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1. 发明申请

US20070038010A1 Process for producing lower olefins by using multiple reaction zones 有权
标题翻译：通过使用多个反应区生产低级烯烃的方法
公开(公告)号：US20070038010A1
公开(公告)日：2007-02-15
申请号：US11502520
申请日：2006-08-11
申请人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Yanhui Yuan , Huiming Zhang
发明人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Yanhui Yuan , Huiming Zhang
IPC分类号： C07C4/02
CPC分类号： C07C11/02 , C07C4/06 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C10G2400/22 , Y02P20/584 , Y02P30/42
摘要： The present invention provides a process for producing lower olefins by catalytic cracking a feedstock comprising an olefins-enriched mixture containing C4 or higher olefins and optionally an organic oxygenate compound. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including low yield and selectivity of lower olefins as the target products, and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking olefins and adopts as a feedstock an olefins-enriched mixture containing one or more C4 or higher olefins and optionally an organic oxygenate compound, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the reaction temperatures in the first and second reaction zones are controlled. The present process, which desirably solves the above technical problem, can be used in industrial production of lower olefins.
摘要翻译：本发明提供了一种通过催化裂化生产低级烯烃的方法，该原料包含含有C4或更高级烯烃和任选的有机含氧化合物的富含烯烃的混合物。在本发明中主要解决的技术问题是克服现有技术中存在的缺点，包括低产率和低烯烃作为目标产物的选择性，催化剂的再生时间短。本发明方法在催化裂化烯烃的条件下进行，并采用含有一种或多种C 4或更高级烯烃和任选的有机含氧化合物的富含烯烃的混合物作为原料，包括以下步骤：a）首先进入第一反应区以与第一结晶硅铝酸盐催化剂接触，所述第一结晶硅铝酸盐催化剂的SiO 2 / Al 2 O 3 N 3摩尔比为至少10 ，从而产生含有低级烯烃的第一反应流出物; b）使第一反应流出物依次进入至少一个第二反应区以与具有SiO 2 / Al 2 O 3的第二结晶硅铝酸盐催化剂接触摩尔比为至少10，从而产生含有低级烯烃的第二反应流出物; 和c）从第二反应流出物分离低级烯烃; 其中控制第一和第二反应区中的反应温度。希望解决上述技术问题的本方法可用于低级烯烃的工业生产。

2. 发明授权

US07692057B2 Process for producing lower olefins by using multiple reaction zones 有权
标题翻译：通过使用多个反应区生产低级烯烃的方法
公开(公告)号：US07692057B2
公开(公告)日：2010-04-06
申请号：US11502520
申请日：2006-08-11
申请人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Yanhui Yuan , Huiming Zhang
发明人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Yanhui Yuan , Huiming Zhang
IPC分类号： C07C4/02 , C10G51/04 , C10G11/05
CPC分类号： C07C11/02 , C07C4/06 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C10G2400/22 , Y02P20/584 , Y02P30/42
摘要： The present invention provides a process for producing lower olefins by catalytic cracking a feedstock comprising an olefins-enriched mixture containing C4 or higher olefins and optionally an organic oxygenate compound. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including low yield and selectivity of lower olefins as the target products, and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking olefins and adopts as a feedstock an olefins-enriched mixture containing one or more C4 or higher olefins and optionally an organic oxygenate compound, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the reaction temperatures in the first and second reaction zones are controlled. The present process, which desirably solves the above technical problem, can be used in industrial production of lower olefins.
摘要翻译：本发明提供了一种通过催化裂化生产低级烯烃的方法，该原料包含含有C4或更高级烯烃和任选的有机含氧化合物的富含烯烃的混合物。在本发明中主要解决的技术问题是克服现有技术中存在的缺点，包括低产率和低烯烃作为目标产物的选择性，催化剂的再生时间短。本发明方法在催化裂化烯烃的条件下进行，并采用含有一种或多种C 4或更高级烯烃和任选的有机含氧化合物的富含烯烃的混合物作为原料，包括以下步骤：a）首先进入与SiO 2 / Al 2 O 3摩尔比为至少10的第一结晶硅铝酸盐催化剂接触的第一反应区，从而产生含有低级烯烃的第一反应流出物; b）使第一反应流出物依次进入至少一个第二反应区，以与SiO 2 / Al 2 O 3摩尔比为至少10的第二结晶硅铝酸盐催化剂接触，从而产生含有低级烯烃的第二反应流出物; 和c）从第二反应流出物分离低级烯烃; 其中控制第一和第二反应区中的反应温度。希望解决上述技术问题的本方法可用于低级烯烃的工业生产。

3. 发明授权

US07692056B2 Process for producing lower olefins from methanol or dimethylether 有权
标题翻译：从甲醇或二甲醚生产低级烯烃的方法
公开(公告)号：US07692056B2
公开(公告)日：2010-04-06
申请号：US11503913
申请日：2006-08-15
申请人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Xiaofeng Chen
发明人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Xiaofeng Chen
CPC分类号： C07C11/02 , B01J2219/0004 , C07C1/20 , C07C2529/40 , Y02P20/52 , Y02P20/584 , Y02P30/42
摘要： The present invention provides a process for producing lower olefins from methanol or dimethyl ether. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including high operation temperature, low yield and selectivity of lower olefins as the target products, and poor stability and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking methanol and dimethyl ether and the presence of diluting gas, and adopts as a feedstock methanol, dimethyl ether or their mixture, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the weight ratio of the diluting gas to the feedstock is 0.01-6:1, while controlling the reaction conditions.
摘要翻译：本发明提供了由甲醇或二甲醚生产低级烯烃的方法。本发明主要解决的技术问题是克服现有技术中存在的缺点，包括作为目标产物的低级烯烃的高操作温度，低产率和选择性，以及催化剂的稳定性和较短的再生期。本工艺在甲醇和二甲醚催化裂解条件下进行，稀释气体的存在，采用甲醇，二甲醚或其混合物为原料，包括以下步骤：a）使原料首先进入与SiO 2 / Al 2 O 3摩尔比至少为10的第一结晶硅铝酸盐催化剂接触的第一反应区，从而产生含有低级烯烃的第一反应流出物; b）使第一反应流出物依次进入至少一个第二反应区，以与SiO 2 / Al 2 O 3摩尔比为至少10的第二结晶硅铝酸盐催化剂接触，从而产生含有低级烯烃的第二反应流出物; 和c）从第二反应流出物分离低级烯烃; 其中稀释气体与原料的重量比为0.01-6:1，同时控制反应条件。

4. 发明申请

US20070038011A1 Process for producing lower olefins from methanol or dimethylether 有权
标题翻译：从甲醇或二甲醚生产低级烯烃的方法
公开(公告)号：US20070038011A1
公开(公告)日：2007-02-15
申请号：US11503913
申请日：2006-08-15
申请人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Xiaofeng Chen
发明人： Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Xiaofeng Chen
IPC分类号： C07C4/02
CPC分类号： C07C11/02 , B01J2219/0004 , C07C1/20 , C07C2529/40 , Y02P20/52 , Y02P20/584 , Y02P30/42
摘要： The present invention provides a process for producing lower olefins from methanol or dimethyl ether. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including high operation temperature, low yield and selectivity of lower olefins as the target products, and poor stability and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking methanol and dimethyl ether and the presence of diluting gas, and adopts as a feedstock methanol, dimethyl ether or their mixture, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the weight ratio of the diluting gas to the feedstock is 0.01-6:1, while controlling the reaction conditions.
摘要翻译：本发明提供了由甲醇或二甲醚生产低级烯烃的方法。本发明主要解决的技术问题是克服现有技术中存在的缺点，包括作为目标产物的低级烯烃的高操作温度，低产率和选择性，以及催化剂的稳定性和较短的再生期。本工艺在甲醇和二甲醚催化裂解条件下进行，稀释气体的存在，采用甲醇，二甲醚或其混合物为原料，包括以下步骤：a）使原料首先进入与第一结晶硅铝酸盐催化剂接触的第一反应区，其具有至少10的SiO 2 / Al 2 O 3 N 3摩尔比，至少为10，至从而产生含有低级烯烃的第一反应流出物; b）使第一反应流出物依次进入至少一个第二反应区以与具有SiO 2 / Al 2 O 3的第二结晶硅铝酸盐催化剂接触摩尔比为至少10，从而产生含有低级烯烃的第二反应流出物; 和c）从第二反应流出物分离低级烯烃; 其中稀释气体与原料的重量比为0.01-6:1，同时控制反应条件。

5. 发明授权

US08304594B2 Process for increasing ethylene and/or propylene yield during conversion of oxygenates 有权
标题翻译：在含氧化合物转化期间提高乙烯和/或丙烯产率的方法
公开(公告)号：US08304594B2
公开(公告)日：2012-11-06
申请号：US12669373
申请日：2008-07-17
申请人： Zaiku Xie , Guozhen Qi , Weimin Yang , Siqing Zhong
发明人： Zaiku Xie , Guozhen Qi , Weimin Yang , Siqing Zhong
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The present invention provides a process for increasing ethylene and/or propylene yield during conversion of oxygenates using a system comprising a reactor and a regenerator, wherein the reactor comprises a fluidized bed reactor and a riser reactor, which process increases ethylene and/or propylene yield by using a mixture of the deactivated catalyst from the fluidized bed reactor and the regenerated catalyst from the regenerator in the riser reactor for further cracking the C4+ hydrocarbon stream separated from the product stream.
摘要翻译：本发明提供一种使用包含反应器和再生器的系统在含氧化合物转化期间提高乙烯和/或丙烯产率的方法，其中反应器包括流化床反应器和提升管反应器，该方法提高了乙烯和/或丙烯产率通过使用来自流化床反应器的失活的催化剂和来自提升管反应器中的再生器的再生催化剂的混合物进一步裂化从产物流分离的C4 +烃流。

6. 发明申请

US20100331596A1 PROCESS FOR INCREASING ETHYLENE AND/OR PROPYLENE YIELD DURING CONVERSION OF OXYGENATES 有权
标题翻译：在氧化剂转化期间增加乙烯和/或丙烯醛的方法
公开(公告)号：US20100331596A1
公开(公告)日：2010-12-30
申请号：US12669373
申请日：2008-07-17
申请人： Zaiku Xie , Guozhen Qi , Weimin Yang , Siqing Zhong
发明人： Zaiku Xie , Guozhen Qi , Weimin Yang , Siqing Zhong
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The present invention provides a process for increasing ethylene and/or propylene yield during conversion of oxygenates using a system comprising a reactor and a regenerator, wherein the reactor comprises a fluidized bed reactor and a riser reactor, which process increases ethylene and/or propylene yield by using a mixture of the deactivated catalyst from the fluidized bed reactor and the regenerated catalyst from the regenerator in the riser reactor for further cracking the C4+ hydrocarbon stream separated from the product stream.
摘要翻译：本发明提供一种使用包含反应器和再生器的系统在含氧化合物转化期间提高乙烯和/或丙烯产率的方法，其中反应器包括流化床反应器和提升管反应器，该方法提高了乙烯和/或丙烯产率通过使用来自流化床反应器的失活的催化剂和来自提升管反应器中的再生器的再生催化剂的混合物进一步裂化从产物流分离的C4 +烃流。

7. 发明申请

US20100179356A1 PROCESSES FOR PRODUCING ETHYLENE GLYCOL FROM OXALATE(S) 有权
标题翻译：用于生产乙酸甘油酯的方法（S）
公开(公告)号：US20100179356A1
公开(公告)日：2010-07-15
申请号：US12642621
申请日：2009-12-18
申请人： Juntao LIU , Weimin Yang , Fengxia Sun , Siqing Zhong , Wanmin Wang
发明人： Juntao LIU , Weimin Yang , Fengxia Sun , Siqing Zhong , Wanmin Wang
IPC分类号： C07C29/136
CPC分类号： B01J35/0006 , B01J21/08 , B01J23/72 , B01J23/745 , B01J23/78 , B01J23/80 , B01J23/868 , B01J23/8892 , B01J37/0201 , C07C29/149 , Y02P20/52 , C07C31/202
摘要： Provided are processes for producing ethylene glycol from oxalate(s), wherein two or more reaction zones in series are used, and oxalate feedstock is fed stagewise, or hydrogen feedstock and optionally a solvent are fed stagewise. The present processes achieve higher selectivity for the product and improved stability of catalysts.
摘要翻译：提供了从草酸生产乙二醇的方法，其中使用串联的两个或更多个反应区，并且草酸进料进料阶段，或者氢原料和任选的溶剂进料阶段进料。本发明方法对产物获得更高的选择性并提高催化剂的稳定性。

8. 发明授权

US08178734B2 Processes for producing ethylene glycol from oxalate(s) 有权
标题翻译：从草酸生产乙二醇的方法
公开(公告)号：US08178734B2
公开(公告)日：2012-05-15
申请号：US12642621
申请日：2009-12-18
申请人： Juntao Liu , Weimin Yang , Fengxia Sun , Siqing Zhong , Wanmin Wang
发明人： Juntao Liu , Weimin Yang , Fengxia Sun , Siqing Zhong , Wanmin Wang
IPC分类号： C07C27/04
CPC分类号： B01J35/0006 , B01J21/08 , B01J23/72 , B01J23/745 , B01J23/78 , B01J23/80 , B01J23/868 , B01J23/8892 , B01J37/0201 , C07C29/149 , Y02P20/52 , C07C31/202
摘要： Provided are processes for producing ethylene glycol from oxalate(s), wherein two or more reaction zones in series are used, and oxalate feedstock is fed stagewise, or hydrogen feedstock and optionally a solvent are fed stagewise. The present processes achieve higher selectivity for the product and improved stability of catalysts.
摘要翻译：提供了从草酸生产乙二醇的方法，其中使用串联的两个或更多个反应区，并且草酸进料进料阶段，或者氢原料和任选的溶剂进料阶段进料。本发明方法对产物获得更高的选择性并提高催化剂的稳定性。

9. 发明申请

US20110127193A1 Catalyst for Catalytic Cracking Fluidized Bed 有权
标题翻译：催化裂化催化剂流化床
公开(公告)号：US20110127193A1
公开(公告)日：2011-06-02
申请号：US12978107
申请日：2010-12-23
申请人： Zaiku Xie , Guangwei Ma , Weimin Yang , Hui Yao , Liang Chen
发明人： Zaiku Xie , Guangwei Ma , Weimin Yang , Hui Yao , Liang Chen
IPC分类号： C10G11/05 , B01J29/40 , B01J29/08 , B01J29/85 , B01J29/18 , B01J29/70
CPC分类号： B01J29/48 , B01J27/1853 , B01J27/187 , B01J27/188 , B01J29/166 , B01J29/26 , B01J29/46 , B01J29/7676 , B01J29/7815 , B01J29/80 , B01J37/0045 , B01J2229/42 , B01J2229/62 , C10G11/18
摘要： The present invention relates to a catalyst for catalytic cracking fluidized-bed, and the technical problems to be primarily solved by the present invention are high reaction temperature, low cryogenic activity of catalysts and worse selectivity during the preparation of ethylene-propylene by catalytically cracking naphtha. The present invention uses the composition having the chemical formula (on the basis of the atom ratio): AaBbPcOx, so as to magnificently solve said problems. The present invention therefore can be industrially used to produce ethylene and propylene by catalytically cracking naphtha.
摘要翻译：本发明涉及催化裂化流化床催化剂，本发明主要解决的技术问题是反应温度高，催化剂低温活性低，乙烯 - 丙烯催化裂化石脑油制备时选择性差。本发明使用具有化学式（以原子比为基准）的组合物：AaBbPcOx，以便极大地解决所述问题。因此，本发明可以在工业上用于通过催化裂化石脑油生产乙烯和丙烯。

10. 发明申请

US20070042904A1 Fluid-bed catalyst for the preparation of ethylene and propylene by catalytic cracking 审中-公开
标题翻译：用于通过催化裂化制备乙烯和丙烯的流化床催化剂
公开(公告)号：US20070042904A1
公开(公告)日：2007-02-22
申请号：US11503925
申请日：2006-08-15
申请人： Zaiku Xie , Hui Yao , Weimin Yang , Guangwei Ma , Jingxian Xiao , Liang Chen
发明人： Zaiku Xie , Hui Yao , Weimin Yang , Guangwei Ma , Jingxian Xiao , Liang Chen
IPC分类号： B01J23/22 , B01J29/06
CPC分类号： B01J23/8877 , B01J23/002 , B01J27/199 , B01J29/072 , B01J2229/42 , B01J2523/00 , C10G2400/20 , B01J2523/27 , B01J2523/3706 , B01J2523/54 , B01J2523/55 , B01J2523/68 , B01J2523/845 , B01J2523/13 , B01J2523/3712 , B01J2523/67 , B01J2523/23 , B01J2523/17 , B01J2523/51 , B01J2523/842 , B01J2523/847 , B01J2523/72 , B01J2523/25 , B01J2523/15
摘要： The present invention relates to a fluid-bed catalyst for the preparation of ethylene and propylene by catalytic cracking. The main technical problems to be solved are a relatively high reaction temperature, and low activities and poor selectivities of the catalyst at a low temperature, during the reaction for preparing ethylene and propylene by catalytically cracking naphtha. The technical solution of the catalyst is a composition of the chemical formula Mo1.0VaAbBcCdOX based on stoichiometric ratio. It has satisfactorily solved the above-mentioned problems, and is useful in the industrial production of ethylene and propylene by catalytically cracking naphtha.
摘要翻译：本发明涉及通过催化裂化制备乙烯和丙烯的流化床催化剂。在通过催化裂化石脑油制备乙烯和丙烯的反应反应期间，要解决的主要技术问题是相对较高的反应温度，低活性和低温催化剂选择性差。催化剂的技术解决方案是化学式为Mo 1 O的组合物，其中C 1，C 2，C 3，C 3 基于化学计量比来计算。它已经令人满意地解决了上述问题，并且在通过催化裂化石脑油工业生产乙烯和丙烯中是有用的。

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