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    • 2. 发明申请
    • 1-ALKENE-ACRYLATE BASED COPOLYMER
    • WO2007105896A1
    • 2007-09-20
    • PCT/KR2007/001209
    • 2007-03-13
    • LG CHEM, LTD.JUNG, Yoo-YoungJEON, Byoung-HoSHIN, Bae-KunLEE, Ki-SooHAN, Yong-Gyu
    • JUNG, Yoo-YoungJEON, Byoung-HoSHIN, Bae-KunLEE, Ki-SooHAN, Yong-Gyu
    • C08F220/10C08F210/00
    • C08F222/10C08F210/02C08F220/12C08F220/14C08F220/18C08F210/14
    • The present invention provides 1-alkene-acrylate based copolymer prepared by a method comprising step of a radical polymerization reaction of 1-alkene and acrylate based monomer under presence of a metal oxide or Lewis acid. The 1-alkene-acrylated based copolymer according to the present invention is a random copolymer of 1-alkene and a polar monomer, and an amount of a polar group contained in the copolymer is very high so that the alkene is not crystalline. Accordingly, when the copolymer is processed into a polymer film, a transparency of the polymer is not affected. Due to such a feature, the copolymer can be used for optical products. The ethylene-acrylate copoylmer in the specific range provided in the present invention can be used for a preparation of a film having high mechanic properties and oxygen blocking. An amount of ethylene of the ethylene-acrylate based copolymer according to the present invention is an important factor to improve mechanical properties, such as flexibility and stretching, and an amount of acrylate is an important factor to improve oxygen blocking and transparency of the film. Accordingly, by controlling amounts of two monomers properly, a resin and film having appropriate transparency, mechanic properties, and gas blocking effect concurrently may be produced.
    • 本发明提供通过包括在金属氧化物或路易斯酸存在下的1-烯烃和丙烯酸酯基单体的自由基聚合反应步骤的方法制备的1-烯烃 - 丙烯酸酯共聚物。 根据本发明的1-烯烃 - 丙烯酸酯基共聚物是1-烯烃和极性单体的无规共聚物,共聚物中所含的极性基团的量非常高,使得烯烃不是结晶的。 因此,当共聚物加工成聚合物膜时,聚合物的透明度不受影响。 由于这样的特征,共聚物可以用于光学产品。 在本发明提供的特定范围内的乙烯 - 丙烯酸酯共酰基树脂可以用于制备具有高机械性能和氧气阻挡性的膜。 本发明的乙烯 - 丙烯酸酯类共聚物的乙烯量是提高机械性能如柔软性和拉伸性的重要因素,丙烯酸酯的量是提高膜的氧阻和透明度的重要因素。 因此,通过适当地控制两种单体的量,可以产生同时具有适当透明性,机械性能和气体阻断效果的树脂和膜。
    • 9. 发明申请
    • METHOD FOR PREPARATION OF 1-ALKENE-ACRYLATE BASED COPOLYMER
    • 制备1-丙烯酸丙烯酸酯共聚物的方法
    • WO2007105898A1
    • 2007-09-20
    • PCT/KR2007/001212
    • 2007-03-13
    • LG CHEM, LTD.JUNG, Yoo-youngJEON, Byoung-hoSHIN, Bae-kunLEE, Ki-sooHAN, Yong-gyu
    • JUNG, Yoo-youngJEON, Byoung-hoSHIN, Bae-kunLEE, Ki-sooHAN, Yong-gyu
    • C08F220/10C08F210/00C08F4/06
    • C08F222/10C08F210/02C08F220/12C08F220/14C08F220/18C08F210/14
    • The present invention provides a method for preparation of an 1-alkene-acrylate based copolymer comprising a step of a radical polymerization reaction of 1-alkene and acrylate based monomer under presence of a metal oxide or Lewis acid, and a method for preparation of an alkene-acrylate based copolymer comprising reacting alkene with an acrylate based monomer under presence of a metal oxide. In the method of preparation according to the present invention, the process is simple and properties of the copolymer can be easily controlled by preparing the copolymer in a mild condition of 100°C or less and 200bar or less. In addition, the amount of the polar group of the copolymer prepared by the method is so high that the copolymer can be used for transparent optical products. Since the alkene-acrylate based copolymer prepared by the method is a random copolymer of ethylene and a polar monomer and the amount of the polar group of the polar monomer so high that the crystallinity of the ethylene monomer does not remain in the copolymer, the ethylene- acrylate based copolymer is not affected from a tra nsparency of the polymer and thus may be used for optical products.
    • 本发明提供一种制备1-烯烃 - 丙烯酸酯基共聚物的方法,其包括在金属氧化物或路易斯酸存在下,1-烯烃和丙烯酸酯类单体的自由基聚合反应的步骤,以及制备 烯烃 - 丙烯酸酯基共聚物,其包含在金属氧化物的存在下使烯烃与丙烯酸酯基单体反应。 在根据本发明的制备方法中,该方法简单,并且通过在100℃以下且200巴以下的温和条件下制备共聚物可以容易地控制共聚物的性质。 此外,通过该方法制备的共聚物的极性基团的量非常高,使得该共聚物可用于透明光学产品。 由于通过该方法制备的基于烯烃 - 丙烯酸酯的共聚物是乙烯和极性单体的无规共聚物和极性单体的极性基团的量如此高以至于乙烯单体的结晶度不会残留在共聚物中,所以乙烯 丙烯酸酯基共聚物不受聚合物的透明度的影响,因此可用于光学产品。