲羟基或叔羟基的化合物及其制备方法
公开(公告)号：US06977309B2
公开(公告)日：2005-12-20
申请号：US10285634
申请日：2002-10-31
申请人： Walter H. Ohrbom , Craig S. Schang
发明人： Walter H. Ohrbom , Craig S. Schang
IPC分类号： C07C271/16 , C08G18/38 , C08G71/04 , C09D175/04 , C07C269/02 , C07C269/04 , C07C269/06 , C07C271/06 , C07C271/08 , C07C271/10
CPC分类号： C09D175/04 , C07C271/16 , C08G18/3831 , C08G71/04
摘要： Provided is a compound having one or more structures of the formula: wherein X is a primary carbamate group, Y is a hydroxy or halide group, n is an integer of 2 or more, n′ is an integer of 1 or more, and R0, R1, R2, R3, R4 and R5 may be H or a group selected from alkyl groups, aliphatic groups, cycloaliphatic groups, aromatic groups and mixtures thereof, with the provisos that at least one R1 or R2 group is selected from the group consisting of aliphatic groups, cycloaliphatic groups, and aromatic groups, and in substantially all structures primary carbamate group X is attached to a carbon atom having a lower degree of substitution than a carbon atom to which functional group Y is attached. The invention provides a method of making the claimed compound.
摘要翻译：本发明提供具有一个或多个下式结构的化合物：其中X是伯氨基甲酸酯基，Y是羟基或卤化物基团，n是2以上的整数，n'是1或更大的整数，R R 1，R 2，R 3，R 3，R 4和R 3，R 3，R 4，可以是H或选自烷基，脂族基团，脂环族基团，芳族基团及其混合物的基团，条件是至少一个R 1或R' SUB> 2 基团选自脂族基团，脂环族基团和芳族基团，并且在基本上所有结构中，伯氨基甲酸酯基团X连接到具有比碳原子低的取代度的碳原子功能组Y所连接。本发明提供一种制备所要求保护的化合物的方法。

94. 发明授权

US06890994B2 Curable coating compositions with carbamate-containing acrylic polymers 失效
标题翻译：含氨基甲酸酯的丙烯酸聚合物的可固化涂料组合物
公开(公告)号：US06890994B2
公开(公告)日：2005-05-10
申请号：US10305284
申请日：2002-11-26
申请人： Walter H. Ohrbom , Craig S. Schang , Donald Campbell , Donald L. St. Aubin
发明人： Walter H. Ohrbom , Craig S. Schang , Donald Campbell , Donald L. St. Aubin
IPC分类号： C07C217/12 , C07C271/16 , C08F20/36 , C08G18/28 , C08G18/38 , C08G71/04 , C09D175/04 , C09D201/02 , C08F2/00
CPC分类号： C07C217/12 , C07C271/16 , C08F20/36 , C08G18/285 , C08G18/3831 , C08G71/04 , C09D175/04 , C09D201/025 , Y10T428/31529 , Y10T428/31663 , C08L2666/16 , C08L2666/02 , C08L2666/28
摘要： The invention provides an acrylic polymer or oligomer comprising random repeating units of the formula: a method of making said polymers and curable coating compositions comprising the same.
摘要翻译：本发明提供了包含下式的无规重复单元的丙烯酸聚合物或低聚物：制备所述聚合物的方法和包含该聚合物的可固化涂料组合物。

95. 发明授权

US06858693B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
标题翻译：具有改进粘合性的氨基甲酸酯官能树脂，其制备方法以及改进层间粘附性的方法
公开(公告)号：US06858693B2
公开(公告)日：2005-02-22
申请号：US10602852
申请日：2003-06-24
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C09D5/00 , C08F8/00 , C08F8/30 , C08F220/00 , C08G18/38 , C08G18/81 , C09D133/00 , C09D157/06 , C09D183/04 , C09D201/02 , C09J5/00 , C08F126/02
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
摘要翻译：本发明提供氨基甲酸酯官能树脂和包含所述树脂的涂料组合物，其相对于随后施加的膜或涂层具有改善的粘合性。更具体地说，本发明涉及具有每个氨基甲酸酯基团至少250克聚合物的氨基甲酸酯官能加成聚合物，它们以小于35重量％的非官能单体，优选小于20重量％，最优选0至小于10重量％，基于聚合物的总重量。本发明还提供一种制备通过所要求保护的方法制备的氨基甲酸酯官能聚合物和氨基甲酸酯官能聚合物的方法。最后，本发明提供了一种用于改善第一涂料组合物与随后施加的材料的粘附性的方法，以及制备包含涂覆的基材，粘合剂组合物和具有至少一个表面的玻璃的复合材料的方法。

96. 发明授权

US06855789B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06855789B2
公开(公告)日：2005-02-15
申请号：US10348484
申请日：2003-03-25
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C09D5/00 , C08F8/00 , C08F8/30 , C08F220/00 , C08G18/38 , C08G18/81 , C09D133/00 , C09D157/06 , C09D183/04 , C09D201/02 , C09J5/00 , C08F126/02
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

97. 发明授权

US06849337B2 Powder coatings containing oxirane groups beta to urethane or urea groups 失效
标题翻译：含有环氧乙烷基团的氨基甲酸酯或脲基团的粉末涂料
公开(公告)号：US06849337B2
公开(公告)日：2005-02-01
申请号：US10265060
申请日：2002-10-04
申请人： Walter H. Ohrbom , Timothy S. December
发明人： Walter H. Ohrbom , Timothy S. December
IPC分类号： C08G18/28 , C08G59/28 , C08G59/32 , C08L33/00 , C08L67/00 , C08L75/04 , C09D163/00 , C09D163/02 , B32B27/38 , C08G59/02 , C08L83/00
CPC分类号： C09D163/00 , C08G18/2845 , C08G59/28 , C08G59/3227 , C08G2150/20 , C08L33/00 , C08L67/00 , C08L75/04 , Y10S524/904 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , C08L2666/02
摘要： A powder coating composition contains solid particulates of a mixture of a solid material having at least two epoxide groups, each beta to a urethane or urea group, and a solid crosslinker reactive with epoxide groups.
摘要翻译：粉末涂料组合物包含具有至少两个环氧基团的固体材料的混合物的固体颗粒，每个β与氨基甲酸酯或脲基团，和与环氧化物基团反应的固体交联剂。

98. 发明授权

US06822040B2 Basecoat composition with improved repair properties 失效
标题翻译：底漆组合物具有改进的修复性能
公开(公告)号：US06822040B2
公开(公告)日：2004-11-23
申请号：US09962700
申请日：2001-09-25
申请人： Leslie G. Baugh , David K. K. Lau , Thomas C. Balch , Sergio E. Balatan , Walter H. Ohrbom , James A. Laugal , David J. Law
发明人： Leslie G. Baugh , David K. K. Lau , Thomas C. Balch , Sergio E. Balatan , Walter H. Ohrbom , James A. Laugal , David J. Law
IPC分类号： C08L5100
CPC分类号： B05D7/536 , B05D7/577 , C09D133/08 , Y10T428/2982 , Y10T428/31529 , C08L2666/54 , C08L2666/14
摘要： A basecoat composition includes an acrylic polymer prepared from a combination of monomers including at least about 30% by weight ethyl acrylate, methyl acrylate, methyl methacrylate, or a combination of these. The basecoat composition also includes methylated melamine-formaldehyde resin and up to about 10% by weight of a butylated melamine-formaldehyde resin, based on the weight of the basecoat composition vehicle and butylated melamine resin. An at least partially cured layer of the basecoat composition offers improved adhesion with a coating composition layer applied over it and cured, whether the coating composition layer applied over it is another layer of the basecoat composition itself or a layer of a clearcoat composition.
摘要翻译：底漆组合物包括由包含至少约30重量％的丙烯酸乙酯，丙烯酸甲酯，甲基丙烯酸甲酯或它们的组合的单体组合组合制备的丙烯酸聚合物。底漆组合物还包括甲基化三聚氰胺甲醛树脂和最多约10重量％的丁基化三聚氰胺 - 甲醛树脂，基于底漆组合物载体和丁基化三聚氰胺树脂的重量。底涂层组合物的至少部分固化的层提供与涂覆在其上并且固化的涂料组合物层的改善的粘合性，涂覆在其上的涂料组合物层是否是底涂层组合物本身的另一层或透明涂层组合物层。

99. 发明授权

US06812300B2 Method for making multifunctional materials 失效
标题翻译：制作多功能材料的方法
公开(公告)号：US06812300B2
公开(公告)日：2004-11-02
申请号：US10325304
申请日：2002-12-20
申请人： Walter H. Ohrbom , Patricia A. Herrel
发明人： Walter H. Ohrbom , Patricia A. Herrel
IPC分类号： C08F830
CPC分类号： C08F8/30
摘要： The invention relates to a method of making multifunctional materials, especially materials comprising at least one primary carbamate group and a grafting moiety (cii). The method of the invention requires the successive or simultaneous reactions of a material P with a grafting material (c) and ammonia. Material P comprises two or more cyclic carbonate groups (bi). Grafting material (c) comprises at least one amine group (ci) and a grafting moiety (cii). The amine group (ci) is selected from primary amines, secondary amines, and mixtures thereof. The resulting multifunctional materials are useful in a variety of curable coating compositions, including solventborne, waterborne, electrodeposition, liquid solvent free coatings, powder, and powder slurry.
摘要翻译：本发明涉及制备多功能材料的方法，特别是包含至少一种伯氨基甲酸酯基团和接枝部分（cii）的材料。本发明的方法需要材料P与接枝材料（c）和氨的连续或同时的反应。材料P包含两个或更多个环状碳酸酯基团（bi）。接枝材料（c）包含至少一个胺基（ci）和接枝部分（cii）。胺基（ci）选自伯胺，仲胺及其混合物。所得多功能材料可用于各种可固化涂料组合物，包括溶剂型，水性，电沉积，液体无溶剂涂料，粉末和粉末浆料。

100. 发明授权

US06740706B2 Method for obtaining coating compositions having reduced VOC 有权
标题翻译：获得具有降低的VOC的涂料组合物的方法
公开(公告)号：US06740706B2
公开(公告)日：2004-05-25
申请号：US10012075
申请日：2001-12-07
申请人： Walter H. Ohrbom , Robert D. Weise , James A. Laugal
发明人： Walter H. Ohrbom , Robert D. Weise , James A. Laugal
IPC分类号： C08L3304
CPC分类号： C08F2/44 , C08F2/06
摘要： The invention relates to an economical method of making a polymer having reduced VOCs and coating compositions containing such polymers. In one embodiment, the method of invention requires providing a reactant mixture (a), providing a solvent mixture (b) comprising a reactive component (c) which is substantially free of any heteroatoms and is not a crystalline solid at room temperature and comprises (i) from 12 to 72 carbon atoms, and (ii) at least two functional groups, and subjecting the reactant mixture (a) in the solvent mixture (b) to polymerization conditions sufficient to polymerize reactant mixture (a) to provide a mixture (d) of a polymer (a′) in solvent mixture (b), wherein reactive component (c) under the polymerization conditions is substantially nonreactive: (1) with the components of reactive mixture (a), (2) in the polymerization of reactant mixture (a) and (3) with the polymer (a′). Coating compositions of the invention comprising polymers made by the disclosed method provide low VOCs without any reduction in application or performance properties.
摘要翻译：本发明涉及制备具有降低的VOC的聚合物和含有这种聚合物的涂料组合物的经济方法。在一个实施方案中，本发明的方法需要提供反应物混合物（a），提供包含基本上不含任何杂原子并且在室温下不是结晶固体的反应性组分（c）的溶剂混合物（b），并且包含 i）12至72个碳原子，和（ii）至少两个官能团，并使溶剂混合物（b）中的反应物混合物（a）经受足以聚合反应混合物（a）的聚合条件以提供混合物 d）在溶剂混合物（b）中的聚合物（a'），其中在聚合条件下的反应性组分（c）基本上是非反应性的：（1）在反应混合物（a），（2）反应物混合物（a）和（3）与聚合物（a'）。包含通过所公开的方法制备的聚合物的本发明的涂料组合物提供低VOC，而不会降低应用或性能。

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