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    • 91. 发明授权
    • Carboxamides and their use as herbicides
    • 羧甲酰胺及其作为除草剂的用途
    • US5201934A
    • 1993-04-13
    • US592287
    • 1990-10-03
    • Peter MuensterGerd SteinerWolfgang FreundBruno WuerzerKarl-Otto Westphalen
    • Peter MuensterGerd SteinerWolfgang FreundBruno WuerzerKarl-Otto Westphalen
    • A01N43/08A01N43/10A01N43/28A01N43/78C07D307/68C07D333/38C07D405/12C07D405/14C07D407/12C07D409/12C07D409/14C07D413/04C07D417/12C07D417/14C07D495/04
    • C07D407/12A01N43/08A01N43/10A01N43/28C07D307/68C07D333/38C07D409/12C07D417/12
    • Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, or one of the groups stated for R.sup.1 ;R.sup.3 and R.sup.4 are nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y.dbd.O,S);R.sup.6 is hydrogen, cycloalkyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkenyl or phenyl,phthalimido, tetrahydrophthalimido, succinimido, maleimido, benzotriazolyl ora group --N.dbd.CR.sup.7 R.sup.8, whereR.sup.7 and R.sup.8 are hydrogen or alkyl, and R.sup.8 may also be cycloalkyl, phenyl, or R.sup.7 and R.sup.8 together form a 4- to 7-membered alkylene chain;and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.2 is hydrogen, R.sup.3 is not hydrogen and R.sup.4 is not hydrogen or methyl, and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.4 is hydrogen, R.sup.3 is not hydrogen or R.sup.2 is not one of the following groups: hydrogen, C.sub.1 -C.sub.4 -alkyl, phenyl, 2-(3,4-dimethoxyphenyl)ethyl or 2,5-dichlorothien-3-yl;processes for the manufacture of compounds I and herbicidal agents containing them.
    • 式Ia至Ic的酰胺酰胺其中X是氧或硫; R1是氢或取代或未取代的环烷基或烷基; R2是羟基,烷氧基,氰基烷基,取代或未取代的链烯基,炔基,苯基或萘基,或为R1所述的一个基团; R3和R4是硝基,氰基,卤素,取代或未取代的氨基,烷氧基,烷硫基,取代或未取代的烯基,炔基,苯基,苯氧基或苯硫基,或为R1表示的基团之一; R5是甲酰基,4,5-二氢恶唑-2-基或COYR 6(Y = O,S); R 6是氢,环烷基,取代或未取代的烷基,烯基,炔基,环烯基或苯基,邻苯二甲酰亚氨基,四氢邻苯二甲酰亚胺基,琥珀酰亚胺基,马来酰亚胺基,苯并三唑基或基团-N = CR 7 R 8,其中R 7和R 8是氢或烷基, 环烷基,苯基或R7和R8一起形成4-至7-元亚烷基链; 如果R5是羧基,甲氧基羰基或乙氧基羰基,R2是氢,R3不是氢,R4不是氢或甲基,如果R5是羧基,甲氧基羰基或乙氧基羰基,R4是氢,R3不是氢或R2不是 以下基团:氢,C 1 -C 4 - 烷基,苯基,2-(3,4-二甲氧基苯基)乙基或2,5-二氯噻吩-3-基; 制备化合物I和含有它们的除草剂的方法。
    • 92. 发明授权
    • Carboxamides, their preparation and their use as herbicides
    • 羧甲酰胺,它们的制备及其作为除草剂的用途
    • US5258357A
    • 1993-11-02
    • US947538
    • 1992-09-21
    • Peter MuensterGerd SteinerWolfgang FreundBruno WuerzerKarl-Otto Westphalen
    • Peter MuensterGerd SteinerWolfgang FreundBruno WuerzerKarl-Otto Westphalen
    • A01N43/08A01N43/10A01N43/28C07D307/68C07D333/38C07D407/12C07D409/12C07D417/12A01N57/08C07D307/38
    • C07D407/12A01N43/08A01N43/10A01N43/28C07D307/68C07D333/38C07D409/12C07D417/12
    • Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, a substituted or unsubstituted 5- to 6-membered heterocyclic structure or one of the groups stated for R.sup.1, orR.sup.1 and R.sup.2 together are a 4- to 7-membered chain which contains, in addition to methylene groups, one of the following groups as ring member: oxygen, sulfur, N-methyl or carbonyl;R.sup.3 and R.sup.4 are each nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, a substituted or unsubstituted 5- to 6 -membered heterocyclic structure, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y=O,S);R.sup.6 is hydrogen, cycloalkyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkenyl or phenyl,a 5- to 6-membered heterocyclic structure, phthalimido, tetrahydrophthalimido, succinimido, maleimido, benzotriazolyl ora group --N.dbd.CR.sup.7 R.sup.8, whereR.sup.7 and R.sup.8 are hydrogen or alkyl, and R.sup.8 may also be cycloalkyl, phenyl, furyl or R.sup.7 and R.sup.8 together form a 4- to 7 -membered alkylene chain; and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.2 is hydrogen, R.sup.3 is not hydrogen and R.sup.4 is not hydrogen or methyl, and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.4 is hydrogen, R.sup.3 is not hydrogen or R.sup.2 is not one of the following groups: hydrogen; C.sub.1 -C.sub.4 -alkyl, phenyl; 2-(3,4-dimethoxyphenyl)ethyl or 2,5 -dichlorothien-3-yl;processes for the manufacture of compounds I and herbicidal agents containing them.
    • 式Ia至Ic的酰胺酰胺其中X是氧或硫; R1是氢或取代或未取代的环烷基或烷基; R 2是羟基,烷氧基,氰基烷基,取代或未取代的烯基,炔基,苯基或萘基,取代或未取代的5至6元杂环结构或对于R1表示的基团之一,或R 1和R 2一起为4- 除了亚甲基之外,还含有以下基团之一的环元素:氧,硫,N-甲基或羰基的7-元链; R 3和R 4各自为硝基,氰基,卤素,取代或未取代的氨基,烷氧基,烷硫基,取代或未取代的5-至6-元杂环结构,取代或未取代的烯基,炔基,苯基,苯氧基或苯硫基, R1表示的组; R5是甲酰基,4,5-二氢恶唑-2-基或COYR 6(Y = O,S); R 6是氢,环烷基,取代或未取代的烷基,烯基,炔基,环烯基或苯基,5-至6-元杂环结构,邻苯二甲酰亚氨基,四氢邻苯二甲酰亚胺基,琥珀酰亚胺基,马来酰亚胺基,苯并三唑基或基团-N = CR 7 R 8,其中R 7和R 8 R 8也可以是环烷基,苯基,呋喃基,或者R 7和R 8一起形成4-7个亚烷基链; 如果R5是羧基,甲氧基羰基或乙氧基羰基,R2是氢,R3不是氢,R4不是氢或甲基,如果R5是羧基,甲氧基羰基或乙氧基羰基,R4是氢,R3不是氢或R2不是 以下组:氢; C 1 -C 4 - 烷基,苯基; 2-(3,4-二甲氧基苯基)乙基或2,5-二氯噻吩-3-基; 制备化合物I和含有它们的除草剂的方法。
    • 96. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20050239653A1
    • 2005-10-27
    • US11079431
    • 2005-03-14
    • Bernd SievernichMax LandesElmar KiblerWolfgang DeynHelmut WalterMartina OttenKarl-Otto WestphalenHerve Vantieghem
    • Bernd SievernichMax LandesElmar KiblerWolfgang DeynHelmut WalterMartina OttenKarl-Otto WestphalenHerve Vantieghem
    • A01N43/40A01N43/72A01N43/78A01N43/80A01N57/00A01N61/00
    • A01N43/78A01N43/80A01N61/00A01N57/20A01N47/36A01N47/30A01N47/12A01N47/06A01N43/90A01N43/88A01N43/82A01N43/76A01N43/707A01N43/70A01N43/653A01N43/58A01N43/54A01N43/50A01N43/42A01N43/40A01N43/18A01N39/04A01N41/10A01N37/48A01N37/46A01N37/40A01N37/26A01N37/22A01N37/18A01N37/12A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are hydrogen, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a heterocyclic radical selected from the group: thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl, it being possible for these to be unsubstituted or mono- or polysubstituted by halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or alkylthio; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least one herbicidal compound from the group of the acetyl-CoA carboxylase inhibitors (ACC), acetolactate synthase inhibitors (ALS), amides, auxin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, enolpyruvylshikimate-3-phosphate synthase inhibitors (ESPS), glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protophorphyrinogen [sic ] IX oxidase inhibitors, photosynthesis inhibitors, synergists, growth substances, cell wall biosynthesis inhibitors and a variety of other herbicides. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 氢,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是选自以下的杂环基:噻唑-2-基,噻唑-4-基,噻唑-5-基,异恶唑-3-基,异恶唑-4-基,异恶唑-4-基, 5,5-二氢异恶唑-3-基,4,5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基,这些可能是未被取代的或被卤素单取代或多取代, 烷基,烷氧基,卤代烷基,卤代烷氧基或烷硫基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 乙酰辅酶A羧化酶抑制剂(ACC),乙酰乳酸合酶抑制剂(ALS),酰胺,生长素除草剂,生长素转运抑制剂,类胡萝卜素生物合成抑制剂,烯醇丙酮酸莽草酸-3(3)的协同有效量的至少一种除草化合物 磷酸合成酶抑制剂(ESPS),谷氨酰胺合成酶抑制剂,脂质生物合成抑制剂,有丝分裂抑制剂,原卟啉原IX氧化酶抑制剂,光合作用抑制剂,增效剂,生长物质,细胞壁生物合成抑制剂和各种其它除草剂。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 99. 发明授权
    • Use of derivatives of 2-oxopyrrole as crop protection agents and novel 2-oxopyrroles
    • 2-氧代吡咯衍生物作为作物保护剂和新的2-氧代吡咯的使用
    • US06548451B1
    • 2003-04-15
    • US09647010
    • 2001-01-24
    • Oliver WagnerMartina OttenKarl-Otto WestphalenHelmut WalterVolker Harries
    • Oliver WagnerMartina OttenKarl-Otto WestphalenHelmut WalterVolker Harries
    • C07D20744
    • C07D207/44A01N43/36C07D207/38C07D401/06C07D403/06C07D403/10C07D405/06C07D409/06C07D413/06C07D417/06
    • The invention relates to the use of 2-oxopyrroles of general formula (I) and their agriculturally usable salts as crop protection agents and to novel 2-oxopyrroles of formula (I). The substituents have the following meanings: R1 represents aryl or heteroaryl and these radicals may carry one to five groups independently of each other or alternatively, the aryl or heteroaryl radical forms a bicyclical system with a fused-on phenyl ring, a fused-on C3-C6 carbocyclic compound or a 5- or 6-membered heterocyclic compound and R2 represents C2-C6-alkyl or aryl or heteroaryl, COOR3 or CONR3R4, R3 and R4 representing, independently of each other, hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C3-C7-cycloalkyl or C2-C6-alkyl-aryl which can optionally be partially or fully halogenated or can carry one to three substituents chosen from the following: C1-C4-alkoxy, C1-C4-halogenalkoxy, C1-C4-alkylthio, C3-C7-cycloalkyl, C5-C7-cycloalkenyl.
    • 本发明涉及通式(I)的2-氧代吡咯并且它们的农业上可用的盐作为农作物保护剂和式(I)的新型2-氧代吡喃的用途。 取代基具有以下含义:R 1表示芳基或杂芳基,并且这些基团可以彼此独立地携带一至五个基团,或者可选地,芳基或杂芳基形成具有稠合的苯环的稠合的C 3环上的双环体系, -C 6碳环化合物或5-或6-元杂环化合物,R 2表示C 2 -C 6 - 烷基或芳基或杂芳基,COOR 3或CONR 3 R 4,R 3和R 4彼此独立地表示氢,C 1 -C 6 - 烷基,C 2 C 1-6 - 烯基,C 3 -C 7 - 环烷基或C 2 -C 6 - 烷基 - 芳基,其可任选地被部分或完全卤化或可以携带一至三个选自以下的取代基:C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基, C 1 -C 4 - 烷硫基,C 3 -C 7 - 环烷基,C 5 -C 7 - 环烯基。