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    • 1. 发明申请
    • Functionalized nanoparticles
    • 官能化纳米粒子
    • US20090099282A1
    • 2009-04-16
    • US11920295
    • 2006-05-17
    • Martin MullerAndreas MuhlebachThomas GiesenbergDidier BauerThomas RuchFrancois RimeLeonhard FeilerRoman LenzLaurent Michau
    • Martin MullerAndreas MuhlebachThomas GiesenbergDidier BauerThomas RuchFrancois RimeLeonhard FeilerRoman LenzLaurent Michau
    • C08K5/5419C04B16/00C08K5/00
    • C09B69/103C09B67/0097C09B68/20C09B68/443C09B69/10
    • The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of formula (1), wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, R1 and R2 are independently of each other hydrogen, nanoparticle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, and Y is a radical of formula —B1-D1 (2a), wherein B1 is the direct bond or a bridge member, and D1 is a radical of a cationic dye, a radical of a phthalocyanine dye which carries no water-solubilizing group, or a radical of a fluorescent dye selected from the group consisting of coumarins, benzocoumarins, xanthenes, benzo[a]xanthenes, benzo[b]xanthenes, benzo[c]xanthenes, phenoxazines, benzo[a]phenoxazines, benzo[b]phenoxazines, benzo[c]phenoxazines, napthalimides, naphtholactams, azlactones, methines, oxazines, thiazines, diketopyrrolopyrroles, quinacridones, benzoxanthenes, thio-epindolines, lactamimides, diphenylmaleimides, acetoacetamides, imidazothiazines, benzanthrones, phthalimides, benzotriazoles, pyrimidines, pyrazines and triazines, or Y is a radical of formula —B2D2 (2b), wherein B2 is an organic radical comprising at least one group having a negative charge, and D2 is a cationic dye selected from the group consisting of monoazo, disazo, polyazo, methine, azamethine, diphenylmethane, triphenylmethane, triaminotriaryl methane, azine, oxazine, cyanine and anthraquinone dyes.
    • 本发明公开了在表面上包含式(1)的共价结合基团的官能化纳米颗粒,其中纳米颗粒是SiO 2,Al 2 O 3或混合的SiO 2和Al 2 O 3纳米颗粒,R 1和R 2彼此独立地是氢,纳米颗粒表面-O-, 或取代基,n为1,2,3,4,5,6,7或8,并且Y为式-B1-D1(2a)的基团,其中B1为直接键或桥式构件,D1为 是阳离子染料的自由基,不含水溶性基团的酞菁染料的基团,或选自香豆素,苯并香豆素,呫吨,苯并[a]呫吨,苯并[b 苯并[c]呫吨酮,苯并[c]呫吨酮,吩恶嗪,苯并[a]吩恶嗪,苯并[b]吩恶嗪,苯并[c]吩恶嗪,萘酰亚胺,萘并内酰胺,吖内酯,次甲基,恶嗪,噻嗪,二酮吡咯并吡咯,喹吖啶酮,苯并恶庚烯,硫代 - ,内酰胺,二苯基马来酰亚胺,乙酰乙酰胺,咪唑硫基 吖嗪,苯并呋喃,邻苯二甲酰亚胺,苯并三唑,嘧啶,吡嗪和三嗪,或Y是式-B2D2(2b)的基团,其中B2是包含至少一个具有负电荷的基团的有机基团,并且D2是选择的阳离子染料 来自由单偶氮,双偶氮,多偶氮,次甲基,氮杂酮,二苯基甲烷,三苯甲烷,三氨基三芳基甲烷,吖嗪,恶嗪,花青和蒽醌染料组成的组。
    • 2. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07786313B2
    • 2010-08-31
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A1和A2各自独立地为芳族或杂芳族基团,琥珀酸酯与至少一种未取代的 或取代的芳族或杂芳族腈,该方法包括在至少一种下式化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4 C 1 -C 10烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5'-,-COO-,-CONR 5 - ,-SO- ,SO 2 - ,-SO 2 NR 5 - 或-NR 5 - 以及R 5和R 5'各自独立地为氢或直链或从C3向上任选支链的C 1 -C 30烷基,C 6 -C 10芳基或C 6 -C 24芳烷基, 这样的混合物在 有机材料和化妆品着色,以及新型二酮吡咯并吡咯颜料混合物。
    • 3. 发明申请
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US20070028807A1
    • 2007-02-08
    • US10576703
    • 2004-10-04
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • C07D487/02C08K5/00
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, -0-, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及一种制备包含至少两种结构不同的式(1)二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团,通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种式(2)的化合物存在下进行反应,其中A是 芳族或杂芳族基团,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是直链或 ,C 3 - 从上至上,任选支链C 1 -C 3亚烷基,C 6 -C 10个芳基或C 6 -C 12亚芳基,X是-S-,-O-,-CR 5 R -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 - , - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,至 在有机材料和化妆品的着色中使用这种混合物,以及新型二酮吡咯并吡咯颜料混合物。
    • 4. 发明申请
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US20080287689A1
    • 2008-11-20
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • C07D487/04
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为另一个 芳族或杂芳族基团,通过琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种下式的化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是线性的,或者是C 1 -C 3 - 3个以上,任选支链C 1 -C 30烷基,C 6 -C 10芳基 或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5, -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 NR 2 - 5 - 或-NR 5 - 和R 5和R 5 - 各自独立地为另一个氢或直链或者从C 3向上,任选支链C 1 -C 30烷基, C 6 -C 12芳基或C 6 -C 24 - 芳烷基,使用这种混合物 在有机材料和化妆品的着色中,以及新型二酮吡咯并吡咯颜料混合物。
    • 5. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07417154B2
    • 2008-08-26
    • US10576703
    • 2004-10-04
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures
    • 本发明涉及一种制备包含至少两种结构不同的式(1)二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团,通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种式(2)的化合物存在下进行反应,其中A是 芳族或杂芳族基团,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是直链或 ,C 3 - 从上至上,任选支链C 1 -C 3亚烷基,C 6 -C 10个芳基或C 6 -C 2 4芳烷基,X是-S-,-O-,-CR 5 R -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 - , - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,至 在有机材料和化妆品的着色中使用这样的混合物,以及新型二酮吡咯并吡咯颜料混合物
    • 6. 发明授权
    • Red colour filter composition
    • 红色滤色片组成
    • US08273269B2
    • 2012-09-25
    • US12993095
    • 2009-05-05
    • Roman LenzGerardus De KeyzerMathias DuggeliPatrick Christopher Holzhuter
    • Roman LenzGerardus De KeyzerMathias DuggeliPatrick Christopher Holzhuter
    • G02B5/23C07D487/02C07D491/02C07D495/02C07D497/02
    • C09B57/004C09B67/0033C09B67/0039C09B69/00G02B5/223
    • A composition, for producing dispersions, thermoplastic masses and/or color filters, comprising (a) a colorant of formula (1) wherein 20-100 mol % R1 are Br and 80-100 mol % R3 are H, especially of formula (Ib) and/or (Ic); (b) from 0 to 150% by weight, based on (a), of C. I. Pigment Red 144, 188, 190, 224, 242 or 2,4,6-trimethylphenylperylene diimide; (c) from 3 to 25% by weight, based on (a), of a di- or tri-azacyclopentylmethyl-substituted colorant (formulae given); (d) from 0 to 10% by weight, preferably from 0.01 to 8% by weight, based on the sum of (a) and (b), of an additionally sulfonated colorant of the same kernels as in (c); and (e) from 0 to 30% by weight, preferably from 3 to 25% by weight, especially from 5 to 20% by weight, based on (a), of a diketopyrrolopyrrole colorant substituted by at least one chain containing a plurality of nitrogen atoms (cf. formula (V)).
    • 一种用于生产分散体,热塑性物质和/或滤色剂的组合物,其包含(a)式(1)的着色剂,其中20-100摩尔%的R 1是Br,80-100摩尔%的R 3是H,特别是式 )和/或(Ic); (b)基于(a)0-150重量%的C.I.颜料红144,188,190,224,242或2,4,6-三甲基苯基亚苯基二酰亚胺; (c)基于(a)3至25重量%的二 - 或三 - 氮杂环戊基甲基取代的着色剂(给出公式); (d)相对于(c)中相同核的另外的磺化着色剂,基于(a)和(b)的总和为0至10重量%,优选为0.01至8重量% 和(e)基于(a)0至30重量%,优选3至25重量%,特别是5至20重量%的由至少一个链取代的二酮吡咯并吡咯着色剂,所述链含有多个 氮原子(参见式(Ⅴ))。
    • 9. 发明授权
    • High-molecular-weight polymeric material comprising diketopyrrolopyrrole pigments
    • 包含二酮吡咯并吡咯颜料的高分子量聚合物材料
    • US07279514B2
    • 2007-10-09
    • US10521651
    • 2003-07-08
    • Roman LenzGerardus De KeyzerOlof WallquistTaher Yousaf
    • Roman LenzGerardus De KeyzerOlof WallquistTaher Yousaf
    • C08K5/3417C07D209/00
    • C08K5/3415C08K5/0041C09B57/004C09B67/0033Y10T428/31786
    • The present invention relates to high-molecular-weight polymeric material comprising at least one diketopyrrolopyrrole pigment of formula (1) wherein R1, is hydrogen, chlorine, methyl, methoxy, CF3 or CN, R2 is hydrogen, chlorine, methyl, methoxy, CF3 or CN, A is hydrogen, chlorine, methyl, mehtoxy, CF3, CN, unsubstituted or substituted phenyl or a radical of formula (2), (2a) or (2b), wherein R5 is hydrogen, chlorine, methyl, methoxy, nitro, CF3 or CN and R6 is hydrogen, chlorine, methyl, methoxy, nitro, CF3 or CN, or R5 and R6 together with the phenyl ring to which they are bonded form an aryl or a heteroaryl and A1 is a radical of formula (2), (2a) or (2b), to the preparation of that material and to the use thereof in colour filters, and to novel diketopyrrolopyrrole pigments.
    • 本发明涉及包含至少一种式(1)的二酮吡咯并吡咯颜料的高分子量聚合物材料,其中R 1是氢,氯,甲基,甲氧基,CF 3, SUB或CN,R 2是氢,氯,甲基,甲氧基,CF 3或CN,A是氢,氯,甲基,Mehtoxy,CF 3 CN,未取代或取代的苯基或式(2),(2a​​)或(2b)的基团,其中R 5是氢,氯,甲基,甲氧基,硝基,CF 3或CN和R 6是氢,氯,甲基,甲氧基,硝基,CF 3或CN或R 5, / SUB和R 6与它们所键合的苯环一起形成芳基或杂芳基,A 1是式(2),(2a​​)的基团 )或(2b),涉及该材料的制备及其在滤色器中的应用,以及新型二酮吡咯并吡咯颜料。