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    • 91. 发明授权
    • Shallow trench isolation filled by high density plasma chemical vapor
deposition
    • 通过高密度等离子体化学气相沉积填充的浅沟槽隔离
    • US6037018A
    • 2000-03-14
    • US108866
    • 1998-07-01
    • Syun-Ming JangChu-Yun FuChen-Hua Douglas Yu
    • Syun-Ming JangChu-Yun FuChen-Hua Douglas Yu
    • C23C16/40H01L21/762B05D3/06H01L21/76
    • H01L21/76232C23C16/402
    • A method for filling shallow trenches 28 with a HDPCVD oxide 50. The invention has two liners: (a) a thermal oxide liner 36 and (b) an overlying conformal O.sub.3 -TEOS protective liner 40. The O.sub.3 -TEOS protective liner 40 prevents the HDPCVD oxide 50 from sputter damaging the trench sidewalls and the masking layer 24. The O.sub.3 -TEOS layer has novel process temperature (400 to 560.degree. C.) and low pressure (40 to 80 torr) that allows the O.sub.3 -TEOS layer to deposit uniformly over thermal oxide liner 36. The method begins by forming pad oxide layer 20 and a barrier layer 24 over a substrate. A trench 28 is formed in the substrate 10 through the pad oxide layer 20 and the barrier layer 24. A thermal oxide liner 36 and a protective O.sub.3 -TEOS liner layer 40 are formed over the walls of the trench 28 and over the barrier layer 24. Lastly, a high density plasma chemical vapor deposition (HDPCVD) oxide layer 50 is formed over the protective liner layer 40 filling the trench 28.
    • 用HDPCVD氧化物50填充浅沟槽28的方法。本发明具有两个衬垫:(a)热氧化物衬垫36和(b)上覆的共形O3-TEOS保护衬垫40.O3-TEOS保护衬垫40防止 HDPCVD氧化物50从溅射破坏沟槽侧壁和掩模层24.O3-TEOS层具有新的工艺温度(400至560℃)和低压(40至80托),允许O 3 -TEOS层沉积 该方法开始于在衬底上形成衬垫氧化物层20和阻挡层24。 沟槽28通过衬垫氧化物层20和阻挡层24形成在衬底10中。热氧化物衬里36和保护性O 3 -TEOS衬里层40形成在沟槽28的壁上并且在阻挡层24上方 最后,在填充沟槽28的保护衬垫层40之上形成高密度等离子体化学气相沉积(HDPCVD)氧化物层50。
    • 92. 发明授权
    • Shallow trench isolation process employing a BPSG trench fill
    • 采用BPSG沟槽填充的浅沟槽隔离工艺
    • US6010948A
    • 2000-01-04
    • US244879
    • 1999-02-05
    • Chen-Hua YuSyun-Ming Jang
    • Chen-Hua YuSyun-Ming Jang
    • H01L21/762
    • H01L21/76224
    • A process for creating BPSG filled, shallow trench isolation regions, in a semiconductor substrate, has been developed. The process features the use of a BPSG layer with about 4 to 4.5 weight percent B.sub.2 O.sub.3, and about 4 to 4.5 weight percent P.sub.2 O.sub.5, in silicon oxide. This BPSG composition, when subjected to a high temperature anneal procedure, results in softening, or reflowing, of the BPSG layer, eliminating seams or voids, in the BPSG layer, that may have been present after BPSG deposition. The removal rate of BPSG, is lower than the removal rate of silicon oxide layer, in buffered HF solutions, thus allowing several buffered HF procedures to be performed without recessing of BPSG in the shallow trench. In addition this composition of BPSG performs as a gettering material for mobile ions, thus contributing to yield and reliability improvements, when used at the isolation region for MOSFET devices.
    • 已经开发了用于在半导体衬底中产生BPSG填充的浅沟槽隔离区的工艺。 该方法的特征在于在氧化硅中使用具有约4至4.5重量%的B 2 O 3和约4至4.5重量%的P 2 O 5的BPSG层。 当经过高温退火过程时,该BPSG组合物导致BPSG层的软化或回流,消除了在BPSG沉积后可能存在的BPSG层中的接缝或空隙。 BPSG的去除率低于缓冲HF溶液中氧化硅层的去除率,从而允许在浅沟槽中不进行BPSG的凹陷而执行几个缓冲的HF程序。 此外,BPSG的这种组合作为移动离子的吸气材料,当在MOSFET器件的隔离区域使用时,有助于提高产量和可靠性。