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91. 发明申请

US20080139830A1 Preparation of substituted aminoanthraquinones 审中-公开
标题翻译：取代的氨基蒽醌的制备
公开(公告)号：US20080139830A1
公开(公告)日：2008-06-12
申请号：US11998701
申请日：2007-11-30
申请人： Horst Berneth
发明人： Horst Berneth
IPC分类号： C09B1/16
CPC分类号： C09B1/325 , C08K5/0041 , C08K5/18 , C09B1/285 , C09B1/5145
摘要： Process for preparing substituted aminoanthraquinones by reacting 1,4-di-hydroxyanthraquinone with amines in the presence of dihydro-1,4-dihydroxyanthraquinone and a boric ester.
摘要翻译：在二氢-1,4-二羟基蒽醌和硼酸酯存在下，使1,4-二羟基蒽醌与胺反应制备取代的氨基蒽醌的方法。

92. 发明授权

US07106489B2 Electrochromic device 失效
标题翻译：电致变色装置
公开(公告)号：US07106489B2
公开(公告)日：2006-09-12
申请号：US10275857
申请日：2001-05-07
申请人： Horst Berneth , Ralf Neigl , Igor Shelepin , Vladimir Gavrilov
发明人： Horst Berneth , Ralf Neigl , Igor Shelepin , Vladimir Gavrilov
IPC分类号： G02F1/153 , G03G5/00
CPC分类号： G02F1/1521 , C09K9/02
摘要： An electrochromic device comprising a pair of glass, plastic plates or plastic films At least one plate or film, is provided with an electrically conductive coating. At least one plate or film and its conductive coating are transparent and the other may be mirrored. The plates or films are joined together and form a volume filled with an electrochromic medium which comprises at least one reducible electrochromic substance OX2 and at least one oxidizable electrochromic substance RED1. The OX2 corresponds to the formula in which R201 and R202, each are alkyl, cycloalkyl, alkenyl, aralkyl, aryl, −[C(PQ)]− or a bivalent bridge B, Z201 is a bivalent radical of the formulae CR210R211, O, C═O or o-phenylene, R210 and R211, each are hydrogen, methyl or ethyl, or CR210R211 is C3- to C7-cycloalkane-1,1-diyl. The rings C, D, E and F, each may be substituted by up to 4 alkyl and/or alkoxy radicals, or respectively, may be linked via a —(CH2)4— or —CH═CH—CH═CH— bridge. P and Q, each are —CN or —COO-alkyl. X— is an anion.
摘要翻译：包括一对玻璃，塑料板或塑料膜的电致变色装置至少一个板或膜具有导电涂层。至少一个板或膜及其导电涂层是透明的，另一个可以被镜像。板或膜连接在一起并形成填充有电致变色介质的体积，该电致变色介质包含至少一种可还原的电致变色物质OX 2和至少一种可氧化的电致变色物质RED 1。 OX 2对应于其中R 201和R 202各自为烷基，环烷基，烯基，芳烷基，芳基， - C（PQ）] - 或二价桥B，Z 201是式CR 210的二价基团， O，CO或邻亚苯基，R 210和R 211各自为氢，甲基或乙基，或CR 21， R 211是C 3〜C 7 - 环烷烃-1,1-二基。环C，D，E和F各自可以被至多4个烷基和/或烷氧基取代，或分别可以通过 - （CH 2 2）4 - / CH 3 - 或-CH-CH-CH-CH-桥。 P和Q各自为-CN或-COO-烷基。 X-是阴离子。

93. 发明授权

US06545793B2 UV-protected electrochromic solution 失效
标题翻译：紫外线保护电致变色溶液
公开(公告)号：US06545793B2
公开(公告)日：2003-04-08
申请号：US10037398
申请日：2002-01-03
申请人： Horst Berneth , Helmut-Werner Heuer , Ralf Neigl
发明人： Horst Berneth , Helmut-Werner Heuer , Ralf Neigl
IPC分类号： G02F115
CPC分类号： G02F1/1521 , C07C49/83 , C07C49/84 , C09K9/02 , C09K15/06 , C09K15/20 , Y10T428/23 , Y10T428/239 , Y10T428/249995 , Y10T428/249997 , Y10T428/31504
摘要： This invention relates to electrochromic devices containing UV-protected electrochromic solutions comprising at least one oxidizable substance RED1 and at least one reducible substance OX2 linked by a bridging group and a UV absorber component.
摘要翻译：本发明涉及包含紫外线保护的电致变色溶液的电致变色装置，该电致变色溶液包含至少一种可氧化物质RED1和至少一种由桥连基团连接的可还原物质OX2和紫外线吸收剂组分。

94. 发明授权

US06183878B2 Electrochromic system 失效
标题翻译：电致变色系
公开(公告)号：US06183878B2
公开(公告)日：2001-02-06
申请号：US09147615
申请日：1999-05-25
申请人： Horst Berneth , Uwe Claussen , Dietrich Haarer , Jochen Schaller , Jürgen Simmerer
发明人： Horst Berneth , Uwe Claussen , Dietrich Haarer , Jochen Schaller , Jürgen Simmerer
IPC分类号： C09K902
CPC分类号： G02F1/1521 , C09K9/02 , G02F2001/1502 , G02F2001/1512 , Y10T428/12271
摘要： The invention concerns an electrochrome system comprising a mixture of reducible and oxidizable substances RED1 and OX2, at lest one RED1′-OX2′ pair being covalently interlinked via a bridge and, for at least one RED1″ or OX2″ substance, the reciprocal conversion of the oxidized form and the reduced form being brought about by the fracture or formation of a &sgr;-bond. The electrochrome system is characterized by simplified electron transfer and reduced secondary reactions.
摘要翻译：本发明涉及一种包含可还原和可氧化物质RED1和OX2的混合物的电化学系统，至少一个RED1'-OX2对通过桥联共价连接，并且对于至少一种RED1“或OX2”物质，通过σ-键的断裂或形成引起的氧化形式和还原形式的转化。电子照相系统的特征在于简化的电子转移和二次反应的减少。

95. 发明授权

US5436323A Cationic 1,3,4-thiadiazole dyestuffs 失效
标题翻译：阳离子1,3,4-噻二唑染料
公开(公告)号：US5436323A
公开(公告)日：1995-07-25
申请号：US86599
申请日：1993-07-01
申请人： Horst Berneth , Werner Hartwich , Karl-Heinrich Lange
发明人： Horst Berneth , Werner Hartwich , Karl-Heinrich Lange
IPC分类号： C09B29/09 , C09B29/00 , C09B43/40 , C09B44/06 , C09B44/20 , C09D11/00 , C09D11/02 , C09D11/16 , C09B29/048 , C09B69/06 , D06P1/41
CPC分类号： C09B29/0092 , C09B43/40 , C09B44/06
摘要： Cationic 1,3,4-thiadiazolyldiphenylamine dyestuffs and corresponding anhydro bases, the dyestuffs having the formula (I) ##STR1## their preparation and their use, and materials dyed with such dyestuffs.
摘要翻译：阳离子1,3,4-噻二唑基二苯胺染料和相应的脱水碱，具有式（I）的染料及其制备及其用途，以及用这种染料染色的材料。

96. 发明授权

US5425978A Substrates secure against unauthorized copying and processes for their preparation 失效
标题翻译：底板可防止未经授权的复制和处理
公开(公告)号：US5425978A
公开(公告)日：1995-06-20
申请号：US139494
申请日：1993-10-19
申请人： Horst Berneth , Uwe Claussen
发明人： Horst Berneth , Uwe Claussen
IPC分类号： B41M3/14 , B42D15/10 , B44F1/12 , G03C5/08 , G09F3/02 , B32B3/00
CPC分类号： B41M3/144 , G03C5/08 , Y10S283/902 , Y10S428/915 , Y10S428/916 , Y10T428/24802 , Y10T428/24835 , Y10T428/24901 , Y10T428/24934
摘要： Novel substrates bearing visible information applied thereto give indiscernible, for example illegible, photocopies when the information applied using colorant combinations of at least one emitting and at least one reflecting colorant whose shades upon viewing without fluorescence being perceived are similar or identical.
摘要翻译：当使用至少一种发光和至少一种反射着色剂的着色剂组合施加的信息时，施加到其上的具有可见信息的新型基底提供了不可忽视的，例如不可读的复印件，其中观察到的阴影在没有感觉到荧光的情况下是相似或相同的。

97. 发明授权

US5208325A Cationic 1,3,4-thiadiazole dyestuffs 失效
公开(公告)号：US5208325A
公开(公告)日：1993-05-04
申请号：US805147
申请日：1991-12-11
申请人： Horst Berneth , Klaus Leverenz
发明人： Horst Berneth , Klaus Leverenz
IPC分类号： C09B44/20 , C07D285/12 , C07D285/135 , C09B44/10 , C09D11/00 , C09D11/02 , D06P1/08 , D06P3/76 , D21H21/28
CPC分类号： C07D285/135 , C09B44/107
摘要： Cationic 1,3,4-thiadiazole dyestuff of the formula ##STR1##in whichR.sup.1 and R.sup.2, independently of one another, denote hydrogen, alkyl, alkenyl, cycloalkyl, aralkyl, aryl, a heterocycle, said heterocycle having a direct bond to the nitrogen atom, or being bound through a methylene or ethylene group, or R.sup.1 and R.sup.2, together with the nitrogen atom to which they are attached form a heterocycle,R.sup.3 denotes alkyl, alkenyl or aralkyl,R.sup.4 denotes hydrogen or alkyl,R.sup.5 denotes acyl,R.sup.6 and R.sup.7, independently of one another, denote hydrogen, alkyl, alkoxy, aryloxy or halogen andR.sup.8 and R.sup.9, independently of one another, denote hydrogen, alkyl, alkenyl, cycloalkyl, aralkyl, aryl, a heterocycle, said heterocycle having a direct bond to the nitrogen atom, or being bound through a methylene or ethylene group, or R.sup.8 and R.sup.9, together with the nitrogen atom to which they are attached form a heterocycle, orR.sup.6 and R.sup.8 together with the nitrogen to which R.sup.8 is attached completes a heterocyclic, said R.sup.6 and R.sup.8 having a total of from 2 to 4 atoms, one of which can be oxygen or nitrogen, said heterocyclic being either unsubstituted or substituted with from 1 to 3 alkyl groups orR.sup.7 and R.sup.9, together with the nitrogen to which R.sup.9 is bound completes a heterocyclic, said R.sup.7 and R.sup.9 having a total of from 2 to 4 atoms, one of which may be oxygen or nitrogen, said heterocyclic being either unsubstituted or substituted with from 1 to 3 alkyl groups, andX.sup.e denotes an anion andin which all alkyl, alkenyl, cycloalkyl, aralkyl, aryl, alkoxy and heterocyclic radicals present may be substituted by nonionic substitutents, carboxyl groups, ammonium groups and/or pyridinium groups wherein the nonionic substituents are substituents selected from the group consisting of cyano, hydroxyl, fluorine, chlorine, bromine, nitro, alkyl, monoalkylamino, dialkylamino, alkoxy, phenyl, acyloxy, acylamino, alkoxycarbonyl and alkoxycarbonyloxy.

98. 发明授权

US4931567A Bis(indolyl)ethylene compounds 失效
标题翻译：双（吲哚基）乙烯化合物
公开(公告)号：US4931567A
公开(公告)日：1990-06-05
申请号：US409186
申请日：1989-09-19
申请人： Hubertus Psaar , Horst Berneth
发明人： Hubertus Psaar , Horst Berneth
IPC分类号： C07D209/14 , C07D209/08 , C07D209/24
CPC分类号： C07D209/08 , C07D209/24
摘要： Bis(indolyl)ethylenes of the formula ##STR1## wherein R.sub.1 denotes hydrogen, alkyl, aralkyl or aryl,R.sub.2 denotes hydrogen, alkyl or aryl,R.sub.3 denotes hydrogen, alkyl, alkenyl, COOH or aryl andR.sub.4 denotes hydrogen, alkyl, alkoxy, cycloalkoxy or halogen, andthese substituents, in turn, can carry non-ionic radicals or a carboxyl group, are obtained by reaction of indoles of the formula ##STR2## with carboxylic acids of the formulaR.sub.3 --CH.sub.2 --COOH (III)their chlorides, esters, for example alkyl esters, or anhydrides in the presence of phosphorus oxychloride.

99. 发明授权

US4835270A Chromogenic 3,1-benzoxazines 失效
标题翻译：显色3,1-苯并恶嗪
公开(公告)号：US4835270A
公开(公告)日：1989-05-30
申请号：US810797
申请日：1988-12-18
申请人： Horst Berneth
发明人： Horst Berneth
IPC分类号： B41M5/136 , B41M5/323 , C07D265/16 , C07D413/04 , C07D413/10 , C07D413/12 , C09B11/02 , C09B11/04 , C09B19/00 , G02F1/17
CPC分类号： C09B11/04 , B41M5/136 , B41M5/323 , C07D265/16 , C07D413/04 , C09B11/02
摘要： Compounds of the formula ##STR1## wherein Z.sup.1 denotes hydrogen, alkyl, cycloalkyl or ##STR2## R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl, heteroalkyl or heteryl,X.sup.1, X.sup.2 and X.sup.3 denote hydrogen, halogen, alkyl, cycloalkyl, aryl, alkanoylamino, aroylamino or heteryl, and at least one of these radicals denotes NH.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,Y.sup.1, Y.sup.2 and Y.sup.3 denote hydrogen, alkyl, cycloalkyl, aralkyl, aryl or heteryl andY.sup.1 +Y.sup.2 denote the remaining members of a 5-membered or 6-membered ring which optionally contains further hetero-atoms,are outstandingly suitable as colour-forming agents for pressure-sensitive, heat-sensitive and electrosensitive recording materials with an acid developer. Deep copies which are fast to light are obtained.
摘要翻译：式（I）的化合物其中Z1表示氢，烷基，环烷基或R1表示氢，烷基，环烷基，芳烷基，芳基，杂烷基或杂芳基，X1，X2和X3表示氢，卤素，烷基，环烷基，芳基，烷酰基氨基，芳酰基氨基或杂芳基，并且这些基团中的至少一个表示NH1Y2，OY3或SY3，Y1，Y2和Y3表示氢，烷基，环烷基，芳烷基，芳基或杂芳基，Y1 + Y2表示任选地含有其它杂原子的5元或6元环非常适合用作用于具有酸显影剂的压敏，热敏和电敏记录材料的着色剂。获得快速光照的深色复印件。

100. 发明授权

US4831141A Chromogenic 3,1-benzoxazines 失效
标题翻译：显色3,1-苯并恶嗪
公开(公告)号：US4831141A
公开(公告)日：1989-05-16
申请号：US56569
申请日：1987-06-01
申请人： Horst Berneth , Gert Jabs
发明人： Horst Berneth , Gert Jabs
IPC分类号： B41M5/136 , B41M5/145 , B41M5/323 , C07D265/16 , C07D413/04 , C09B19/00 , C09B67/22
CPC分类号： B41M5/20 , B41M5/136 , B41M5/323 , C09B19/00
摘要： The invention relates to chromogenic 3,1-benzoxazines of the formula ##STR1## wherein X.sup.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, chlorine or OY.sup.1,X.sup.2 denotes NY.sup.2 Y.sup.3,X.sup.3 denotes OY.sup.4 or NY.sup.5 Y.sup.6,R.sup.1 -R.sup.3 independently of one another denote hydrogen, C.sub.1 -C.sub.4 -alkyl, chlorine, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -mono- or -dialkylamino, orR.sup.1 together with Y.sup.2,R.sup.2 or R.sup.3 together with Y.sup.4 or Y.sup.5, orR.sup.2 and R.sup.3 simultaneously with Y.sup.5 and Y.sup.6 denote a 2 to 4-membered bridge which can contain one oxygen atom or one nitrogen atom and can carry up to 4 methyl groups, and whereinR.sup.1 and R.sup.3 simultaneously represent hydrogen only if R.sup.2 with Y.sup.4 or Y.sup.5 forms one of the abovementioned bridges,R.sup.4 denotes hydrogen, methyl or chlorine,Y.sup.1 and Y.sup.4 independently of one another denote C.sub.1 -C.sub.4 -alkyl, cyclohexyl or benzyl and Y.sup.2, Y.sup.3, Y.sup.5 and Y.sup.6 independently of one another denote hydrogen, C.sub.1 -C.sub.4 -alkyl, cyclohexyl or benzyl,are used for pressure-copying, thermoreactive or electrochromic recording materials.
摘要翻译：本发明涉及式IMAMA的显色3,1-苯并恶嗪，其中X1表示氢，C1-C4-烷基，氯或OY1，X2表示NY2Y3，X3表示OY4或NY5Y6，R1-R3彼此独立地表示氢，C1-C4-烷基，氯，C1-C4-烷氧基或C1-C4-单 - 或二烷基氨基，或R1与Y2，R2或R3一起与Y4或Y5或R2和R3同时与Y5和Y6表示可以含有一个氧原子或一个氮原子并且可以携带多达4个甲基的2至4元桥，其中只有当具有Y 4或Y 5的R 2形成上述桥之一时，R 1和R 3同时表示氢，R 4表示氢，甲基或氯，Y1和Y4彼此独立地表示C1-C4-烷基，环己基或苄基，Y2，Y3，Y5和Y6彼此独立地表示氢，C1-C4-烷基，环己基或苄基用于压力复制，热反应或电致变色记录材料。

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