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    • 91. 发明申请
    • Grading PrxCa1-xMnO3 thin films by metalorganic chemical vapor deposition
    • 通过金属有机化学气相沉积法分级PrxCa1-xMnO3薄膜
    • US20060068099A1
    • 2006-03-30
    • US10957304
    • 2004-09-30
    • Tingkai LiLawrence CharneskiWei-Wei ZhuangDavid EvansSheng Hsu
    • Tingkai LiLawrence CharneskiWei-Wei ZhuangDavid EvansSheng Hsu
    • C23C16/00
    • C23C16/40H01L45/04H01L45/1233H01L45/147H01L45/1616
    • The present invention discloses a method to achieve grading PCMO thin film for use in RRAM memory devices since the contents of Ca, Mn and Pr in a PCMO film can have great influence on its switching property. By choosing precursors for Pr, Ca and Mn having different deposition rate behaviors with respect to deposition temperature or vaporizer temperature, PCMO thin film of grading Pr, Ca or Mn distribution can be achieved by varying that process condition during deposition. The present invention can also be broadly applied to the fabrication of any multicomponent grading thin film process by varying any of the deposition parameters after preparing multiple precursors to have different deposition rate behaviors with respect to that particular process parameter. The present invention starts with a proper selection of precursors in which the selected precursors have different deposition rates with respect to at least one deposition condition such as deposition temperature or vaporizer temperature. The precursors can then be arranged in different delivery systems, or can be pre-mixed in a proper ratio for use in a delivery system, or in any other combinations such as a mixture of two or three liquid precursors using a direct liquid injection and a separate gaseous precursor delivery system for gaseous process gas. Then by varying the appropriate deposition condition, a grading thin film can be achieved.
    • 本发明公开了一种用于RRAM存储器件中的PCMO薄膜分级的方法,因为PCMO薄膜中Ca,Mn和Pr的含量对其开关性能有很大的影响。 通过选择相对于沉积温度或蒸发器温度具有不同沉积速率行为的Pr,Ca和Mn的前体,可以通过在沉积期间改变该工艺条件来实现分级Pr,Ca或Mn分布的PCMO薄膜。 本发明还可以广泛地应用于任何多组分分级薄膜工艺的制造,其通过在制备多种前体之后改变任何沉积参数以相对于该特定工艺参数具有不同的沉积速率行为。 本发明开始于适当选择前体,其中所选择的前体相对于至少一个沉积条件例如沉积温度或蒸发器温度具有不同的沉积速率。 然后可将前体布置在不同的递送系统中,或者可以以适当的比例预先混合以用于递送系统,或者以任何其它组合例如使用直接液体注射的两种或三种液体前体的混合物 用于气态工艺气体的单独的气态前体输送系统。 然后通过改变适当的沉积条件,可以实现分级薄膜。
    • 96. 发明申请
    • Single inductor dual output buck converter with frequency and time varying offset control
    • 单电感双输出降压转换器,具有频率和时变偏移控制
    • US20050110471A1
    • 2005-05-26
    • US10722270
    • 2003-11-25
    • Valerian MayegaJun ChenJames KrugDavid Evans
    • Valerian MayegaJun ChenJames KrugDavid Evans
    • G05F1/577H02M3/155H02M3/156
    • H02M3/156H02M3/155
    • A single-inductor dual-output buck converter and control method that facilitates power conversion by converting a single DC power source/supply into two separate DC outputs, each of which can be configured to provide a selected/desired voltage by selection of respective duty cycles. The topology of the inverter includes a pair of diodes or switches that can selectively re-circulate inductor current. The converter is generally operated at a fixed frequency with four stages of operation. A first and third stage of operation provide power to a first and second output, respectively. A second and fourth stage of operation re-circulate inductor current and can partially recharge a battery type power source. The power output for each stage (voltage and current) can be selectively obtained by computing and employing appropriate time periods for the stages of operation that correspond to appropriate duty cycles.
    • 单电感双输出降压转换器和控制方法,通过将单个DC电源/电源转换为两个独立的直流输出来促进功率转换,每个直流输出可以被配置为通过选择相应的占空比来提供选定/期望的电压 。 逆变器的拓扑结构包括一对二极管或开关,可以选择性地重新循环电感电流。 转换器通常以固定频率工作,具有四个操作阶段。 第一和第三操作阶段分别为第一和第二输出提供电力。 第二和第四阶段的操作重新循环电感电流,并且可以部分地为电池型电源充电。 可以通过对与适当的占空比相对应的操作阶段计算和采用适当的时间周期来选择性地获得每个级的电力输出(电压和电流)。
    • 98. 发明申请
    • Integrated circuit having barrier metal surface treatment prior to Cu deposition
    • 在Cu沉积之前具有阻挡金属表面处理的集成电路
    • US20050003663A1
    • 2005-01-06
    • US10903610
    • 2004-07-29
    • Wei PanJer-Shen MaaDavid EvansSheng Hsu
    • Wei PanJer-Shen MaaDavid EvansSheng Hsu
    • H01L21/3205C23C16/02C23C16/18H01L21/28H01L21/285H01L21/768H01L21/4763H01L21/44
    • H01L21/76843C23C16/0209C23C16/18H01L21/28556H01L21/76864H01L21/76876
    • A rapid thermal process (RTP) provides steps wherein silicon wafers that are pre-coated with barrier metal films by either in-situ or ex-situ CVD or physical vapor deposition (PVD) are pre-treated, prior to deposition of a Cu film thereon, in a temperature range of between 250 and 550 degrees Celsius in a non-reactive gas such as hHydrogen gas (H2), argon (Ar), or helium (He), or in an ambient vacuum. The chamber pressure typically is between 0.1 mTorr and 20 Torr, and the RTP time typically is between 30 to 100 seconds. Performing this rapid thermal process before deposition of the Cu film results in a thin, shiny, densely nucleated, and adhesive Cu film deposited on a variety of barrier metal surfaces. The pre-treatment process eliminates variations in the deposited Cu film caused by Cu precursors and is insensitive to variation in precursor composition, volatility, and other precursor variables. Accordingly, the process disclosed herein is an enabling technology for the use of metal organic CVD (MOCVD) Cu in IC fabrication.
    • 快速热处理(RTP)提供了在沉积Cu膜之前预处理通过原位或原位CVD或物理气相沉积(PVD)预涂覆有阻挡金属膜的硅晶片的步骤 在非反应性气体例如氢气(H 2),氩气(Ar)或氦气(He)中,或在环境真空中,在250-550℃的温度范围内。 室压力通常在0.1mTorr和20Torr之间,并且RTP时间通常在30至100秒之间。 在沉积Cu膜之前进行这种快速热处理会导致沉积在各种阻挡金属表面上的薄而有光泽,致密成核和粘附的Cu膜。 预处理过程消除了由Cu前体引起的沉积的Cu膜的变化,并且对前体组成,挥发性和其它前体变量的变化不敏感。 因此,本文公开的方法是在IC制造中使用金属有机CVD(MOCVD)Cu的使能技术。