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91. 发明授权

US5641843A Process for polymerization of alpha-olefins 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US5641843A
公开(公告)日：1997-06-24
申请号：US560515
申请日：1995-11-17
申请人： Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
发明人： Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F4/64 , C08F4/654 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/655 , C08F4/656
CPC分类号： C08F210/16 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65925 , Y10S526/941
摘要： A process for producing an alpha-olefin polymer, which comprises polymerizing an alpha-olefin in the presence of a catalyst formed from(A) a solid catalyst component comprising an inorganic carrier and deposited thereon a compound of a transition metal of Group IVB of the periodic table treated with an organometallic compound, and(B) an aluminoxane.
摘要翻译：一种制备α-烯烃聚合物的方法，其包括在由（A）包含无机载体的固体催化剂组分形成的催化剂存在下聚合α-烯烃，并将其上沉积有第ⅣB族过渡金属的化合物用有机金属化合物处理的周期表，和（B）铝氧烷。

92. 发明授权

US5336747A Random 1-butene/ethylene copolymer 失效
标题翻译：随机1-丁烯/乙烯共聚物
公开(公告)号：US5336747A
公开(公告)日：1994-08-09
申请号：US961854
申请日：1992-10-16
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： C08F210/08 , C08F210/16
CPC分类号： C08F210/08
摘要： A highly crystalline semi-rigid random 1-butene/ethylene copolymer consisting of 1-butene and ethylene, said copolymer having the following characteristics (A) to (K);(A) it consists of 99 to 90 mole % of the 1-butene component and 1 to 10 mole % of the ethylene component,(B) it has an intrinsic viscosity (.eta.), measured in decalin at 130.degree. C., of from 0.5 to 6 dl/g,(C) it has a DSC melding point (Tm) measured by a differential scanning calorimeter, of from 100.degree. to 120.degree. C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 20 to 58%,(E) the amount (W.sub.1 in % by weight) of that portion of it which is soluble in boiling methyl acetate is not more than 2%,(F) the amount (W.sub.2 in % by weight) of that portion of it which is soluble in a 1:1 by volume mixture of acetone and n-decane at 10.degree. C. is less than 5 .times. (.eta.).sup.-1.2,(G) it has a yield strength of 30 to 180 kg/cm.sup.2,(H) it has a tensile strength at break of 200 to 800 kg/cm.sup.2,(I) it has an elongation at break of from 350 to 800%,(J) it has a torsional rigidity of 200 to 2000 kg/cm.sup.2 and(K) it has a Young's modulus of 400 to 4000 kg/cm.sup.2.
摘要翻译：由1-丁烯和乙烯组成的高结晶半刚性无规1-丁烯/乙烯共聚物，所述共聚物具有以下特征（A）至（K）; （A）由99〜90摩尔％的1-丁烯成分和1〜10摩尔％的乙烯成分组成，（B）其在130℃的萘烷中测定的特性粘度（η）为（C）通过差示扫描量热计测得的DSC熔点（Tm）为100〜120℃，（D）具有通过X射线测定的结晶度衍生物为20〜58％（E）可溶于沸腾乙酸甲酯的部分的量（W1重量％）为2％以下（F）量（W 2以％计，重量）可溶于丙酮和正癸烷的1:1体积比的混合物在10℃下的该部分小于5×（eta）-1.2（G），其屈服强度为30 （H），断裂时的拉伸强度为200〜800kg / cm 2，（I）断裂伸长率为350〜800％，（J）扭转刚性为200 至2000kg / cm 2，（K），其杨氏模量为400〜4000kg / cm 2。

93. 发明授权

US5126301A Solid catalyst for polymerizing an olefin 失效
标题翻译：用于聚合烯烃的固体催化剂
公开(公告)号：US5126301A
公开(公告)日：1992-06-30
申请号：US492341
申请日：1990-03-12
申请人： Toshiyuki Tsutsui , Ken Yoshitsugu , Akinori Toyota , Norio Kashiwa
发明人： Toshiyuki Tsutsui , Ken Yoshitsugu , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F4/02 , C08F4/60 , C08F4/64 , C08F4/649 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/904 , Y10S526/941 , Y10S526/943
摘要： A solid catalyst for polymerizing an olefin is prepared from an organometallic compound, a fine-particle carrier, an aluminoxane, a compound of group IVB transition metal in periodic table, and an olefin polymer produced in a preliminary polymerization. The catalyst has a high polymerization activity and is capable of producing an olefin polymer having a narrow molecular- weight distribution. When the catalyst is used for producing an olefin copolymer, the resulting copolymer has both narrow molecular-weight distribution and composition distribution.
摘要翻译：用于聚合烯烃的固体催化剂由有机金属化合物，细颗粒载体，铝氧烷，周期表中IVB族过渡金属的化合物和在预聚合中制备的烯烃聚合物制备。该催化剂具有高聚合活性，能够制备分子量分布窄的烯烃聚合物。当催化剂用于制备烯烃共聚物时，所得共聚物具有窄的分子量分布和组成分布。

94. 发明授权

US5122491A Catalyst for polymerizing an olefin and process for polymerizing an olefin 失效
标题翻译：用于聚合烯烃的催化剂和聚合烯烃的方法
公开(公告)号：US5122491A
公开(公告)日：1992-06-16
申请号：US290110
申请日：1988-12-16
申请人： Mamoru Kioka , Norio Kashiwa , Toshiyuki Tsutsui , Akinori Toyota
发明人： Mamoru Kioka , Norio Kashiwa , Toshiyuki Tsutsui , Akinori Toyota
IPC分类号： C08F4/62 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/904 , Y10S526/943
摘要： An olefin is polymerized or copolymerized under the presence of an olefin-polymerizing catalyst prepared from (A) a transition-metal compound or (A') a transition-metal compound loaded on a fine-particle carrier, said transition metal being selected from group IVB in the periodic table; (B) an aluminoxane; and (C) an organoaluminum compound represented by the general formula [I] or [II]:R.sup.1.sub.m Al(OR.sup.2).sub.3-m [I]R.sup.3.sub.n Al(OSiR.sup.4.sub.3).sub.3-n [II]wherein R.sup.1, R.sup.2, and R.sup.3 are selected from hydrocarbon radicals, R.sup.4 is selected from the group consisting of hydrocarbon, alkoxy, and aryloxy radicals, and m and n are positive numbers of 0
摘要翻译： PCT No.PCT / JP88 / 00384 Sec。 371日期：1988年12月16日 102（e）日期1988年12月16日PCT提交1988年4月19日PCT公布。出版物WO88 / 08432 日本11月3日，1988年。烯烃在由（A）过渡金属化合物或（A'）负载在细粒载体上的过渡金属化合物制备的烯烃聚合催化剂存在下聚合或共聚合，所述过渡金属选自周期表中的IVB族; （B）铝氧烷; 和（C）由通式[I]或[II]表示的有机铝化合物：R1mA1（OR2）3-m [I] R3nAl（OSiR43）3-n [II]其中R1，R2和R3选自烃基，R 4选自烃，烷氧基和芳氧基，m和n是0

95. 发明授权

US5003019A Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers 失效
标题翻译：环烯烃无规共聚物，烯属无规共聚物，和制备环烯烃无规共聚物的方法
公开(公告)号：US5003019A
公开(公告)日：1991-03-26
申请号：US162200
申请日：1988-02-29
申请人： Naoshi Ishimaru , Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
发明人： Naoshi Ishimaru , Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/06 , C08F210/14 , C08F232/00
CPC分类号： C08F232/00 , C08F210/00 , C08F210/06 , C08F210/14 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A cyclo-olefinic random copolymer composed of an alpha-olefin component having 3 to 20 carbon atoms and a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclo-olefin component, and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; andan olefinic random copolymer composed of (A) an olefin component having 3 to 20 carbon atoms and (B) a cyclic polyene component and as required, (C) a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component (A) having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclic polyene component (B) and 0 to 90 mole % of recurring units derived from said cyclo-olefin component (C), and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and a process for production thereof.Also provided is a process for producing a cyclo-olefinic random copolymer, which comprises copolymerizing an alpha-olefin and a cyclo-olefin in the presence of a catalyst formed from(A) a compound of a transition metal of Group IVB of the periodic table having as a ligand a multidentate coordination compound in which at least two conjugated cycloalkadienyl groups or substituted products thereof are bonded via a lower alkylene group, and(B) an aluminoxane.

96. 发明授权

US4981605A Liquid modified ethylenic random copolymer and its uses 失效
标题翻译：液体改性乙烯无规共聚物及其用途
公开(公告)号：US4981605A
公开(公告)日：1991-01-01
申请号：US201024
申请日：1988-06-01
申请人： Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
发明人： Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F8/08 , C09D7/12 , C10M107/04 , C10M143/18
CPC分类号： C10M143/18 , C08F8/00 , C08F8/08 , C09D7/125 , C10M107/04 , C08F2800/10 , C10M2205/00 , C10M2205/02 , C10M2205/0206 , C10M2205/022 , C10M2205/0225 , C10M2205/12 , C10N2220/02 , C10N2240/00 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/401 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/10
摘要： A liquid modified ethylenic random copolymer selected from an epoxidization product of a liquid ethylenic random copolymer of ethylene and an alpha-olefin having 3 to 20 carbon atoms and a hydroxylation product of a liquid ethylenic random copolymer of ethylene and an alpha-olefin having 3 to 20 carbon atoms. The modified copolymer is characterized in that (i) the liquid modified ethylenic random copolymer has an ethylene component content of 10 to 85 mole % and an alpha-olefin component content of 15 to 90 mole %, (ii) in the .sup.13 C-NMR spectrum of the liquid modified ethylenic random copolymer, signals of .alpha..beta. and .beta..gamma. based on the methylene chain between two adjacent tertiary carbon atoms in the main chain of the copolymer are not observed, (iii) the liquid modified ethylenic random copolymer has a number average molecular weight (Mn), measured by a vapor pressure osmometer, of 200 to 10,000, and (iv) where the liquid modified ethylenic random copolymer is the epoxidized product, each epoxy group therein is positioned at the polymer chain end of the liquid ethylenic random copolymer, and the content of the epoxy groups is 0.01 to 0.5 mole per 100 g of the liquid epoxidized ethylenic random copolymer, and where the liquid modified ethylenic random copolymer is the hydroxylated product, each hydroxyl group therein is bonded to a carbon atom derived from ethylene or the alpha-olefin and positioned at the polymer chain end of the liquid ethylenic random copolymer, and the contents of the hydroxyl groups is 0.01 to 1 mole per 100 g of the liquid hydroxylated ethylenic random copolymer. Also provided are a lubricant oil additive and a paint additive each being composed of the above liquid modified ethylenic random copolymer.

97. 发明授权

US4952649A Process for producing olefin polymers or copolymers and catalyst components used therefor 失效
标题翻译：用于生产烯烃聚合物或共聚物和催化剂组分的方法
公开(公告)号：US4952649A
公开(公告)日：1990-08-28
申请号：US169171
申请日：1988-03-11
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/00 , B01J31/14 , B01J37/04 , C08F4/02 , C08F4/06 , C08F4/10 , C08F4/12 , C08F4/16 , C08F4/60 , C08F4/64 , C08F4/654 , C08F4/658 , C08F10/00 , C08F10/04
CPC分类号： C08F10/00 , Y10S526/904 , Y10S526/909
摘要： A solid titanium catalyst component (A) of a catalyst system useful in the polymerization of olefins or copolymerization of two or more olefins or one or more olefins and a diene is prepared by contacting a liquid hydrocarbon solution of (i) a magnesium compound, such as magnesium chloride, with (ii) a liquid titanium compound, such as TiCl.sub.4, or a solution of a titanium compound in a hydrocarbon solvent, to form a solid product. The solid product is formed in the presence of (D) an electron donor, e.g. methyl formate, acetic acid, acetic anhydride, acetone, methyl ether, butyl Cellosolve, dimethyl carbonate, methyl silicate. The solid product is also contacted with a polycarboxylic acid ester, e.g. diethyl methylsuccinate. The polymerization or copolymerization of the olefin is carried out in the presence of the solid titanium catalyst (A) and (B) an organometallic compound of a Group I to III metal and (C) an organic silicon compound having an Si--O--C bond. Granular or spherical polyethylene, polypropylene, poly(butene-1), poly(4-methylpentene-1), etc. are produced in high yield, with good flowability, high bulk density, and narrow particle size distribution. The polymers can be produced over a wide range of melt index values without reduction in stereospecificity. Catalyst activity is retained with passage of time.
摘要翻译：通过使（ⅰ）镁化合物的液体烃溶液（例如镁）与其它烯烃和二烯烃的液体烃溶液接触，制备可用于烯烃聚合或两种或多种烯烃或一种或多种烯烃和二烯的共聚合的催化剂体系的固体钛催化剂组分（A）与（ii）液体钛化合物如TiCl 4或钛化合物在烃溶剂中的溶液形成固体产物。在（D）电子给体的存在下形成固体产物，例如甲酸甲酯，乙酸，乙酸酐，丙酮，甲基醚，丁基溶纤剂，碳酸二甲酯，硅酸甲酯。固体产物也与多元羧酸酯例如，甲基琥珀酸二乙酯烯烃的聚合或共聚在固体钛催化剂（A）和（B）I至III族金属的有机金属化合物和（C）具有Si-O-C键的有机硅化合物的存在下进行。以高产率，良好的流动性，高堆积密度和窄的粒度分布产生颗粒或球形聚乙烯，聚丙烯，聚（丁烯-1），聚（4-甲基戊烯-1）等。聚合物可以在宽范围的熔体指数值下生产而不降低立体定向性。催化剂活性随着时间的推移而保持。

98. 发明授权

US4923833A Catalyst for olefin polymerization and processes for its production 失效
标题翻译：用于烯烃聚合的催化剂及其生产方法
公开(公告)号：US4923833A
公开(公告)日：1990-05-08
申请号：US245400
申请日：1988-08-23
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65925 , Y10S526/904 , Y10S526/943
摘要： The solid catalyst of this invention for olefin polymerization comprises a compound of a transition metal of Group IV of the periodic table and an aluminoxane as catalyst ingredients. The catalyst is characteristic in that it has a high specific surface area, and shows very high polymerization activity on the homopolymerization or copolymerization of olefins. Polymers obtained by using the catalyst of the invention have a high bulk density, a uniform particle size, a low fine powder content and a narrow molecular weight distribution, and in the case of copolymers, a narrow composition distribution as well.

99. 发明授权

US4894421A Low-crystalline propylene random copolymer composition, process for production thereof, and polypropylene composite laminated structure 失效
标题翻译：低结晶丙烯无规共聚物组合物，其制备方法和聚丙烯复合层压结构
公开(公告)号：US4894421A
公开(公告)日：1990-01-16
申请号：US292539
申请日：1988-12-30
申请人： Mamoru Kioka , Masahiro Sugi , Akinori Toyota , Norio Kashiwa
发明人： Mamoru Kioka , Masahiro Sugi , Akinori Toyota , Norio Kashiwa
IPC分类号： B32B27/32 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06 , B32B27/32 , C08F210/16 , Y10T428/31913
摘要： A novel low-crystalline propylene random copolymer composition comprising[I] 60 to 95% by weight of a propylene random copolymer and[II] 5 to 40% by weight of a low-crystalline propylene random copolymerwhich has excellent heat-sealability, heat-seal imparting property, transparency and antiblocking property and containing a reduced amount of a hydrocarbon-soluble component, a process for production thereof, and polypropylene composite laminated structure having improved heat-sealability and heat seal strength at low temperatures.

100. 发明授权

US4874734A Process for producing solid catalyst for polymerization of olefins 失效
标题翻译：生产烯烃聚合用固体催化剂的方法
公开(公告)号：US4874734A
公开(公告)日：1989-10-17
申请号：US174967
申请日：1988-03-29
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/901 , Y10S526/904 , Y10S526/943
摘要： A process for producing a solid catalyst for polymerization of olefins, which comprises bringing a solution of an aluminoxane into contact with a suspension of a particulate carrier having supported thereon a compound of a transition metal of Group IVB of the periodic table in a solvent in which the aluminoxane is insoluble or sparingly soluble. In another aspect, the invention provides a process for producing a solid catalyst for polymerization of olefins, which comprises bringing a suspension of a particulate carrier having supported thereon a compound of a transition metal of Group IVB of the periodic table in a solution of an aluminoxane into contact with a solvent in which the aluminoxane is insoluble or sparingly soluble.

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