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1. 发明申请

US20070287845A1 Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol 有权
标题翻译：羟甲基糠醛还原方法和生产呋喃二甲醇的方法
公开(公告)号：US20070287845A1
公开(公告)日：2007-12-13
申请号：US11760634
申请日：2007-06-08
申请人： Michael Lilga , Richard Hallen , Todd Werpy , James White , Johnathan Holladay , John Frye , Alan Zacher
发明人： Michael Lilga , Richard Hallen , Todd Werpy , James White , Johnathan Holladay , John Frye , Alan Zacher
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 H 2被提供到反应器中，起始材料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂接触，温度小于或等于250℃。氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H 2 H 2和氢化催化剂。 HMF在等于或高于30℃的温度下相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器中提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

2. 发明申请

US20070173643A1 Process for Producing Cyclic Compounds 有权
标题翻译：生产环状化合物的方法
公开(公告)号：US20070173643A1
公开(公告)日：2007-07-26
申请号：US11688022
申请日：2007-03-19
申请人： Todd Werpy , John Frye , James White , Johnathan Holladay , Alan Zacher
发明人： Todd Werpy , John Frye , James White , Johnathan Holladay , Alan Zacher
IPC分类号： C07D207/267 , C07D223/10 , C07D205/02
CPC分类号： C07D207/404
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkylating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Ammonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100° C. to about 400° C. to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化为环状化合物来处理初始二羰基化合物的方法。环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的氨含量以产生约1：1至约1.5：1的氨与二羧酸酯化合物的比例。加入烷基化剂并将该初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸钠引入容器中，并调节氨以提供小于2:1的氨与琥珀酸的比例。甲基化剂与琥珀酸酯在大于100℃至约400℃的温度下反应，生成N-甲基琥珀酰亚胺，将其纯化并氢化形成NMP。

3. 发明申请

US20050064560A1 Methods of producing compounds from plant material 审中-公开
标题翻译：从植物材料生产化合物的方法
公开(公告)号：US20050064560A1
公开(公告)日：2005-03-24
申请号：US10980927
申请日：2004-11-03
申请人： Todd Werpy , Andrew Schmidt , John Frye , Alan Zacher , James Franz , Mikhail Alnajjar , Gary Neuenschwander , Eric Alderson , Rick Orth
发明人： Todd Werpy , Andrew Schmidt , John Frye , Alan Zacher , James Franz , Mikhail Alnajjar , Gary Neuenschwander , Eric Alderson , Rick Orth
IPC分类号： C08B30/10 , C11B1/10 , C12P19/02
CPC分类号： C07C29/00 , C07C29/60 , C08B30/10 , C11B1/10 , C07C31/202 , C07C31/225 , C07C31/205
摘要： The invention includes methods of processing plant material by adding water to form a mixture, heating the mixture, and separating a liquid component from a solid-comprising component. At least one of the liquid component and the solid-comprising component undergoes additional processing. Processing of the solid-comprising component produces oils, and processing of the liquid component produces one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention includes a process of forming glycerol, ethylene glycol, lactic acid and propylene glycol from plant matter by adding water, heating and filtering the plant matter. The filtrate containing starch, starch fragments, hemicellulose and fragments of hemicellulose is treated to form linear poly-alcohols which are then cleaved to produce one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention also includes a method of producing free and/or complexed sterols and stanols from plant material.
摘要翻译：本发明包括通过加入水以形成混合物来加工植物材料的方法，加热混合物，以及从含固体组分分离液体组分。液体组分和固体组分中的至少一种经受另外的处理。固体成分组分的加工产生油，并且液体组分的加工产生甘油，乙二醇，乳酸和丙二醇中的一种或多种。本发明包括通过加水，加热和过滤植物物质从植物物质形成甘油，乙二醇，乳酸和丙二醇的方法。将含有淀粉，淀粉碎片，半纤维素和半纤维素片段的滤液处理形成线性多元醇，然后将其切割以产生甘油，乙二醇，乳酸和丙二醇中的一种或多种。本发明还包括从植物材料生产游离和/或络合的甾醇和甾烷醇的方法。

4. 发明申请

US20070135303A1 Methods of making textured catalysts 有权
标题翻译：制造织构化催化剂的方法
公开(公告)号：US20070135303A1
公开(公告)日：2007-06-14
申请号：US11651360
申请日：2007-01-08
申请人： Todd Werpy , John Frye , Yong Wang , Alan Zacher
发明人： Todd Werpy , John Frye , Yong Wang , Alan Zacher
IPC分类号： B01J23/00
CPC分类号： B01J23/44 , B01J21/06 , B01J21/063 , B01J21/066 , B01J21/18 , B01J23/40 , B01J23/464 , B01J35/04 , B01J37/0211 , B01J37/038
摘要： A textured catalyst having a hydrothermally-stable support, a metal oxide and a catalyst component is described. Methods of conducting aqueous phase reactions that are catalyzed by a textured catalyst are also described. The invention also provides methods of making textured catalysts and methods of making chemical products using a textured catalyst.
摘要翻译：描述了具有水热稳定载体，金属氧化物和催化剂组分的织构化催化剂。还描述了通过织构化催化剂催化的进行水相反应的方法。本发明还提供了制造织构化催化剂的方法和使用织构化催化剂制备化学产品的方法。

5. 发明申请

US20050065337A1 Methods of producing compounds from plant materials 有权
标题翻译：从植物材料生产化合物的方法
公开(公告)号：US20050065337A1
公开(公告)日：2005-03-24
申请号：US10980928
申请日：2004-11-03
申请人： Todd Werpy , Andrew Schmidt , John Frye , Alan Zacher , James Franz , Mikhail Alnajjar , Gary Neuenschwander , Eric Alderson , Rick Orth
发明人： Todd Werpy , Andrew Schmidt , John Frye , Alan Zacher , James Franz , Mikhail Alnajjar , Gary Neuenschwander , Eric Alderson , Rick Orth
IPC分类号： C08B30/10 , C11B1/10 , C07H1/06
CPC分类号： C07C29/00 , C07C29/60 , C08B30/10 , C11B1/10 , C07C31/202 , C07C31/225 , C07C31/205
摘要： The invention includes methods of processing plant material by adding water to form a mixture, heating the mixture, and separating a liquid component from a solid-comprising component. At least one of the liquid component and the solid-comprising component undergoes additional processing. Processing of the solid-comprising component produces oils, and processing of the liquid component produces one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention includes a process of forming glycerol, ethylene glycol, lactic acid and propylene glycol from plant matter by adding water, heating and filtering the plant matter. The filtrate containing starch, starch fragments, hemicellulose and fragments of hemicellulose is treated to form linear poly-alcohols which are then cleaved to produce one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention also includes a method of producing free and/or complexed sterols and stanols from plant material.
摘要翻译：本发明包括通过加入水以形成混合物来加工植物材料的方法，加热混合物，以及从含固体组分分离液体组分。液体组分和固体组分中的至少一种经受另外的处理。固体成分组分的加工产生油，并且液体组分的加工产生甘油，乙二醇，乳酸和丙二醇中的一种或多种。本发明包括通过加水，加热和过滤植物物质从植物物质形成甘油，乙二醇，乳酸和丙二醇的方法。将含有淀粉，淀粉碎片，半纤维素和半纤维素片段的滤液处理形成线性多元醇，然后将其切割以产生甘油，乙二醇，乳酸和丙二醇中的一种或多种。本发明还包括从植物材料生产游离和/或络合的甾醇和甾烷醇的方法。

6. 发明申请

US20070173652A1 Method of forming a dianhydrosugar alcohol 失效
标题翻译：形成二脱水糖醇的方法
公开(公告)号：US20070173652A1
公开(公告)日：2007-07-26
申请号：US11341961
申请日：2006-01-26
申请人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy , Xinjie Zhang
发明人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy , Xinjie Zhang
IPC分类号： C07D311/22
CPC分类号： C07D307/20 , C07D493/04 , Y02P20/127
摘要： The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.
摘要翻译：本发明包括生产二脱水甘油糖的方法。多元醇在第一催化剂存在下反应形成单环糖。将单环糖转移到第二反应器中，在第二反应器中，在第二催化剂的存在下将其转化为二脱水甘油醇。本发明包括形成异山梨醇的方法。在固体酸催化剂存在下，在第一温度下进行初始反应。初始反应包括使山梨醇反应生成1,4-脱水山梨糖醇，3,6-脱水山梨糖醇，2,5-甘露聚糖和2,5-己烷。利用第二温度，将1,4-脱水山梨醇和3,6-脱水山梨醇转化为异山梨醇。本发明包括从含有异山梨醇和至少一种另外的组分的混合物中纯化异山梨醇的方法。第一蒸馏从混合物中除去第一部分的异山梨醇。然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分的异山梨醇。

7. 发明申请

US20070173651A1 Two-stage dehydration of sugars 有权
标题翻译：糖两步脱水
公开(公告)号：US20070173651A1
公开(公告)日：2007-07-26
申请号：US11341930
申请日：2006-01-26
申请人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy
发明人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy
IPC分类号： C07D311/22
CPC分类号： C07D493/04
摘要： The invention includes methods for producing dianhydrosugar alcohol by providing an acid catalyst within a reactor and passing a starting material through the reactor at a first temperature. At least a portion of the staring material is converted to a monoanhydrosugar isomer during the passing through the column. The monoanhydrosugar is subjected to a second temperature which is greater than the first to produce a dianhydrosugar. The invention includes a method of producing isosorbide. An initial feed stream containing sorbitol is fed into a continuous reactor containing an acid catalyst at a temperature of less than 120° C. The residence time for the reactor is less than or equal to about 30 minutes. Sorbitol converted to 1,4-sorbitan in the continuous reactor is subsequently provided to a second reactor and is dehydrated at a temperature of at least 120° C. to produce isosorbide.
摘要翻译：本发明包括通过在反应器内提供酸催化剂并使原料在第一温度下通过反应器来生产二脱水甘油的方法。在通过色谱柱期间，至少一部分起始物质被转化为单一脱氢葡萄糖异构体。单糖酐经受大于第一温度的第二温度以产生二脱水糖。本发明包括一种生产异山梨醇的方法。含有山梨醇的初始进料流在小于120℃的温度下进料到含有酸催化剂的连续反应器中。反应器的停留时间小于或等于约30分钟。随后将连续反应器中转化为1,4-脱水山梨醇的山梨糖醇提供给第二反应器，并在至少120℃的温度下脱水以制备异山梨醇。

8. 发明申请

US20050087720A1 Deicing/anti-icing fluids 有权
标题翻译：除冰/防冰液
公开(公告)号：US20050087720A1
公开(公告)日：2005-04-28
申请号：US10833942
申请日：2004-04-28
申请人： William Samuels , H. Conkle , Bruce Monzyk , Kevin Simmons , John Frye , Todd Werpy , Sara Kuczek , Satya Chauhan
发明人： William Samuels , H. Conkle , Bruce Monzyk , Kevin Simmons , John Frye , Todd Werpy , Sara Kuczek , Satya Chauhan
IPC分类号： C09K3/18
CPC分类号： C09K3/18 , C09K3/185
摘要： A nontoxic deicing/anti-icing fluid includes a freezing point depressant selected from short chain polyols having 3 to 5 carbons atoms, and mixtures thereof, a wetting agent, an antioxidant/preservative, and water. The fluid has an LD50 greater than about 10,000 mg/L. Another deicing/anti-icing fluid includes the freezing point depressant, a vinylpyrrolidone polymer having a molecular weight between about 10,000 and about 700,000, and water. A runway deicing fluid includes glycerol, a buffer, an antioxidant/preservative, and water. Another deicing/anti-icing fluid includes a freezing point depressant having hydrophobic character, a wetting agent comprising an organophosphorus compound capable of producing an organic wettable surface, and water.
摘要翻译：无毒除冰/防冰液体包括选自具有3至5个碳原子的短链多元醇及其混合物，润湿剂，抗氧化剂/防腐剂和水的凝固点抑制剂。流体具有大于约10,000mg / L的LD 50。另一种除冰/防冰液体包括冰点抑制剂，分子量介于约10,000至约700,000之间的乙烯基吡咯烷酮聚合物和水。跑道除冰液包括甘油，缓冲剂，抗氧化剂/防腐剂和水。另一种除冰/防冰流体包括具有疏水性的凝固点抑制剂，包含能够产生有机可湿性表面的有机磷化合物的润湿剂和水。

9. 发明申请

US20140162326A1 METHODS FOR PREPARATION OF AMMONIUM SALTS OF C4 DIACIDS BY FERMENTAION AND INTEGRATED METHODS FOR MAKING C4 DERIVATIVES 审中-公开
标题翻译：通过发酵和制备C4衍生物的一体化方法制备C4 DIACIDS的氨基磺酸盐的方法
公开(公告)号：US20140162326A1
公开(公告)日：2014-06-12
申请号：US14233285
申请日：2012-07-09
申请人： ChiCheng Ma , Todd Werpy
发明人： ChiCheng Ma , Todd Werpy
IPC分类号： C07D207/267 , C07C29/149 , C07D307/33
CPC分类号： C07C51/493 , C07C29/149 , C07C51/412 , C07C51/42 , C07D207/267 , C07D307/33 , C12P7/46 , C07C55/02 , C07C57/15 , C07C59/245 , C07C55/10
摘要： Methods for forming ammonium salts of C4 diacids in a fermentation process with removal of divalent metal carbonate salts are disclosed. The pH of fermentation broths for production of C4 diacids is controlled by adding alkaline oxygen containing calcium or magnesium compounds, which forms divalent metal salts of the diacids. The divalent metal salts of the diacids are substituted with ammonium by introduction of ammonium salts at elevated temperature and pressure forming soluble ammonium salts thereof. C02 or bicarbonate is simultaneously added to the fennentation media at the elevated temperature and pressure. Reducing the temperature and pressure forms insoluble divalent metal carbonate salts that are separated from the solubilized ammonium diacid salts.
摘要翻译：公开了在除去二价金属碳酸盐的发酵过程中形成C4二酸铵盐的方法。用于生产C4二酸的发酵液的pH值通过加入形成二酸的二价金属盐的含钙或镁化合物的碱性氧来控制。二元酸的二价金属盐通过在升高的温度下引入铵盐和压力形成其可溶性铵盐而被铵取代。在升高的温度和压力下，将CO 2或碳酸氢盐同时加入到收纳介质中。降低温度和压力形成不溶性二价金属碳酸盐，其与可溶性二铵酸盐分离。

10. 发明授权

US06670483B2 Methods of making pyrrolidones 有权
公开(公告)号：US06670483B2
公开(公告)日：2003-12-30
申请号：US10280462
申请日：2002-10-25
申请人： Todd Werpy , John G. Frye, Jr. , Yong Wang , Alan H. Zacher
发明人： Todd Werpy , John G. Frye, Jr. , Yong Wang , Alan H. Zacher
IPC分类号： C07D207267
CPC分类号： C07D207/267 , C07D201/02 , C07D201/08
摘要： The present invention provides methods for making N-methylpyrrolidine and analogous compounds via hydrogenation. Novel catalysts for this process, and novel conditions/yields are also described. Other process improvements may include extraction and hydrolysis steps. Some preferred reactions take place in the aqueous phase. Starting materials for making N-methylpyrrolidine may include succinic acid, N-methylsuccinimide, and their analogs.

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