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1. 发明申请

WO2007034131A1 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2007034131A1
公开(公告)日：2007-03-29
申请号：PCT/GB2006/002935
申请日：2006-08-08
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT N.V. , LAWRENCE, Nathan , ROBINSON, Kay, Louise , JIANG, Li , PAGELS, Markus , HACKETT, Simon
发明人： LAWRENCE, Nathan , ROBINSON, Kay, Louise , JIANG, Li , PAGELS, Markus , HACKETT, Simon
IPC分类号： G01N27/333 , G01N27/49 , E21B49/08
CPC分类号： E21B49/08 , E21B47/01 , G01N27/48
摘要： An electro-chemical sensor is described having two molecular redox systems one being sensitive the other insensitive to the species to be detected and both being covalently bound to a polymer and having a detector to detect relative shifts in the voltammograms of the two redox systems.
摘要翻译：描述了一种电化学传感器，其具有两个分子氧化还原系统，一个对待检测物质敏感的分子氧化还原体系，并且两者共价结合到聚合物上并具有检测器以检测两种氧化还原体系的伏安图的相对位移。

2. 发明申请

WO2008015435A1 AN EROSION AND WEAR RESISTANT SONOELECTROCHEMICAL PROBE 审中-公开
标题翻译：耐腐蚀和耐磨耗的电化学探针
公开(公告)号：WO2008015435A1
公开(公告)日：2008-02-07
申请号：PCT/GB2007/002933
申请日：2007-08-01
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT N.V. , HALL, Clive , JIANG, Li , JONES, Timothy , MEREDITH, Andrew , LAWRENCE, Nathan , PAGELS, Markus
发明人： HALL, Clive , JIANG, Li , JONES, Timothy , MEREDITH, Andrew , LAWRENCE, Nathan , PAGELS, Markus
IPC分类号： G01N27/30 , G01N27/38
CPC分类号： G01N27/308 , G01N27/26 , G01N27/38
摘要： The present invention provides methods and systems incorporating conducting diamond electrodes into a high power acoustic resonator. More specifically in certain embodiments of the present invention, diamond electrodes may be integrated into a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the electrodes and increasing the rate of mass transport to the diamond electrodes. The diamond electrodes may be used as working, reference or counter electrodes or a combination of two or more of such electrodes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the diamond electrodes may be coupled with the acoustic horn.
摘要翻译：本发明提供了将导电金刚石电极结合到高功率声谐振器中的方法和系统。更具体地，在本发明的某些实施例中，金刚石电极可以集成到高功率声谐振器中，以提供鲁棒的感测装置，其可以提供对电极的声学清洁并且提高质量传输到金刚石电极的速率。金刚石电极可以用作工作电极，参考电极或对电极，或两个或多个这样的电极的组合。在某些方面，高功率声谐振器可以包括用于聚焦声能的声喇叭，并且金刚石电极可以与声喇叭耦合。

3. 发明申请

WO2005066618A1 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2005066618A1
公开(公告)日：2005-07-21
申请号：PCT/GB2004/005397
申请日：2004-12-22
申请人： SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT N.V. , SCHLUMBERGER CANADA LIMITED , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER OILFIELD ASSISTANCE LIMITED , SCHLUMBERGER OVERSEAS S.A. , SCHLUMBERGER SEACO INC. , SCHLUMBERGER SURENCO S.A. , SERVICES PETROLIERS SCHLUMBERGER , JIANG, Li , JONES, Timothy, Gareth, John , COMPTON, Richard , LAWRENCE, Nathan , WILDGOOSE, Gregory, George , PANDURANGAPPA, Malingappagari , MULLINS, Oliver, Clinton , MEREDITH, Andrew
发明人： JIANG, Li , JONES, Timothy, Gareth, John , COMPTON, Richard , LAWRENCE, Nathan , WILDGOOSE, Gregory, George , PANDURANGAPPA, Malingappagari , MULLINS, Oliver, Clinton , MEREDITH, Andrew
IPC分类号： G01N27/416
CPC分类号： G01N27/308 , E21B47/10 , G01N27/302 , G01N27/3335
摘要： An electro-chemical sensor is described having two molecular redox systems sensitive to the same species and having an detector to detect relative shifts in the voltammograms of the two redox systems.
摘要翻译：描述了一种电化学传感器，其具有对相同物质敏感的两个分子氧化还原系统，并且具有检测器以检测两个氧化还原体系的伏安图的相对位移。

4. 发明申请

WO2004011929A1 METHODS AND APPARATUS FOR THE MEASUREMENT OF HYDROGEN SULPHIDE AND THIOLS IN FLUIDS 审中-公开
标题翻译：用于测量流体中硫化氢和硫酸的方法和装置
公开(公告)号：WO2004011929A1
公开(公告)日：2004-02-05
申请号：PCT/GB2003/002991
申请日：2003-07-10
申请人： SCHLUMBERGER TECHNOLOGY B.V. , PETROLEUM RESEARCH AND DEVELOPMENT N.V. , SCHLUMBERGER CANADA LIMITED , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER OILFIELD ASSISTANCE LIMITED , SCHLUMBERGER OVERSEAS S.A. , SCHLUMBERGER SERVICES LIMITED , SCHLUMBERGER SURENCO S.A. , SERVICES PETROLIERS SCHLUMBERGER , JIANG, Li , JONES, Timothy, Gareth, John , LAWRENCE, Nathan , THOMPSON, Mary , COMPTON, Richard
发明人： JIANG, Li , JONES, Timothy, Gareth, John , LAWRENCE, Nathan , THOMPSON, Mary , COMPTON, Richard
IPC分类号： G01N33/00
CPC分类号： G01N33/0044 , E21B49/10 , G01N27/49
摘要： An electrochemical sensor for measuring the amount of hydrogen sulphide or thiols in a fluid comprises an electrically conductive porous electrode within which are dispersed a precursor and a reaction solution which together with the hydrogen sulphide or thiols a redox reaction resulting in an electrical current dependent upon the amount of hydrogen sulphide or thiols in the fluid. The reaction solution may be initially provided in the pores of the porous electrode, or derived in use from the fluid itself.
摘要翻译：用于测量流体中硫化氢或硫醇的量的电化学传感器包括导电多孔电极，其中分散有前体和反应溶液，其与硫化氢或硫醇一起进行氧化还原反应，导致电流取决于流体中的硫化氢或硫醇的量。反应溶液可以最初设置在多孔电极的孔中，或者在使用中从流体本身获得。

5. 发明申请

WO2008065324A1 SYSTEM AND METHOD FOR QUALITATIVE AND QUANTITATIVE ANALYSIS OF GASEOUS COMPONENTS OF MULTIPHASE HYDROCARBON MIXTURES 审中-公开
标题翻译：多相烃混合气体组分定性和定量分析的系统与方法
公开(公告)号：WO2008065324A1
公开(公告)日：2008-06-05
申请号：PCT/GB2007/003572
申请日：2007-09-21
申请人： SCHLUMBERGER TECHNOLOGY B. V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT N.V. , LAWRENCE, Nathan , ROBINSON, Kay
发明人： LAWRENCE, Nathan , ROBINSON, Kay
IPC分类号： G01N27/49 , G01N33/28
CPC分类号： G01N33/2841 , G01N27/4045
摘要： Embodiments of the present invention provide systems and methods for detection and/or measurement of gaseous components of multiphase mixtures containing one or more hydrocarbons that may be retrieved down a wellbore or may be being transported in a pipeline. More specifically, but not by way of limitation, embodiments of the present invention may provide for separation of the gaseous components from the multiphase mixtures and detection and/or measurement of the separated gaseous components by direct oxidation or reduction.
摘要翻译：本发明的实施方案提供了用于检测和/或测量含有一种或多种烃的多相混合物的气体组分的系统和方法，所述烃可以沿着井眼回收或者可以在管道中运输。更具体地但不是限制，本发明的实施方案可以提供气相组分与多相混合物的分离，并通过直接氧化或还原来检测和/或测量分离的气体组分。

6. 发明申请

WO2011064632A2 PREPARATION OF SETTING SLURRIES 审中-公开
标题翻译：准备条件的准备
公开(公告)号：WO2011064632A2
公开(公告)日：2011-06-03
申请号：PCT/IB2010/002658
申请日：2010-10-15
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC. , VIDICK, Benoit , HARTSHORNE, Robert, Seth , LAWRENCE, Nathan , JOHNSON, Carl , MONTEIRO, Glen , WOODROW, Jonathan
发明人： VIDICK, Benoit , HARTSHORNE, Robert, Seth , LAWRENCE, Nathan , JOHNSON, Carl , MONTEIRO, Glen , WOODROW, Jonathan
CPC分类号： E21B33/14 , C04B40/0032 , C09K8/467 , C04B28/02 , C04B40/0039 , C04B2103/22
摘要： When preparing a settable slurry such as a cement slurry for cementing an oil well, cement or other solid powder is mixed with water and a set retarder. In order to be able to run a convenient and rapid check on the concentration of retarder after dilution at the site of use, a tracer material is mixed with the retarder in known amount during manufacture. The tracer is chosen to enable its concentration to be determined analytically after dilution at the site of use, thereby providing a way to determine the concentration of set retarder after such dilution. The tracer may be a redox-active material and its concentration may be determined by voltammetry. Tracer may likewise be mixed with additives other than set retarder.
摘要翻译：在制备用于固井的水泥浆等可固化浆料时，将水泥或其它固体粉末与水和缓凝剂混合。为了能够在使用地点稀释后对缓凝剂的浓度进行方便快速的检查，在制造过程中将示踪剂材料与缓凝剂以已知量混合。选择示踪剂以使其浓度在使用位置稀释后分析测定，由此提供确定这种稀释后缓凝剂浓度的方法。示踪剂可以是氧化还原活性物质，其浓度可以通过伏安法测定。示踪剂也可以与除缓凝剂之外的添加剂混合。

7. 发明申请

WO2012059708A1 ELECTROCHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2012059708A1
公开(公告)日：2012-05-10
申请号：PCT/GB2011/001509
申请日：2011-10-20
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , LAWRENCE, Nathan , MEREDITH, Andrew
发明人： LAWRENCE, Nathan , MEREDITH, Andrew
IPC分类号： G01N27/30 , G01N27/48
CPC分类号： G01N27/30 , G01N27/302 , G01N27/4167
摘要： A voltammetric pH sensor, especially for characterising wellbore fluids, comprises a plurality of electrodes with a redox active organic compound attached to an electrode and having at least one functional group convertible electrochemically between reduced and oxidized forms with transfer of at least one proton between the compound and surrounding aqueous phase, wherein the compound has at least one substituent group which promotes hydrogen bonding at a said functional group and thereby increases the reaction rate of proton transfer. The substituent group may form an internal hydrogen bond with a redox-convertible group or may enhance polarity to promote electrostatic interaction with water molecules and reduce activation energy. Typical examples include alizarin or 1, 2 - dihydroxy- anthraquinone (RH=72 - 48 - 0 ), quinizarin or 1, 4 - dihydroxy- anthraquinone (RN=81 - 64 - 1), 2 - acetoxy-benzoquinone (RN=1125 - 55 - 9 ), chloranil or 2, 3, 4, 5 - tetrachloro -benzoquinone (RN=118 - 75 - 2 ) and 1, 4 - diamino - 2, 3 - dichloro - anthraquinone (RN=81 - 42 - 5 ) deposited on a glassy carbon electrode. In this way, anomalous measurements at low ionic strenght and low concentrations of pH buffering species can be overcome.
摘要翻译：特别是用于表征井筒流体的伏安pH传感器包括多个电极，其具有连接到电极上的氧化还原活性有机化合物，并且具有至少一个可在还原和氧化形式之间电化学转化的官能团，其中化合物之间至少一个质子转移和周围的水相，其中所述化合物具有至少一个在所述官能团上促进氢键的取代基，从而提高质子转移的反应速率。取代基可以与氧化还原可转换基团形成内部氢键，或者可以提高极性以促进与水分子的静电相互作用并降低活化能。典型的实例包括茜素或1,2-二羟基 - 蒽醌（RH = 72-48-0），茜素或1,4-二羟基 - 蒽醌（RN = 81-64-1），2-乙酸基 - 苯醌（RN = 1125 - 55 - 9），氯醌或2,3,4,5-四氯 - 苯醌（RN = 118 - 75 - 2）和1,4-二氨基-2,3-二氯 - 蒽醌（RN = 81 - 42 - 5 ）沉积在玻璃碳电极上。以这种方式，可以克服低离子强度和低浓度pH缓冲物种的异常测量。

8. 发明申请

WO2012017306A2 ELECTROCHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2012017306A2
公开(公告)日：2012-02-09
申请号：PCT/IB2011/001820
申请日：2011-08-04
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED (SHL) , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER (SPS) , PRAD RESEARCH AND DEVELOPMENT LIMITED A British Virgin Islands Company , SCHLUMBERGER SEACO, INC. , LAWRENCE, Nathan , MEREDITH, Andrew
发明人： LAWRENCE, Nathan , MEREDITH, Andrew
IPC分类号： G01N27/30
CPC分类号： G01N27/302 , G01N27/4167
摘要： An electrochemical sensor for measuring an analyte in a fluid, the electrochemical sensor having a first working electrode that includes a redox species sensitive to the analyte to be measured and a second working electrode made from a conducting substrate absent the redox species. The electrochemical sensor being capable of operation so that electrochemical effects of active contaminants in the fluid can be removed/attenuated from electrochemical signals produced by the reduction/oxidation of the redox species in the presence of the analyte.
摘要翻译：一种用于测量流体中的分析物的电化学传感器，所述电化学传感器具有第一工作电极，所述第一工作电极包括对待测量的分析物敏感的氧化还原物质，以及由不含氧化还原物质的导电基材制成的第二工作电极。电化学传感器能够进行操作，从而可以通过在分析物存在下由氧化还原物质的还原/氧化产生的电化学信号去除/减弱活性污染物在流体中的电化学效应。

9. 发明申请

WO2011070408A2 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2011070408A2
公开(公告)日：2011-06-16
申请号：PCT/IB2010/002641
申请日：2010-10-14
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC. , LAFITTE, Valerie , LAWRENCE, Nathan
发明人： LAFITTE, Valerie , LAWRENCE, Nathan
IPC分类号： G01N27/30 , G01N33/18 , E21B47/00
CPC分类号： G01N27/3335 , G01N33/18
摘要： An electrochemical sensor for the presence or concentration of an analyte has at least one electrode and at least one electrochemically active species able to undergo electrochemical reaction in response to electrical potential applied to the electrode, where the said reaction is modified by the presence of the analyte. This sensor has the novel characteristic that at least one said electrochemically active species is encapsulated within polymer particles. These particles are preferably formed from an amorphous polymer with a glass transition temperature above the temperature of the fluid to which the sensor is exposed. The encapsulating polymer protects the analyte species from degradation, but a small analyte such as a hydrogen or bisulfide ion can pass through the polymer and undergo reaction at the active species.
摘要翻译：用于分析物的存在或浓度的电化学传感器具有至少一个电极和至少一个电化学活性物质，其能够响应于施加到电极的电势而经历电化学反应，其中所述反应通过分析物的存在而被修饰。该传感器具有将至少一种所述电化学活性物质包封在聚合物颗粒内的新颖特征。这些颗粒优选由玻璃化转变温度高于传感器所暴露的流体的温度的无定形聚合物形成。封装聚合物保护分析物物质免于降解，但是小分析物例如氢或二硫化物离子可以通过聚合物并在活性物质上进行反应。

10. 发明申请

WO2010106404A2 DERIVATISATION OF CARBON 审中-公开
标题翻译：碳的衍生物
公开(公告)号：WO2010106404A2
公开(公告)日：2010-09-23
申请号：PCT/IB2010/000293
申请日：2010-02-12
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED A British Virgin Islands Company , SCHLUMBERGER SEACO, INC. , ZOU, Fenglou , LAWRENCE, Nathan , JONES, Timothy
发明人： ZOU, Fenglou , LAWRENCE, Nathan , JONES, Timothy
IPC分类号： C01B31/02 , C01B31/04 , B82B3/00
CPC分类号： C07C201/12 , B82Y30/00 , B82Y40/00 , C01B32/156 , C01B32/174 , C01B32/194 , C01B32/20 , C01B32/21 , C01B32/28 , C01B32/354 , G01N27/308
摘要： A molecular species is covalently attached to elemental carbon by exposing the carbon to a reaction mixture containing a strong base and a compound of the formula (I) or (II) in which X denotes a covalently attached atom or group capable of forming an X - anion and each Z is a moiety comprising a plurality of atoms, but which does not have a hydrogen atom directly attached to the atom which itself is directly attached to the -CH 2 X or -CHX group. The carbon substrate may be graphite or carbon nanotubes.
摘要翻译：通过将碳暴露于含有强碱和式（I）或（II）的化合物的反应混合物中，分子物质共价连接到元素碳上，其中X表示共价连接的原子或能够形成X- 阴离子，每个Z是包含多个原子的部分，但不具有与本身直接连接到-CH 2 X或-CHX基团的原子直接相连的氢原子。碳衬底可以是石墨或碳纳米管。

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