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    • 91. 发明授权
    • Method to reduce MOL damage on NiSi
    • 减少NiSi上MOL损伤的方法
    • US07994038B2
    • 2011-08-09
    • US12366378
    • 2009-02-05
    • Karthik RamaniPaul R. Besser
    • Karthik RamaniPaul R. Besser
    • H01L21/3205
    • H01L21/823807H01L21/28052H01L21/823814H01L21/823835H01L29/458H01L29/665H01L29/6653H01L29/7843
    • Transistor devices are formed with nickel silicide layers formulated to prevent degradation upon removal of overlying stress liners. Embodiments include transistors with nickel silicide layers having a platinum composition gradient increasing in platinum content toward the upper surfaces thereof, i.e., increasing in platinum in a direction away from the gate electrode and source/drain regions. Embodiments include forming a first layer of nickel having a first amount of platinum and forming, on the first layer of nickel, a second layer of nickel having a second amount of platinum, the second weight percent of platinum being greater than the first weight percent. The layers of nickel are then annealed to form a nickel silicide layer having the platinum composition gradient increasing in platinum toward the upper surface. The platinum concentration gradient protects the nickel silicide layer during subsequent processing, as during etching to remove overlying stress liners, thereby avoiding a decrease in device performance.
    • 晶体管器件形成有硅化镍层,配制成防止去除上覆应力衬垫时的退化。 实施方案包括具有镍化硅层的晶体管,其铂组分梯度朝向其上表面增加铂含量,即铂在远离栅电极和源/漏区的方向上增加。 实施例包括形成具有第一量的铂的第一镍层,并在第一层镍上形成具有第二量铂的第二层镍,第二重量百分比的铂大于第一重量百分数。 然后将镍层退火以形成铂化合物梯度朝向上表面逐渐增加的铂硅化镍层。 铂浓度梯度在后续处理期间保护硅化镍层,如在蚀刻期间去除上覆的应力衬垫,从而避免器件性能的降低。
    • 100. 发明授权
    • Method of forming junction leakage free metal silicide in a semiconductor wafer by alloying refractory metal
    • 通过合金化难熔金属在半导体晶片中形成结无​​漏电金属硅化物的方法
    • US06204177B1
    • 2001-03-20
    • US09185515
    • 1998-11-04
    • Paul R. BesserNick KeplerKarsten Wieczorek
    • Paul R. BesserNick KeplerKarsten Wieczorek
    • H01L2144
    • H01L29/665H01L21/28518H01L29/456H01L29/4933
    • A method of forming metal silicide in a semiconductor wafer with reduced junction leakage introduces an alloy at cobalt grain boundaries within a cobalt layer that overlays a silicon layer. The alloy element can be precipitated during deposition of the cobalt and the alloy element, or by an intermediate anneal after deposition. The cobalt layer and the silicon layer are then annealed to form metal silicide regions. By precipitating an alloy at the cobalt grain boundaries, cobalt diffusion at the grain boundaries is retarded during a first rapid thermal annealing step. Bulk diffusion is encouraged, and a more uniform silicide film with reduced interface roughness is produced. Since the interface roughness is reduced with the methods of the present invention, junction leakage is reduced. This allows shallower junctions to be fabricated, leading to devices with improved performance.
    • 在具有减少的结漏电的半导体晶片中形成金属硅化物的方法在覆盖硅层的钴层内的钴晶界处引入合金。 在钴和合金元素的沉积期间,或者通过沉积后的中间退火,合金元素可以沉淀。 然后将钴层和硅层退火以形成金属硅化物区域。 通过在钴晶界析出合金,在第一快速热退火步骤期间,在晶界处的钴扩散被延迟。 鼓励扩散,并产生具有降低的界面粗糙度的更均匀的硅化物膜。 由于通过本发明的方法减小了界面粗糙度,所以结漏电减少。 这允许制造较浅的结,导致具有改进性能的器件。