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    • 8. 发明专利
    • GAS DETECTING DEVICE
    • JP2001074692A
    • 2001-03-23
    • JP25449199
    • 1999-09-08
    • NIPPON SOKENDENSO CORP
    • MIZUTANI KEIGOIMAMURA HIROOMAKINO TASUKEKAWACHI HIDEOMI
    • G01N27/409G01N27/416
    • PROBLEM TO BE SOLVED: To detect the total concentration of NOx to which NO and NO2 are added in a gas detecting device wherein a sensor cell comprising a measur ing electrode and a reference electrode which are installed so as to be adjacent to an oxygen-ion-conductive solid electrolyte material is provided and the concen tration of oxygen nitrides in an exhaust gas is detected on the basis of an electromotive force which is generated across the measuring electrode and the reference electrode. SOLUTION: A catalyst 7 by which the reversible reaction of NO with NO2 in an exhaust gas reaching a sensor cell 2 is set to an equilibrium state is installed on the upstream side of the exhaust gas from the sensor cell 2. By the catalyst 7, the reversible reaction NO with NO2 in the exhaust gas reaching the measuring electrode 21 of the sensor cell 2 is set to the equilibrium state, and the concentration of NO2 in the equilibrium state is detected by the sensor cell 2. The concentration of O2 in the exhaust gas is detected by an oxygen- concentration detecting cell 3. On the basis of the two detected concentrations and on the basis of the equilibrium constant, of the reversible reaction, which can be found in advance, the total concentration of NOx is found.