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1. 发明授权

US4130563A .DELTA.4-Oxazolin-2-ones and process therefor 失效
标题翻译： {66 4-恶唑啉-2-酮及其制备方法
公开(公告)号：US4130563A
公开(公告)日：1978-12-19
申请号：US770259
申请日：1977-02-18
申请人： Karl-Heinz Scholz , Willy Hartmann , Hans-Georg Heine
发明人： Karl-Heinz Scholz , Willy Hartmann , Hans-Georg Heine
IPC分类号： C07D263/22 , C07D263/26 , C07D263/38 , C07D263/58
CPC分类号： C07D263/58 , C07D263/22 , C07D263/26 , C07D263/38
摘要： Compounds having the formula ##STR1## wherein R is hydrogen or an acyl radical are prepared by chlorinating 3-acyl-oxazolidin-2-ones, followed by dehydrochlorination and optionally by saponification and reacylation. The compounds are useful as starting material for substitution and addition reactions and as vinyl monomers in homo- and copolymerizations, whereby oxazolidin-2-one rings containing polymers are formed. These polymers can be used as antistatic agents, dyeing auxiliaries and ion exchangers.
摘要翻译：通过氯化3-酰基 - 恶唑烷-2-酮，然后脱氯化氢并任选通过皂化和再酰化来制备具有式“IMAGE”的化合物，其中R是氢或酰基。该化合物可用作取代和加成反应的起始原料，并且可用作均聚和共聚中的乙烯基单体，由此形成含有恶唑烷-2-酮环的聚合物。这些聚合物可用作抗静电剂，染色助剂和离子交换剂。

2. 发明授权

US4238618A Process for the preparation of diacylated 4-imidazolin-2-ones 失效
标题翻译：二酰化4-咪唑啉-2-酮的制备方法
公开(公告)号：US4238618A
公开(公告)日：1980-12-09
申请号：US884520
申请日：1978-03-08
申请人： Karl-Heinz Scholz , Willy Hartmann , Hans-Georg Heine
发明人： Karl-Heinz Scholz , Willy Hartmann , Hans-Georg Heine
IPC分类号： C07D233/70 , C07D235/02 , C07D235/26
CPC分类号： C07D235/02 , C07D233/70 , C07D235/26
摘要： A process for the preparation of a diacylated 4-imidazolin-2-one of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, optionally substituted alkyl, cycloalkyl, aryl and alkoxy, which comprises contacting a compound of the formula of II ##STR2## wherein R.sup.1 and R.sup.2 of the previously assigned significance with a source of chlorine at a temperature from 20.degree. to 150.degree. C. in the presence of a radical forming agent or under ultra-violet light and thereafter dehydrohalogenating or dehalogenating the resultant chlorinated product the diacylated 4-imidazolin-2-ones prepared by the process are useful for photochemical cycloadditions and as intermediates for the preparation of compounds in the biotin series.
摘要翻译：制备式（I）的二酰化4-咪唑啉-2-酮的方法，其中R 1和R 2独立地表示氢，任选取代的烷基，环烷基，芳基和烷氧基，其包括使式的II（II）化合物，其中在自由基形成剂存在下或在紫外光下，在20至150℃的温度下，将具有氯源的先前指定的含义的R 1和R 2在脱卤化氢或脱卤化所得氯化产物，通过该方法制备的二酰化4-咪唑啉-2-酮可用于光化学环加成和作为制备生物素系列中化合物的中间体。

3. 发明授权

US4294973A Process for the preparation of diacylated 4-imidazolin-2-ones 失效
标题翻译：二酰化4-咪唑啉-2-酮的制备方法
公开(公告)号：US4294973A
公开(公告)日：1981-10-13
申请号：US101610
申请日：1979-12-10
申请人： Karl-Heinz Scholz , Willy Hartmann , Hans-Georg Heine
发明人： Karl-Heinz Scholz , Willy Hartmann , Hans-Georg Heine
IPC分类号： C07D233/70 , C07D235/02 , C07D235/26
CPC分类号： C07D235/02 , C07D233/70 , C07D235/26
摘要： A process for the preparation of a diacylated 4-imidazolin-2-one of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, optionally substituted alkyl, cycloalkyl, aryl and alkoxy, which comprises contacting a compound of the formula ##STR2## wherein R.sup.1 and R.sup.2 have the previously assigned significance with a source of chlorine at a temperature from 20.degree. to 150.degree. C. in the presence of a radical forming agent or under ultra-violet light and thereafter dehydrohalogenating or dehalogenating the resultant chlorinated product.The diacylated 4-imidazolin-2-ones prepared by the process are useful for photochemical cycloadditions and as intermediates for the preparation of compounds in the biotin series.
摘要翻译：制备式（I）的二酰化4-咪唑啉-2-酮的方法，其中R 1和R 2独立地表示氢，任选取代的烷基，环烷基，芳基和烷氧基，其包括使式（II）其中R1和R2在自由基形成剂存在下或在紫外光下在20℃至150℃的温度下具有预先给出的氯源，然后脱卤化氢或脱卤得到的氯化产物。通过该方法制备的二酰化4-咪唑啉-2-酮可用于光化学环加成和作为制备生物素系列中化合物的中间体。

4. 发明授权

US4288370A Halogenovinyl-substituted tetra-hydrofuran-2-ones 失效
标题翻译：卤代乙烯基取代的四氢呋喃-2-酮
公开(公告)号：US4288370A
公开(公告)日：1981-09-08
申请号：US89344
申请日：1979-10-30
申请人： Hans-Georg Heine , Armin Hubner , Willy Hartmann
发明人： Hans-Georg Heine , Armin Hubner , Willy Hartmann
IPC分类号： C07C49/687 , C07C49/693 , C07D307/33 , C07D307/94 , C07D307/32
CPC分类号： C07D307/33 , C07C49/687 , C07C49/693 , C07D307/94
摘要： Halogenovinyl-substituted tetrahydrofuran-2-ones of the formula ##STR1## are prepared by reacting a peracid such as peracetic, perpropionic or m-chloroperbenzoic acid with a halogenvinyl-substituted cyclobutanene of the formula ##STR2## in which R.sup.1 to R.sup.8 can be hydrogen, halogen, cyano or various organic radicals, or in pairs can make up a ring. Products wherein R.sup.3 is not hydrogen or R.sup.1 is not halogen are new. The products are useful as intermediates in making insecticides.
摘要翻译：通过使过酸如过乙酸，过丙酸或间氯过苯甲酸与式为“IMAGE”的卤代乙烯基取代的环丁腈反应制备式“IMAGE”的卤代乙烯基取代的四氢呋喃-2-酮，其中R 1至R 8可以是氢，卤素，氰基或各种有机基团，或成对可以构成环。 R3不是氢或R1不是卤素的产物是新的。该产品可用作制造杀虫剂的中间体。

5. 发明授权

US4252738A 1,2-Halohydrincarboxylic acid esters and a process for their preparation 失效
标题翻译： 1,2-卤代羧酸羧酸酯及其制备方法
公开(公告)号：US4252738A
公开(公告)日：1981-02-24
申请号：US887900
申请日：1978-03-17
申请人： Willy Hartmann , Hans-Georg Heine
发明人： Willy Hartmann , Hans-Georg Heine
IPC分类号： C07C69/013 , B01J23/00 , B01J31/00 , C07B61/00 , C07C45/54 , C07C67/00 , C07C253/00 , C07C255/46 , C07D317/44 , C07C120/00 , C07C69/12 , C07C69/74 , C07C69/78
CPC分类号： C07D317/44 , C07C45/54
摘要： 1,2-Halohydrincarboxylic acid esters of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are identical or different and represent hydrogen, cyano and optionally substituted alkyl, alkenyl, aralkyl, aryl, alkoxycarbonyl, acyloxy, alkoxy and aryloxy, and furthermoreR.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4, or R.sup.1 and R.sup.3 and/or R.sup.2 and R.sup.4 can be linked, forming a ring with the carbon atoms to which they are bonded;R.sup.5 represents hydrogen and optionally substituted alkyl, alkenyl, aralkyl, aryl, alkoxy and alkoxycarbonyl andX represents fluorine, chlorine, bromine and iodine; a process for preparing such 1,2-halohydrincarboxylic acid esters by reacting a cyclobutane-cis-1,2-diol of the formula ##STR2## with an orthoester of the formula ##STR3## wherein R.sup.1 -R.sup.5 have the previously ascribed significance and R.sup.6 -R.sup.8 are identical or different and represent optionally substituted alkyl, alkenyl, aralkyl and aryl, (or a ketene-acetal corresponding thereto) to give a 1,3-dioxolane and reacting the resultant 1,3-dioxolane with a halogenosilane or an acid halide. Also disclosed is a process for preparing compounds of the formula ##STR4## by contacting a 1,2-halohydrin ester of the formula given above with a base suitably at a temperature of 20.degree. to 150.degree. C.
摘要翻译：式（I）的其中R 1，R 2，R 3和R 4相同或不同并表示氢，氰基和任选取代的烷基，烯基，芳烷基，芳基，烷氧基羰基，酰氧基，烷氧基的1,2-卤代羧酸羧酸酯和芳氧基，此外，R 1和R 2和/或R 3和R 4，或R 1和R 3和/或R 2和R 4可以连接，与它们所键合的碳原子形成环; R5表示氢和任选取代的烷基，烯基，芳烷基，芳基，烷氧基和烷氧基羰基，X表示氟，氯，溴和碘; 通过使式（II）的环丁烷 - 顺-1,2-二醇与式（III）的原酸酯反应制备这种1,2-卤代醇羧酸酯的方法，其中R1-R5具有以前的含义和R6-R8相同或不同，表示任选取代的烷基，烯基，芳烷基和芳基（或与其对应的乙烯酮缩醛），得到1,3-二氧戊环并使所得1,3-二氧戊环与卤代硅烷或酰卤。还公开了通过使上述式I的1,2-卤代醇与碱适宜地在20-150℃的温度下接触来制备式（V）的化合物的方法。

6. 发明授权

US4225704A Preparation of halogenovinyl-substituted tetra-hydrofuran-2-ones 失效
标题翻译：卤代乙烯基取代的四氢呋喃-2-酮的制备
公开(公告)号：US4225704A
公开(公告)日：1980-09-30
申请号：US936988
申请日：1978-08-25
申请人： Hans-Georg Heine , Armin Hubner , Willy Hartmann
发明人： Hans-Georg Heine , Armin Hubner , Willy Hartmann
IPC分类号： C07C49/687 , C07C49/693 , C07D307/33 , C07D307/94 , C07D307/20
CPC分类号： C07D307/33 , C07C49/687 , C07C49/693 , C07D307/94
摘要： Halogenovinyl-substituted tetrahydrofuran-2-ones of the formula ##STR1## are prepared by reacting a peracid such as peracetic, perpropionic or m-chloroperbenzoic acid with a halogenvinyl-substituted cyclobutanone of the formula ##STR2## in which R.sup.1 to R.sup.8 can be hydrogen, halogen, cyano or various organic radicals, or in pairs can make up a ring.Products wherein R.sup.3 is not hydrogen or R.sup.1 is not halogen are new. The products are useful as intermediates in making insecticides.
摘要翻译：通过使过酸如过乙酸，过丙酸或间氯过苯甲酸与式（IMAGE）的卤素乙烯基取代的环丁酮反应制备式IMAMA的卤代乙烯基取代的四氢呋喃-2-酮，其中R 1至R 8可以是氢，卤素，氰基或各种有机基团，或成对可以构成环。 R3不是氢或R1不是卤素的产物是新的。该产品可用作制造杀虫剂的中间体。

7. 发明授权

US4529813A Production of insecticidally active vinyl-cyclopropane carboxylic acid esters 失效
标题翻译：杀虫活性乙烯基 - 环丙烷羧酸酯的生产
公开(公告)号：US4529813A
公开(公告)日：1985-07-16
申请号：US130506
申请日：1980-03-14
申请人： Hans-Georg Heine , Willy Hartmann
发明人： Hans-Georg Heine , Willy Hartmann
IPC分类号： C07C69/743 , A01N53/00 , A01N53/10 , C07C45/00 , C07C45/51 , C07C45/63 , C07C45/68 , C07C45/76 , C07C49/457 , C07C49/647 , C07C49/687 , C07C49/693 , C07C49/697 , C07C51/00 , C07C61/35 , C07C61/40 , C07C62/08 , C07C67/00 , C07C69/74 , C07C233/10 , C07C233/38 , C07C255/45 , C07C313/00 , C07C317/44 , C07C67/02 , C07C69/02
CPC分类号： C07C255/31 , A01N53/00 , C07C45/00 , C07C45/516 , C07C45/63 , C07C45/68 , C07C45/76 , C07C49/687 , C07C49/693 , C07C49/697 , C07C51/00 , C07C61/40 , C07C62/08 , C07C67/42 , C07C2101/02 , C07C2101/04 , C07C2101/14 , C07C2102/50
摘要： Insecticidally active vinyl-cyclopropane carboxylic acid esters of the formula ##STR1## are prepared by reacting ##STR2## in which R.sup.12 is a radical selected from the group consisting of ##STR3## with an alcoholate of the formulaM--O--R.sup.8.Various processes for making the intermediates are also described. Many of the intermediates and end products are new.
摘要翻译：式（I）的杀虫活性乙烯基 - 环丙烷羧酸酯通过使其中R12是选自下列基团的基团与式M-O-R8的醇化物反应的“IMAGE”制备。还描述了制备中间体的各种方法。许多中间体和最终产品都是新的。

8. 发明授权

US4291176A Production of insecticidally active vinyl-cyclopropane carboxylic acid esters 失效
标题翻译：杀虫活性乙烯基 - 环丙烷羧酸酯的生产
公开(公告)号：US4291176A
公开(公告)日：1981-09-22
申请号：US827514
申请日：1977-08-24
申请人： Hans-Georg Heine , Willy Hartmann
发明人： Hans-Georg Heine , Willy Hartmann
IPC分类号： C07C69/743 , A01N53/00 , A01N53/10 , C07C45/00 , C07C45/51 , C07C45/63 , C07C45/68 , C07C45/76 , C07C49/457 , C07C49/647 , C07C49/687 , C07C49/693 , C07C49/697 , C07C51/00 , C07C61/35 , C07C61/40 , C07C62/08 , C07C67/00 , C07C69/74 , C07C233/10 , C07C233/38 , C07C255/45 , C07C313/00 , C07C317/44 , C07C49/27 , C07C49/45 , C07C49/533 , C07C49/54 , C07C49/80
CPC分类号： C07C255/31 , A01N53/00 , C07C45/00 , C07C45/516 , C07C45/63 , C07C45/68 , C07C45/76 , C07C49/687 , C07C49/693 , C07C49/697 , C07C51/00 , C07C61/40 , C07C62/08 , C07C67/42 , C07C2101/02 , C07C2101/04 , C07C2101/14 , C07C2102/50
摘要： Insecticidally active vinyl-cyclopropane carboxylic acid esters of the formula ##STR1## are prepared by reacting ##STR2## in which R.sup.12 is a radical selected from the group consisting of ##STR3## with an alcoholate of the formulaM--O--R.sup.8.Various processes for making the intermediates are also described. Many of the intermediates and end products are new.
摘要翻译：式（I）的杀虫活性乙烯基 - 环丙烷羧酸酯通过使其中R12是选自下列基团的基团与式M-O-R8的醇化物反应的“IMAGE”制备。还描述了制备中间体的各种方法。许多中间体和最终产品都是新的。

9. 发明授权

US4216172A Preparation of cyclobutanones 失效
标题翻译：环丁酮的制备
公开(公告)号：US4216172A
公开(公告)日：1980-08-05
申请号：US886229
申请日：1978-03-13
申请人： Hans-Georg Heine , Willy Hartmann
发明人： Hans-Georg Heine , Willy Hartmann
IPC分类号： C07C49/385 , C07C45/00 , C07C45/51 , C07C49/587 , C07C67/00 , C07C69/757 , C07C231/00 , C07C231/12 , C07C235/82 , C07C253/00 , C07C255/46 , C07C255/56 , C07F9/38 , C07F9/40 , C07C45/02
CPC分类号： C07C45/516
摘要： A process for the preparation of a cyclobutanone of the formula ##STR1## in which R.sup.1 to R.sup.6 each independently is a hydrogen, halogen, cyano, alkoxy, alkoxycarbonyl, carboxamido, dialkylphosphono, alkyl, cycloalkyl, aryl, aralkyl or alkenyl radical, or two of them together with the carbon atom to which each is linked form a ring,comprising reacting an N,N-disubstituted carboxylic acid amide of the formula ##STR2## in which R.sup.7 and R.sup.8 each independently is an alkyl, cycloalkyl, alkenyl, aryl or aralkyl radical or together form a ring, with an inorganic acid halide, and then reacting the product with a tertiary amine, an olefin of the formula ##STR3## and a Lewis acid, and subsequently hydrolyzing the mass. Preferably isobutyric acid dimethylamide is employed as the carboxylic acid amide, phosgene is employed as the inorganic acid halide, triethylamine is employed as the tertiary amine and zinc chloride or titanium tetrachloride is employed as the Lewis acid. The products are known intermediates for insecticides.
摘要翻译：制备式“IMAGE”的环丁酮的方法，其中R 1至R 6各自独立地为氢，卤素，氰基，烷氧基，烷氧基羰基，甲酰氨基，二烷基膦酰基，烷基，环烷基，芳基，芳烷基或烯基，或两个它们与各自连接的碳原子一起形成环，包括使式“IMAGE”的N，N-二取代的羧酸酰胺与其中R 7和R 8各自独立地为烷基，环烷基，烯基，芳基或芳烷基或与无机酰卤一起形成环，然后使产物与叔胺，式“IMAGE”的烯烃和路易斯酸反应，随后水解该物质。优选使用异丁酸二甲基酰胺作为羧酸酰胺，光气用作无机酰卤，三乙胺用作叔胺，氯化锌或四氯化钛用作路易斯酸。该产品是已知的杀虫剂中间体。

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