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1. 发明授权

US09433929B2 Mixed metal oxide catalysts 有权
公开(公告)号：US09433929B2
公开(公告)日：2016-09-06
申请号：US13200219
申请日：2011-09-21
申请人： James F. Brazdil , Mark A. Toft , Stephen T. McKenna
发明人： James F. Brazdil , Mark A. Toft , Stephen T. McKenna
IPC分类号： B01J27/19 , B01J23/887 , B01J37/03 , B01J23/00 , B01J35/00 , C07C253/26 , B01J21/08 , B01J37/00
CPC分类号： C07C253/26 , B01J21/08 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/0045 , B01J37/031 , B01J2523/00 , G01N23/20 , Y02P20/52 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/41 , C07C255/08
摘要： Catalytic compositions are provided that are effective for providing increased acrylonitrile product without a significant decrease in hydrogen cyanide and/or acetonitrile production and provide an overall increase in production of acrylonitrile, hydrogen cyanide and acetonitrile. The catalytic compositions include a complex of metal oxides and include at least about 15% m-phase plus t-phase by weight and have a weight ratio of m-phase to m-phase plus t-phase of 0.45 or greater.

2. 发明授权

US09550729B2 Mixed metal oxide catalysts 有权
标题翻译：混合金属氧化物催化剂
公开(公告)号：US09550729B2
公开(公告)日：2017-01-24
申请号：US15225956
申请日：2016-08-02
申请人： James F. Brazdil , Mark A. Toft , Stephen T. McKenna
发明人： James F. Brazdil , Mark A. Toft , Stephen T. McKenna
IPC分类号： C07C253/26 , B01J23/00 , B01J23/887 , G01N23/20
CPC分类号： C07C253/26 , B01J21/08 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/0045 , B01J37/031 , B01J2523/00 , G01N23/20 , Y02P20/52 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/41 , C07C255/08
摘要： Catalytic compositions are provided that are effective for providing increased acrylonitrile product without a significant decrease in hydrogen cyanide and/or acetonitrile production and provide an overall increase in production of acrylonitrile, hydrogen cyanide and acetonitrile. The catalytic compositions include a complex of metal oxides and include at least about 15% m-phase plus t-phase by weight and have a weight ratio of m-phase to m-phase plus t-phase of 0.45 or greater.
摘要翻译：提供催化组合物，其对于提供增加的丙烯腈产物是有效的，而不显着降低氰化氢和/或乙腈生产，并提供丙烯腈，氰化氢和乙腈的总体生产增加。催化剂组合物包括金属氧化物的复合物，并且包括至少约15％的m相加上t相，并且m相与m相加上t相的重量比为0.45以上。

3. 发明申请

US20130072710A1 Mixed metal oxide catalysts 有权
标题翻译：混合金属氧化物催化剂
公开(公告)号：US20130072710A1
公开(公告)日：2013-03-21
申请号：US13200219
申请日：2011-09-21
申请人： James F. Brazdil , Mark A. Toft , Stephen T. McKenna
发明人： James F. Brazdil , Mark A. Toft , Stephen T. McKenna
IPC分类号： C07C253/30 , B01J21/10 , G01N23/20 , B01J23/887
CPC分类号： C07C253/26 , B01J21/08 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/0045 , B01J37/031 , B01J2523/00 , G01N23/20 , Y02P20/52 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/41 , C07C255/08
摘要： Catalytic compositions are provided that are effective for providing increased acrylonitrile product without a significant decrease in hydrogen cyanide and/or acetonitrile production and provide an overall increase in production of acrylonitrile, hydrogen cyanide and acetonitrile. The catalytic compositions include a complex of metal oxides and include at least about 15% m-phase plus t-phase by weight and have a weight ratio of m-phase to m-phase plus t-phase of 0.45 or greater.
摘要翻译：提供催化组合物，其对于提供增加的丙烯腈产物是有效的，而不显着降低氰化氢和/或乙腈生产，并提供丙烯腈，氰化氢和乙腈的总体生产增加。催化剂组合物包括金属氧化物的复合物，并且包括至少约15％的m相加上t相，并且m相与m相加上t相的重量比为0.45以上。

4. 发明申请

US20080139423A1 Preparation of Monomers for Grafting to Polyolefins, and Lubricationg Oil Compositions Containing Graft Copolymer 有权
标题翻译：用于接枝到聚烯烃的单体的制备和含有接枝共聚物的润滑油组合物
公开(公告)号：US20080139423A1
公开(公告)日：2008-06-12
申请号：US12029277
申请日：2008-02-11
申请人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
发明人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
IPC分类号： C10M159/12 , C10M169/04
CPC分类号： C10M159/12 , C08F8/30 , C08F8/32 , C08F255/00 , C08F255/02 , C08F255/06 , C08L51/06 , C10M133/56 , C10M149/06 , C10M149/10 , C10M2205/02 , C10M2205/04 , C10M2215/285 , C10M2217/024 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2240/10 , C10N2270/00 , C08F10/00 , C08L2666/02
摘要： A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts. Also described is a lubricating oil comprising a base oil and a grafted polyolefin as described above.
摘要翻译：公开了含有一种或多种接枝到聚烯烃上的烯属不饱和的，脂族或芳族的含氮和氧的可接枝单体的接枝共聚物。新单体，制备这种单体的方法和包含这些单体的接枝共聚物是基于酰化剂与胺的反应形成反应产物。反应产物可以包括由酰化剂和胺的组合形成的多于一种的化合物。单体是反应产物的可接枝的，烯属不饱和的，脂族或芳族的含氮和氧的化合物。单体可以但不必从产物混合物中回收。优选的单体是马来酸酐和4-氨基二苯胺的反应产物。还描述了制备分散剂粘度指数改进剂的方法。本发明的单体可以以溶液或熔体接枝到聚烯烃上。还描述了包含如上所述的基础油和接枝聚烯烃的润滑油。

5. 发明授权

US5084259A Crystalline nickel aluminum borates 失效
标题翻译：结晶镍铝硼酸盐
公开(公告)号：US5084259A
公开(公告)日：1992-01-28
申请号：US669903
申请日：1991-03-15
申请人： Larry C. Satek , Stephen T. McKenna , Vincent F. Smith, Jr.
发明人： Larry C. Satek , Stephen T. McKenna , Vincent F. Smith, Jr.
IPC分类号： B01J23/75 , B01J23/755 , B01J29/04 , C01B35/12 , C07C45/41 , C07C51/265
CPC分类号： C07C51/265 , B01J23/75 , B01J23/755 , B01J29/04 , C01B35/128 , C07C45/41
摘要： The preparation, structure, and properties of solid inorganic materials containing aluminum, boron, oxygen and at least one Group VIII metallo element, selected from the group consisting of cobalt and nickel is described. Also described in the use of such materials in catalytic compositions for the conversion of organic compounds. In particular, the new materials having the general formula:(x) (M.sub.m :M'.sub.n)O.(y)Al.sub.2 O.sub.3.(z)B.sub.2 O.sub.3where M and M' are metallo elements selected from the group consisting of nickel and cobalt, m and n are numbers from 0 to 1 inclusive, such that m+n=1, and x, y and z are numbers representing molar amounts of the oxides are described as well as the use of such materials in various catalyzed processes including hydrogenation of hydrocarbons and oxygen containing hydrocarbons, dehydrogenation to functionalize alkylaromatic compounds, isomerization of alkylaromatic compounds, oligomerization of olefins, and oxidation of hydrocarbons and oxygen containing hydrocarbons.
摘要翻译：描述了选自钴和镍的含有铝，硼，氧和至少一种第Ⅷ族金属元素的固体无机材料的制备，结构和性能。还描述了在用于转化有机化合物的催化组合物中使用这种材料。特别是具有以下通式的新材料：（x）（Mm：M'n）O.（y）Al2O3。（z）B2O3其中M和M'是选自镍和钴的金属元素， m和n是从0到1的数字，其中m + n = 1，x，y和z是表示氧化物的摩尔数的数字，以及这些材料在各种催化方法中的应用，包括氢化烃和含氧烃，脱氢以官能化烷基芳族化合物，烷基芳族化合物的异构化，烯烃的低聚和烃和含氧烃的氧化。

6. 发明授权

US4801571A Catalyst and process for production of an alpha, beta-ethylenically unsaturated monocarboxylic acid 失效
标题翻译：用于生产α，β-烯属不饱和一元羧酸的催化剂和方法
公开(公告)号：US4801571A
公开(公告)日：1989-01-31
申请号：US71476
申请日：1987-07-09
申请人： Ruth A. Montag , Stephen T. McKenna
发明人： Ruth A. Montag , Stephen T. McKenna
IPC分类号： B01J35/10 , B01J23/14 , C07B61/00 , C07C51/00 , C07C51/353 , C07C57/04 , C07C67/00
CPC分类号： C07C51/353 , B01J23/14
摘要： A catalyst and process for production of an alpha, beta-ethylenically unsaturated monocarboxylic acid made by condensing formaldehyde with, for example, propionic acid, which catalyst is made from a SiO.sub.2 -SnO.sub.2 mixed-oxide component consisting of porous silica gel and tin (IV) oxide and a cesium ion component.

7. 发明授权

US07981847B2 Preparation of monomers for grafting to polyolefins, and lubricating oil compositions containing graft copolymer 有权
标题翻译：用于接枝到聚烯烃上的单体的制备和含有接枝共聚物的润滑油组合物
公开(公告)号：US07981847B2
公开(公告)日：2011-07-19
申请号：US12029277
申请日：2008-02-11
申请人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
发明人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
IPC分类号： C10M149/00 , C10M159/12 , C08F8/04
CPC分类号： C10M159/12 , C08F8/30 , C08F8/32 , C08F255/00 , C08F255/02 , C08F255/06 , C08L51/06 , C10M133/56 , C10M149/06 , C10M149/10 , C10M2205/02 , C10M2205/04 , C10M2215/285 , C10M2217/024 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2240/10 , C10N2270/00 , C08F10/00 , C08L2666/02
摘要： A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts. Also described is a lubricating oil comprising a base oil and a grafted polyolefin as described above.
摘要翻译：公开了含有一种或多种接枝到聚烯烃上的烯属不饱和的，脂族或芳族的含氮和氧的可接枝单体的接枝共聚物。新单体，制备这种单体的方法和包含这些单体的接枝共聚物是基于酰化剂与胺的反应形成反应产物。反应产物可以包括由酰化剂和胺的组合形成的多于一种的化合物。单体是反应产物的可接枝的，烯属不饱和的，脂族或芳族的含氮和氧的化合物。单体可以但不必从产物混合物中回收。优选的单体是马来酸酐和4-氨基二苯胺的反应产物。还描述了制备分散剂粘度指数改进剂的方法。本发明的单体可以以溶液或熔体接枝到聚烯烃上。还描述了包含如上所述的基础油和接枝聚烯烃的润滑油。

8. 发明授权

US07371713B2 Preparation of monomers for grafting to polyolefins, and lubricating oil compositions containing grafted copolymer 有权
标题翻译：制备用于接枝到聚烯烃上的单体，以及含有接枝共聚物的润滑油组合物
公开(公告)号：US07371713B2
公开(公告)日：2008-05-13
申请号：US10444548
申请日：2003-05-23
申请人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
发明人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
IPC分类号： C10M159/12 , C08F255/00
CPC分类号： C10M159/12 , C08F8/30 , C08F8/32 , C08F255/00 , C08F255/02 , C08F255/06 , C08L51/06 , C10M133/56 , C10M149/06 , C10M149/10 , C10M2205/02 , C10M2205/04 , C10M2215/285 , C10M2217/024 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2240/10 , C10N2270/00 , C08F10/00 , C08L2666/02
摘要： A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts. Also described is a lubricating oil comprising a base oil and a grafted polyolefin as described above.
摘要翻译：公开了含有一种或多种接枝到聚烯烃上的烯属不饱和的，脂族或芳族的含氮和氧的可接枝单体的接枝共聚物。新单体，制备这种单体的方法和包含这些单体的接枝共聚物是基于酰化剂与胺的反应形成反应产物。反应产物可以包括由酰化剂和胺的组合形成的多于一种的化合物。单体是反应产物的可接枝的，烯属不饱和的，脂族或芳族的含氮和氧的化合物。单体可以但不必从产物混合物中回收。优选的单体是马来酸酐和4-氨基二苯胺的反应产物。还描述了制备分散剂粘度指数改进剂的方法。本发明的单体可以以溶液或熔体接枝到聚烯烃上。还描述了包含如上所述的基础油和接枝聚烯烃的润滑油。

9. 发明申请

US20120323018A1 Preparation of Monomers for Grafting to Polyolefins, and Lubricating Oil Compositions Containing Grafted Copolymer 审中-公开
标题翻译：用于接枝到聚烯烃的单体的制备和含有接枝共聚物的润滑油组合物
公开(公告)号：US20120323018A1
公开(公告)日：2012-12-20
申请号：US13164374
申请日：2011-06-20
申请人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
发明人： Irwin L. Goldblatt , Shean-Jer Chen , Manish R. Patel , Stephen T. McKenna
IPC分类号： C07D207/40 , C07C63/00
CPC分类号： C07D207/40
摘要： A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of malcic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts. Also described is a lubricating oil comprising a base oil and a grafted polyolefin as described above.
摘要翻译：公开了含有一种或多种接枝到聚烯烃上的烯属不饱和的，脂族或芳族的含氮和氧的可接枝单体的接枝共聚物。新单体，制备这种单体的方法和包含这些单体的接枝共聚物是基于酰化剂与胺的反应形成反应产物。反应产物可以包括由酰化剂和胺的组合形成的多于一种的化合物。单体是反应产物的可接枝的，烯属不饱和的，脂族或芳族的含氮和氧的化合物。单体可以但不必从产物混合物中回收。优选的单体是苹果酸酐和4-氨基二苯胺的反应产物。还描述了制备分散剂粘度指数改进剂的方法。本发明的单体可以以溶液或熔体接枝到聚烯烃上。还描述了包含如上所述的基础油和接枝聚烯烃的润滑油。

10. 发明授权

US5264407A Crystalline metalloaluminum borates 失效
标题翻译：结晶金属硼酸硼酸盐
公开(公告)号：US5264407A
公开(公告)日：1993-11-23
申请号：US804801
申请日：1991-12-09
申请人： Larry C. Satek , Stephen T. McKenna , Vincent F. Smith, Jr.
发明人： Larry C. Satek , Stephen T. McKenna , Vincent F. Smith, Jr.
IPC分类号： B01J23/75 , B01J23/755 , B01J29/04 , C01B35/12 , C07C45/41 , C07C51/265 , B01J21/02
CPC分类号： B01J29/04 , B01J23/75 , B01J23/755 , C01B35/128 , C07C45/41 , C07C51/265
摘要： The preparation, structure, and properties of solid inorganic materials containing aluminum, boron, oxygen and at least one Group VIII metallo element, selected from the group consisting of cobalt and nickel is described. Also described is the use of such materials in catalytic compositions for the conversion of organic compounds. In particular, the new materials having the general formula:(x)(M.sub.m :M'.sub.n)O.(y)Al.sub.2 O.sub.3.(z)B.sub.2 O.sub.3where M and M' are metallo elements selected from the group consisting of nickel and cobalt, m and n are numbers form 0 to 1, inclusive, such that m+n=1, and x, y and z are numbers representing molar amounts of the oxides are described as well as the use of such materials in various catalyzed processes including hydrogenation of hydrocarbons and oxygen containing hydrocarbons, dehydrogenation to functionalize alkylaromatic compounds, isomerization of alkylaromatic compounds, oligomerization of olefins, and oxidation of hydrocarbons and oxygen containing hydrocarbons.
摘要翻译：描述了选自钴和镍的含有铝，硼，氧和至少一种第Ⅷ族金属元素的固体无机材料的制备，结构和性能。还描述了这样的材料在催化组合物中用于有机化合物转化的用途。特别是具有以下通式的新材料：（x）（Mm：M'n）O.（y）Al2O3。（z）B2O3其中M和M'是选自镍和钴的金属元素， m和n是0至1的数字，包括端值，使得m + n = 1，x，y和z是表示氧化物摩尔量的数字，以及这些材料在各种催化方法中的应用，包括氢化的烃和含氧烃，脱氢以官能化烷基芳族化合物，烷基芳族化合物的异构化，烯烃的低聚和烃和含氧烃的氧化。

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