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    • 5. 发明专利
    • PREPARATION OF HIGH CHLORIDE (100) FLAT PLATE-LIKE PARTICLE EMULSION
    • JPH11218864A
    • 1999-08-10
    • JP33233398
    • 1998-11-24
    • EASTMAN KODAK CO
    • MASKASKY JOE ESCACCIA VICTOR P
    • G03C1/015G03C1/005G03C1/035
    • PROBLEM TO BE SOLVED: To obtain the 100} flat plate-like silver halide particles high in average aspect ratio and reduced in thickness in the optimum conditions and high in ratio of the projection areas of the flat plate-like particles to those of the total particles by specifying the ratio of an iodide to bromide at the time of conversion of halides. SOLUTION: In a process I, silver halide particle nuclei groups having crystal lattice dislocation lines for promoting growth of high chloride (100) flat plate-like particle nuclei groups occupying 1-10 mol.% of the total silver halide particles are formed in the dispersion medium. In a process II, silver ions, and halide ions in an amount of >50 mol.% of silver ions are introduced into the dispersion medium to grow the high chloride 100} flat plate-like porticles. In process I, precipitation of the silver halide particle nuclei is started in the dispersion medium, and iodide ions and bromide ions are introduced in a I /Br molar ratio 1×10 :1-5×10 :1 to substitute them for the precipitated chloride, and then, precipitation of the particle nuclei are finished by introducing additional sliver ions and additional halide ions.