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    • 91. 发明授权
    • Blends of higher alpha-olefin polymers and 1,2-epoxide polymers
    • 高级α-烯烃聚合物和1,2-环氧化物聚合物的共混物
    • US4478980A
    • 1984-10-23
    • US416794
    • 1982-09-13
    • Joginder LalPaul H. Sandstrom
    • Joginder LalPaul H. Sandstrom
    • C08G65/14C08L23/20C08L71/02C08L71/00
    • C08L23/20C08G65/14C08L71/02
    • There is disclosed a rubbery composition comprising a blend of between 95/5 and 5/95 weight percent of (1) a rubbery interpolymer consisting of (a) at least 80 weight percent of at least one .alpha.-olefin containing from 5 to 10 carbon atoms and (b) up to 20 weight percent of a nonconjugated polyene containing from 5 to 30 carbon atoms with (2) a saturated polymer of an .alpha.-olefin oxide prepared from at least one monomer having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of hydrogen or a lower alkyl radical containing from 1 to 8 carbon atoms and R.sub.3 and R.sub.4 are selected from the group consisting of hydrogen, a lower alkyl radical containing from 1 to 8 carbon atoms and an alkoxyalkyl radical containing up to 12 carbon atoms, an aryl radical, a haloalkyl radical containing from 1 to 12 carbon atoms and in which R.sub.3 and R.sub.4 taken together may be trimethylene, tetramethylene, or hexamethylene, thereby forming a cyclic epoxide, or (3) an unsaturated copolymer of an .alpha.-olefin oxide prepared from 80 to 99.5 weight percent of at least one monomer having the structure I; with from 0.5 to 20 weight percent of a comonomer selected from the group consisting of butadiene monoxide, isoprene monoxide, 1,2-epoxy-3-allyloxypropane (allyl glycidyl ether), 4,5-epoxy-1-hexene, 4,5-epoxy-2-hexene, 1,5-cyclooctadiene monoepoxide, 1-vinyl-3,4-epoxycyclohexane and limonene monoxide.
    • 公开了一种橡胶组合物,其包含95/5和5/95重量%的共混物(1)由(a)至少80重量%的至少一种含有5-10个碳原子的α-烯烃组成的橡胶互聚物 原子和(b)至多20重量%的含有5至30个碳原子的非共轭多烯与(2)由至少一种具有以下结构的单体制备的α-烯烃氧化物的饱和聚合物:(I) 其中R 1和R 2选自氢或含有1至8个碳原子的低级烷基,R 3和R 4选自氢,含有1至8个碳原子的低级烷基和 含有至多12个碳原子的烷氧基烷基,芳基,含有1至12个碳原子的卤代烷基,其中R 3和R 4可以是三亚甲基,四亚甲基或六亚甲基,从而形成环状环氧化物,或(3) 不饱和的 由80至99.5重量%的至少一种具有结构I的单体制备的α-烯烃氧化物的共聚物; 与0.5〜20重量%的选自丁二烯一氧化物,异戊二烯一氧化物,1,2-环氧-3-烯丙氧基丙烷(烯丙基缩水甘油醚),4,5-环氧-1-己烯,4,5 环氧-2-己烯,1,5-环辛二烯单环氧化物,1-乙烯基-3,4-环氧环己烷和柠檬烯一氧化物。
    • 95. 发明授权
    • Green strength of elastomers
    • 弹性体的绿色强度
    • US4094831A
    • 1978-06-13
    • US734773
    • 1976-10-22
    • Paul H. Sandstrom
    • Paul H. Sandstrom
    • C08C19/40C08F236/04C08F8/00C08F224/00C08L7/00C08L63/00
    • C08F236/04C08C19/40
    • The green strength of synthetic elastomers is improved by forming interpolymers from at least one type of various synthetic elastomer forming monomers with an epoxy containing monomer having the formula: ##STR1## where R.sub.1 contains from 0 to 8 carbon atoms and R.sub.2 contains from 1 to 4 carbon atoms. Typical elastomer forming monomers include at least one conjugated diene having from 4 to 10 carbon atoms, olefins having from 2 to 14 carbon atoms along with a diene having from 4 to 6 carbon atoms, and combinations thereof. The interpolymer preferably is blended with synthetic elastomers or natural rubber (cis-1,4-polyisoprene) and utilized for various industrial uses such as tire carcasses including radial truck tire carcasses. The green strength is further improved if a small amount of an epoxy cross-linking agent is utilized. Examples of suitable cross-linking agents include monoamines and polyamines, monoanhydrides and polyanhydrides, and monocarboxylic acids, as well as polycarboxylic acids. Desirably, the interpolymer of the synthetic elastomer forming monomer and the epoxy containing monomer is blended with various types of synthetic elastomers or natural rubber in the presence of an epoxy cross-linking agent in a suitable mixing vessel such as a Banbury.
    • 合成弹性体的生坯强度通过从至少一种类型的各种合成弹性体形成单体与具有下式的含环氧基的单体形成共聚物得到改进:其中R 1含有0至8个碳原子,R 2含有 1至4个碳原子。 典型的弹性体形成单体包括至少一种具有4至10个碳原子的共轭二烯,具有2至14个碳原子的烯烃以及具有4至6个碳原子的二烯及其组合。 共聚物优选与合成弹性体或天然橡胶(顺式-1,4-聚异戊二烯)共混,并用于各种工业用途,例如轮胎胎体,包括径向卡车轮胎胎体。 如果使用少量的环氧交联剂,则生坯强度进一步提高。 合适的交联剂的实例包括单胺和多胺,一元酸酐和聚酐,以及一元羧酸以及多元羧酸。 理想的是,合成弹性体形成单体和含环氧基的单体的互聚物在各种类型的合成弹性体或天然橡胶中在环氧交联剂的存在下在合适的混合容器如Banbury中混合。