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1. 发明申请

US20120094116A1 POLYAMIDE BLEND FILM 有权
标题翻译：聚酰亚胺薄膜
公开(公告)号：US20120094116A1
公开(公告)日：2012-04-19
申请号：US13332470
申请日：2011-12-21
申请人： Roland WURSCHE , Sonja Bollmann , Harald Häger , Martin Wielpütz , Kirsten Alting , Michael Beyer , Franz-Erich Baumann
发明人： Roland WURSCHE , Sonja Bollmann , Harald Häger , Martin Wielpütz , Kirsten Alting , Michael Beyer , Franz-Erich Baumann
IPC分类号： B32B27/34 , C09D177/06 , B60R13/02 , B32B27/06 , B60R13/04
CPC分类号： C08L77/06 , B32B5/18 , B32B27/34 , C08L77/02 , C08L2205/02 , C09D177/00 , C09D177/06 , Y10T428/12493 , Y10T428/249992 , Y10T428/26 , Y10T428/269 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , C08L2666/20
摘要： A film whose outer layer is composed of a molding composition which is in essence composed of the following components: a) from 3 to 50% by weight of a polyamide, selected from the group of PA11 and PA12, and b) from 50 to 97% by weight of a polyamide, selected from the group of PA1012 and PA1212, where the percentages are based on the entirety of components a) and b), is suitable for decoration of moldings which retain their gloss during their service time.
摘要翻译：其外层由本发明组成的成型组合物构成的膜，该组合物本质上由以下组分组成：a）3至50重量％的选自PA11和PA12的聚酰胺，以及b）50至97 选自PA1012和PA1212的聚酰胺的重量％，其中百分比基于组分a）和b）的组分，适用于在其使用时间内保持其光泽的模制品的装饰。

2. 发明授权

US08357455B2 Transparent moulding compound 有权
标题翻译：透明模塑料
公开(公告)号：US08357455B2
公开(公告)日：2013-01-22
申请号：US11813103
申请日：2005-11-09
申请人： Franz-Erich Baumann , Roland Wursche , Harald Häger , Sonja Bollmann , Kirsten Alting
发明人： Franz-Erich Baumann , Roland Wursche , Harald Häger , Sonja Bollmann , Kirsten Alting
IPC分类号： B32B27/34
CPC分类号： B32B27/34 , A63C5/124 , B32B27/08 , B32B2250/24 , B32B2307/412 , B32B2307/5825 , B32B2307/75 , B32B2519/00 , C08G69/265 , C08L77/06 , C08L2205/02 , C09D177/06 , Y10T156/10 , Y10T428/1345 , Y10T428/2969 , Y10T428/31725 , C08L2666/20
摘要： The invention relates to the use of a molding composition which comprises at least 50% by weight of a copolyamide, which is composed of the following monomer combination: a) from 65 to 99 mol % of a substantially equimolar mixture composed of an unbranched aliphatic diamine having from 6 to 18 carbon atoms and of an unbranched aliphatic dicarboxylic acid having from 6 to 18 carbon atoms, where the mixture composed of diamine and dicarboxylic acid comprises an average of from 8 to 12 carbon atoms, b) from 1 to 35 mol % of a substantially equimolar mixture composed of a cycloaliphatic diamine having from 8 to 20 carbon atoms and of a dicarboxylic acid having from 6 to 18 carbon atoms, for production of a printable or printed item, such as a ski topcoat.
摘要翻译：本发明涉及包含至少50重量％共聚酰胺的模塑组合物的用途，该共聚酰胺由以下单体组合组成：a）65至99mol％的基本上等摩尔的混合物，其由无支链的脂族二胺具有6至18个碳原子和具有6至18个碳原子的无支链脂族二羧酸，其中由二胺和二羧酸组成的混合物包含平均8至12个碳原子，b）1至35摩尔％的由具有8至20个碳原子的脂环族二胺和具有6至18个碳原子的二羧酸组成的基本上等摩尔的混合物，用于制备可印刷或印刷的物品，例如滑雪面漆。

3. 发明授权

US07879938B2 Compositions comprising an organic polymer as the matrix and inorganic particles as the filler, process for the preparation thereof and applications of the same 有权
标题翻译：作为基质的有机聚合物和无机粒子作为填料的组合物，其制备方法及其应用
公开(公告)号：US07879938B2
公开(公告)日：2011-02-01
申请号：US11822862
申请日：2007-07-10
申请人： Harald Häger , Franz-Erich Baumann , Wolfgang Lortz , Werner Höss , Michael Wicker , Rüdiger Carloff , Uwe Schneider
发明人： Harald Häger , Franz-Erich Baumann , Wolfgang Lortz , Werner Höss , Michael Wicker , Rüdiger Carloff , Uwe Schneider
IPC分类号： C08K9/06 , C08L69/00 , C08L67/00 , C08L77/00
CPC分类号： D01F1/10 , B82Y30/00 , C08J3/215 , C08J5/005 , C08K9/04 , C08L77/00 , D01F6/60 , D01F6/62
摘要： Compositions comprising an organic polymer as the matrix and inorganic particles as the filler and exhibiting in mixture a) 20 to 99.9% by wt. of an organic polymer and b) 0.1 to 80% by wt. of inorganic particles, where the sum of the constituents a) and b) amounts to 100% by wt.; and optionally c) 0 to 100 parts by weight of b) of various additives, in which case the content of the additives c) relates to the sum of a) and b), calculated as 100 parts by weight. characterized in that the composition can be obtained by incorporating particles and optionally other additives into the polymer matrix, in which case the particles to be incorporated i) are aggregates of globular primary particles; ii) the size of the primary particles is in a range of 0.5 nm to less than 100 nm; iii) the volume-weighted median value d50 of the particles is in a range of greater than 0.50 μm to 0.5 μm, determined by means of static light scattering; and iv) the inorganic particles are modified with functional groups, the inorganic particles exhibiting at least three types of functional groups of varying reactivity. The compositions can be prepared in a number of way, for example, by reprecipitation from the dissolved state or by mixing in an extruder and are used for preparing fibers, films and shaped articles with improved mechanical properties.
摘要翻译：包含作为基质的有机聚合物和作为填料的无机颗粒和以混合物表示的组合物a）20-99.9重量％的有机聚合物，和b）0.1-80重量％的无机颗粒，其中组分a）和b）的总量相当于100重量％。并且任选地c）0至100重量份的b）各种添加剂，在这种情况下，添加剂c）的含量涉及以100重量份计算的a）和b）之和。其特征在于，可以通过将颗粒和任选的其它添加剂并入聚合物基质中来获得组合物，在这种情况下，待加入的颗粒i）是球状初级颗粒的聚集体; ii）一次颗粒的尺寸在0.5nm至小于100nm的范围内; iii）颗粒的体积加权中值d50在通过静态光散射确定的大于0.50μm至0.5μm的范围内; 和iv）无机颗粒用官能团改性，无机颗粒表现出至少三种具有不同反应性的官能团。组合物可以以多种方式制备，例如通过从溶解状态再沉淀或通过在挤出机中混合，并用于制备具有改善的机械性能的纤维，薄膜和成型制品。

4. 发明申请

US20120264877A1 PROCESS FOR PRODUCING ULTRAFINE POWDERS BASED ON POLYAMIDES, ULTRAFINE POLYAMIDE POWDERS AND THEIR USE 审中-公开
标题翻译：基于聚氨酯，超级聚酰胺粉及其使用生产超细粉的方法
公开(公告)号：US20120264877A1
公开(公告)日：2012-10-18
申请号：US13494082
申请日：2012-06-12
申请人： Harald Häger , Franz-Erich Baumann , Wolfgang Lortz , Christoph Batz-Sohn
发明人： Harald Häger , Franz-Erich Baumann , Wolfgang Lortz , Christoph Batz-Sohn
IPC分类号： C08L77/00 , B29C47/00 , B29C45/00 , C09D177/00 , B29C49/00
CPC分类号： C08J3/12 , C08J3/128 , C08J3/14 , C08J2377/00 , C09D177/00 , Y10S524/904
摘要： Process for preparing ultrafine powders based on polyamides by contacting polyamides having a relative solution viscosity ηrel in the range from 1.5 to 2.0, measured in 0.5% m-cresol solution at 25° C., with an alcoholic medium in the presence of inorganic particles suspended therein under the action of pressure and/or temperature to generate an at least partial solution, and then precipitating the polyamide from the at least partial solution; the resulting ultrafine polyamide powders have a specific BET surface area of 5-100 m2/g; a fineness d50 of less than 70 μm; an apparent density AD from 250 to 1000 g/l; and a particle content of 0.1 to 80% by weight of inorganic particles based on the total weight of the polyamide powder; which powders are equally suitable for coatings and for mouldings and components with improved mechanical properties.
摘要翻译：通过使具有相对溶液粘度和相对浓度的相对比例在1.5至2.0的范围内的聚酰胺制备基于聚酰胺制备的超细粉末的方法，其在25℃的0.5％间甲酚溶液中，在无机物存在下用醇介质在压力和/或温度的作用下悬浮在其中的颗粒以产生至少部分溶液，然后从所述至少部分溶液中沉淀聚酰胺; 所得超细聚酰胺粉末的BET比表面积为5-100m 2 / g; 细度d50小于70μm; 表观密度AD为250〜1000g / l; 和基于聚酰胺粉末的总重量的无机颗粒的0.1〜80重量％的颗粒含量; 这些粉末同样适用于涂料和具有改进的机械性能的模制品和组分。

5. 发明申请

US20130299750A1 COMPOSITION OF POLYAMIDES WITH LOW CONCENTRATION OF CARBOXAMIDE GROUPS AND ELECTRICALLY CONDUCTIVE CARBON 有权
标题翻译：碳酰胺基团和电导电碳浓度低的聚酰亚胺组合物
公开(公告)号：US20130299750A1
公开(公告)日：2013-11-14
申请号：US13882689
申请日：2011-10-31
申请人： Sylvia Anita Hermasch , Roland Wursche , Harald Häger , Kathrin Lehmann
发明人： Sylvia Anita Hermasch , Roland Wursche , Harald Häger , Kathrin Lehmann
IPC分类号： H01B1/04
CPC分类号： H01B1/24 , C08K3/04 , C08K3/041 , C08K3/042 , C08K5/10 , C08K5/20 , C08K5/3445 , C08K7/24 , C08L33/08 , C08L71/02 , C08L77/00 , C08L79/02 , C09D5/032 , C09D5/24 , H01B1/04
摘要： A polyamide composition comprising the following components: a) at least 40 parts by weight of a polyamide whose monomer units contain an arithmetic average of at least 7.5 carbon atoms, b) 0.1 to 15 parts by weight of at least one salt with a non-metallic cation, c) 0.1 to 25 parts by weight of at least one dispersant based on esters or amides and d) an electrically conductive carbon selected from the group of carbon black, graphite powder, carbon fibres, carbon nanotubes and/or graphene, in an amount which results in a specific surface resistance of the polymer composition to IEC 60167 of 10−1 to 1010 Ω, e) 0 to 5 parts by weight of at least one metal salt, and optionally f) customary assistants and additives, where the polyamide of component a) is not a PA12 if carbon nanotubes are present as component d), and where the sum of the parts by weight of components a) to f) is 100, can be used for production of mouldings with improved electrical conductivity and improved surface quality.
摘要翻译：一种聚酰胺组合物，其包含以下组分：a）至少40重量份的单体单元含有至少7.5个碳原子的算术平均值的聚酰胺，b）0.1至15重量份的至少一种具有非 - 金属阳离子，c）0.1至25重量份的至少一种基于酯或酰胺的分散剂，以及d）选自碳黑，石墨粉，碳纤维，碳纳米管和/或石墨烯的导电碳，导致根据IEC 60167的聚合物组合物的比表面电阻为10-1至1010Ω的量，e）0至5重量份的至少一种金属盐，以及任选的f）常规助剂和添加剂，其中组分a）的聚酰胺不是PA12，如果碳纳米管作为组分d）存在，并且其中组分a）至f）的重量份之和为100，则可用于生产具有改进的导电性的模制品，改善表面质量性。

6. 发明授权

US09418773B2 Composition of polyamides with low concentration of carboxamide groups and electrically conductive carbon 有权
标题翻译：具有低浓度甲酰胺基团和导电碳的聚酰胺的组成
公开(公告)号：US09418773B2
公开(公告)日：2016-08-16
申请号：US13882689
申请日：2011-10-31
申请人： Sylvia Anita Hermasch , Roland Wursche , Harald Häger , Kathrin Lehmann
发明人： Sylvia Anita Hermasch , Roland Wursche , Harald Häger , Kathrin Lehmann
IPC分类号： H01B1/24 , C09D5/24 , C08L77/00 , C09D5/03 , H01B1/04 , C08K3/04 , C08K5/10 , C08K5/20 , C08K5/3445
CPC分类号： H01B1/24 , C08K3/04 , C08K3/041 , C08K3/042 , C08K5/10 , C08K5/20 , C08K5/3445 , C08K7/24 , C08L33/08 , C08L71/02 , C08L77/00 , C08L79/02 , C09D5/032 , C09D5/24 , H01B1/04
摘要： A polyamide composition comprising the following components: a) at least 40 parts by weight of a polyamide whose monomer units contain an arithmetic average of at least 7.5 carbon atoms, b) 0.1 to 15 parts by weight of at least one salt with a non-metallic cation, c) 0.1 to 25 parts by weight of at least one dispersant based on esters or amides and d) an electrically conductive carbon selected from the group of carbon black, graphite powder, carbon fibers, carbon nanotubes and/or graphene, in an amount which results in a specific surface resistance of the polymer composition to IEC 60167 of 10−1 to 1010Ω, e) 0 to 5 parts by weight of at least one metal salt, and optionally f) customary assistants and additives, where the polyamide of component a) is not a PA12 if carbon nanotubes are present as component d), and where the sum of the parts by weight of components a) to f) is 100, can be used for production of mouldings with improved electrical conductivity and improved surface quality.
摘要翻译：一种聚酰胺组合物，其包含以下组分：a）至少40重量份的单体单元含有至少7.5个碳原子的算术平均值的聚酰胺，b）0.1至15重量份的至少一种具有非 - 金属阳离子，c）0.1至25重量份的至少一种基于酯或酰胺的分散剂，以及d）选自碳黑，石墨粉，碳纤维，碳纳米管和/或石墨烯的导电碳，导致根据IEC 60167的聚合物组合物的比表面电阻为10-1至1010Ω的量，e）0至5重量份的至少一种金属盐，以及任选地f）常规助剂和添加剂，其中聚酰胺的组分a）不是PA12，如果碳纳米管作为组分d）存在，并且其中组分a）至f）的重量份数之和为100，则可以用于具有改进的导电性和改进的模制品的生产表面质量 y。

7. 发明授权

US07601771B2 Polymer compositions containing polymers and ionic liquids 有权
标题翻译：含聚合物和离子液体的聚合物组合物
公开(公告)号：US07601771B2
公开(公告)日：2009-10-13
申请号：US10519402
申请日：2003-06-13
申请人： Friedrich Georg Schmidt , Frank-Martin Petrat , Andreas Pawlik , Harald Häger , Bernd Weyershausen
发明人： Friedrich Georg Schmidt , Frank-Martin Petrat , Andreas Pawlik , Harald Häger , Bernd Weyershausen
IPC分类号： C08K5/34 , C08K5/3435 , C08K5/3492 , C08K5/15 , C08K5/42 , C08K5/41
CPC分类号： C08K5/19
摘要： The invention relates to a polymer composition which comprises at least one at least semicrystalline polymer having no ionic groups and comprises at least one compound with plasticizing properties, and which comprises having 0.1 to 30% by weight of ionic liquid as plasticizer, and also to the use of this polymer composition, and a process for its preparation.
摘要翻译：本发明涉及一种聚合物组合物，其包含至少一种至少具有不含离子基团的至少半结晶聚合物，并且包含至少一种具有增塑性能的化合物，并且其包含0.1至30重量％的作为增塑剂的离子液体，使用该聚合物组合物及其制备方法。

8. 发明申请

US20090230347A1 FORMULATION COMPRISING A POLYMERIZABLE MONOMER AND/OR A POLYMER AND, DISPERSED THEREIN, A SUPERPARAMAGNETIC POWDER 审中-公开
标题翻译：包含可聚合单体和/或聚合物的配制剂，分散剂，超级粉末
公开(公告)号：US20090230347A1
公开(公告)日：2009-09-17
申请号：US11720613
申请日：2005-11-29
申请人： Markus Pridöhl , Guido Zimmermann , Michael Kröll , Harald Häger
发明人： Markus Pridöhl , Guido Zimmermann , Michael Kröll , Harald Häger
IPC分类号： H01F1/26 , C09J5/06 , H05B6/80
CPC分类号： B82Y25/00 , C09J9/00 , C09J11/04 , H01F1/0063 , H01F1/37
摘要： Formulation comprising a polymerizable monomer and/or a polymer and, dispersed therein, a superparamagnetic powder, which comprises aggregated primary particles, the primary particles being built up from magnetic metal oxide domains having a diameter of from 2 to 100 nm in a nonmagnetic metal oxide or metalloid oxide matrix. Process for heating the formulation in a magnetic or electromagnetic alternating field. Use of the formulation as an adhesive composition.
摘要翻译：包含可聚合单体和/或聚合物并且分散在其中的超顺磁性粉末，其包含聚集的初级颗粒，所述初级颗粒由非磁性金属氧化物中的直径为2至100nm的磁性金属氧化物畴构成或类金属氧化物基体。在磁场或电磁场中加热制剂的方法。使用该制剂作为粘合剂组合物。

9. 发明授权

US06355358B1 Multilayer composite 有权
标题翻译：多层复合材料
公开(公告)号：US06355358B1
公开(公告)日：2002-03-12
申请号：US09605363
申请日：2000-06-29
申请人： Michael Böer , Guido Schmitz , Georg Oenbrink , Harald Häger , Ralf Richter
发明人： Michael Böer , Guido Schmitz , Georg Oenbrink , Harald Häger , Ralf Richter
IPC分类号： B32B702
CPC分类号： B32B27/08 , B32B1/08 , B32B25/08 , B32B27/34 , B32B27/36 , B32B2307/202 , B32B2367/00 , B32B2377/00 , B32B2597/00 , C08G69/48 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1321 , Y10T428/139 , Y10T428/1393 , Y10T428/31504 , Y10T428/31725 , Y10T428/31736 , Y10T428/31786 , C08L51/00
摘要： A thermoplastic multilayer composite, and articles made therefrom, which has at least one layer I of a thermoplastic molding composition, at least one layer II of a further thermoplastic molding composition, bonded together with at least one layer of an adhesion promoter disposed between at least one layer I and at least one layer II. The adhesion promoter is at least 5% by weight of a graft copolymer prepared from 0.5 to 25% by weight, based on the total amount of graft copolymer, of a polyamine having at least 4 nitrogen atoms and having a number average molecular weight Mn of at least 146 g/mol, and polyamide-forming monomers selected from lactams, &ohgr;-aminocarboxylic acids, equimolar mixtures of diamines and dicarboxylic acids, and their mixtures.
摘要翻译：一种热塑性多层复合材料及其制成的制品，其具有至少一层热塑性模塑组合物，至少一层另外的热塑性模塑组合物，其至少与至少一层粘附促进剂层结合在一起，一层I和至少一层II。粘合促进剂为至少5重量％的接枝共聚物，其接枝共聚物的制备方法为0.5至25重量％，基于接枝共聚物的总量，具有至少4个氮原子且具有数均分子量Mn的多胺至少146g / mol和选自内酰胺，ω-氨基羧酸，二胺和二羧酸的等摩尔混合物的聚酰胺形成单体及其混合物。

10. 发明授权

US07704586B2 Plastic molded bodies having two-dimensional and three-dimensional image structures produced through laser subsurface engraving 失效
标题翻译：通过激光地下雕刻制造的具有二维和三维图像结构的塑料成型体
公开(公告)号：US07704586B2
公开(公告)日：2010-04-27
申请号：US11368602
申请日：2006-03-07
申请人： Klaus-Dieter Schübel , Jürgen Kreutz , Wilhelm Wolff , Günther Ittmann , Thomas Hasskerl , Harald Häger , Ralf Richter , Wolfgang Stuber
发明人： Klaus-Dieter Schübel , Jürgen Kreutz , Wilhelm Wolff , Günther Ittmann , Thomas Hasskerl , Harald Häger , Ralf Richter , Wolfgang Stuber
IPC分类号： B32B5/00 , B32B7/00 , B42D15/00
CPC分类号： B44C5/00 , B23K2103/42 , B23K2103/50 , B41M5/24 , B41M5/267 , B44C1/228 , B44F1/06 , Y10T428/24
摘要： The present invention relates to plastic molded bodies having two-dimensional or three-dimensional image structures produced in the interior through laser subsurface engraving. The plastic molded bodies are made of plastic materials which have a content of nanoscale metal oxides having particle sizes from 1 to 500 nm, both the plastic material and also the included metal oxide being transparent to the laser light used for producing the image structures. The plastic materials from which the molded bodies are manufactured particularly contain metal oxides having particle sizes from 5 to 100 nm at a content of 0.0001 to 0.1 weight-percent. Typical metal oxides are nanoscale indium-tin oxide or antimony-tin oxide.
摘要翻译：本发明涉及具有通过激光地下雕刻在内部制造的二维或三维图像结构的塑料模塑体。塑料成型体由塑料材料制成，其具有粒径为1至500nm的纳米级金属氧化物的含量，塑料材料和所包含的金属氧化物对于用于制造图像结构的激光是透明的。制造成型体的塑料材料特别含有0.0001-0.1重量％的粒度为5〜100nm的金属氧化物。典型的金属氧化物是纳米级氧化铟锡或氧化锑锡。

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