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1. 发明申请

WO2006135377A3 COATED NANOPARTICLES AND QUANTUM DOTS FOR SOLUTION-BASED FABRICATION OF PHOTOVOLTAIC CELLS 审中-公开
标题翻译：用于基于溶液的光伏电池制造的包覆纳米颗粒和量子点
公开(公告)号：WO2006135377A3
公开(公告)日：2009-06-04
申请号：PCT/US2005026412
申请日：2005-07-26
申请人： NANOSOLAR INC , SAGER BRIAN M , YU DONG , ROBINSON MATTHEW R
发明人： SAGER BRIAN M , YU DONG , ROBINSON MATTHEW R
IPC分类号： B05D5/12 , B05D7/00 , B05D7/24 , B22F1/00 , B22F1/02
CPC分类号： H01L31/0322 , B22F1/0018 , B22F1/025 , B22F2999/00 , B82Y20/00 , B82Y30/00 , C23C16/45544 , C23C18/1216 , C23C18/52 , H01L31/035281 , H01L31/0384 , H01L31/0749 , H01L51/0026 , H01L51/0037 , H01L51/426 , Y02E10/541 , Y02E10/549 , Y10S977/773 , Y10S977/857 , Y10S977/89 , Y10S977/892 , Y10T428/12181 , Y10T428/2991 , B22F1/02 , B22F2202/15 , B22F2202/01
摘要： CIGS absorber layers fabricated using coated semiconducting nanoparticles and/or quantum dots are disclosed. Core nanoparticles and/or quantum dots containing one or more elements from group IB and/or IIIA and/or VIA may be coated with one or more layers containing elements group IB, IIIA or VIA. Using nanoparticles with a defined surface area, a layer thickness could be tuned to give the proper stoichiometric ratio, and/or crystal phase, and/or size, and/or shape. The coated nanoparticles could then be placed in a dispersant for use as an ink, paste, or paint. By appropriate coating of the core nanoparticles, the resulting coated nanoparticles can have the desired elements intermixed within the size scale of the nanoparticle, while the phase can be controlled by tuning the stochiometry, and the stoichiometry of the coated nanoparticle may be tuned by controlling the thickness of the coating(s).
摘要翻译：公开了使用涂覆的半导体纳米颗粒和/或量子点制造的CIGS吸收层。含IB和/或IIIA和/或VIA的一种或多种元素的核心纳米颗粒和/或量子点可以涂覆有含有IB，IIIA或VIA族元素的一层或多层。使用具有限定表面积的纳米颗粒，可以调节层厚度以获得适当的化学计量比和/或晶体相，和/或尺寸和/或形状。然后将涂覆的纳米颗粒置于分散剂中用作油墨，糊剂或油漆。通过适当地涂覆核心纳米颗粒，所得到的涂覆的纳米颗粒可以将期望的元素混合在纳米颗粒的尺寸范围内，而可以通过调整化学计量来控制相位，并且涂覆的纳米颗粒的化学计量可以通过控制涂层厚度。

2. 发明公开

EP2396823A4 SOLAR CELL ABSORBER LAYER FORMED FROM EQUILIBRIUM PRECURSOR(S) 审中-公开
标题翻译：从前体平衡（N）形太阳电池吸收层
公开(公告)号：EP2396823A4
公开(公告)日：2013-09-11
申请号：EP10741889
申请日：2010-02-16
申请人： WOODRUFF JACOB , VAN DUREN JEROEN K J , ROBINSON MATTHEW R , SAGER BRIAN M
发明人： WOODRUFF JACOB , VAN DUREN JEROEN K J , ROBINSON MATTHEW R , SAGER BRIAN M
IPC分类号： H01L31/032 , C23C14/06 , C23C14/58 , C23C18/08 , C23C28/02 , H01L21/36 , H01L31/18
CPC分类号： H01L31/0322 , C23C18/08 , C23C18/1204 , C23C18/127 , C23C18/1279 , C23C18/1283 , C23C18/1295 , C23C28/021 , C23C28/023 , C23C28/321 , C23C28/322 , C23C28/34 , C23C28/341 , C23C28/345 , C23C28/36 , H01L21/02425 , H01L21/02568 , H01L21/02601 , H01L21/02614 , H01L21/02628 , H01L31/1864 , Y02E10/541 , Y02P70/521

3. 发明申请

WO2008095146A2 SOLAR CELL ABSORBER LAYER FORMED FROM METAL ION PRECURSORS 审中-公开
标题翻译：从金属离子前驱体形成的太阳能电池吸收层
公开(公告)号：WO2008095146A2
公开(公告)日：2008-08-07
申请号：PCT/US2008052730
申请日：2008-01-31
申请人： VAN DUREN JEROEN K J , ROBINSON MATTHEW R , SAGER BRIAN M
发明人： VAN DUREN JEROEN K J , ROBINSON MATTHEW R , SAGER BRIAN M
IPC分类号： H01L31/04
CPC分类号： H01L31/03928 , H01L31/06 , H01L31/0749 , Y02E10/541 , Y02P70/521
摘要： Methods and devices are provided for forming an absorber layer. In one embodiment, a method is provided comprising of depositing a solution on a substrate to form a precursor layer. The solution comprises of at least one polar solvent, at least one binder, and at least one Group IB and/or IIIA hydroxide. The precursor layer is processed in one or more steps to form a photovoltaic absorber layer. In one embodiment, the absorber layer may be created by processing the precursor layer into a solid film and then thermally reacting the solid film in an atmosphere containing at least an element of Group VIA of the Periodic Table to form the photovoltaic absorber layer. Optionally, the absorber layer may be processed by thermal reaction of the precursor layer in an atmosphere containing at least an element of Group VIA of the Periodic Table to form the photovoltaic absorber layer.
摘要翻译：提供了用于形成吸收层的方法和装置。在一个实施方案中，提供了一种方法，其包括在基底上沉积溶液以形成前体层。溶液包含至少一种极性溶剂，至少一种粘合剂和至少一种IB族和/或IIIA型氢氧化物。在一个或多个步骤中处理前体层以形成光伏吸收层。在一个实施方案中，吸收层可以通过将前体层加工成固体膜，然后在至少含有元素周期表第VIA族元素的气氛中使固体膜热反应形成光伏吸收层来产生。任选地，吸收层可以通过前体层在至少含有周期表第VIA族元素的气氛中进行热反应来加工，以形成光伏吸收层。

4. 发明申请

WO2010094048A3 SOLAR CELL ABSORBER LAYER FORMED FROM EQUILIBRIUM PRECURSOR(S) 审中-公开
标题翻译：由平衡前体形成的太阳能电池吸收层（S）
公开(公告)号：WO2010094048A3
公开(公告)日：2010-12-16
申请号：PCT/US2010024342
申请日：2010-02-16
申请人： WOODRUFF JACOB , VAN DUREN JEROEN K J , ROBINSON MATTHEW R , SAGER BRIAN M
发明人： WOODRUFF JACOB , VAN DUREN JEROEN K J , ROBINSON MATTHEW R , SAGER BRIAN M
IPC分类号： H01L31/042
CPC分类号： H01L31/0322 , C23C18/08 , C23C18/1204 , C23C18/127 , C23C18/1279 , C23C18/1283 , C23C18/1295 , C23C28/021 , C23C28/023 , C23C28/321 , C23C28/322 , C23C28/34 , C23C28/341 , C23C28/345 , C23C28/36 , H01L21/02425 , H01L21/02568 , H01L21/02601 , H01L21/02614 , H01L21/02628 , H01L31/1864 , Y02E10/541 , Y02P70/521
摘要： Methods and devices are provided for forming an absorber layer. In one embodiment, a method is provided comprising of depositing a solution on a substrate to form a precursor layer. The solution comprises of at least one equilibrium and/or near equilibrium material. The precursor layer is processed in one or more steps to form a photovoltaic absorber layer. In one embodiment, the absorber layer may be created by processing the precursor layer into a solid film and then thermally reacting the solid film in an atmosphere containing at least an element of Group VIA of the Periodic Table to form the photovoltaic absorber layer. Optionally, the absorber layer may be processed by thermal reaction of the precursor layer in an atmosphere containing at least an element of Group VIA of the Periodic Table to form the photovoltaic absorber layer.
摘要翻译：提供了用于形成吸收层的方法和装置。在一个实施例中，提供了一种方法，包括在基底上沉积溶液以形成前体层。该溶液包含至少一种平衡和/或接近平衡的材料。前体层在一个或多个步骤中被处理以形成光伏吸收层。在一个实施例中，吸收层可以通过将前体层加工成固体膜，然后在包含元素周期表第VIA族元素的至少一种元素的气氛中使固体膜热反应以形成光伏吸收体层来形成。任选地，吸收层可以通过前体层在包含元素周期表第VIA族元素的至少一种元素的气氛中的热反应来处理，以形成光伏吸收层。

5. 发明申请

WO2006101986A2 METTALIC DISPERSION AND FORMATION OF COMPOUND FILM FOR PHOTOVOLTAIC DEVICE ACTIVE LAYER 审中-公开
标题翻译：金属分散体和形成用于光伏器件活性层的复合膜
公开(公告)号：WO2006101986A2
公开(公告)日：2006-09-28
申请号：PCT/US2006009534
申请日：2006-03-16
申请人： NANOSOLAR INC , ROBINSON MATTHEW R , ROSCHEISEN MARTIN R , EBERSPACHER CHRIS , VAN DUREN JEROEN K J , LEIDHOLM CRAIG R
发明人： ROBINSON MATTHEW R , ROSCHEISEN MARTIN R , EBERSPACHER CHRIS , VAN DUREN JEROEN K J , LEIDHOLM CRAIG R
IPC分类号： H02N6/00
CPC分类号： H01L31/0322 , C23C18/02 , C23C18/1216 , C23C18/1258 , C23C18/1279 , C23C18/1287 , H01L21/02568 , H01L21/02601 , H01L21/02628 , H01L31/0749 , Y02E10/541
摘要： A compound film may be formed by formulating a mixture of elemental nanoparticles composed of the IB, the IIIA, and, optionally, the VIA group of elements having a controlled overall composition. The nanoparticle mixture is combined with a suspension of nanoglobules of gallium to form a dispersion. The dispersion may be deposited onto a substrate to form a layer on the substrate. The layer may then be reacted in a suitable atmosphere to form the compound film. The compound film may be used as a light-absorbing layer in a photovoltaic device. Optionally, the compound film for an active layer of a photovoltaic device may be formed in two or more sub-layers. A first sub-layer having a first component of the active layer may be formed on a substrate with a first process. A second sub-layer including a second component of the active layer may then be formed using a second process such that the first sublayer is disposed between the second sub-layer and the substrate. The second component may have a different chemical composition than the first component. The first and/or second sub-layer may comprise one or more components in the form of particles and/or globules. This procedure may be repeated any number of times for any number of sub-layers so that active layer can be built up sequentially. The different chemical compositions of the components in the sub-layers can provide the active layer with a graded bandgap.
摘要翻译：可以通过配制由IB，IIIA和任选地具有受控整体组成的元素的VIA族组成的元素纳米颗粒的混合物来形成化合物膜。将纳米颗粒混合物与镓的纳米金属的悬浮液组合以形成分散体。可以将分散体沉积在基底上以在基底上形成层。然后可以在合适的气氛中反应该层以形成化合物膜。复合膜可以用作光伏器件中的光吸收层。可选地，用于光伏器件的有源层的化合物膜可以形成为两个或更多个子层。具有有源层的第一分量的第一子层可以用第一工艺形成在衬底上。然后可以使用第二工序形成包括有源层的第二部件的第二子层，使得第一子层设置在第二子层和衬底之间。第二组分可以具有与第一组分不同的化学组成。第一和/或第二子层可以包括颗粒和/或小球形式的一种或多种组分。对于任何数量的子层，该过程可以重复任意次数，以便可以顺序地建立活动层。子层中组分的不同化学组成可以为活性层提供渐变的带隙。

6. 发明公开

EP2353188A4 HYBRID TRANSPARENT CONDUCTIVE ELECTRODES 审中-公开
标题翻译： HYBRID，透明，导电电极
公开(公告)号：EP2353188A4
公开(公告)日：2015-04-08
申请号：EP09829656
申请日：2009-10-30
申请人： POON HAK FEI , ROBINSON MATTHEW R , ERBEN CHRISTOPHER , VAN DUREN JEROEN K J , SHEATS JAMES R
发明人： POON HAK FEI , ROBINSON MATTHEW R , ERBEN CHRISTOPHER , VAN DUREN JEROEN K J , SHEATS JAMES R
IPC分类号： H01L31/042 , H01L31/05
CPC分类号： H01L31/1884 , H01L31/022466 , H01L31/022483 , Y02E10/50

7. 发明专利

AU2012275284B2 Transparent conductors incorporating additives and related manufacturing methods 未知
公开(公告)号：AU2012275284B2
公开(公告)日：2015-06-11
申请号：AU2012275284
申请日：2012-06-28
申请人： ROBINSON MATTHEW R , SRINIVAS ARJUN DANIEL , YOUNG MIICHAEL EUGENE
发明人： SRINIVAS ARJUN DANIEL , ROBINSON MATTHEW R , YOUNG MICHAEL EUGENE
IPC分类号： H01L51/52 , H01B5/14 , H01L51/56 , H05B33/26
摘要： A transparent conductor includes a film of a conductive ceramic. Additives are at least partially incorporated into the film. The additives are at least one of electrically conductive and semiconducting, and at least one of the additives has an aspect ratio of at least 3.

8. 发明申请

WO2007146964A3 THIN-FILM DEVICES FROMED FROM SOLID PARTICLES 审中-公开
标题翻译：来自固体颗粒的薄膜装置
公开(公告)号：WO2007146964A3
公开(公告)日：2008-02-28
申请号：PCT/US2007071048
申请日：2007-06-12
申请人： ROBINSON MATTHEW R , EBERSPACHER CHRIS , VAN DUREN JEROEN K J
发明人： ROBINSON MATTHEW R , EBERSPACHER CHRIS , VAN DUREN JEROEN K J
IPC分类号： H01L21/203
CPC分类号： H01L31/0322 , Y02E10/541
摘要： Methods and devices are provided for forming thin-films from solid group IIIA-based particles. In one embodiment of the present invention, a method is described comprising of providing a first material comprising an alloy of a) a group IIIA-based material and b) at least one other material. The material may be included in an amount sufficient so that no liquid phase of the alloy is present within the first material in a temperature range between room temperature and a deposition or pre-deposition temperature higher than room temperature, wherein the group IIIA-based material is otherwise liquid in that temperature range. The other material may be a group IA material. A precursor material may be formulated comprising a) particles of the first material and b) particles containing at least one element from the group consisting of: group IB, IIIA, VIA element, alloys containing any of the foregoing elements, or combinations thereof. The temperature range described above may be between about 2O0C and about 2000C. It should be understood that the alloy may have a higher melting temperature than a melting temperature of the IIIA-based material in elemental form.
摘要翻译：提供了用于从基于固体IIIA的颗粒形成薄膜的方法和装置。在本发明的一个实施方案中，描述了一种方法，其包括提供包含a）基于IIIA族的材料和b）至少一种其它材料的合金的第一材料。可以以足够的量包含材料，使得在室温和高于室温的沉积或预沉积温度之间的温度范围内，第一材料中不存在液相，其中基于IIIA族的材料在该温度范围内为液体。另一种材料可以是IA族材料。可以配制前体材料，其包括：a）第一材料的颗粒，和b）含有至少一种元素的颗粒，所述元素包括：IB，IIIA族，VIA族元素，含有任何上述元素的合金，或其组合。上述温度范围可以在约20℃至约200℃之间。应当理解，该合金的熔融温度可以比基于IIIA的材料的元素形式的熔融温度更高。

9. 发明申请

WO2007101138A2 HIGH-THROUGHPUT PRINTING OF SEMICONDUCTOR PRECURSOR LAYER FROM INTER-METALLIC NANOFLAKE PARTICLES 审中-公开
标题翻译：来自金属间纳米颗粒的半导体前驱层的高通量印刷
公开(公告)号：WO2007101138A2
公开(公告)日：2007-09-07
申请号：PCT/US2007062766
申请日：2007-02-23
申请人： VAN DUREN JEROEN K J , LEIDHOLM CRAIG R , ROBINSON MATTHEW R
发明人： VAN DUREN JEROEN K J , LEIDHOLM CRAIG R , ROBINSON MATTHEW R
CPC分类号： H01L31/06 , B82Y30/00 , C23C18/1204 , C23C18/1225 , C23C18/1241 , C23C18/127 , C23C18/1283 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： Methods and devices are provided for transforming non-planar or planar precursor materials in an appropriate vehicle under the appropriate conditions to create dispersions of planar particles with stoichiometric ratios of elements equal to that of the feedstock or precursor materials, even after selective forces settling. In particular, planar particles disperse more easily, , form much denser coatings (or form coatings with more interparticle contact area), and anneal into fused, dense films at a lower temperature and/or time than their counterparts made from spherical nanoparticles. These planar particles may be nanoflakes that have a high aspect ratio. The resulting dense films formed from nanoflakes are particularly useful in forming photovoltaic devices. . In one embodiment, at least one set of the particles in the ink may be inter-metallic flake particles (microflake or nanoflake) containing at least one group IB-IIIA inter-metallic alloy phase.
摘要翻译：提供了用于在合适的条件下在合适的载体中转化非平面或平面前体材料的方法和装置，以产生具有等于原料或前体材料的化学计量比的化学计量比的平面颗粒的分散体，即使在选择性力沉降之后。特别地，平面颗粒更容易分散，形成更密集的涂层（或形成具有更多颗粒间接触面积的涂层），并在比球形纳米颗粒制成的对应物更低的温度和/或时间下退火成熔融的致密膜。这些平面颗粒可以是具有高纵横比的纳米片。由纳米片形成的致密膜特别适用于形成光电器件。。在一个实施方案中，油墨中的至少一组颗粒可以是含有至少一种IB-IIIA族金属间合金相的金属间薄片（微花纹或纳米薄片）。

10. 发明申请

WO2013003638A2 TRANSPARENT CONDUCTORS INCORPORATING ADDITIVES AND RELATED MANUFACTURING METHODS 审中-公开
标题翻译：包含添加剂和相关制造方法的透明导体
公开(公告)号：WO2013003638A2
公开(公告)日：2013-01-03
申请号：PCT/US2012044724
申请日：2012-06-28
申请人： SRINIVAS ARJUN DANIEL , ROBINSON MATTHEW R , YOUNG MICHAEL EUGENE
发明人： SRINIVAS ARJUN DANIEL , ROBINSON MATTHEW R , YOUNG MICHAEL EUGENE
CPC分类号： H01B1/02 , G02F1/13439 , G06F3/044 , G06F3/045 , H01B13/30 , H01L51/0021 , H01L51/5206 , H01L2251/5369
摘要： A transparent conductor includes a film of a conductive ceramic. Additives are at least partially incorporated into the film. The additives are at least one of electrically conductive and semiconducting, and at least one of the additives has an aspect ratio of at least 3.
摘要翻译：透明导体包括导电陶瓷膜。添加剂至少部分并入膜中。添加剂是导电和半导体中的至少一种，并且至少一种添加剂具有至少3的纵横比。

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