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91. 发明授权

US07850842B2 Zr02-base catalyst carrier and method for the production thereof 有权
标题翻译： ZrO 2 - 基催化剂载体及其制备方法
公开(公告)号：US07850842B2
公开(公告)日：2010-12-14
申请号：US10513041
申请日：2003-05-02
申请人： Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
发明人： Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
IPC分类号： C10G35/06 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： C07C5/3332 , B01J21/066 , B01J23/002 , B01J23/63 , B01J35/002 , B01J35/10 , B01J35/109 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C2521/06 , Y02P20/52 , C07C11/06 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要： The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.
摘要翻译：本发明涉及制备催化剂载体的方法，其中如果需要，二氧化锆粉末与粘合剂混合，如果需要，成孔剂如果需要，可以使用酸，水，并且如果需要，可提供另外的添加剂以得到可捏合组合物和组合物均化，成型以产生成形体，干燥和煅烧，其中粘合剂是单体，低聚或聚合的有机硅化合物。合适的粘合剂是单体，低聚或聚合硅烷，烷氧基硅烷，芳氧基硅烷，丙烯酰氧硅烷，肟基硅烷，卤代硅烷，氨基硅烷，氨基硅烷，酰胺基硅烷，硅氮烷或硅氧烷。本发明还提供了以这种方式制备的催化剂载体，包含载体的催化剂及其作为脱氢催化剂的用途。

92. 发明授权

US07754647B2 Activated metathesis catalysts 失效
标题翻译：活化复分解催化剂
公开(公告)号：US07754647B2
公开(公告)日：2010-07-13
申请号：US12098165
申请日：2008-04-04
申请人： Markus Schubert , Michael Hesse , Juergen Stephan , Volker Boehm , Andreas Brodhagen , Frank Poplow , Martina Sinner-Lang , Uwe Diehlmann , Gerhard Cox , Jochen Pfeifer
发明人： Markus Schubert , Michael Hesse , Juergen Stephan , Volker Boehm , Andreas Brodhagen , Frank Poplow , Martina Sinner-Lang , Uwe Diehlmann , Gerhard Cox , Jochen Pfeifer
IPC分类号： B01J23/00 , B01J21/08 , B01J20/00 , B01J29/00
CPC分类号： C07C6/04 , B01J21/08 , B01J23/28 , B01J23/30 , B01J23/36 , B01J27/22 , B01J37/0203 , B01J37/082 , C07C2523/28 , C07C2523/30 , C07C2523/36 , Y02P20/52 , C07C11/02 , C07C11/107 , C07C11/06
摘要： The present invention provides a process for preparing a supported catalyst (catalyst C) having a support (support S) selected from among oxides, phosphates, silicates, carbides, borides and nitrides of main group elements and elements of transition groups VI and II and mixtures of the abovementioned compounds and an active component (activator A) comprising one or more compounds containing one or more elements of transition groups V, VI and VII customary for the catalysis of metathesis reactions.
摘要翻译：本发明提供一种制备负载型催化剂（催化剂C）的方法，所述负载型催化剂（催化剂C）具有选自主要元素的氧化物，磷酸盐，硅酸盐，碳化物，硼化物和氮化物中的载体（载体S）和转变基团VI和II的元素以及混合物的上述化合物和包含一种或多种含有一种或多种通常用于复分解反应催化的过渡基团V，VI和VII元素的化合物（活化剂A）。

93. 发明申请

US20090312588A1 PROCESS FOR HYDROGENATING UNSATURATED HYDROCARBONS IN THE PRESENCE OF CATALYSTS CONTAINING COPPER AND ZINC 失效
标题翻译：在含有铜和锌的催化剂存在下加氢不饱和烃的方法
公开(公告)号：US20090312588A1
公开(公告)日：2009-12-17
申请号：US12374191
申请日：2007-07-05
申请人： Stephan Hatscher , Michael Hesse
发明人： Stephan Hatscher , Michael Hesse
IPC分类号： C07C5/03
CPC分类号： B01J23/80 , B01J37/0009 , B01J37/03 , B01J37/06 , C07C5/09 , C07C2523/80 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： Unsaturated hydrocarbons are hydrogenated over catalysts which comprise copper and zinc and whose active composition, in unreduced form, consists essentially of from 10 to 95% by weight of copper oxide, calculated as copper(II) oxide (CuO), from 5 to 90% by weight of zinc oxide (ZnO), optionally from 0.1 to 50% by weight of zirconium dioxide (ZrO2) and optionally from 0.1% by weight to 50% by weight of Al2O3, the proportions by weight adding up to 100% by weight.
摘要翻译：不饱和烃在包含铜和锌的催化剂上氢化，并且其未还原形式的活性组合物基本上由10至95重量％的氧化铜计算，氧化铜（II）（CuO）为5-90重量％的氧化锌（ZnO），任选的0.1至50重量％的二氧化锆（ZrO 2）和任选的0.1重量％至50重量％的Al 2 O 3，其重量比加至100重量％。

94. 发明授权

US07524444B2 Shaped bodies containing metal-organic frameworks 有权
标题翻译：包含金属 - 有机骨架的成形体
公开(公告)号：US07524444B2
公开(公告)日：2009-04-28
申请号：US10983629
申请日：2004-11-09
申请人： Michael Hesse , Ulrich Mueller , Omar Yaghi
发明人： Michael Hesse , Ulrich Mueller , Omar Yaghi
IPC分类号： B29C43/02
CPC分类号： F17C11/005 , B01J20/0244 , B01J20/226 , B01J20/28011 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J20/3035 , B01J20/3042 , B01J31/1691 , B01J35/1028 , B01J37/0009 , B01J2231/005 , B01J2531/26 , Y02E60/324 , Y10T428/249953 , Y10T428/249967 , Y10T428/24997 , Y10T428/25 , Y10T428/298
摘要： The present invention relates to shaped bodies containing a metal-organic framework material (MOF) as well as a process for the preparation thereof and their use especially as catalyst or storage medium.
摘要翻译：本发明涉及含有金属 - 有机骨架材料（MOF）的成形体以及其制备方法及其特别用作催化剂或储存介质的用途。

95. 发明申请

US20080262281A1 Catalyst Used for the Oxidation of Hydrogen, and Method for the Dehydrogenation of Hydrocarbons 审中-公开
标题翻译：用于氧化氢的催化剂和烃脱氢方法
公开(公告)号：US20080262281A1
公开(公告)日：2008-10-23
申请号：US11547500
申请日：2005-03-22
申请人： Christian Walsdorff , Falk Simon , Gerald Vorberg , Gotz-Peter Schindler , Michael Hesse
发明人： Christian Walsdorff , Falk Simon , Gerald Vorberg , Gotz-Peter Schindler , Michael Hesse
IPC分类号： C07C5/327 , B01J23/42
CPC分类号： B01J23/626 , B01J21/04 , B01J35/1009 , B01J35/1014 , B01J37/0009 , C07C5/3337 , C07C2523/60 , C07C15/46
摘要： A catalyst for the oxidation of hydrogen in a process for the dehydrogenation of hydrocarbons, wherein the catalyst comprises, supported on α-aluminum oxide, from 0.01 to 0.1% by weight of platinum and from 0.01 to 0.1% by weight of tin, based on the total weight of the catalyst, a process for the oxidation of hydrogen and a process for the dehydrogenation of hydrocarbons with an integrated oxidation process using the catalyst described.
摘要翻译：一种在烃脱氢方法中氧化氢气的催化剂，其中催化剂包含负载在α-氧化铝上的0.01至0.1重量％的铂和0.01至0.1重量％的锡，基于催化剂的总重量，氢氧化的方法和使用所述催化剂的使用一体化氧化方法使烃脱氢的方法。

96. 发明申请

US20080227634A1 Porous Organo-Metallic Skeleton Material Containing an Additional Polymer 有权
标题翻译：含有附加聚合物的多孔有机金属骨架材料
公开(公告)号：US20080227634A1
公开(公告)日：2008-09-18
申请号：US12093656
申请日：2006-11-14
申请人： Ulrich Muller , Michael Hesse , Markus Schubert , Melanie Urtel , Jens Assmann , Philippe Desbois
发明人： Ulrich Muller , Michael Hesse , Markus Schubert , Melanie Urtel , Jens Assmann , Philippe Desbois
IPC分类号： B01J20/26
CPC分类号： B01J31/1691 , B01D53/02 , B01D2257/108 , B01J20/226 , B01J20/28097 , B01J20/3206 , B01J20/327 , B01J20/3272 , B01J20/3276 , B01J20/3278 , B01J31/06 , B01J31/2239 , B01J2531/16 , B01J2531/22 , B01J2531/23 , B01J2531/26 , B01J2531/31 , B01J2531/842 , B01J2531/847 , C01B3/0015 , C25B3/12 , F17C11/00 , Y02E60/328
摘要： The invention relates to a porous metal-organic framework material for taking up at least one substance, the framework material comprising at least one at least bidentate organic compound bound by coordination to at least one metal ion, and the framework material having at least in part pores which comprise a polymer which is suitable to adsorb the at least one substance. In addition, the invention relates to a method for producing the framework material, a method for taking up at least one substance by the framework material and also to the use of the framework material, in particular for the storage, separation, controlled release or chemical reaction of a substance taken up.
摘要翻译：本发明涉及用于吸收至少一种物质的多孔金属 - 有机骨架材料，所述骨架材料包含至少一种至少二齿的有机化合物，所述至少二齿有机化合物通过配位至少一种金属离子结合，所述骨架材料至少部分地具有包含适于吸附至少一种物质的聚合物的孔。此外，本发明涉及一种生产骨架材料的方法，一种通过骨架材料吸收至少一种物质的方法，还涉及骨架材料的使用，特别是用于储存，分离，控释或化学品物质的反应。

97. 发明申请

US20080221302A1 Catalyst and Process for the Polymerization of Cyclic Ethers 有权
标题翻译：催化剂和循环醚聚合方法
公开(公告)号：US20080221302A1
公开(公告)日：2008-09-11
申请号：US12088208
申请日：2006-11-30
申请人： Stephan Hatscher , Michael Hesse , Tobias Wabnitz , Stefan Kashammer , Rolf Pinkos
发明人： Stephan Hatscher , Michael Hesse , Tobias Wabnitz , Stefan Kashammer , Rolf Pinkos
IPC分类号： C08G65/20
CPC分类号： B01J21/16 , B01J23/40 , B01J23/745 , B01J23/75 , B01J37/0009 , B01J37/0036 , C08G65/10 , C08G65/20 , C08G65/2642
摘要： The present invention provides a catalyst comprising a mixture of at least one acid-activated sheet silicate with a transition metal oxide of groups 8 and/or 9 of the Periodic Table of the Elements and also a process for preparing polytetrahydrofuran, polytetrahy-drofuran copolymers, diesters or monoesters of these polymers, in which tetrahydrofuran is polymerized in the presence of at least one telogen and/or comonomer over such a catalyst.
摘要翻译：本发明提供一种催化剂，其包含至少一种酸活化的硅酸盐与元素周期表第8和/或9族的过渡金属氧化物的混合物，以及制备聚四氢呋喃，聚四氢呋喃共聚物的方法，这些聚合物的二酯或单酯，其中四氢呋喃在这种催化剂存在下在至少一种开环和/或共聚单体存在下聚合。

98. 发明授权

US07411081B2 Process for preparing and organometallic framework material 有权
标题翻译：制备方法和有机金属骨架材料
公开(公告)号：US07411081B2
公开(公告)日：2008-08-12
申请号：US10755231
申请日：2004-01-13
申请人： Ulrich Mueller , Gerald Lippert , Olga Schubert , Michael Hesse , Reinhard Hess , Michael Stoesser , Omar M. Yaghi
发明人： Ulrich Mueller , Gerald Lippert , Olga Schubert , Michael Hesse , Reinhard Hess , Michael Stoesser , Omar M. Yaghi
IPC分类号： C07F3/06 , C07F15/00 , C07F15/02 , B01J31/12
CPC分类号： C07F3/003 , B01J20/226
摘要： A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one further group which is not a carboxy group and which is capable of forming a hydrogen bridge linkage.
摘要翻译：一种制备有机金属骨架材料的方法，包括使至少一种金属盐与至少一种能够与所述金属盐的金属离子配位的至少二齿化合物在水性溶剂体系和至少一种碱的存在下反应，其中在至少一个二齿化合物至少包含羧基和至少一个不是羧基并且能够形成氢桥键的另外的基团。

99. 发明授权

US07371917B2 Preparation of olefins by metathesis over a carbide or oxycarbide of a transition metal 失效
标题翻译：通过在过渡金属的碳化物或碳氧化物上复分解制备烯烃
公开(公告)号：US07371917B2
公开(公告)日：2008-05-13
申请号：US10811940
申请日：2004-03-30
申请人： Markus Schubert , Till Gerlach , Michael Hesse , Juergen Stephan , Volker Boehm , Andreas Brodhagen , Frank Poplow
发明人： Markus Schubert , Till Gerlach , Michael Hesse , Juergen Stephan , Volker Boehm , Andreas Brodhagen , Frank Poplow
IPC分类号： C07C6/02
CPC分类号： C07C6/04 , B01J21/08 , B01J23/30 , B01J27/22 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/08 , C07C2523/14 , C07C2527/22
摘要： Process for preparing a compound having a nonaromatic C—C double or triple bond (compound A) from another compound or a mixture of other compounds having a nonaromatic C—C double or triple bond (compound B), which comprises bringing the compound (B) into contact with a heterogeneous catalyst comprising carbides or oxycarbides of a transition element at from 50 to 500° C.
摘要翻译：制备具有非芳族CC双键或三键（化合物B）的其它化合物或其它化合物的混合物的具有非芳族CC双键或三键的化合物（化合物A）的方法（化合物B），其包括使化合物（B）与包含50-500℃的过渡元素的碳化物或碳氧化物的多相催化剂

100. 发明申请

US20080096761A1 Preparation of supports for catalysts 审中-公开
标题翻译：催化剂载体的制备
公开(公告)号：US20080096761A1
公开(公告)日：2008-04-24
申请号：US10588390
申请日：2005-02-02
申请人： Shahram Mihan , Michael Hesse
发明人： Shahram Mihan , Michael Hesse
IPC分类号： B01J32/00
CPC分类号： C08F210/16 , B01J37/036 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F4/025 , C08F4/24 , C08F4/65916
摘要： The invention relates to a process for preparing a support for catalysts, which comprises: a) preparing a hydrogel; b) milling the hydrogel to give a finely particulate hydrogel; c) producing a slurry based on the finely particulate hydrogel; d) drying the slurry comprising the finely particulate hydrogel to give the support for catalysts, wherein a finely particulate hydrogel in which at least 5% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦3 μm; and/or at least 40% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦12 μm, and/or at least 75% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦35 μm, is produced in step b).
摘要翻译：本发明涉及一种制备催化剂载体的方法，其包括：a）制备水凝胶; b）研磨水凝胶以得到细颗粒水凝胶; c）基于细颗粒水凝胶生产浆料; d）干燥包含细颗粒状水凝胶的浆料，得到催化剂载体，其中细颗粒状水凝胶，其中基于颗粒总体积的至少5体积％的颗粒的粒径范围从0um到<= 3mum; 和/或至少40体积％的颗粒，基于颗粒的总体积，其粒度范围为>0μm至≤12μm，和/或至少75体积％基于粒子的总体积的颗粒的粒度在>0μm至<=35μm的范围内，在步骤b）中产生。

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