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    • 9. 发明授权
    • Methods of making composite aluminum nitride ceramic articles having
embedded filler
    • 制备具有嵌入填料的复合氮化铝陶瓷制品的方法
    • US5420085A
    • 1995-05-30
    • US7387
    • 1993-01-21
    • Marc S. NewkirkHarry R. ZwickerAndrew W. UrquhartHarold D. LesherTerry D. ClaarMichael K. AghajanianJohn P. Biel, Jr.
    • Marc S. NewkirkHarry R. ZwickerAndrew W. UrquhartHarold D. LesherTerry D. ClaarMichael K. AghajanianJohn P. Biel, Jr.
    • C04B35/65C04B35/76C04B35/80C04B41/50C04B41/87C04B35/58
    • C04B41/5025C04B35/652C04B35/76C04B35/80C04B41/87
    • A method of making self-supporting ceramic composite structures having filler embedded therein includes infiltrating a permeable mass of filler with polycrystalline material comprising an oxidation reaction product obtained by oxidation of a parent metal such as aluminum and optionally, containing therein non-oxidized constituents of the parent metal. The structure is formed by placing a parent metal adjacent to a permeable filler and heating the assembly to melt the parent metal and provide a molten body of parent metal which is contacted with a suitable vapor-phase oxidant. Within a certain temperature region and optionally, aided by one or more dopants in or on the parent metal, molten parent metal will migrate through previously formed oxidation reaction product into contact with the oxidant, causing the oxidation reaction product to grow so as to embed the adjacent filler and provide the composite structure. In a preferred embodiment, a parent metal comprising aluminum is oxidized by a vapor-phase oxidant comprising nitrogen to form a ceramic matrix comprising an aluminum nitride oxidation reaction product. In a particularly preferred embodiment, one or more protective coatings are applied to the filler prior to formation of the aluminum nitride oxidation reaction product matrix.
    • 制造具有嵌入其中的填料的自支撑陶瓷复合结构的方法包括用多晶材料渗透可渗透的填料,所述多晶材料包含通过氧化母体金属如铝而获得的氧化反应产物,并且任选地含有其中的非氧化成分 母金属。 通过将母体金属放置在可渗透填料附近并加热该组件以熔化母体金属并提供与合适的气相氧化剂接触的母体金属的熔融体来形成结构。 在一定温度范围内,任选地,由母体金属中或母体金属上的一种或多种掺杂剂辅助,熔融母体金属将迁移通过预先形成的氧化反应产物与氧化剂接触,使氧化反应产物生长,从而嵌入 相邻填料并提供复合结构。 在优选的实施方案中,包含铝的母体金属被包含氮的气相氧化剂氧化以形成包含氮化铝氧化反应产物的陶瓷基体。 在特别优选的实施方案中,在形成氮化铝氧化反应产物基质之前,将一种或多种保护性涂料施加到填料上。